Flexible biosensors with high accuracy and reliable operation in detecting pH and uric acid levels in body fluids are fabricated using well-engineered metaldoped porous carbon as electrode material.The gold nanopartic...Flexible biosensors with high accuracy and reliable operation in detecting pH and uric acid levels in body fluids are fabricated using well-engineered metaldoped porous carbon as electrode material.The gold nanoparticles@N-doped carbon in situ are prepared using wool keratin as both a novel carbon precursor and a stabilizer.The conducting electrode material is fabricated at 500℃ under customized parameters,which mimics A-B type(two different repeating units) polymeric material and displays excellent deprotonation performance(pH sensitivity).The obtained pH sensor exhibits high pH sensitivity of 57 mV/pH unit and insignificant relative standard deviation of 0.088%.Conversely,the composite carbon material with sp^2 structure prepared at 700℃ is doped with nitrogen and gold nanoparticles,which exhibits good conductivity and electrocatalytic activity for uric acid oxidation.The uric acid sensor has linear response over a range of 1-150 μM and a limit of detection 0.1 μM.These results will provide new avenues where biological material will be the best start,which can be useful to target contradictory applications through molecular engineering at mesoscale.展开更多
Letter handwriting,especially stroke correction,is of great importance for recording languages and expressing and exchanging ideas for individual behavior and the public.In this study,a biodegradable and conductive ca...Letter handwriting,especially stroke correction,is of great importance for recording languages and expressing and exchanging ideas for individual behavior and the public.In this study,a biodegradable and conductive carboxymethyl chitosan-silk fibroin(CSF)film is prepared to design wearable triboelectric nanogenerator(denoted as CSF-TENG),which outputs of V_(oc)≈165 V,I_(sc)≈1.4μA,and Q_(sc)≈72 mW cm^(−2).Further,in vitro biodegradation of CSF film is performed through trypsin and lysozyme.The results show that trypsin and lysozyme have stable and favorable biodegradation properties,removing 63.1%of CSF film after degrading for 11 days.Further,the CSF-TENG-based human-machine interface(HMI)is designed to promptly track writing steps and access the accuracy of letters,resulting in a straightforward communication media of human and machine.The CSF-TENG-based HMI can automatically recognize and correct three representative letters(F,H,and K),which is benefited by HMI system for data processing and analysis.The CSF-TENG-based HMI can make decisions for the next stroke,highlighting the stroke in advance by replacing it with red,which can be a candidate for calligraphy practice and correction.Finally,various demonstrations are done in real-time to achieve virtual and real-world controls including writing,vehicle movements,and healthcare.展开更多
Negative permittivity of the material may lead to the enhanced radiation of an antenna embedded in a finite plasma,which suggests a potential way to solve blackout problem in space technology.However,the enhanced radi...Negative permittivity of the material may lead to the enhanced radiation of an antenna embedded in a finite plasma,which suggests a potential way to solve blackout problem in space technology.However,the enhanced radiation phenomenon is still lack of strict theoretical investigations of surface plasmon polaritons(SPPs) in plasma in GHz frequency.In this paper,we demonstrate the SPPs excited at a plasma/vacuum interface in GHz frequency by the consistency of the simulated and theoretical results.With SPPs,plasma layer thicker than skin depth can be penetrated with w <w,pwhich is a complement of wave propagation theory in plasma.We also discuss the influences of thickness d,collision frequency Γ,and different plasma frequencies on SPPs.For plasma frequencies with large difference,common numerical methods have difficulties in result comparison under the same mesh size because of the computer capacity and memory.The analytical multilayer method used in the paper does not need to generate mesh,so the studies of plasma frequencies with large difference can be carried out.The simulation shows that the SPPs can be excited for an arbitrary plasma frequency.We believe the study will be beneficial for the problem of wave propagation in plasma science and technology.展开更多
