The Dongfengnanshan Cu polymetallic deposit is one representative deposit of the Tianbaoshan ore district in the Yanbian area, northeast(NE) China. There occur two types of ore bodies in this deposit, the stratiform o...The Dongfengnanshan Cu polymetallic deposit is one representative deposit of the Tianbaoshan ore district in the Yanbian area, northeast(NE) China. There occur two types of ore bodies in this deposit, the stratiform ore bodies and veintype ones, controlled by the Early Permian strata and the Late Hercynian diorite intrusion, respectively. Due to the ambiguous genetic type of the stratiform ore bodies, there has been controversy on the relationship between them and veintype ore bodies. To determine the genetic type of stratiform ore bodies, laser ablation inductively coupled plasma mass spectrometry(LA-ICP-MS) in situ trace elements and S–Pb isotope analysis have been carried on the sulfides in the stratiform ore bodies. Compared with that in skarn, Mississippi Valley-type(MVT), and epithermal deposits, sphalerite samples in the stratiform ore bodies of the Dongfengnanshan deposit are significantly enriched in Fe, Mn, and In, while depleted in Ga, Ge, and Cd, which is similar to the sphalerite in volcanic-associated massive sulfide(VMS) deposits. Co/Ni ratio of pyrrhotites in the stratiform ore bodies is similar to that in VMS-type deposits. The concentrations of Zn and Cd of chalcopyrites are similar to those of recrystallized VMS-type deposits. These characteristics also reflect the intermediate ore-forming temperature of the stratiform ore bodies in this deposit. Sulfur isotope compositions of sulfides are similar to those of VMS-type deposits, reflecting that sulfur originated from the Permian Miaoling Formation. Lead isotope compositions indicate mixed-source for lead. Moreover, the comparison of the Dongfengnanshan stratiform ore bodies with some VMStype deposits in China and abroad, on the trace elements and S–Pb isotope characteristics of the sulfides reveals that the stratiform ore bodies of the Dongfengnanshan deposit belong to the VMS-type, and have closely genetic relationship with the early Permian marine volcanic sedimentary rocks.展开更多
The metallogenetic porphyry bodies in the Nongping Au-Cu deposit, in the eastern Yanbian area, mainly include porphyritic granodiorite and biotite granodiorite porphyry. They are featured with high silicon and enrichm...The metallogenetic porphyry bodies in the Nongping Au-Cu deposit, in the eastern Yanbian area, mainly include porphyritic granodiorite and biotite granodiorite porphyry. They are featured with high silicon and enrichment in sodium, and classified into sodic rocks of low-K tholeiitic basalt series. Except slightly low Sr content, the rock basically has the geochemical characteristics of the adakite： relatively high A12O3 content, relatively low MgO content, depletion in Y and Yb; relative enrichment in large ion lithophile elements （LILEs） and light rare-earth elements （LREEs）, relatively low content of high field strength elements （HFSEs）; positive Eu anomaly or weak negative Eu anomaly. In situ zircon dating technology LA-MC-ICP-MS was used to conduct single-grain zircon dating of biotite granodiorite porphyry, and the results show that the age of metallogenetic porphyry body is 100.04±0.88 Ma, indicating that the porphyry bodies were emplaced in the late Cretaceous period. According to the regional tectonic setting and the comparison with the same kind of deposits, we think that the metallogenetic porphyry bodies in the Nongping Au-Cu deposit have a close genetic connection with the subduction of the Pacific plate in the late Yanshanian period. The adakitic magma generated from partial melting of the subducting plate has high formation temperature, high oxygen fugacity, and volatile constituents＇ enrichment, so it is helpful for enrichment of metallogenetic elements and plays an important role in the formation of porphyry Au-Cu deposits in this region.展开更多
The Yangbishan iron-tungsten deposit in the Shuangyashan area of Heilongjiang Province is located in the center of the Jiamusi Massif in northeastern China. The rare earth element and trace element compositions of the...The Yangbishan iron-tungsten deposit in the Shuangyashan area of Heilongjiang Province is located in the center of the Jiamusi Massif in northeastern China. The rare earth element and trace element compositions of the scheelite show that it formed in a reducing environment and inherited the rare earth element features of the ore-forming fluid. The geochemical characteristics of the gneissic granite associated with the tungsten mineralization show that the magma formed in this reducing environment and originated from the partial melting of metamorphosed shale that contained organic carbon and was enriched with tungsten. In addition, in situ Hf isotopic analysis of zircons from the gneissic granite indicates that they probably originated from the partial melting of a predominantly Paleo-Mesoproterozoic crustal source. According to LA-ICP-MS zircon dating, the Yangbishan ore- related gneissic granite has an Early Paleozoic crystallization age of 520.6 ＋ 2.8 Ma. This study, together with previous data, indicates that the massifs of northeastern China, including Erguna, Xing＇an, Songliao, Jiamusi, and Khanka massifs, belonged to an orogenic belt that existed along the southern margin of the Siberian Craton during the late Pan-African period. The significant continental movements of this orogeny resulted in widespread magmatic activity in northeastern China from 530 Ma to 470 Ma under a tectonic setting that transitioned from compressional syn-collision to extensional post- collision.展开更多
