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One-pot synthesis of 2,5-bis(hydroxymethyl)furan from biomass derived 5-(chloromethyl)furfural in high yield 被引量:1
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作者 Binglin Chen Yunchao Feng +9 位作者 sen ma Weizhen Xie Guihua Yan Zheng Li Jonathan Sperry Shuliang Yang Xing Tang Yong Sun Lu Lin Xianhai Zeng 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第1期421-428,I0011,共9页
5-(Chloromethyl)furfural(CMF),as a new platform molecular,has become a hot topic in the field of biorefinery.Herein,the one-pot conversion of CMF to 2,5-bis(hydroxymethyl)furan(BHMF)in the water phase was demonstrated... 5-(Chloromethyl)furfural(CMF),as a new platform molecular,has become a hot topic in the field of biorefinery.Herein,the one-pot conversion of CMF to 2,5-bis(hydroxymethyl)furan(BHMF)in the water phase was demonstrated for the first time.A 91%BHMF yield was obtained over Ru/Cu Oxcatalyst,and BHMF was mainly produced by the consecutive hydrolysis and hydrogenation of CMF with 5-hydroxymethylfurfural(HMF)as an intermediate.Kinetic studies revealed that the conversion of HMF to BHMF was the rate-determining step.Remarkably,the characterizations and density functional theory(DFT)calculations further revealed the lower electron density of Ru NPs in Ru/Cu Oxcatalyst,resulting in a larger adsorption energy and a smaller free energy difference for the formation of alcohols.The present findings offered a new pathway for biomass-derived diol production through CMF as a potential source. 展开更多
关键词 2 5-Bis(hydroxymethyl)furan Hydrolysis Hydrogenation Biomass conversion Heterogeneous catalysis
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Influences of four processing methods on main nutritional components of foxtail millet: A review 被引量:4
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作者 Tongshuai Yang sen ma +2 位作者 Jingke Liu Binghua Sun Xiaoxi Wang 《Grain & Oil Science and Technology》 2022年第3期156-165,共10页
Foxtail millet, originated from China and now cultivated worldwide, is a kind of high dietary fiber whole grain food, and has a high level of vitamins and proteins. Furthermore, foxtail millet has many positive effect... Foxtail millet, originated from China and now cultivated worldwide, is a kind of high dietary fiber whole grain food, and has a high level of vitamins and proteins. Furthermore, foxtail millet has many positive effects on the adjuvant treatment of diabetes, cancer, and cardiovascular diseases because of the abundance in polyphenols. Nonetheless, foxtail millet has poor processing characteristics due to the absence of gluten, restricting the development of foxtail millet products. Studies have demonstrated that heat-moisture treatment, extrusion, superfine grinding, and microbial fermentation are promising methods to improve the processing qualities of foxtail millet. Heat-moisture treatment is helpful to increase the content of resistant starch but has less influence on other components, further reduce the GI value of foxtail millet. The extrusion has positive effects on improving the solubility of foxtail millet starch and increasing the contents of polyunsaturated fatty acid, linoleic and linolenic acids, and adverse effects on reducing the solubility of foxtail millet proteins and causing losses of nutrients due to Maillard reaction. Superfine grinding can reduce the particle size of foxtail millet to obtain a better mouthfeel of foxtail millet products. The superfine foxtail millet flour has better solubility, higher freeze-thaw stability, and lower gelatinization temperature. Microbial fermentation contributes positively to reducing the molecular weight and retrogradation value of foxtail millet starch, degrading rapidly digested starch, and improving the digestibility of foxtail millet protein. This paper briefly introduced the effects of different processing methods on foxtail millet nutrients, aiming to provide references for increasing the variety and improving the quality of foxtail millet products. 展开更多
关键词 Foxtail millet Heat-moisture treatment EXTRUSION Superfine grinding Microbial fermentation NUTRIENTS Health food
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A systematic review of highland barley:Ingredients,health functions and applications 被引量:2
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作者 Yiming Lyu sen ma +1 位作者 Jingke Liu Xiaoxi Wang 《Grain & Oil Science and Technology》 2022年第1期35-43,共9页