Triboelectric nanogenerator(TENG)converts mechanical energy into valuable electrical energy,offering a solution for future energy needs.As an indispensable part of TENG,textile TENG(T-TENG)has incredible advantages in...Triboelectric nanogenerator(TENG)converts mechanical energy into valuable electrical energy,offering a solution for future energy needs.As an indispensable part of TENG,textile TENG(T-TENG)has incredible advantages in harvesting biomechanical energy and physiological signal monitoring.However,the application of T-TENG is restricted,partly because the fabric structure parameter and structure on T-TENG performance have not been fully exploited.This study comprehensively investigates the effect of weaving structure on fabric TENGs(F-TENGs)for direct-weaving yarn TENGs and post-coating fabric TENGs.For direct-weaving F-TENGs,a single-yarn TENG(Y-TENG)with a core-sheath structure is fabricated using conductive yarn as the core layer yarn and polytetrafluoroethylene(PTFE)filaments as the sheath yarn.Twelve fabrics with five different sets of parameters were designed and investigated.For post-coating F-TENGs,fabrics with weaving structures of plain,twill,satin,and reinforced twill were fabricated and coated with conductive silver paint.Overall,the twill F-TENGs have the best electrical outputs,followed by the satin F-TENGs and plain weave F-TENGs.Besides,the increase of the Y-TENG gap spacing was demonstrated to improve the electrical output performance.Moreover,T-TENGs are demonstrated for human-computer interaction and self-powered real-time monitoring.This systematic work provides guidance for the future T-TENG’s design.展开更多
Yarn sensors have shown promising application prospects in wearable electronics owing to their shape adaptability, good flexibility, and weavability. However, it is still a critical challenge to develop simultaneously...Yarn sensors have shown promising application prospects in wearable electronics owing to their shape adaptability, good flexibility, and weavability. However, it is still a critical challenge to develop simultaneously structure stable, fast response, body conformal, mechanical robust yarn sensor using full microfibers in an industrial-scalable manner. Herein, a full-fiber auxetic-interlaced yarn sensor(AIYS) with negative Poisson’s ratio is designed and fabricated using a continuous, mass-producible, structure-programmable, and low-cost spinning technology. Based on the unique microfiber interlaced architecture, AIYS simultaneously achieves a Poisson’s ratio of-1.5, a robust mechanical property(0.6 c N/dtex), and a fast train-resistance responsiveness(0.025 s), which enhances conformality with the human body and quickly transduce human joint bending and/or stretching into electrical signals. Moreover, AIYS shows good flexibility, washability, weavability, and high repeatability. Furtherly, with the AIYS array, an ultrafast full-letter sign-language translation glove is developed using artificial neural network. The sign-language translation glove achieves an accuracy of 99.8% for all letters of the English alphabet within a short time of 0.25 s. Furthermore, owing to excellent full letter-recognition ability, real-time translation of daily dialogues and complex sentences is also demonstrated. The smart glove exhibits a remarkable potential in eliminating the communication barriers between signers and non-signers.展开更多
It is of great importance to explore a creative route to improve the degradation e ciency of organic pollutants in wastewater.Herein,we construct a unique hybrid system by combining self-powered triboelectric nanogene...It is of great importance to explore a creative route to improve the degradation e ciency of organic pollutants in wastewater.Herein,we construct a unique hybrid system by combining self-powered triboelectric nanogenerator(TENG)with carbon dots-TiO_(2)sheets doped three-dimensional graphene oxide photocatalyst(3 DGA@CDs-TNs),which can significantly enhance the degradation e ciency of brilliant green(BG)and direct blue 5 B(DB)owing to the powerful interaction of TENG and 3 DGA@CDs-TNs photocatalyst.The power output of TENG can be applied for wastewater purification directly,which exhibits a selfpowered electrocatalytic technology.Furthermore,the results also verify that TENG can replace conventional electric catalyst to remove pollutants e ectively from wastewater without any consumption.Subsequently,the unstable fragments and the plausible removal pathways of the two pollutants are proposed.Our work sheds light on the development of e cient and sustainable TENG/photocatalyst system,opening up new opportunities and possibilities for comprehensive utilization of random energy.展开更多