The Shanmen deposit, located in the Siping area of Jilin Province, is one of large-scale silver deposits in Northeast(NE) China. Due to its high Ag grade, associated gold resources and special tectonic location, this ...The Shanmen deposit, located in the Siping area of Jilin Province, is one of large-scale silver deposits in Northeast(NE) China. Due to its high Ag grade, associated gold resources and special tectonic location, this deposit has important theoretical and ore-prospecting significance. To present new data on the ore genesis, mineralization time and tectonic settings, the relationship between silver mineralization and intrusions in this deposit has been studied and some analyses have been carried out, including LA-ICP-MS zircon U-Pb dating, whole-rock major and trace element analysis and Sr-Nd-Pb isotope analysis of the granitoids associated with silver mineralization. Studies on deposit geology indicate that the ore-hosting granodiorite and monzogranite have intimate genetic relationships with silver mineralization. LA-ICP-MS zircon U-Pb dating results of the both intrusions are 167.6 ± 1.9 Ma and 167.0 ± 1.5 Ma, respectively, implying that the two intrusions and associated silver mineralization in the Shanmen deposit formed during the Middle Jurassic. Major element analytical data suggest that the two intrusions are high-K calc–alkaline series I-type granites and belong to metaluminous and peraluminous rocks. Both intrusions have similar REE characteristics with regard to the relative enrichment of LREEs, depletion of HREEs, obvious fractionation of LREEs and HREEs(ΣLREE/ΣHREE = 8.68–14.09,(La/Yb)_N = 12.51–21.96), moderately negative Eu anomalies as well as weakly negative Ce anomalies(δEu = 0.56–0.71, δCe = 0.93–1.09). Moreover, the samples are generally enriched in LILEs and depleted in HFSEs. The rock assemblages and geochemical characteristics of granitoids in the Shanmen deposit suggest that they formed in an active continental margin associated with the Paleo-Pacific plate subduction. The Sr-Nd-Pb isotope compositions show that both the granodiorite and monzogranite have low Sr initial ratios and high Sm/Nd initial ratios. The ε_(Nd)(t) values and young Nd-model ages are-3.2 to-1.7 and 990 Ma to 1110 Ma, respectively. Considering the Sr-Nd isotope compositions, in conjunction with the relatively high ~(206)Pb, ~(207)Pb and ~(208)Pb, alongside the relatively low ~(204)Pb, it can be concluded that the Middle Jurassic intermediate-acidic magma represented by the studied monzogranite and granodiorite in the Shanmen deposit, was derived from the partial melting of juvenile lower crust enriched in mantle-derived materials and affected by the mixing of ancient crustal materials during the ascension and intrusion processes.展开更多
The Xiaohongshilazi mineral deposit in Jilin Province,China,is located in the accretion zone in the northern margin of the North China Block. The deposit contains two types of ore bodies: layered Pb-Zn ore bodies in v...The Xiaohongshilazi mineral deposit in Jilin Province,China,is located in the accretion zone in the northern margin of the North China Block. The deposit contains two types of ore bodies: layered Pb-Zn ore bodies in volcanic rock and vein-hosted Pb-Zn ore bodies controlled by fractures. The vein Pb-Zn ore bodies are strictly controlled by tectonic fracture zones trending in S-N direction,which comprise sulfide veins or sulfidebearing quartz veins distributed along faults or structural fissures. The ores mainly appear mesh-vein and vein structures,and also show solid-solution separation and metasomatic textures. The metal minerals are mainly sphalerite,galena,and pyrite,etc. Wall-rock alteration includes mainly sericitization,chloritization,silicification and carbonatization,etc. Microscope observations and Raman spectroscopy analyses indicate that the oreforming fluid of the vein Pb-Zn ore bodies was mainly magmatic water with low temperature,low salinity,and a shallow depth of metallogenesis( ~ 1.5 km). Sulfur and lead isotope analyses indicate that the sulfide source is mainly formation sulfur or biogenic sulfur,which is similar to the sulfur source of hydrothermal deposit( negative( δ^(34) S values),while the main Pb source was the upper crust with some mantle input. This article argues that the vein Pb-Zn ore body of the Xiaohongshilazi deposit is a low-to medium-temperature hydrothermal vein type related to the formation of a shallow magma chamber.展开更多
基金supported by the National Natural Science Foundation of China (NSFC) (No. 41772062)
