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氟虫腈亚砜荧光衍生化、HPLC-FLD检测方法的建立及应用 被引量:2
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作者 王梦 周香菊 +6 位作者 聂嘉文 彭大勇 陈继光 张清峰 唐道邦 刘佳 尹忠平 《食品工业科技》 CAS 北大核心 2021年第20期286-293,共8页
建立了氟虫腈代谢物-氟虫腈亚砜的柱前荧光衍生化方法,并将其应用于鸡蛋中的残留检测。优化后的柱前荧光衍生化反应主要条件如下:催化缩合剂为EDC/DMAP;反应溶剂为二氯甲烷;氟虫腈亚砜与荧光衍生试剂的用量比为1:8;45℃水浴中反应75 mi... 建立了氟虫腈代谢物-氟虫腈亚砜的柱前荧光衍生化方法,并将其应用于鸡蛋中的残留检测。优化后的柱前荧光衍生化反应主要条件如下:催化缩合剂为EDC/DMAP;反应溶剂为二氯甲烷;氟虫腈亚砜与荧光衍生试剂的用量比为1:8;45℃水浴中反应75 min。衍生产物为N-(3-氰基-1-(2,6-二氯-4-(三氟甲基)苯基)-4-((三氟甲基)硫代)-1H-吡唑-5-基)-4-(2-(9-乙基-9H-咔唑-3-基)-1H-菲并[9,10-d]咪唑-1-基)丁酰胺(DX1),具有很高的荧光强度。衍生化产物DX1的高效液相色谱-荧光检测(HPLC-FLD)的主要条件如下:C_(18)色谱柱;等度洗脱;流动相:乙腈/水(80/20,v/v);流速:1.0 mL/min;λex=310 nm,λem=404 nm;进样量20μL;柱温40℃。在上述检测条件下,氟虫腈亚砜HPLC-FLD检测方法的检测限为0.033μg/L,定量限为0.092μg/L。在此基础上,建立了鸡蛋残留氟虫腈亚砜提取和检测的HPLC-FLD方法,检测限和定量限分别达到了0.052和0.132μg/kg,精密度、稳定性和重现性在保留时间和峰面积上的RSD分别小于0.04%和2.7%,上机检测可在20 min内完成。该方法具有较好的灵敏度、精确性和可靠性,可应用于鸡蛋中残留氟虫腈亚砜的检测。 展开更多
关键词 氟虫腈亚砜 柱前荧光衍生化 高效液相色谱-荧光检测 氟虫腈代谢物 定量检测
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Pekeris波导中垂直发射阵的阵增益快速估计
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作者 衣晓锋 彭大勇 +1 位作者 曾娟 马力 《声学学报》 EI CSCD 北大核心 2020年第3期341-349,共9页
为了利用单换能器的声强级估计垂直发射阵的声强级,研究了Pekeris波导中快速估计发射阵增益的方法。首先,基于等效深度简正波理论,计算了Pekeris波导中垂直发射阵的平均声强,进而得到用模态阶数求和表示的发射阵增益的表达式。然后对模... 为了利用单换能器的声强级估计垂直发射阵的声强级,研究了Pekeris波导中快速估计发射阵增益的方法。首先,基于等效深度简正波理论,计算了Pekeris波导中垂直发射阵的平均声强,进而得到用模态阶数求和表示的发射阵增益的表达式。然后对模态阶数用积分代替求和,并对引入的误差进行修,得到3/2次方衰减场区发射阵增益的快速估计表达式;有效声影区声场由于只剩1阶简正模态,可直接简化得到发射阵增益的快速估计表达式,在海底参数未知时可用海深近似代替等效深度来估计有效声影区的发射阵增益。计算机仿真和海上实验得到的阵增益快速估计误差均小于1 dB,验证了快速估计方法的有效性,这一发射阵增益快速估计方法可以为工程应用提供参考。 展开更多
关键词 发射阵 Pekeris 阵增益 快速估计
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浅海低频垂直相控阵多模声场聚焦
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作者 衣晓锋 彭大勇 +1 位作者 侯倩男 郭圣明 《应用声学》 CSCD 北大核心 2019年第4期615-622,共8页
为了提高低频垂直相控阵声场聚焦的环境适应性,增强环境失配情况下的声场聚焦效果,提出一种多模声场聚焦方法。该方法利用环境失配对低阶模态影响相对较小的特点,只利用前 3阶模态进行发射权系数的计算。仿真结果表明,多模声场具有较大... 为了提高低频垂直相控阵声场聚焦的环境适应性,增强环境失配情况下的声场聚焦效果,提出一种多模声场聚焦方法。该方法利用环境失配对低阶模态影响相对较小的特点,只利用前 3阶模态进行发射权系数的计算。仿真结果表明,多模声场具有较大的聚焦跨度,在环境失配情况下仍能在期望的聚焦位置实现良好的聚焦效果。进一步地,根据巴斯微扰理论计算分析了多模声场的混响特性。由于多模声场聚焦将能量集中到了掠射角较小的低阶模态中,因此比最优权系数聚焦具有更低的混响平均强度。多模聚焦对聚焦深度进行扫描可以实现目标的深度分辨,这在水下目标探测方面具有较高的应用前景。 展开更多
关键词 相控阵 声场聚焦 多模 混响抑制
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Fast estimation of array gain of vertical transmit array in Pekeris waveguide
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作者 YI Xiaofeng peng dayong +1 位作者 ZENG Juan MA Li 《Chinese Journal of Acoustics》 CSCD 2020年第3期287-299,共13页