Several p H-dependent processes and reactions take place in the human body;hence,the p H of body fluids is the best indicator of disturbed health conditions.However,accurate and real-time diagnosis of the p H of body ...Several p H-dependent processes and reactions take place in the human body;hence,the p H of body fluids is the best indicator of disturbed health conditions.However,accurate and real-time diagnosis of the p H of body fluids is complicated because of limited commercially available p H sensors.Hence,we aimed to prepare a flexible,transparent,disposable,userfriendly,and economic strip-based solid-state p H sensor using palladium nanoparticles(Pd NPs)/N-doped carbon(NC)composite material.The Pd NPs/NC composite material was synthesized using wool keratin(WK)as a precursor.The insitu prepared Pd NPs played a key role in the controlled switching of protein structure to the N-doped carbon skeleton withπ–πarrangement at the mesoscale level,which mimics the A–B type polymeric structure,and hence,is highly susceptible to H+ions.The optimized carbonization condition in the presence of Pd NPs showed that the material obtained using a modified Ag/Ag Cl reference electrode had the highest p H sensitivity with excellent stability and durability.The optimized p H sensor showed high specificity and selectivity with a sensitivity of 55 m V/p H unit and a relative standard deviation of 0.79%.This study is the first to synthesize Pd NPs using WK as a stabilizing and reducing agent.The applicability of the sensor was investigated for biological samples,namely,saliva and gastric juices.The proposed protocol and material have implications in solid-state chemistry,where biological material will be the best choice for the synthesis of materials with anticipated performance.展开更多
A wearable sensing system that can reconstruct dynamic 3D human body models for virtual cloth fitting is highly important in the era of information and metaverse.However,few research has been conducted regarding confo...A wearable sensing system that can reconstruct dynamic 3D human body models for virtual cloth fitting is highly important in the era of information and metaverse.However,few research has been conducted regarding conformal sen-sors for accurately measuring the human body circumferences for dynamic 3D human body reshaping.Here,we develop a stretchable spring-sheathed yarn sensor(SSYS)as a smart ruler,for precisely measuring the circumference of human bodies and long-term tracking the movement for the dynamic 3D body reconstruction.The SSYS has a robust property,high resilience,high stability(>18000),and ultrafast response(12 ms)to external deformation.It is also washable,wearable,tailorable,and durable for long-time wearing.Moreover,geometric,and mechanical behaviors of the SSYS are systematically investigated both theoretically and experimentally.In addition,a transfer learning algorithm that bridges the discrepancy of real and virtual sensing performance is devel-oped,enabling a small body circumference measurement error of 1.79%,notice-ably lower than that of traditional learning algorithm.Furtherly,3D human bodies that are numerically consistent with the actual bodies are reconstructed.The 3D dynamic human body reconstruction based on the wearing sensing sys-tem and transfer learning algorithm enables excellent virtual fitting and shirt customization in a smart and highly efficient manner.This wearable sensing technology shows great potential in human-computer interaction,intelligent fitting,specialized protection,sports activities,and human physiological health tracking.展开更多
