In Wuhan urban agglomeration （WUA）, the population growth and concentration, the industrial development and urban sprawl have been affecting the environment ftmdamentally. Comparing with Yangtze delta metropolitan r...In Wuhan urban agglomeration （WUA）, the population growth and concentration, the industrial development and urban sprawl have been affecting the environment ftmdamentally. Comparing with Yangtze delta metropolitan region, the level of urbanization and industrialization of WUA has lagged behind for about 10 years; but the problems in environmental protection and rehabilitation are commonly serious. In the future, WUA should avoid unnecessary mistakes and seek a win-win strategy for economy and environment in its large-scale development stage. Based on the analysis of the changing of main environmental pollutants and the coupled curves in past decades, the paper discussed the important links among the urban environmental pollutions, industry growth and urban sprawl in WUA. It is concluded that the integration of economic and environmental policies in urban development is more required and significant at the large urban agglomeration region. Four proactive and long-term strategies need to be adopted to provide prior guidance and better protection for the development of WUA.展开更多
The structures, energetics, and isomerization of a possible interstellar [Si, O, S] system were explored at the CCSD（T）/aug-cc-pVQZ//CCSD（T）/aug-cc-pVTZ level. On the schemaitc potential energy surface（PES）, we ...The structures, energetics, and isomerization of a possible interstellar [Si, O, S] system were explored at the CCSD（T）/aug-cc-pVQZ//CCSD（T）/aug-cc-pVTZ level. On the schemaitc potential energy surface（PES）, we found that silicon oxysulfide（OSiS） produced in laboratory is the global minimum. An analysis of the Wiberg bond index（WBI）, bond order and the bond length, shows that silicon oxysulfide contains SiO and SiS double bonds in ac- cordance with the results of SchnOckel. Besides silicon oxysulfide, another interesting cyclic minimum（c-SiOS） was found to have a very high kinetic stability stabilized by the least barrier of 120.9 kJ/mol. In light of the fact that no cyclic sulfide-containing species has been detected in space, c-SiOS could be a very promising candidate. The presented results might provide useful information on detected interstellar molecules O=Si=S and c-SiOS.展开更多
基金The National Natural Science Foundation of China (No. 40225004 40335049)
文摘In Wuhan urban agglomeration （WUA）, the population growth and concentration, the industrial development and urban sprawl have been affecting the environment ftmdamentally. Comparing with Yangtze delta metropolitan region, the level of urbanization and industrialization of WUA has lagged behind for about 10 years; but the problems in environmental protection and rehabilitation are commonly serious. In the future, WUA should avoid unnecessary mistakes and seek a win-win strategy for economy and environment in its large-scale development stage. Based on the analysis of the changing of main environmental pollutants and the coupled curves in past decades, the paper discussed the important links among the urban environmental pollutions, industry growth and urban sprawl in WUA. It is concluded that the integration of economic and environmental policies in urban development is more required and significant at the large urban agglomeration region. Four proactive and long-term strategies need to be adopted to provide prior guidance and better protection for the development of WUA.
基金Supported by the Natural Science Foundation of Ningxia Hui Autonemous Region, China（No.NZ 1105）.
文摘The structures, energetics, and isomerization of a possible interstellar [Si, O, S] system were explored at the CCSD（T）/aug-cc-pVQZ//CCSD（T）/aug-cc-pVTZ level. On the schemaitc potential energy surface（PES）, we found that silicon oxysulfide（OSiS） produced in laboratory is the global minimum. An analysis of the Wiberg bond index（WBI）, bond order and the bond length, shows that silicon oxysulfide contains SiO and SiS double bonds in ac- cordance with the results of SchnOckel. Besides silicon oxysulfide, another interesting cyclic minimum（c-SiOS） was found to have a very high kinetic stability stabilized by the least barrier of 120.9 kJ/mol. In light of the fact that no cyclic sulfide-containing species has been detected in space, c-SiOS could be a very promising candidate. The presented results might provide useful information on detected interstellar molecules O=Si=S and c-SiOS.