In order to estimate the sound intensity level of vertical transmit array(VTA)from that of single transducer,a fast estimation method of transmit array gain(TAG)in Pekeris waveguide is studied.At first,the average sou... In order to estimate the sound intensity level of vertical transmit array(VTA)from that of single transducer,a fast estimation method of transmit array gain(TAG)in Pekeris waveguide is studied.At first,the average sound intensity of VTA is calculated on the basis of normal mode theory with the effective depth,and the TAG expressed by the summation of modes is derived.Then by using integral,instead of summation,of modes order,the fast estimation expression of TAG in 3/2 power field is derived along with error correction.Because only the first mode exists in effective shadow zone(ESZ),the fast estimation expression of TAG in ESZ is derived by directly simplifying the former expression.All of the fast estimation errors of computer simulations and experiment in shallow water are less than 1 dB,which can verify the validity of the fast estimation method.This fast estimation method of TAG can provide references for practical application. 展开更多
关键词 WAVEGUIDE ESTIMATION MODE
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Using the system function to analyze the performance of transducer's impedance measurement method
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作者 LI Haifeng ZENG Juan +3 位作者 GAO Tianfu LIU Haijun peng dayong ZHAO Wenyao 《Chinese Journal of Acoustics》 2013年第3期211-221,共11页
Prom investigation of the advantages and disadvantages of conventional tri-voltage method,a method for the measurement of the transmitting transducer's impedance was presented to solve the difficult problem of examin... Prom investigation of the advantages and disadvantages of conventional tri-voltage method,a method for the measurement of the transmitting transducer's impedance was presented to solve the difficult problem of examining the consistency of the transmitting phased array on the single-mode excitation sea spot.In the method based on the system function, the circuit structure of tri-voltage method was used but new parameters were measured.The principle of the method was given first.Then when resistors with different nominal values were used in the circuit,the measured results for the impedance of transducers were reported.The results were compared with the higher precision impedance analyzer.Finally,the error analysis was performed according to the impedance formula and the equivalent circuit parameters were fitted.Under the condition of guaranteeing the sampling precision,by performance analyzing, the resistor value in series was chosen relatively smaller than the impedance of transducer,the measurement of impedance could achieve the same precision as the higher precision impedance analyzer.Finally,the least squares curve-fitting of measured curves indicated that the transducer equivalent electrical parameters could be extracted accurately and used to design the matching network. 展开更多
关键词 Using the system function to analyze the performance of transducer’s impedance measurement method
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