Due to its high nutritional and dietotherapy values,highland barley has attracted the attention and favor of people all over the world in recent years.It has been demonstrated that the nutritional components of highla... Due to its high nutritional and dietotherapy values,highland barley has attracted the attention and favor of people all over the world in recent years.It has been demonstrated that the nutritional components of highland barley are comprehensive and unique,with the characteristics of high protein,high fiber,high vitamin,lowfat,low sugar and variety of bioactive components.As the most important component in highland barley,highland barley starch not only has low digestibility,but also has good freeze-thaw stability,high solubility,good emulsion stability and superior film forming performance,which makes it have great application value in food,medicine and industrial production.The content of highland barley protein,which is rich in 18 kinds of amino acids,is higher than that of most grains,and its derivatives play an important role in medical treatment.Unfortunately,highland barley protein cannot form gluten network structure,which limits the application in daily staple food to a certain extent.Highland barley also contains a large amount of dietary fiber,especiallyβ-glucan.Long-term consumption could significantly reduce the incidence of chronic diseases and metabolic syndromes such as heart disease and diabetes.However,the research on the application of highland barley is still in the laboratory stage,which failed to achieve large-scale application in the actual production.The value of highland barley has not been brought into full play,which leads to the waste of its resources and the reduction of its added value.This paper reviewed themacronutrients,health functions and applications of highland barley,aiming to provide some reference for the development of highland barley in food and health industry. 展开更多
关键词 Highland barley MACRONUTRIENTS Physicochemical property APPLICATION
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Highly Flexible and Broad‑Range Mechanically Tunable All‑Wood Hydrogels with Nanoscale Channels via the Hofmeister Effect for Human Motion Monitoring
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作者 Guihua Yan Shuaiming He +9 位作者 Gaofeng Chen sen ma Anqi Zeng Binglin Chen Shuliang Yang Xing Tang Yong Sun Feng Xu Lu Lin Xianhai Zeng 《Nano-Micro Letters》 SCIE EI CAS CSCD 2022年第5期192-205,共14页
Wood-based hydrogel with a unique anisotropic structure is an attractive soft material,but the presence of rigid crystalline cellulose in natural wood makes the hydrogel less flexible.In this study,an all-wood hydroge... Wood-based hydrogel with a unique anisotropic structure is an attractive soft material,but the presence of rigid crystalline cellulose in natural wood makes the hydrogel less flexible.In this study,an all-wood hydrogel was constructed by cross-linking cellulose fibers,polyvinyl alcohol(PVA)chains,and lignin molecules through the Hofmeister effect.The all-wood hydrogel shows a high tensile strength of 36.5 MPa and a strain up to~438%in the longitudinal direction,which is much higher than its tensile strength(~2.6 MPa)and strain(~198%)in the radial direction,respectively.The high mechanical strength of all-wood hydrogels is mainly attributed to the strong hydrogen bonding,physical entanglement,and van der Waals forces between lignin molecules,cellulose nanofibers,and PVA chains.Thanks to its excellent flexibility,good conductivity,and sensitivity,the all-wood hydrogel can accurately distinguish diverse macroscale or subtle human movements,including finger flexion,pulse,and swallowing behavior.In particular,when“An Qi”was called four times within 15 s,two variations of the pronunciation could be identified.With recyclable,biodegradable,and adjustable mechanical properties,the all-wood hydrogel is a multifunctional soft material with promising applications,such as human motion monitoring,tissue engineering,and robotics materials. 展开更多
关键词 Wood hydrogel Hofmeister effect Tunable mechanical strength FLEXIBLE BIODEGRADABLE
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Quality deterioration and improvement of wheat gluten protein in frozen dough 被引量:14
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作者 Wenjuan Feng sen ma Xiaoxi Wang 《Grain & Oil Science and Technology》 2020年第1期29-37,共9页
Frozen dough technology can effectively recover sensory quality of frozen flour products.This technique has gradually drawn the research interest in the industrialization of staple food.However,the quality of the fina... Frozen dough technology can effectively recover sensory quality of frozen flour products.This technique has gradually drawn the research interest in the industrialization of staple food.However,the quality of the final frozen products remains inferior to that of fresh products.This study reviewed the deterioration of gluten network in dough caused by ice recrystallization and various additives.This study also investigated the optimization of the freezing process and other empirical improvement techniques.Suggestions for future research were also provided. 展开更多
关键词 FROZEN DOUGH GLUTEN PROTEIN POOR quality Improved technology
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Study on the effect of wheat bran dietary fiber on the rheological properties of dough 被引量:13
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作者 Ning Liu sen ma +1 位作者 Li Li Xiaoxi Wang 《Grain & Oil Science and Technology》 2019年第1期1-5,共5页
