Rechargeable neutral aqueous zinc-air batteries(ZABs)are a promising type of energy storage device with longer operating life and less corrosiveness compared with conventional alkaline ZABs.However,the neutral ZABs no...Rechargeable neutral aqueous zinc-air batteries(ZABs)are a promising type of energy storage device with longer operating life and less corrosiveness compared with conventional alkaline ZABs.However,the neutral ZABs normally possess poor oxygen evolution reactions(OERs)and oxygen reduction reactions performance,resulting in a large charge–discharge voltage gap and low round-trip efficiency.Herein,we demonstrate a sunlight-assisted strategy for achieving an ultralow voltage gap of 0.05 V in neutral ZABs by using the FeOOH-decorated BiVO4(Fe-BiVO4)as an oxygen catalyst.Under sunlight,the electrons move from the valence band(VB)of Fe-BiVO_(4) to the conduction band producing holes in VB to promote the OER process and hence reduce the overpotential.Meanwhile,the photopotential generated by the Fe-BiVO_(4) compensates a part of the charging potential of neutral ZABs.Accordingly,the energy loss of the battery could be compensated via solar energy,leading to a record-low gap of 0.05 V between the charge and discharge voltage with a high round-trip efficiency of 94%.This work offers a simple but efficient pathway for solar-energy utilization in storage devices,further guiding the design of high energy efficiency of neutral aqueous ZABs.展开更多
Symmetric Na-ion cells using the NASICON-structured electrodes could simplify the manufacturing process,reduce the cost,facilitate the recycling post-process,and thus attractive in the field of large-scale stationary ...Symmetric Na-ion cells using the NASICON-structured electrodes could simplify the manufacturing process,reduce the cost,facilitate the recycling post-process,and thus attractive in the field of large-scale stationary energy storage.However,the long-term cycling performance of such batteries is usually poor.This investigation reveals the unavoidable side reactions between the NASICON-type Na_(3)V_(2)(PO_(4))_(3)(NVP)anode and the commercial liquid electrolyte,leading to serious capacity fading in the symmetric NVP//NVP cells.To resolve this issue,an all-solid-state composite electrolyte is used to replace the liquid electrolyte so that to overcome the side reaction and achieve high anode/electrolyte interfacial stability.The ferroelectric engineering could further improve the interfacial ion conduction,effectively reducing the electrode/electrolyte interfacial resistances.The NVP//NVP cell using the ferroelectric-engineered composite electrolyte can achieve a capacity retention of 86.4%after 650 cycles.Furthermore,the electrolyte can also be used to match the Prussianblue cathode NaxFeyFe(CN)_(6−z)·nH_(2)O(NFFCN).Outstanding long-term cycling stability has been obtained in the all-solid-state NVP//NFFCN cell over 9000 cycles at a current density of 500 mA g^(-1),with a fading rate as low as 0.005%per cycle.展开更多
Aerosol deposition(AD)method is a kind of additive manufacturing technology for fabricating dense films such as metals and ceramics at room temperature.It resolves the challenge of integrating ceramic films onto tempe...Aerosol deposition(AD)method is a kind of additive manufacturing technology for fabricating dense films such as metals and ceramics at room temperature.It resolves the challenge of integrating ceramic films onto temperaturesensitive substrates,including metals,glasses,and polymers.It should be emphasized that the AD is a spray coating technology that uses powder without thermal assistance to generate films with high density.Compared to the traditional sputter-based approach,the AD shows several advantages in efficiency,convenience,better interfacial bonding and so on.Therefore,it opens some possibilities to the field of batteries,especially all-solidstate batteries(ASSBs)and draws much attention not only for research but also for large scale applications.The purpose of this work is to provide a critical review on the science and technology of AD as well as its applications in the field of batteries.The process,mechanism and effective parameters of AD,and recent developments in AD applications in the field of batteries will be systematically reviewed so that a trend for AD will be finally provided.展开更多
The Pamir Plateau can be divided into three secondary tectonic units from north to south:the North,the Middle and the South Pamir Blocks.The North Pamir Block belonged to the southern margin of Tarim-Karakum,thermochr...The Pamir Plateau can be divided into three secondary tectonic units from north to south:the North,the Middle and the South Pamir Blocks.The North Pamir Block belonged to the southern margin of Tarim-Karakum,thermochronological study of the Pamir structural intersection indicates that accretion of the Middle Pamir Block to the Eurasian Continental Margin and its subduction and collision with the North Pamir Block occurred in the Middle–Late Jurassic.Due to the Neo-Tethys closure in the Early Cretaceous,the South Pamir Block began to collide with the accretion(the Middle Pamir Block)of the Eurasian Continental Margin.Affected by the collision and continuous convergence between the Indian Plate and the Eurasian Plate since the Cenozoic,Pamir is in a multi-stage differential uplift process.During 56.1–48.5 Ma,North Pamir took the lead in uplifting,that is,the first rapid uplift in the Pamir region began there.The continuous compression and contraction of the Indian and Eurasian plates during 22.0–15.1 Ma forced the Pamir tectonic syntaxis to begin its overall uplift,i.e.Pamir began to enter the second rapid uplift stage in the Early Oligocene,which lasted until the Middle Miocene.During 14.6–8.5Ma,South Pamir was in a rapid uplift stage,while North Pamir was in a relatively stable state,showing asymmetry of tectonic deformation in the Pamir region in space.Since 6.5 Ma,Pamir began to rapidly uplift again.展开更多
