In this study,graphene-carbon nanotube(CNT) hybrid films were directly synthesized on polycrystalline copper(Cu) substrates by thermal chemical vapor deposition(CVD) method.Graphene films were synthesized on Cu ...In this study,graphene-carbon nanotube(CNT) hybrid films were directly synthesized on polycrystalline copper(Cu) substrates by thermal chemical vapor deposition(CVD) method.Graphene films were synthesized on Cu substrate at 1000 ℃ in mixture of gases:argon(Ar),hydrogen(H2),and methane(CH4).Then,carbon nanotubes(CNTs) were grown uniformly on the surface of graphene/Cu films at 750 ℃ in mixture of Ar,H2.and acetylene(C2H2) gases.Ferric salt FeCl3solution deposited onto the surface of graphene/Cu substrate by spin coating method was used as precursor for the growth of the CNTs.The density and quality of the CNTs on the surface of graphene/Cu films can be controlled by varying the concentration of FeCl3salt catalyst.展开更多
基金supported mainly by the National Foundation for Science and Technology Development(No.103.992012.15)A part of work was supported by VAST 03.06/14-15.Besides
文摘In this study,graphene-carbon nanotube(CNT) hybrid films were directly synthesized on polycrystalline copper(Cu) substrates by thermal chemical vapor deposition(CVD) method.Graphene films were synthesized on Cu substrate at 1000 ℃ in mixture of gases:argon(Ar),hydrogen(H2),and methane(CH4).Then,carbon nanotubes(CNTs) were grown uniformly on the surface of graphene/Cu films at 750 ℃ in mixture of Ar,H2.and acetylene(C2H2) gases.Ferric salt FeCl3solution deposited onto the surface of graphene/Cu substrate by spin coating method was used as precursor for the growth of the CNTs.The density and quality of the CNTs on the surface of graphene/Cu films can be controlled by varying the concentration of FeCl3salt catalyst.