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Micro-aluminum powder with bi-or tri-component alloy coating as a promising catalyst:Boosting pyrolysis and combustion of ammonium perchlorate
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作者 Chao wang Ying Liu +6 位作者 Mingze Wu Jia Li Ying Feng Xianjin Ning Hong Li ningfei wang Baolu Shi 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第3期100-113,共14页
A novel design of micro-aluminum(μAl)powder coated with bi-/tri-component alloy layer,such as:Ni-P and Ni-P-Cu(namely,Al@Ni-P,Al@Ni-P-Cu,respectively),as combustion catalysts,were introduced to release its huge energ... A novel design of micro-aluminum(μAl)powder coated with bi-/tri-component alloy layer,such as:Ni-P and Ni-P-Cu(namely,Al@Ni-P,Al@Ni-P-Cu,respectively),as combustion catalysts,were introduced to release its huge energy inside Al-core and promote rapid pyrolysis of ammonium perchlorate(AP)at a lower temperature in aluminized propellants.The microstructure of Al@Ni-P-Cu demonstrates that a three-layer Ni-P-Cu shell,with the thickness of~100 nm,is uniformly supported byμAl carrier(fuel unit),which has an amorphous surface with a thickness of~2.3 nm(catalytic unit).The peak temperature of AP with the addition of Al@Ni-P-Cu(3.5%)could significantly drop to 316.2℃ at high-temperature thermal decomposition,reduced by 124.3℃,in comparison to that of pure AP with 440.5℃.It illustrated that the introduction of Al@Ni-P-Cu could weaken or even eliminate the obstacle of AP pyrolysis due to its reduction of activation energy with 118.28 kJ/mol.The laser ignition results showed that the ignition delay time of Al@Ni-P-Cu/AP mixture with 78 ms in air is shorter than that of Al@Ni-P/AP(118 ms),decreased by 33.90%.Those astonishing breakthroughs were attributed to the synergistic effects of adequate active sites on amorphous surface and oxidation exothermic reactions(7597.7 J/g)of Al@Ni-P-Cu,resulting in accelerated mass and/or heat transfer rate to catalyze AP pyrolysis and combustion.Moreover,it is believed to provide an alternative Al-based combustion catalyst for propellant designer,to promote the development the propellants toward a higher energy. 展开更多
关键词 Micro-aluminum powder(μAl) Nano-sized alloy coating Combustion catalyst Ammonium perchlorate Pyrolysis behavior Ignition and combustion
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Investigations of the mechanical response of dummy HTPB propellant grain under ultrahigh acceleration overload conditions using onboard flight-test measurements
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作者 Yiming Zhang ningfei wang +3 位作者 Weihua Ma Ran wang Long Bai Yi Wu 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第2期473-484,共12页
In this paper,to study the mechanical responses of a solid propellant subjected to ultrahigh acceleration overload during the gun-launch process,specifically designed projectile flight tests with an onboard measuremen... In this paper,to study the mechanical responses of a solid propellant subjected to ultrahigh acceleration overload during the gun-launch process,specifically designed projectile flight tests with an onboard measurement system were performed.Two projectiles containing dummy HTPB propellant grains were successfully recovered after the flight tests with an ultrahigh acceleration overload value of 8100 g.The onboard-measured time-resolved axial displacement,contact stress and overload values were successfully obtained and analysed.Uniaxial compression tests of the dummy HTPB propellant used in the gunlaunched tests were carried out at low and intermediate strain rates to characterize the propellant's dynamic properties.A linear viscoelastic constitutive model was employed and applied in finite-element simulations of the projectile-launching process.During the launch process,the dummy propellant grain exhibited large deformation due to the high acceleration overload,possibly leading to friction between the motor case and propellant grain.The calculated contact stress showed good agreement with the experimental results,though discrepancies in the overall displacement of the dummy propellant grain were observed.The dynamic mechanical response process of the dummy propellant grain was analysed in detail.The results can be used to estimate the structural integrity of the analysed dummy propellant grain during the gun-launch process. 展开更多
关键词 Gun-launched flight test Dummy HTPB propellant Onboard measurements Utrahigh overload Mechanical response
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Application and development of the pulsed plasma thruster 被引量:4
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作者 武志文 黄天坤 +3 位作者 刘向阳 林永樑 王宁飞 季路成 《Plasma Science and Technology》 SCIE EI CAS CSCD 2020年第9期114-127,共14页