The Fukushima nuclear accident in Japan on March 11,2011,produced large amounts of Cs-polluted soil which must be controlled to prevent the spread of hazardous Cs into the environment.In this paper,the effects of heat...The Fukushima nuclear accident in Japan on March 11,2011,produced large amounts of Cs-polluted soil which must be controlled to prevent the spread of hazardous Cs into the environment.In this paper,the effects of heat treatment on the structure and properties of Cs-containing glass-ceramics,as a simulated nuclear waste form,were systematically investigated.Cesium atoms are chemically bonded in the pollucite structure,and the amorphous phase further encapsulates the pollucite crystals in the glassceramics,thus providing an extra protective layer for the immobilized Cs.XRD analysis,Raman and FT-IR studies on the glass-ceramics synergistically indicated that the optimum crystallization temperature for pollucite is around 1000℃.The pollucite is predominantly the main crystalline phase with a narrow crystal size distribution between 0.5 and 2 mm.Standard leaching test results show that the leaching rate of Cs was very low(3.0×10^(-3) g/(m^(2)·d)).The study offers a practical method for immobilizing Cs in pollucite-base glass-ceramics.Moreover,the experimentally obtained data may provide some important references for converting Cs-polluted soil into pollucite-base glass-ceramics waste form.展开更多
Development of biomaterial based flexible electronics has got intensive attention owing to the potential applications in the wearable and epidermal devices.Silk fibroin,as a natural textile material with excellent per...Development of biomaterial based flexible electronics has got intensive attention owing to the potential applications in the wearable and epidermal devices.Silk fibroin,as a natural textile material with excellent performance,has been widely concerned by industry and academy.However,the property of electrical insulation limits his development in the field of flexible electronics.In this paper,a regenerated silk fibroin/carbon nanotube(RSF/CNT)conductive film has been successfully fabricated and applied in flexible capacitive-type pressure sensor and wearable triboelectric nanogenerator by a facile method.The electrical conductivity and mechanical property of RSF/CNT film was optimized by investigating with different composite ratio from 10 to 90%(W_(RSF)/W_(CNT)).The RSF/CNT film has a good photothermal response and electric heating performance.We furtherly demonstrated that the RSF/CNT based sensor can be used as epidermal self-powered sensor for multifunction human motion monitoring and Morse code compilation.The observed research results have shown that the RSF/CNT film has a wide range of potential application prospects in the wearable electronics field.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.51502253,U1405226,21503175,51773171,and 21705135)Natural Science Foundation of Guangdong Province(Grant No.2016A030310369)+5 种基金Natural Science Foundation of Fujian Province(Grant No.2017J01104)the Fundamental Research Funds for the Central Universities of China(Grant Nos.20720160127 and 20720180013)Doctoral Fund of the Ministry of Education(Grant No.20130121110018)NUS Ac RF Tier 1(Grant No.R-144-000-367-112)the “111” Project(Grant No.B16029)the 1000 Talents Program funding from the Xiamen University。
文摘Flexible biosensors with high accuracy and reliable operation in detecting pH and uric acid levels in body fluids are fabricated using well-engineered metaldoped porous carbon as electrode material.The gold nanoparticles@N-doped carbon in situ are prepared using wool keratin as both a novel carbon precursor and a stabilizer.The conducting electrode material is fabricated at 500℃ under customized parameters,which mimics A-B type(two different repeating units) polymeric material and displays excellent deprotonation performance(pH sensitivity).The obtained pH sensor exhibits high pH sensitivity of 57 mV/pH unit and insignificant relative standard deviation of 0.088%.Conversely,the composite carbon material with sp^2 structure prepared at 700℃ is doped with nitrogen and gold nanoparticles,which exhibits good conductivity and electrocatalytic activity for uric acid oxidation.The uric acid sensor has linear response over a range of 1-150 μM and a limit of detection 0.1 μM.These results will provide new avenues where biological material will be the best start,which can be useful to target contradictory applications through molecular engineering at mesoscale.
