Water has become an effective means to trace the mantle source of basaltic magmas recently. To investigate the source of the potassium-rich component in the Xiaogulihe ultrapotassic volcanic rocks of NE China, we meas...Water has become an effective means to trace the mantle source of basaltic magmas recently. To investigate the source of the potassium-rich component in the Xiaogulihe ultrapotassic volcanic rocks of NE China, we measured the water content of clinopyroxene （cpx） phenocrysts by Fourier transform infrared spectrometry and calculated the H2O content of the equilibrated melts according to the partition coefficients of H2O between cpx phenocrysts and basaltic melts. The estimated H2O content of the ＂primary＂ magmas is low （0.36 wt%-0.50 wt%）, within the range of mid-ocean ridge basalts and ocean island basalts, while it is obviously lower than that of backarc basin basalts and island arc basalts. The calculated H20/Ce ratio of the ＂primary＂ magmas is about 15, which might be similar to that of the dehydrated sediments （〈100）, but observably lower than that of the normal depleted mantle （DMM, H2O/Ce = 150-210）. The low water content and especially low H2O/Ce ratio of the ＂primary＂ magmas demonstrate that the K-rich component of these ultrapotassic volcanic rocks seems unlikely tooriginate from K-bearing hydrous minerals （such as phlogopite） in metasomatic subcontinental lithospheric mantle. Combined with the low 206pb/204pb ratios, moderately high 87Sr/86Sr ratios of the bulk rocks and the high δ18O values of olivine phenocrysts, we suggest that the K-rich component in the mantle source of the Xiaogulihe ultrapotassic volcanic rocks may come from ancient continental-derived sediments which dehydrated significantly during subduction （e.g., dry K-hollandite）.展开更多
Recycled oceanic crust （ROC） has long been suggested to be a candidate introducing en- riched geochemical signatures into the mantle source of intraplate basalts. The different parts of oceanic crust are characteriz...Recycled oceanic crust （ROC） has long been suggested to be a candidate introducing en- riched geochemical signatures into the mantle source of intraplate basalts. The different parts of oceanic crust are characterized by variable oxygen isotope compositions （δ^18O=3.7‰ to 13.6‰）. To trace the sig- natures of ROC in the mantle source of intraplate basalts, we measured the δ^18O values of clinopyroxene （cpx） phenocrysts in the Cenozoic basalts from the Shuangliao volcanic field, NE China using secondary ion mass spectrometer （SIMS）. The δ^18O values of the Shuangliao cpx phenocrysts in four basalts ranging from 4.10‰ to 6.73‰ （with average values 5.93‰±0.36‰, 5.95‰±0.30‰0, 5.58‰±=0.66‰e, and 4.55‰±= 0.38‰, respectively） apparently exceed those of normal mantle-derived cpx （5.6‰±0.2‰） and fall in the typical oxygen isotope range of altered oceanic crust. The δ^18O values display the negative correlations with the Eu, Sr anomalies of whole rocks and erupted ages, demonstrating that （1） the ROC is the main enriched component in the mantle source of the Shuangliao basalts and （2） the contributions of ROC var- ied with time. The basalt with the lowest δ^18O value is characterized by a significant K positive anomaly, highest H2O/Ce and Ba/Th ratios, suggesting that the mantle source of basalts with low δ^18O can also in- clude a water-rich sediment component that may be the trigger for partial melting. Considering the continuous subduction of the Pacific slab, the temporal heterogeneity of the source components is likely to be caused by the Pacific slab subduction.展开更多
基金supported by the National Natural Science Foundation of China(41225005)the Research Fund for the Doctoral Program of Higher Education of China(RFDP20113402130001)
文摘Water has become an effective means to trace the mantle source of basaltic magmas recently. To investigate the source of the potassium-rich component in the Xiaogulihe ultrapotassic volcanic rocks of NE China, we measured the water content of clinopyroxene （cpx） phenocrysts by Fourier transform infrared spectrometry and calculated the H2O content of the equilibrated melts according to the partition coefficients of H2O between cpx phenocrysts and basaltic melts. The estimated H2O content of the ＂primary＂ magmas is low （0.36 wt%-0.50 wt%）, within the range of mid-ocean ridge basalts and ocean island basalts, while it is obviously lower than that of backarc basin basalts and island arc basalts. The calculated H20/Ce ratio of the ＂primary＂ magmas is about 15, which might be similar to that of the dehydrated sediments （〈100）, but observably lower than that of the normal depleted mantle （DMM, H2O/Ce = 150-210）. The low water content and especially low H2O/Ce ratio of the ＂primary＂ magmas demonstrate that the K-rich component of these ultrapotassic volcanic rocks seems unlikely tooriginate from K-bearing hydrous minerals （such as phlogopite） in metasomatic subcontinental lithospheric mantle. Combined with the low 206pb/204pb ratios, moderately high 87Sr/86Sr ratios of the bulk rocks and the high δ18O values of olivine phenocrysts, we suggest that the K-rich component in the mantle source of the Xiaogulihe ultrapotassic volcanic rocks may come from ancient continental-derived sediments which dehydrated significantly during subduction （e.g., dry K-hollandite）.
基金supported by the National Natural Science Foundation of China(Nos.41225005 and 41173047)
文摘Recycled oceanic crust （ROC） has long been suggested to be a candidate introducing en- riched geochemical signatures into the mantle source of intraplate basalts. The different parts of oceanic crust are characterized by variable oxygen isotope compositions （δ^18O=3.7‰ to 13.6‰）. To trace the sig- natures of ROC in the mantle source of intraplate basalts, we measured the δ^18O values of clinopyroxene （cpx） phenocrysts in the Cenozoic basalts from the Shuangliao volcanic field, NE China using secondary ion mass spectrometer （SIMS）. The δ^18O values of the Shuangliao cpx phenocrysts in four basalts ranging from 4.10‰ to 6.73‰ （with average values 5.93‰±0.36‰, 5.95‰±0.30‰0, 5.58‰±=0.66‰e, and 4.55‰±= 0.38‰, respectively） apparently exceed those of normal mantle-derived cpx （5.6‰±0.2‰） and fall in the typical oxygen isotope range of altered oceanic crust. The δ^18O values display the negative correlations with the Eu, Sr anomalies of whole rocks and erupted ages, demonstrating that （1） the ROC is the main enriched component in the mantle source of the Shuangliao basalts and （2） the contributions of ROC var- ied with time. The basalt with the lowest δ^18O value is characterized by a significant K positive anomaly, highest H2O/Ce and Ba/Th ratios, suggesting that the mantle source of basalts with low δ^18O can also in- clude a water-rich sediment component that may be the trigger for partial melting. Considering the continuous subduction of the Pacific slab, the temporal heterogeneity of the source components is likely to be caused by the Pacific slab subduction.