Different from other alloys,the observation in this work on the dendritic mushy zone shows that the freckles are formed in two different regions before and after peritectic reaction in directional solidification of Sn...Different from other alloys,the observation in this work on the dendritic mushy zone shows that the freckles are formed in two different regions before and after peritectic reaction in directional solidification of Sn−Ni peritectic alloys.In addition,the experimental results demonstrate that the dendritic morphology is influenced by the temperature gradient zone melting and Gibbs−Thomson effects.A new Rayleigh number(Ra_(P))is proposed in consideration of both effects and peritectic reaction.The prediction of Ra_(P) confirms the freckle formation in two regions during peritectic solidification.Besides,heavier thermosolutal convection in samples with larger diameter is also demonstrated.展开更多
高光谱遥感图像虽然具有较高的光谱分辨率,但只能提供二维光谱信息,而激光雷达(Light Detection and Ranging, LiDAR)可以提供可靠的三维数据和森林的冠层特征,二者结合能够优势互补,协同提高地物分类能力。基于此,本文提出了一种利用...高光谱遥感图像虽然具有较高的光谱分辨率,但只能提供二维光谱信息,而激光雷达(Light Detection and Ranging, LiDAR)可以提供可靠的三维数据和森林的冠层特征,二者结合能够优势互补,协同提高地物分类能力。基于此,本文提出了一种利用高光谱和机载激光雷达数据进行树种识别的方法,探讨了二者协同对树种精细分类的影响,最后通过公开数据的实验来验证方法的有效性。结果表明,高光谱和激光雷达数据结合后,树种分类精度得到了显著提高。通过本文提出的方法,即使使用少量特征也能大大提高分类精度。整体分类准确率最高达到93.21%,比单个高光谱数据的分类准确率提高9.31%。展开更多
基金This work was supported by the National Natural Science Foundation of China(Grant No.22278349)Natural Science Foundation of Hebei Province(Grant No.B2023203026)+2 种基金Youth Foundation of Hebei Educational Committee(Grant No.QN2020137)Cultivation Project for Basic Research and Innovation of Yanshan University(Grant No.2021LGZD015)Subsidy for Hebei Key Laboratory of Applied Chemistry after Operation Performance(Grant No.22567616H).
文摘Rechargeable neutral aqueous zinc-air batteries(ZABs)are a promising type of energy storage device with longer operating life and less corrosiveness compared with conventional alkaline ZABs.However,the neutral ZABs normally possess poor oxygen evolution reactions(OERs)and oxygen reduction reactions performance,resulting in a large charge–discharge voltage gap and low round-trip efficiency.Herein,we demonstrate a sunlight-assisted strategy for achieving an ultralow voltage gap of 0.05 V in neutral ZABs by using the FeOOH-decorated BiVO4(Fe-BiVO4)as an oxygen catalyst.Under sunlight,the electrons move from the valence band(VB)of Fe-BiVO_(4) to the conduction band producing holes in VB to promote the OER process and hence reduce the overpotential.Meanwhile,the photopotential generated by the Fe-BiVO_(4) compensates a part of the charging potential of neutral ZABs.Accordingly,the energy loss of the battery could be compensated via solar energy,leading to a record-low gap of 0.05 V between the charge and discharge voltage with a high round-trip efficiency of 94%.This work offers a simple but efficient pathway for solar-energy utilization in storage devices,further guiding the design of high energy efficiency of neutral aqueous ZABs.
基金supported by the National University of Singapore(Chongqing)Research Institute,National University of Singapore,Chongqing Postdoctoral Research Special Funding(2021XM2002)Overseas Postdoctoral Research Start-up Funding,Natural Science Foundation of Chongqing(cstc2021jcyjmsxmX0086)+1 种基金Chongqing Innovative Project for oversea-experience researchers(cx2023037)the Open Project Program of Fujian Key Laboratory of Special Energy Manufacturing.
文摘Symmetric Na-ion cells using the NASICON-structured electrodes could simplify the manufacturing process,reduce the cost,facilitate the recycling post-process,and thus attractive in the field of large-scale stationary energy storage.However,the long-term cycling performance of such batteries is usually poor.This investigation reveals the unavoidable side reactions between the NASICON-type Na_(3)V_(2)(PO_(4))_(3)(NVP)anode and the commercial liquid electrolyte,leading to serious capacity fading in the symmetric NVP//NVP cells.To resolve this issue,an all-solid-state composite electrolyte is used to replace the liquid electrolyte so that to overcome the side reaction and achieve high anode/electrolyte interfacial stability.The ferroelectric engineering could further improve the interfacial ion conduction,effectively reducing the electrode/electrolyte interfacial resistances.The NVP//NVP cell using the ferroelectric-engineered composite electrolyte can achieve a capacity retention of 86.4%after 650 cycles.Furthermore,the electrolyte can also be used to match the Prussianblue cathode NaxFeyFe(CN)_(6−z)·nH_(2)O(NFFCN).Outstanding long-term cycling stability has been obtained in the all-solid-state NVP//NFFCN cell over 9000 cycles at a current density of 500 mA g^(-1),with a fading rate as low as 0.005%per cycle.