基金This study was financially supported by National Natural Science Foundation of China(NO.31470509)China Postdoctoral Science Foundation(No.2019T120390)+1 种基金China Scholarship Council(NO.202006790091)the Opening Project of China National Textile and Apparel Council Key Laboratory of Natural Dyes,Soochow University(No.SDHY2122)。
文摘Letter handwriting,especially stroke correction,is of great importance for recording languages and expressing and exchanging ideas for individual behavior and the public.In this study,a biodegradable and conductive carboxymethyl chitosan-silk fibroin(CSF)film is prepared to design wearable triboelectric nanogenerator(denoted as CSF-TENG),which outputs of V_(oc)≈165 V,I_(sc)≈1.4μA,and Q_(sc)≈72 mW cm^(−2).Further,in vitro biodegradation of CSF film is performed through trypsin and lysozyme.The results show that trypsin and lysozyme have stable and favorable biodegradation properties,removing 63.1%of CSF film after degrading for 11 days.Further,the CSF-TENG-based human-machine interface(HMI)is designed to promptly track writing steps and access the accuracy of letters,resulting in a straightforward communication media of human and machine.The CSF-TENG-based HMI can automatically recognize and correct three representative letters(F,H,and K),which is benefited by HMI system for data processing and analysis.The CSF-TENG-based HMI can make decisions for the next stroke,highlighting the stroke in advance by replacing it with red,which can be a candidate for calligraphy practice and correction.Finally,various demonstrations are done in real-time to achieve virtual and real-world controls including writing,vehicle movements,and healthcare.
基金the financial support of National Natural Science Foundation of China(Nos.11405020,61520106013,51661145025,61727816)
文摘Negative permittivity of the material may lead to the enhanced radiation of an antenna embedded in a finite plasma,which suggests a potential way to solve blackout problem in space technology.However,the enhanced radiation phenomenon is still lack of strict theoretical investigations of surface plasmon polaritons(SPPs) in plasma in GHz frequency.In this paper,we demonstrate the SPPs excited at a plasma/vacuum interface in GHz frequency by the consistency of the simulated and theoretical results.With SPPs,plasma layer thicker than skin depth can be penetrated with w <w,pwhich is a complement of wave propagation theory in plasma.We also discuss the influences of thickness d,collision frequency Γ,and different plasma frequencies on SPPs.For plasma frequencies with large difference,common numerical methods have difficulties in result comparison under the same mesh size because of the computer capacity and memory.The analytical multilayer method used in the paper does not need to generate mesh,so the studies of plasma frequencies with large difference can be carried out.The simulation shows that the SPPs can be excited for an arbitrary plasma frequency.We believe the study will be beneficial for the problem of wave propagation in plasma science and technology.
基金the National Undergraduate Innovation Program Training Project(No.202110755022)。
文摘Triboelectric nanogenerator(TENG)converts mechanical energy into valuable electrical energy,offering a solution for future energy needs.As an indispensable part of TENG,textile TENG(T-TENG)has incredible advantages in harvesting biomechanical energy and physiological signal monitoring.However,the application of T-TENG is restricted,partly because the fabric structure parameter and structure on T-TENG performance have not been fully exploited.This study comprehensively investigates the effect of weaving structure on fabric TENGs(F-TENGs)for direct-weaving yarn TENGs and post-coating fabric TENGs.For direct-weaving F-TENGs,a single-yarn TENG(Y-TENG)with a core-sheath structure is fabricated using conductive yarn as the core layer yarn and polytetrafluoroethylene(PTFE)filaments as the sheath yarn.Twelve fabrics with five different sets of parameters were designed and investigated.For post-coating F-TENGs,fabrics with weaving structures of plain,twill,satin,and reinforced twill were fabricated and coated with conductive silver paint.Overall,the twill F-TENGs have the best electrical outputs,followed by the satin F-TENGs and plain weave F-TENGs.Besides,the increase of the Y-TENG gap spacing was demonstrated to improve the electrical output performance.Moreover,T-TENGs are demonstrated for human-computer interaction and self-powered real-time monitoring.This systematic work provides guidance for the future T-TENG’s design.
