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Hybridization of iron phthalocyanine and MoS_(2)for high-efficiency and durable oxygen reduction reaction
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作者 Haibing Meng Xiaolong Liu +5 位作者 Xiao Chen Ying Han Chenhui Zhou qinyuan jiang Ting Tan Rufan Zhang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2022年第8期528-538,I0014,共12页
Hybrid catalysts based on iron phthalocyanine(FePc)have raised much attention due to their promising applications in electrocatalytic oxygen reduction reaction(ORR).Various hybridization strategies have been developed... Hybrid catalysts based on iron phthalocyanine(FePc)have raised much attention due to their promising applications in electrocatalytic oxygen reduction reaction(ORR).Various hybridization strategies have been developed for improving their activity and durability.However,the influence of different hybridization strategies on their catalytic performance remains unclear.In this study,Fe Pc was effectively distributed on molybdenum disulfide(MoS_(2))forming Fe Pc-based hybrid catalysts,namely Fe Pc-MoS_(2),Fe Pc*-MoS_(2),and Fe Pc-Py-MoS_(2),respectively,to disclose the related influence.Through direct hybridization,the stacked and highly dispersed Fe Pc on MoS_(2)resulted in Fe Pc-MoS_(2),and Fe Pc*-MoS_(2),respectively,in which the substrate and Fe Pc are mainly bound through van der Waals interactions.Through covalent hybridization strategy using pyridyl(Py)as a linker,Fe Pc-Py-MoS_(2)hybrid catalyst was prepared.Experimental and theoretical results disclosed that the linker hybridization of Fe Pc and MoS_(2)facilitated the exposure of Fe-N4 sites,maintained the intrinsic activity of Fe Pc by forming a more dispersed phase and increased the durability via Fe-N bonding,rendering the Fe Pc-Py-MoS_(2)an excellent ORR hybrid catalyst.Compared with van der Waals hybridized Fe Pc-MoS_(2)and Fe Pc*-MoS_(2)in alkaline media,the linker hybridized Fe Pc-Py-MoS_(2)showed an obviously enhanced ORR activity with a half-wave potential(E_(1/2))of 0.88 V vs RHE and an ultralow Tafel slope of 26 m V dec-1.Besides,the Fe Pc-Py-MoS_(2)exhibited a negligible decay of E_(1/2) after 50,000 CV cycles for ORR,showing its superior durability.This work gives us more insight into the influence of different hybrid strategies on Fe Pc catalysts and provides further guidance for the development of highly efficient and durable ORR catalysts. 展开更多
关键词 FePc MoS_(2) Hybridization strategies Charge transfer ORR performance
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Oxygen-deficient tungsten oxide nanoflowers for dynamically tunable near-infrared light transmittance of smart windows
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作者 Ya Huang Baoshun Wang +8 位作者 Pei Lyu Siming Zhao Xueke Wu Shiliang Zhang Run Li qinyuan jiang Fei Wang Yanlong Zhao Rufan Zhang 《Nano Research》 SCIE EI CSCD 2023年第10期12165-12172,共8页
Electrochromic smart windows have attracted much attention in energy-saving buildings because of their ability to selectively modulate visible(VIS)and near-infrared(NIR)light transmittance.As is known,the NIR region a... Electrochromic smart windows have attracted much attention in energy-saving buildings because of their ability to selectively modulate visible(VIS)and near-infrared(NIR)light transmittance.As is known,the NIR region accounts for about 50%of the total solar radiation.Therefore,reducing the NIR transmittance of windows will play a crucial role in reducing the energy consumption of buildings.However,for most of the reported electrochromic materials(ECMs)-based windows,it remains a longlasting challenge about how to achieve a low NIR transmittance during the past decades.In this work,we synthesize oxygendeficient tungsten oxide(WO_(3−x))nanoflowers(NFs)by a simple and efficient method that is facile for their mass production.The WO_(3−x)NFs exhibit low NIR transmittance of only 4.11%,0.60%,and 0.19%at 1200,1600,and 1800 nm,respectively,due to the localized surface plasmon resonance(LSPR)effect.Besides,the WO_(3−x)NFs exhibit an excellent dual-band modulating ability for both VIS and NIR light.They are able to operate in three distinct modes,including a bright mode,a cool mode,and a dark mode.Moreover,the WO_(3−x)NFs exhibit a fast bleaching/coloring time(1.54/6.67 s),and excellent cycling stability(97.75%of capacity retention after 4000 s). 展开更多
关键词 electrochromic tungsten oxide DUAL-BAND smart window infrared
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Multicolored structural coloration of carbon nanotube fibers
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作者 Run Li Shiliang Zhang +8 位作者 Hang Chen Ya Huang Baoshun Wang Xueke Wu qinyuan jiang Siming Zhao Fei Wang Yanlong Zhao Rufan Zhang 《SusMat》 2023年第1期102-110,共9页
Carbon nanotube fibers(CNTFs)are endowed with excellent mechanical,electrical,and thermal properties and are considered promising candidates in numerous cutting-edge fields.However,the inherent black color of CNTFs hi... Carbon nanotube fibers(CNTFs)are endowed with excellent mechanical,electrical,and thermal properties and are considered promising candidates in numerous cutting-edge fields.However,the inherent black color of CNTFs hinders their practical application in fields with high aesthetic requirements such as wearable devices and smart textiles.Due to the smooth surface and chemical inertness,CNTFs are hard to be dyed by conventional chemical dyes or colorful inks.Herein,we realize a structural coloration of CNTFs by coating them with two metal oxide layers via atomic layer deposition.The three elements of color,that is,hue,saturation,and brightness,can be controlled by adjusting the types and thickness of each oxide layer.Colorful CNTFs with wide color gamut and high saturation are achieved through different combinations.A film interference model is also established to reveal the mechanism of the structural coloration,which is a comprehensive result of thin-film interference and surface roughness briefly.The calculated reflectance well fits the measured results by introducing surface roughness parameters.Moreover,the colored CNTFs are not iridescent because of retinal signal delay,which will further expand their applications. 展开更多
关键词 atomic layer deposition carbon nanotube structural color
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Progress and perspective on high-strength and multifunctional carbon nanotube fibers 被引量:2
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作者 Run Li qinyuan jiang Rufan Zhang 《Science Bulletin》 SCIE EI CSCD 2022年第8期784-787,共4页
Materials are foundations of human civilization.From the Stone Age to the present new material age,the history of human civilization is also a history of the development of materials.The mass production of a new gener... Materials are foundations of human civilization.From the Stone Age to the present new material age,the history of human civilization is also a history of the development of materials.The mass production of a new generation of materials with strength,flexibility and fatigue resistance that are orders of magnitude higher than the current materials is of great importance in both science and engineering. 展开更多
关键词 碳纳米管纤维 materials. FATIGUE
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