基金supported by National University of Singapore (Chongqing) Research InstituteNational University of Singapore+2 种基金Chongqing Postdoctoral Research Special FundingOverseas Postdoctoral Research Start-up FundingNatural Science Foundation of Chongqing, China (cstc2021jcyj-msxmX0086)
文摘Aerosol deposition(AD)method is a kind of additive manufacturing technology for fabricating dense films such as metals and ceramics at room temperature.It resolves the challenge of integrating ceramic films onto temperaturesensitive substrates,including metals,glasses,and polymers.It should be emphasized that the AD is a spray coating technology that uses powder without thermal assistance to generate films with high density.Compared to the traditional sputter-based approach,the AD shows several advantages in efficiency,convenience,better interfacial bonding and so on.Therefore,it opens some possibilities to the field of batteries,especially all-solidstate batteries(ASSBs)and draws much attention not only for research but also for large scale applications.The purpose of this work is to provide a critical review on the science and technology of AD as well as its applications in the field of batteries.The process,mechanism and effective parameters of AD,and recent developments in AD applications in the field of batteries will be systematically reviewed so that a trend for AD will be finally provided.
基金This work was supported by the Projects of the China Geological Survey(grant nos 12120114018601,121201011000150010).
文摘The Pamir Plateau can be divided into three secondary tectonic units from north to south:the North,the Middle and the South Pamir Blocks.The North Pamir Block belonged to the southern margin of Tarim-Karakum,thermochronological study of the Pamir structural intersection indicates that accretion of the Middle Pamir Block to the Eurasian Continental Margin and its subduction and collision with the North Pamir Block occurred in the Middle–Late Jurassic.Due to the Neo-Tethys closure in the Early Cretaceous,the South Pamir Block began to collide with the accretion(the Middle Pamir Block)of the Eurasian Continental Margin.Affected by the collision and continuous convergence between the Indian Plate and the Eurasian Plate since the Cenozoic,Pamir is in a multi-stage differential uplift process.During 56.1–48.5 Ma,North Pamir took the lead in uplifting,that is,the first rapid uplift in the Pamir region began there.The continuous compression and contraction of the Indian and Eurasian plates during 22.0–15.1 Ma forced the Pamir tectonic syntaxis to begin its overall uplift,i.e.Pamir began to enter the second rapid uplift stage in the Early Oligocene,which lasted until the Middle Miocene.During 14.6–8.5Ma,South Pamir was in a rapid uplift stage,while North Pamir was in a relatively stable state,showing asymmetry of tectonic deformation in the Pamir region in space.Since 6.5 Ma,Pamir began to rapidly uplift again.
基金the National Natural Science Foundation of China(No.51871118)the Basic Scientific Research Business Expenses of the Central University and Open Project of Key Laboratory for Magnetism and Magnetic Materials of the Ministry of Education,Lanzhou University,China(No.LZUMMM2021005)+1 种基金the Science and Technology Project of Lanzhou City,China(No.2019-1-30)the State Key Laboratory of Special Rare Metal Materials,China(No.SKL2020K003).
文摘Different from other alloys,the observation in this work on the dendritic mushy zone shows that the freckles are formed in two different regions before and after peritectic reaction in directional solidification of Sn−Ni peritectic alloys.In addition,the experimental results demonstrate that the dendritic morphology is influenced by the temperature gradient zone melting and Gibbs−Thomson effects.A new Rayleigh number(Ra_(P))is proposed in consideration of both effects and peritectic reaction.The prediction of Ra_(P) confirms the freckle formation in two regions during peritectic solidification.Besides,heavier thermosolutal convection in samples with larger diameter is also demonstrated.
文摘高光谱遥感图像虽然具有较高的光谱分辨率,但只能提供二维光谱信息,而激光雷达(Light Detection and Ranging, LiDAR)可以提供可靠的三维数据和森林的冠层特征,二者结合能够优势互补,协同提高地物分类能力。基于此,本文提出了一种利用高光谱和机载激光雷达数据进行树种识别的方法,探讨了二者协同对树种精细分类的影响,最后通过公开数据的实验来验证方法的有效性。结果表明,高光谱和激光雷达数据结合后,树种分类精度得到了显著提高。通过本文提出的方法,即使使用少量特征也能大大提高分类精度。整体分类准确率最高达到93.21%,比单个高光谱数据的分类准确率提高9.31%。