基金supported by a National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIT) (NRF-2020R1A2C3003344 and NRF-2020R1A4A2002728)
文摘Yarn sensors have shown promising application prospects in wearable electronics owing to their shape adaptability, good flexibility, and weavability. However, it is still a critical challenge to develop simultaneously structure stable, fast response, body conformal, mechanical robust yarn sensor using full microfibers in an industrial-scalable manner. Herein, a full-fiber auxetic-interlaced yarn sensor(AIYS) with negative Poisson’s ratio is designed and fabricated using a continuous, mass-producible, structure-programmable, and low-cost spinning technology. Based on the unique microfiber interlaced architecture, AIYS simultaneously achieves a Poisson’s ratio of-1.5, a robust mechanical property(0.6 c N/dtex), and a fast train-resistance responsiveness(0.025 s), which enhances conformality with the human body and quickly transduce human joint bending and/or stretching into electrical signals. Moreover, AIYS shows good flexibility, washability, weavability, and high repeatability. Furtherly, with the AIYS array, an ultrafast full-letter sign-language translation glove is developed using artificial neural network. The sign-language translation glove achieves an accuracy of 99.8% for all letters of the English alphabet within a short time of 0.25 s. Furthermore, owing to excellent full letter-recognition ability, real-time translation of daily dialogues and complex sentences is also demonstrated. The smart glove exhibits a remarkable potential in eliminating the communication barriers between signers and non-signers.
基金financially supported by the National Key R&D Program of China(Grant Nos.2016YFA0202704 and 2019YFA0706900)the Beijing Municipal Natural Science Foundation(Grant No.2212052)+1 种基金the China Postdoctoral Science Foundation(Grant No.2019T120390)the Jiangsu Planned Projects for Postdoctoral research funds(Grant No.2018K018A)。
文摘It is of great importance to explore a creative route to improve the degradation e ciency of organic pollutants in wastewater.Herein,we construct a unique hybrid system by combining self-powered triboelectric nanogenerator(TENG)with carbon dots-TiO_(2)sheets doped three-dimensional graphene oxide photocatalyst(3 DGA@CDs-TNs),which can significantly enhance the degradation e ciency of brilliant green(BG)and direct blue 5 B(DB)owing to the powerful interaction of TENG and 3 DGA@CDs-TNs photocatalyst.The power output of TENG can be applied for wastewater purification directly,which exhibits a selfpowered electrocatalytic technology.Furthermore,the results also verify that TENG can replace conventional electric catalyst to remove pollutants e ectively from wastewater without any consumption.Subsequently,the unstable fragments and the plausible removal pathways of the two pollutants are proposed.Our work sheds light on the development of e cient and sustainable TENG/photocatalyst system,opening up new opportunities and possibilities for comprehensive utilization of random energy.
基金supported by the National Natural Science Foundation of China(Grant Nos.51502253,U1405226,21503175,and 21705135)Natural Science Foundation of Guangdong Province,China(Grant No.2016A030310369)Natural Science Foundation of Fujian Province,China(Grant No.2017J01104)。
文摘Several p H-dependent processes and reactions take place in the human body;hence,the p H of body fluids is the best indicator of disturbed health conditions.However,accurate and real-time diagnosis of the p H of body fluids is complicated because of limited commercially available p H sensors.Hence,we aimed to prepare a flexible,transparent,disposable,userfriendly,and economic strip-based solid-state p H sensor using palladium nanoparticles(Pd NPs)/N-doped carbon(NC)composite material.The Pd NPs/NC composite material was synthesized using wool keratin(WK)as a precursor.The insitu prepared Pd NPs played a key role in the controlled switching of protein structure to the N-doped carbon skeleton withπ–πarrangement at the mesoscale level,which mimics the A–B type polymeric structure,and hence,is highly susceptible to H+ions.The optimized carbonization condition in the presence of Pd NPs showed that the material obtained using a modified Ag/Ag Cl reference electrode had the highest p H sensitivity with excellent stability and durability.The optimized p H sensor showed high specificity and selectivity with a sensitivity of 55 m V/p H unit and a relative standard deviation of 0.79%.This study is the first to synthesize Pd NPs using WK as a stabilizing and reducing agent.The applicability of the sensor was investigated for biological samples,namely,saliva and gastric juices.The proposed protocol and material have implications in solid-state chemistry,where biological material will be the best choice for the synthesis of materials with anticipated performance.