The aim of the study was to determine the influence of wheat bran dietary fiber on wheat flour dough rheological properties.In this paper,wheat bran dietary fiber(WBDF)with different levels(0,3%,6%,9%,12%)were added t... The aim of the study was to determine the influence of wheat bran dietary fiber on wheat flour dough rheological properties.In this paper,wheat bran dietary fiber(WBDF)with different levels(0,3%,6%,9%,12%)were added to wheat flour and the characterization of dough rheological properties was conducted by rapid visco-analyzer,farinograph,as well as rotational rheometer.The results from pasting properties showed a gradual reduction in peak viscosity,trough viscosity,final viscosity and setback with increasing WBDF content.At high WBDF concentration,the significant increase of water absorption,formation time as well as weakening degree implied the harder formation of gluten network structure and the competition for water between gluten and WBDF particles.Such conclusion was in line with the findings from dynamic rheology tests,in which the doughs containing WBDF were more sensitive to strain regardless of their rigid and stiff texture.This study revealed vulnerable dough structure induced by WBDF,as well as the strengthened elastic property,elaborating the harmful effects ofWBDF on the rheological properties of doughs. 展开更多
关键词 WHEAT BRAN DIETARY fiber WHEAT DOUGH RHEOLOGICAL properties VISCOELASTICITY
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Effects of insoluble dietary fiber from wheat bran on noodle quality 被引量:8
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作者 Mengxu Lei Jihong Huang +6 位作者 Xiaoling Tian Peng Zhou Qi Zhu Limin Li Li Li sen ma Xiaoxi Wang 《Grain & Oil Science and Technology》 2021年第1期1-9,共9页
Benefiting from its favorable effects in promoting intestinal peristalsis,increasing satiety and reducing postprandial blood sugar,wheat bran insoluble dietary fiber(IDF)could be added to noodles to improve the nutrit... Benefiting from its favorable effects in promoting intestinal peristalsis,increasing satiety and reducing postprandial blood sugar,wheat bran insoluble dietary fiber(IDF)could be added to noodles to improve the nutrition value of noodle products.However,the addition of IDF usually results in an adverse effect on the quality characteristics of fiber fortified products,leading to unfavorable texture and consumption drop.It was found that IDF could weaken dough characteristics,thereby causing the quality deterioration of noodles,but the mechanism is unclear as yet.This study aimed to investigate the effects of different amounts of IDF on the texture quality and cooking quality of noodles.The water distribution,rheological properties,pasting properties and cooking properties of the noodles were determined by low-field nuclear magnetic resonance(LF-NMR),dynamic rheometer,and rapid visco-analyzer.The results of the LF-NMR showed that the increased IDF in the noodles resulted in a contraction of relaxation time and an increase in the proportion of loosely bound water.At a high amount of IDF,the water absorption and tensile distance of the noodles significantly decreased and the cooking loss rate increased,with a downward trend in peak viscosity,final viscosity and setback values.Moreover,IDF could improve the storage modulus and loss modulus of sheeted dough and enhance the texture of noodles.Furthermore,the correlations between IDF addition amounts and rheological properties as well as cooking properties were analyzed,and the results confirmed that noodles with the IDF amount of 2%–4%had higher nutrition and quality.This study provides the basis for future development and improvement of IDF-enriched health foods. 展开更多
关键词 Wheat bran Dietary fiber Water distribution Rheological properties IDF noodles
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Comprehensive utilization of corn starch processing by-products:A review 被引量:5
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作者 Runyang Zhang sen ma +7 位作者 Li Li Minghui Zhang Shuangqi Tian Dongying Wang Kunlun Liu Huamin Liu Wenxue Zhu Xuede Wang 《Grain & Oil Science and Technology》 2021年第3期89-107,I0002,I0003,共21页
Corn is a high starchy cereal crop with the highest production and provides over 85%of the starch produced worldwide.Various by-products,differentiated by technological process features such as steep liquor,corn germ,... Corn is a high starchy cereal crop with the highest production and provides over 85%of the starch produced worldwide.Various by-products,differentiated by technological process features such as steep liquor,corn germ,corn bran,gluten,are created largely during corn starch processing.They are inexpensive,nutrient-rich,and vary widely in chemical composition such as proteins,oils,carbohydrates,and minerals.In an increasingly resource-constrained modern world,the utilization approach of these by-products for non-starch industrial processing is attractive widely considering both nutritive value and economic aspects.In fact,at present,applications of these by-products can often be found in feed,fermentation,nutrient extraction and other industries.For example,protein-rich corn gluten can be used as a good