The application and development of pulsed plasma thrusters(PPTs)in recent years are reviewed in this paper.The advantages of PPTs are discussed.The schematics,propulsion performance parameters and key physical process... The application and development of pulsed plasma thrusters(PPTs)in recent years are reviewed in this paper.The advantages of PPTs are discussed.The schematics,propulsion performance parameters and key physical processes of PPTs are described.Some representative PPT products and flight systems developed in recent years are presented to show the performance of the PPT.Studies about how electrode structures,discharge circuits,propellant materials,energy discharge method,propellant feed method,ignition method and number of thruster heads influence the PPT performance are presented and analyzed.The ignitor design method,ignition process and propellant carbonization are introduced to discuss the reliability and lifetime issues in PPTs.The modeling methods of the discharge circuit,as well as ablation,ionization and acceleration in PPTs are presented.Finally,the application of PPTs in the future is analyzed and some suggestions for PPT development are proposed. 展开更多
关键词 pulsed plasma thruster PERFORMANCE MODELING design propellant material
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Experimental investigation on the evolution of plasma properties in the discharge channel of a pulsed plasma thruster
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作者 周阳 王宁飞 +3 位作者 刘向阳 林永樑 谢侃 武志文 《Plasma Science and Technology》 SCIE EI CAS CSCD 2020年第6期156-163,共8页
Pulsed plasma thrusters(PPTs)are an attractive form of micro-thrusters due to advantages such as their compactness and lightweight design compared to other electric propulsion systems.Experimental investigations on th... Pulsed plasma thrusters(PPTs)are an attractive form of micro-thrusters due to advantages such as their compactness and lightweight design compared to other electric propulsion systems.Experimental investigations on their plasma properties are beneficial in clarifying the complex process of plasma evolution during the micro-second pulse discharge of a PPT.In this work,the multi-dimensional evolutions of the light intensity of the PPT plasma with wavelength,time,and position were identified.The plasma pressure was obtained using an iterative process with composition calculations.The results show that significant ion recombination occurred in the discharge channel since the line intensities of CII,CIII,CIV,and FII decreased and those of CI and FI increased as the plasma moved downstream.At the center of the discharge channel,the electron temperature and electron density were in the order of 10000 K and 1017 cm-3,respectively.These had maximum values of 13750 K and 2.3?×?1017 cm-3 and the maximum temperature occurred during the first half-cycle while the maximum number density was measured during the second half-cycle.The estimated plasma pressure was in the order of 105 Pa and exhibited a maximum value of 2.69?×?105 Pa. 展开更多
关键词 pulsed plasma thruster plasma properties emission spectra electric propulsion
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Numerical study on combustion efficiency of aluminum particles in solid rocket motor 被引量:1
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作者 Junlong wang ningfei wang +4 位作者 Xiangrui ZOU Wei DONG Yintao ZHOU Dingjiang XIE Baolu SHI 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2023年第5期66-77,共12页
The combustion of aluminum particles in solid rocket motor plays an important role in energy release of propellants. However, due to the limited residence time, aluminum particles may not be burned completely, thus hi... The combustion of aluminum particles in solid rocket motor plays an important role in energy release of propellants. However, due to the limited residence time, aluminum particles may not be burned completely, thus hindering the improvement of specific impulse. This study aims to explore the characteristics of aluminum combustion efficiency and its influencing factors by experiments and numerical simulations, providing a guideline for engine performance improvement. As an input of simulation, the initial agglomerate size was measured by a high pressure system. Meanwhile, the size distribution of the particles in plume was measured by ground firing test to validate the numerical model. Then, a two-phase flow model coupling combustion of micro aluminum particle was developed, by which the detailed effects of particle size, detaching position and nozzle convergent section structure on aluminum combustion efficiency were explored. The results suggest that the average combustion temperature in the chamber drops with increasing initial particle size,while the maximum temperature increases slightly. In the tested motors, the aluminum particle burns completely as its diameter is smaller than 50 μm, and beyond 50 μm the combustion efficiency decreases obviously with the increase of initial size. As the diameter approaches to 75 μm, the combustion efficiency becomes more sensitive to particle size. The combustion efficiency of aluminum particle escaping from end-burning surfaces is significantly higher than that from internal burning surface, where the particle combustion efficiency decreases during approaching the convergent section. Furthermore, the combustion efficiency decreases slightly with increasing nozzle convergent section angle. And theoretically it is feasible to improve combustion efficiency of aluminum particles by designing the convergent profile of nozzle. 展开更多
关键词 ALUMINUM Combustion efficiency Eulerian-Lagrangian Particle size Solid rocket motor
