The complexation of gallium with 2-hydroxy-5-T-butylphenol-4’-methoxy-azobenzene (HR) has been studied by atomic absorption and spectrophotometric methods. The optimal conditions for the formation and extraction of t...The complexation of gallium with 2-hydroxy-5-T-butylphenol-4’-methoxy-azobenzene (HR) has been studied by atomic absorption and spectrophotometric methods. The optimal conditions for the formation and extraction of the complex were found. The maximum light absorption of the complex in n-butanol is in the range of 450 - 470 nm. The molar absorption coefficient is (3.3 - 4.2)<span style="white-space:nowrap;"><span style="white-space:nowrap;">⋅</span></span>10<sup>4</sup>. The stability constant of the gallium coordination compound in n-butanol is <em>β</em><sub>l</sub> = 4.2<span style="white-space:nowrap;"><span style="white-space:nowrap;">⋅</span></span>10<sup>10</sup>. The developed technique allows to determine the gallium content within n × 10<sup><span style="white-space:nowrap;"><span style="white-space:nowrap;">−</span></span>1</sup> - n × 10<sup><span style="white-space:nowrap;"><span style="white-space:nowrap;">−</span></span>4</sup>%. The selective and sensitive technique for the extraction-atomic absorption determination of gallium in soils has been developed.展开更多
The complex of molybdenum (VI) with stilbene-2,2’-disulfonic acid-4,4’’bis (azo-1’’)-3’’, 4’’ dioxybenzene (stillbazo) in the presence of a cationic surfactant cetylpyridinium chloride (CPCl) was studied spec...The complex of molybdenum (VI) with stilbene-2,2’-disulfonic acid-4,4’’bis (azo-1’’)-3’’, 4’’ dioxybenzene (stillbazo) in the presence of a cationic surfactant cetylpyridinium chloride (CPCl) was studied spectrophotometrically. It was found that in the presence of CPCl, a mixed-ligand complex with a component ratio of 1:2:4 is formed. The effect of pH, time, temperature, the concentration of reagents, and CPCl in the formation of homogeneous ligand and mixed-ligand complexes were studied. The stability constants (lg<em>β</em><sub><em>k</em></sub> = 86 × 10<sup>8</sup>) and the molar absorption coefficient of the mixed-ligand complex (<em>ε</em><sub><em>к</em></sub> = 11,835) were determined. It was found that Beer’s law is observed at a concentration of 0.05 - 17.00 μg/ml. A method has been developed for the spectrophotometric determination of molybdenum (VI) in complex industrial facilities.展开更多
文摘The complexation of gallium with 2-hydroxy-5-T-butylphenol-4’-methoxy-azobenzene (HR) has been studied by atomic absorption and spectrophotometric methods. The optimal conditions for the formation and extraction of the complex were found. The maximum light absorption of the complex in n-butanol is in the range of 450 - 470 nm. The molar absorption coefficient is (3.3 - 4.2)<span style="white-space:nowrap;"><span style="white-space:nowrap;">⋅</span></span>10<sup>4</sup>. The stability constant of the gallium coordination compound in n-butanol is <em>β</em><sub>l</sub> = 4.2<span style="white-space:nowrap;"><span style="white-space:nowrap;">⋅</span></span>10<sup>10</sup>. The developed technique allows to determine the gallium content within n × 10<sup><span style="white-space:nowrap;"><span style="white-space:nowrap;">−</span></span>1</sup> - n × 10<sup><span style="white-space:nowrap;"><span style="white-space:nowrap;">−</span></span>4</sup>%. The selective and sensitive technique for the extraction-atomic absorption determination of gallium in soils has been developed.
文摘The complex of molybdenum (VI) with stilbene-2,2’-disulfonic acid-4,4’’bis (azo-1’’)-3’’, 4’’ dioxybenzene (stillbazo) in the presence of a cationic surfactant cetylpyridinium chloride (CPCl) was studied spectrophotometrically. It was found that in the presence of CPCl, a mixed-ligand complex with a component ratio of 1:2:4 is formed. The effect of pH, time, temperature, the concentration of reagents, and CPCl in the formation of homogeneous ligand and mixed-ligand complexes were studied. The stability constants (lg<em>β</em><sub><em>k</em></sub> = 86 × 10<sup>8</sup>) and the molar absorption coefficient of the mixed-ligand complex (<em>ε</em><sub><em>к</em></sub> = 11,835) were determined. It was found that Beer’s law is observed at a concentration of 0.05 - 17.00 μg/ml. A method has been developed for the spectrophotometric determination of molybdenum (VI) in complex industrial facilities.