文摘The Dongfengnanshan Cu polymetallic deposit is one representative deposit of the Tianbaoshan ore district in the Yanbian area, northeast(NE) China. There occur two types of ore bodies in this deposit, the stratiform ore bodies and veintype ones, controlled by the Early Permian strata and the Late Hercynian diorite intrusion, respectively. Due to the ambiguous genetic type of the stratiform ore bodies, there has been controversy on the relationship between them and veintype ore bodies. To determine the genetic type of stratiform ore bodies, laser ablation inductively coupled plasma mass spectrometry(LA-ICP-MS) in situ trace elements and S–Pb isotope analysis have been carried on the sulfides in the stratiform ore bodies. Compared with that in skarn, Mississippi Valley-type(MVT), and epithermal deposits, sphalerite samples in the stratiform ore bodies of the Dongfengnanshan deposit are significantly enriched in Fe, Mn, and In, while depleted in Ga, Ge, and Cd, which is similar to the sphalerite in volcanic-associated massive sulfide(VMS) deposits. Co/Ni ratio of pyrrhotites in the stratiform ore bodies is similar to that in VMS-type deposits. The concentrations of Zn and Cd of chalcopyrites are similar to those of recrystallized VMS-type deposits. These characteristics also reflect the intermediate ore-forming temperature of the stratiform ore bodies in this deposit. Sulfur isotope compositions of sulfides are similar to those of VMS-type deposits, reflecting that sulfur originated from the Permian Miaoling Formation. Lead isotope compositions indicate mixed-source for lead. Moreover, the comparison of the Dongfengnanshan stratiform ore bodies with some VMStype deposits in China and abroad, on the trace elements and S–Pb isotope characteristics of the sulfides reveals that the stratiform ore bodies of the Dongfengnanshan deposit belong to the VMS-type, and have closely genetic relationship with the early Permian marine volcanic sedimentary rocks.
基金financially supported by the China Geological Survey (No.1212011085485)Basic Research Foundation of Jilin University (No. 200903025 and 201004001)
文摘The metallogenetic porphyry bodies in the Nongping Au-Cu deposit, in the eastern Yanbian area, mainly include porphyritic granodiorite and biotite granodiorite porphyry. They are featured with high silicon and enrichment in sodium, and classified into sodic rocks of low-K tholeiitic basalt series. Except slightly low Sr content, the rock basically has the geochemical characteristics of the adakite： relatively high A12O3 content, relatively low MgO content, depletion in Y and Yb; relative enrichment in large ion lithophile elements （LILEs） and light rare-earth elements （LREEs）, relatively low content of high field strength elements （HFSEs）; positive Eu anomaly or weak negative Eu anomaly. In situ zircon dating technology LA-MC-ICP-MS was used to conduct single-grain zircon dating of biotite granodiorite porphyry, and the results show that the age of metallogenetic porphyry body is 100.04±0.88 Ma, indicating that the porphyry bodies were emplaced in the late Cretaceous period. According to the regional tectonic setting and the comparison with the same kind of deposits, we think that the metallogenetic porphyry bodies in the Nongping Au-Cu deposit have a close genetic connection with the subduction of the Pacific plate in the late Yanshanian period. The adakitic magma generated from partial melting of the subducting plate has high formation temperature, high oxygen fugacity, and volatile constituents＇ enrichment, so it is helpful for enrichment of metallogenetic elements and plays an important role in the formation of porphyry Au-Cu deposits in this region.
基金supported by the National Key R&D Program of China(2017YFC0601304)the National Basic Research Program of China(also called 973 Program)(No.2013CB429802)the National Natural Science Foundation of China(NSFC)(No.41272094)
文摘The Yangbishan iron-tungsten deposit in the Shuangyashan area of Heilongjiang Province is located in the center of the Jiamusi Massif in northeastern China. The rare earth element and trace element compositions of the scheelite show that it formed in a reducing environment and inherited the rare earth element features of the ore-forming fluid. The geochemical characteristics of the gneissic granite associated with the tungsten mineralization show that the magma formed in this reducing environment and originated from the partial melting of metamorphosed shale that contained organic carbon and was enriched with tungsten. In addition, in situ Hf isotopic analysis of zircons from the gneissic granite indicates that they probably originated from the partial melting of a predominantly Paleo-Mesoproterozoic crustal source. According to LA-ICP-MS zircon dating, the Yangbishan ore- related gneissic granite has an Early Paleozoic crystallization age of 520.6 ＋ 2.8 Ma. This study, together with previous data, indicates that the massifs of northeastern China, including Erguna, Xing＇an, Songliao, Jiamusi, and Khanka massifs, belonged to an orogenic belt that existed along the southern margin of the Siberian Craton during the late Pan-African period. The significant continental movements of this orogeny resulted in widespread magmatic activity in northeastern China from 530 Ma to 470 Ma under a tectonic setting that transitioned from compressional syn-collision to extensional post- collision.