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Direct thrust test and asymmetric performance of porous ionic liquid electrospray thruster
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作者 Yuntao GUO Wei SUN +4 位作者 Zhenning SUN Zhiwen WU Jianwu HE Chao YANG ningfei wang 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2023年第4期120-133,共14页
In order to meet the demand of CubeSats for low power and high-performance micro-propulsion system,a porous ionic liquid electrospray thruster prototype is developed in this study.1010 conical emitter arrays are fabri... In order to meet the demand of CubeSats for low power and high-performance micro-propulsion system,a porous ionic liquid electrospray thruster prototype is developed in this study.1010 conical emitter arrays are fabricated on an area of 3.24 cm^(2) by computer numerical control machining technology.The propellant is 1-ethyl-3-methylimidazolium tetrafluoroborate.The over-all dimension of the assembled prototype is 3 cm×3 cm×1 cm,with a total weight of about 15 g(with propellant).The performance of this prototype is tested under vacuum.The results show that it can work in the voltage range of±2.0 kV to±3.0 kV,and the maximum emission current and input power are about 355 lA and 1.12 W.Time of Flight(TOF)mass spectrometry results show that cationic monomers and dimers dominate the beam in positive mode,while a higher proportion of higher-order solvated ion clusters in negative mode.The maximum specific impulse is 2992 s in positive mode and 849 s in negative mode.The thrust is measured in two methods:one is calculated by TOF results and the other is directly measured by high-precision torsional thrust stand.The thrust(T)obtained by these two methods conforms to a certain scaling law with respect to the emis-sion current(I_(em))and the applied voltage(V_(app)),following the scale of T-Iem_(Vapp)^(0.5),and the thrust range is from 2.1 lN to 42.6 lN.Many thruster performance parameters are significantly different in positive and negative modes.We speculate that due to the higher solvation energy of the anion,more solvated ion clusters are formed rather than pure ions under the same electric field.It may help to improve thruster performance if porous materials with smaller pore sizes are used as reservoirs.Although there are still many problems,most of the performance parameters of ILET-3 are good,which can theoretically meet the requirements of CubeSats for micro-propulsion system. 展开更多
关键词 Asymmetric performance Direct thrust test Ionic liquid electrospray thruster Time of flight mass spectrometry Torsional thrust stand
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Ion engine grids:Function,main parameters,issues,configurations,geometries,materials and fabrication methods 被引量:4
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作者 Miguel SANGREGORIO Kan XIE +2 位作者 ningfei wang Ning GUO Zun ZHANG 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2018年第8期1635-1649,共15页
Ion optics are crucial components of ion thrusters and the study of the different ion extraction solutions used since the beginning of the electric propulsion era is essential to understand the evolution of ion engine... Ion optics are crucial components of ion thrusters and the study of the different ion extraction solutions used since the beginning of the electric propulsion era is essential to understand the evolution of ion engines. This work describes ion engine grids' main functions, parameters and issues related to thermal expansion and sputter erosion, and then introduces a review of ion optics used for significant launched and tested ion thrusters since 1970. Configurations, geometries, materials and fabrication methods are analyzed to understand when typical ion thrusters use two or three grids, what are the thicknesses and aperture sizes of the screen, accelerator and decelerator grids, why molybdenum and carbon-based materials such as pyrolytic graphite and carbon–carbon are the best available options for ion optics and what is the manufacturing method for each material. 展开更多
关键词 离子引擎 制造方法 几何学 格子 材料 函数 配置 离子推进器
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A brief review of alternative propellants and requirements for pulsed plasma thrusters in micropropulsion applications 被引量:3
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作者 William Yeong Liang LING Song ZHANG +4 位作者 Hao FU Mengcheng HUANG Justin QUANSAH Xiangyang LIU ningfei wang 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2020年第12期2999-3010,共12页