基金National Nature Science Foundation of China(No.12074322,No.62072383)Science and Technology Project of Xiamen City(3502Z20183012)+1 种基金Science and Technology Planning Project of Guangdong Province(2018B030331001)Shenzhen Science and technology plan project(JCYJ20180504170208402)。
文摘A wearable sensing system that can reconstruct dynamic 3D human body models for virtual cloth fitting is highly important in the era of information and metaverse.However,few research has been conducted regarding conformal sen-sors for accurately measuring the human body circumferences for dynamic 3D human body reshaping.Here,we develop a stretchable spring-sheathed yarn sensor(SSYS)as a smart ruler,for precisely measuring the circumference of human bodies and long-term tracking the movement for the dynamic 3D body reconstruction.The SSYS has a robust property,high resilience,high stability(>18000),and ultrafast response(12 ms)to external deformation.It is also washable,wearable,tailorable,and durable for long-time wearing.Moreover,geometric,and mechanical behaviors of the SSYS are systematically investigated both theoretically and experimentally.In addition,a transfer learning algorithm that bridges the discrepancy of real and virtual sensing performance is devel-oped,enabling a small body circumference measurement error of 1.79%,notice-ably lower than that of traditional learning algorithm.Furtherly,3D human bodies that are numerically consistent with the actual bodies are reconstructed.The 3D dynamic human body reconstruction based on the wearing sensing sys-tem and transfer learning algorithm enables excellent virtual fitting and shirt customization in a smart and highly efficient manner.This wearable sensing technology shows great potential in human-computer interaction,intelligent fitting,specialized protection,sports activities,and human physiological health tracking.
基金The work was supported by the Anhui emphatic research and developmental projects(201904a05020079).
文摘The Fukushima nuclear accident in Japan on March 11,2011,produced large amounts of Cs-polluted soil which must be controlled to prevent the spread of hazardous Cs into the environment.In this paper,the effects of heat treatment on the structure and properties of Cs-containing glass-ceramics,as a simulated nuclear waste form,were systematically investigated.Cesium atoms are chemically bonded in the pollucite structure,and the amorphous phase further encapsulates the pollucite crystals in the glassceramics,thus providing an extra protective layer for the immobilized Cs.XRD analysis,Raman and FT-IR studies on the glass-ceramics synergistically indicated that the optimum crystallization temperature for pollucite is around 1000℃.The pollucite is predominantly the main crystalline phase with a narrow crystal size distribution between 0.5 and 2 mm.Standard leaching test results show that the leaching rate of Cs was very low(3.0×10^(-3) g/(m^(2)·d)).The study offers a practical method for immobilizing Cs in pollucite-base glass-ceramics.Moreover,the experimentally obtained data may provide some important references for converting Cs-polluted soil into pollucite-base glass-ceramics waste form.
基金This work was supported by Open Project Funding of the Key Laboratory of High Performance Fibers and Products,Science Foundation of Zhejiang Sci-Tech University(20202090-Y).
文摘Development of biomaterial based flexible electronics has got intensive attention owing to the potential applications in the wearable and epidermal devices.Silk fibroin,as a natural textile material with excellent performance,has been widely concerned by industry and academy.However,the property of electrical insulation limits his development in the field of flexible electronics.In this paper,a regenerated silk fibroin/carbon nanotube(RSF/CNT)conductive film has been successfully fabricated and applied in flexible capacitive-type pressure sensor and wearable triboelectric nanogenerator by a facile method.The electrical conductivity and mechanical property of RSF/CNT film was optimized by investigating with different composite ratio from 10 to 90%(W_(RSF)/W_(CNT)).The RSF/CNT film has a good photothermal response and electric heating performance.We furtherly demonstrated that the RSF/CNT based sensor can be used as epidermal self-powered sensor for multifunction human motion monitoring and Morse code compilation.The observed research results have shown that the RSF/CNT film has a wide range of potential application prospects in the wearable electronics field.
