The title complex [Ni(TSSB)(phen)H2O]?C2H5OH?0.5H2O (C23H26N3NiO6.5S, TSSB = taurine salicylaldehyde Schiff base, phen = 1,10-phenanthroline) has been synthesized by the reaction of taurine salicylaldehyde Schiff base...The title complex [Ni(TSSB)(phen)H2O]?C2H5OH?0.5H2O (C23H26N3NiO6.5S, TSSB = taurine salicylaldehyde Schiff base, phen = 1,10-phenanthroline) has been synthesized by the reaction of taurine salicylaldehyde Schiff base (TSSB), 1,10-phenanthroline and nickel acetate in water-ethanol. Its single-crystal structure was determined by X-ray diffraction method. The crystal belongs to triclinic, space group P1 with a = 1.0562(2), b = 1.1604(2), c = 2.1170(3) nm, α = 103.257(3), β = 96.958(4), γ = 105.179(3)°, Mr = 539.24, V = 2.3917(6) nm3, Z = 4, Dc = 1.498 g/cm3, μ = 0.945 mm-1 and F(000) = 1124. The compound is a one-dimensional network, infinitely extending with hydrogen bonds. The Ni(Ⅱ) is 6-coordinated by one nitrogen and two oxygen atoms from taurine salicylaldehyde Schiff base, two nitrogen from 1,10-phenanthroline and one oxygen from water to form a distorted octahedronal coordination geometry.展开更多
Earth temperature is one of the most important factors influencing the mechanical properties of frozen soil. Based on the field investigation of the characteristics of ground deformation and ground failure caused by t...Earth temperature is one of the most important factors influencing the mechanical properties of frozen soil. Based on the field investigation of the characteristics of ground deformation and ground failure caused by the M S8 1 earthquake in the west of the Kunlun Mountain Pass, China, the influence of temperature on the dynamic constitutive relationship, dynamic elastic modulus, damping ratio and dynamic strength of frozen soil was quantitatively studied by means of the dynamic triaxial test. Moreover, the characteristics of ground motion on a permafrost site under different temperatures were analyzed for the four profiles of permafrost along the Qinghai Xizang(Tibet) Railway using the time histories of ground motion acceleration with 3 exceedance probabilities of the Kunlun Mountains area. The influences of temperature on the seismic displacement, velocity, acceleration and response spectrum on permafrost ground were studied quantitatively. A scientific basis was presented for earthquake disaster mitigation for engineering foundations, highways and underground engineering in permafrost areas.展开更多
The main factors that influence the temperature field of frozen subgrade were analyzed.The experimental equipment for simulating frozen subgrade was built up,and the declining regulating tubes were placed at the foot ...The main factors that influence the temperature field of frozen subgrade were analyzed.The experimental equipment for simulating frozen subgrade was built up,and the declining regulating tubes were placed at the foot of the embankment. By means of this equipment two simulating experiments of controlling temperature filed of frozen sub- grade were carried out in the laboratory.One method is to collect natural cold energy,and the other one is to collect natural cold energy ccompanied by artificial refrigeration simultaneously.The result indicates that the latter is an ef- fective method for maintaining the stability of the frozen subgrade.展开更多
基金Supported by the NSF of Guangxi Province (No. 0339034), the Science Research Foundation of Guangxi Universities and Minister of Education Foundation of Guangxi (No. [2004]20)
文摘The title complex [Ni(TSSB)(phen)H2O]?C2H5OH?0.5H2O (C23H26N3NiO6.5S, TSSB = taurine salicylaldehyde Schiff base, phen = 1,10-phenanthroline) has been synthesized by the reaction of taurine salicylaldehyde Schiff base (TSSB), 1,10-phenanthroline and nickel acetate in water-ethanol. Its single-crystal structure was determined by X-ray diffraction method. The crystal belongs to triclinic, space group P1 with a = 1.0562(2), b = 1.1604(2), c = 2.1170(3) nm, α = 103.257(3), β = 96.958(4), γ = 105.179(3)°, Mr = 539.24, V = 2.3917(6) nm3, Z = 4, Dc = 1.498 g/cm3, μ = 0.945 mm-1 and F(000) = 1124. The compound is a one-dimensional network, infinitely extending with hydrogen bonds. The Ni(Ⅱ) is 6-coordinated by one nitrogen and two oxygen atoms from taurine salicylaldehyde Schiff base, two nitrogen from 1,10-phenanthroline and one oxygen from water to form a distorted octahedronal coordination geometry.
文摘Earth temperature is one of the most important factors influencing the mechanical properties of frozen soil. Based on the field investigation of the characteristics of ground deformation and ground failure caused by the M S8 1 earthquake in the west of the Kunlun Mountain Pass, China, the influence of temperature on the dynamic constitutive relationship, dynamic elastic modulus, damping ratio and dynamic strength of frozen soil was quantitatively studied by means of the dynamic triaxial test. Moreover, the characteristics of ground motion on a permafrost site under different temperatures were analyzed for the four profiles of permafrost along the Qinghai Xizang(Tibet) Railway using the time histories of ground motion acceleration with 3 exceedance probabilities of the Kunlun Mountains area. The influences of temperature on the seismic displacement, velocity, acceleration and response spectrum on permafrost ground were studied quantitatively. A scientific basis was presented for earthquake disaster mitigation for engineering foundations, highways and underground engineering in permafrost areas.
基金Projects 2002CB412704 supported by the National Key Basic Research and Development Foundation of the Ministry of Sciences and Technology of China KZCX1-SW-04 supported by the Knowledge Innovation Program of the Chinese Academy of SciencesSKLFSE200304
文摘The main factors that influence the temperature field of frozen subgrade were analyzed.The experimental equipment for simulating frozen subgrade was built up,and the declining regulating tubes were placed at the foot of the embankment. By means of this equipment two simulating experiments of controlling temperature filed of frozen sub- grade were carried out in the laboratory.One method is to collect natural cold energy,and the other one is to collect natural cold energy ccompanied by artificial refrigeration simultaneously.The result indicates that the latter is an ef- fective method for maintaining the stability of the frozen subgrade.