Technological miniaturization has enabled the development of small satellites weighing as little as 1 kg.Unfortunately,there is still a lack of suitable efficient micropropulsion systems at these scales.The pulsed pla... Technological miniaturization has enabled the development of small satellites weighing as little as 1 kg.Unfortunately,there is still a lack of suitable efficient micropropulsion systems at these scales.The pulsed plasma thruster is a structurally simple form of electric propulsion.This simplicity also makes it ideally suited for miniaturization.Its history can be traced back to applications in satellites that are much larger than micro/nano-satellites.The vast majority of modern pulsed plasma thrusters use solid polytetrafluoroethylene(PTFE)as a propellant.Unfortunately,at lower discharge energy levels such as those necessitated by the power limitations of micro/nano-satellites,PTFE has a tendency to exhibit carbon deposition,which can ultimately lead to thruster failure.In this new era of small satellites,it is important to consider alternative propellants in the miniaturization of pulsed plasma thrusters.This brief review discusses the needs and limitations of small satellites and alternative propellants that may be able to meet these needs.Such propellants may be able to offer advantages such as a longer thruster lifetime,a higher specific impulse,or a higher thrust-topower ratio.This would enable the development of different types of pulsed plasma thrusters that can be tailored towards specific mission requirements. 展开更多
关键词 CUBESAT Electric propulsion Micropropulsion Plasma physics PROPELLANT Pulsed plasma thruster
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Experimental and numerical study on pressure oscillation in a combustor with rotary valve 被引量:2
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作者 Yunzhi XI ningfei wang +2 位作者 Junwei LI Zhihui ZHANG Lei HAN 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2021年第5期298-314,共17页
A rotary valve coupled in a combustor assembly can generate periodic pressure oscillations inside the combustor and can be used to study the combustion instability in the combustion chamber of a rocket engine.This pap... A rotary valve coupled in a combustor assembly can generate periodic pressure oscillations inside the combustor and can be used to study the combustion instability in the combustion chamber of a rocket engine.This paper proposes a cold gas flow experimental system based on a rotary valve and a corresponding rotation model.A 3 D numerical model is proposed to obtain the transient flow inside the rotary valve,and the dynamic mesh technique and User-Defined Functions(UDFs)are adopted to implement a swing motion instead of a rotary motion.Several cold gas flow experiments are carried out at rotating speeds of 75225,and 375 rpm to verify the validity of the numerical model.The effects of rotating speed,stroke length ratio and radius of the RED(Rotor Exhaust Duct)on the pressure oscillations are studied using this numerical model.The results show that the maximum and peak-to-peak values of the pressure oscillations gradually decrease with increasing rotating speed.The ratio of the corresponding peak-to-peak value to the maximum pressure(pressure amplitude ratio)is reduced from 1.81 to 0.6%.The stroke length ratio affects the pressure waveform because it leads to a change in the time spent in the non-exhaust stage.When the stroke length ratio is 0,the waveform closely resembles a sine wave.With the increase in the stroke length ratio,the pressure waveform exhibits a more square or a triangular wave shape.Finally,a high-frequency and high-amplitude pressure oscillation can be obtained by appropriately increasing the radius of the RED. 展开更多
关键词 Cold gas test Dynamic mesh Numerical simulation Pressure oscillation Rotary valve
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Transient flow characteristics and performance of a solid rocket motor with a pintle valve 被引量:1
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作者 Anchen SONG ningfei wang +2 位作者 Junwei LI Baoyin MA Xinjian CHEN 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2020年第12期3189-3205,共17页
The pintle valve is currently the most promising technology among all thrust control methods for solid rocket motors.Pintle structure and working condition play a critical role in the successful operation of a pintle ... The pintle valve is currently the most promising technology among all thrust control methods for solid rocket motors.Pintle structure and working condition play a critical role in the successful operation of a pintle motor.Here,2D transient simulations of a pintle motor using dynamic meshing are performed.Reynolds-averaged Navier–Stokes equations are solved with the implementation of an RNG k–e turbulence model.In cold flow test,emphasis is placed on the effect of pintle structure,and in hot flow test,emphasis is placed on the effect of propellant pressure exponent.Validation is performed first by comparing the present results with available cold-test experimental data.This shows that the transient simulations can provide good predictions for pintle motors with a relative error of less than 2%in terms of the chamber pressure.It can be found that,when the gas supply system is different,the working principles and conditions of pintle motors are different.The feedback process in propellant combustion has a significant impact on its operation and the effect on the pintle motor performance of different pintle structures is achieved by different variations in the equivalent throat area.Finally,the pressure exponent is an important parameter in hot flow test and changes of thrust in hot flow test are not monotonic,because changes in the flow field and motor performance are asynchronous. 展开更多
关键词 Numerical simulation Pintle motor Shock wave Solid propellant rocket Variable thrust
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