基金financially supported by the National Key R&D Program of China (No. 2017YFC0601304)。
文摘The Shanmen deposit, located in the Siping area of Jilin Province, is one of large-scale silver deposits in Northeast(NE) China. Due to its high Ag grade, associated gold resources and special tectonic location, this deposit has important theoretical and ore-prospecting significance. To present new data on the ore genesis, mineralization time and tectonic settings, the relationship between silver mineralization and intrusions in this deposit has been studied and some analyses have been carried out, including LA-ICP-MS zircon U-Pb dating, whole-rock major and trace element analysis and Sr-Nd-Pb isotope analysis of the granitoids associated with silver mineralization. Studies on deposit geology indicate that the ore-hosting granodiorite and monzogranite have intimate genetic relationships with silver mineralization. LA-ICP-MS zircon U-Pb dating results of the both intrusions are 167.6 ± 1.9 Ma and 167.0 ± 1.5 Ma, respectively, implying that the two intrusions and associated silver mineralization in the Shanmen deposit formed during the Middle Jurassic. Major element analytical data suggest that the two intrusions are high-K calc–alkaline series I-type granites and belong to metaluminous and peraluminous rocks. Both intrusions have similar REE characteristics with regard to the relative enrichment of LREEs, depletion of HREEs, obvious fractionation of LREEs and HREEs(ΣLREE/ΣHREE = 8.68–14.09,(La/Yb)_N = 12.51–21.96), moderately negative Eu anomalies as well as weakly negative Ce anomalies(δEu = 0.56–0.71, δCe = 0.93–1.09). Moreover, the samples are generally enriched in LILEs and depleted in HFSEs. The rock assemblages and geochemical characteristics of granitoids in the Shanmen deposit suggest that they formed in an active continental margin associated with the Paleo-Pacific plate subduction. The Sr-Nd-Pb isotope compositions show that both the granodiorite and monzogranite have low Sr initial ratios and high Sm/Nd initial ratios. The ε_(Nd)(t) values and young Nd-model ages are-3.2 to-1.7 and 990 Ma to 1110 Ma, respectively. Considering the Sr-Nd isotope compositions, in conjunction with the relatively high ~(206)Pb, ~(207)Pb and ~(208)Pb, alongside the relatively low ~(204)Pb, it can be concluded that the Middle Jurassic intermediate-acidic magma represented by the studied monzogranite and granodiorite in the Shanmen deposit, was derived from the partial melting of juvenile lower crust enriched in mantle-derived materials and affected by the mixing of ancient crustal materials during the ascension and intrusion processes.
基金Supported by Project of Natural Science Foundation of Jilin Province(No.20170101084JC)
文摘The Xiaohongshilazi mineral deposit in Jilin Province,China,is located in the accretion zone in the northern margin of the North China Block. The deposit contains two types of ore bodies: layered Pb-Zn ore bodies in volcanic rock and vein-hosted Pb-Zn ore bodies controlled by fractures. The vein Pb-Zn ore bodies are strictly controlled by tectonic fracture zones trending in S-N direction,which comprise sulfide veins or sulfidebearing quartz veins distributed along faults or structural fissures. The ores mainly appear mesh-vein and vein structures,and also show solid-solution separation and metasomatic textures. The metal minerals are mainly sphalerite,galena,and pyrite,etc. Wall-rock alteration includes mainly sericitization,chloritization,silicification and carbonatization,etc. Microscope observations and Raman spectroscopy analyses indicate that the oreforming fluid of the vein Pb-Zn ore bodies was mainly magmatic water with low temperature,low salinity,and a shallow depth of metallogenesis( ~ 1.5 km). Sulfur and lead isotope analyses indicate that the sulfide source is mainly formation sulfur or biogenic sulfur,which is similar to the sulfur source of hydrothermal deposit( negative( δ^(34) S values),while the main Pb source was the upper crust with some mantle input. This article argues that the vein Pb-Zn ore body of the Xiaohongshilazi deposit is a low-to medium-temperature hydrothermal vein type related to the formation of a shallow magma chamber.