animal feed,and corn germ can be used as a raw material for the high-quality edible oil industry.Undoubtedly,increasing utilization means that these by-products will no longer be treated as waste but will be transformed into high value-added products.In this work,the separation process and chemical composition of several main by-products of the corn starch industry is briefly described,and the application in many industrial fields of these by-products over the last ten years are discussed in particular.This review attempts to summarize all aspects of the application and research of these by-products.For the by-products of the corn starch industry,the most promising way is to be utilized in high value and used to produce high value-added products.According to the characteristics of their chemical composition,they have a better application prospect and research significance in the industries directly related to human beings,such as medicine,green food and health care products.In fact,in recent years,some researchers have recognized this and carried out the research.It is clear fromthese studies that the main issues to be faced nowand in the future are how to produce efficiently while maintaining the quality of the product and using it effectively.The retrospective discussions also provide some ideas for other grain and oilseed crops to be fully utilized. 展开更多
关键词 Corn starch processing By-products UTILIZATION
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Microstructure observation of multilayers separated from wheat bran 被引量:1
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作者 Xiaoling Tian Zhen Wang +5 位作者 Shukai Yang Xiaoxi Wang Li Li Binghua Sun sen ma Shiquan Zheng 《Grain & Oil Science and Technology》 2021年第4期165-173,共9页
In order to understand more clearly the morphology of the structural layers of the soft and hard wheat bran to understand the effect of mechanical force on the wheat grain,we observed the microstructure of each layer ... In order to understand more clearly the morphology of the structural layers of the soft and hard wheat bran to understand the effect of mechanical force on the wheat grain,we observed the microstructure of each layer of the wheat bran from soft and hard mature wheat.Based on the differences in mechanical properties and water permeability of each wheat bran layer,the mature wheat grains were alternately treated under cold and heat conditions and separated by manual dissection.The microstructure of each layer of wheat bran from soft and hard mature wheat was determined by optical and fluorescence microscopy.Seven different structure layers were observed by optical microscopy,named them as epidermis,epicarp,cross cells,tube cells,testa,nucellar layer,and aleurone layer.All the layers of the outer bran of wheat grains were separated,except for the tube cells layer.The autofluorescence imagings of five layers were obtained.It was found that the morphology of the structural layers of the soft and hard wheat bran did not differ much,except for the aleurone layer.The aleurone layer of soft wheat bran was significantly different from that of the hard wheat bran,which is fuller and denser compared to soft wheat.In this study,more aleurone grains were lost in the aleurone layer obtained by the outsidein peeling method.The mastery of the morphology of each structural layer of the bran helps us to quickly quantify the degree of peeling of wheat milling,and to make immediate adjustments to the process.At the same time,we understand that the contents of the aleurone cells have different binding strengths with the nucellar layer and the starchy endosperm.The paper is instructive to deep investigation of wheat milling mechanism and product process refinement. 展开更多
关键词 Wheat bran MICROSTRUCTURE MORPHOLOGY Mechanical property
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Recent advances in quality deterioration and improvement of starch in frozen dough 被引量:1
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作者 Wenjuan Feng sen ma Xiaoxi Wang 《Grain & Oil Science and Technology》 2020年第4期154-163,共10页
Starch with different particle sizes has different compositions and different physical and chemical properties.The amylopectin content and protein content and lipid content of small granule B starch are higher than th... Starch with different particle sizes has different compositions and different physical and chemical properties.The amylopectin content and protein content and lipid content of small granule B starch are higher than that of A-type starch,which can form spiral complex to limit the expansion of starch.Under the same treatment conditions,B-type starch is more vulnerable to damage,sensitive to freezing storage,even breaks in freezing storage,and has higher gelatinization temperature than other starch during freezing.Amylose contained in A-type has high content,high crystallinity,high degree of ordering after frozen storage and insensitivity to frozen storage,which is beneficial to improve the stability of pores and texture of frozen dough.With the extension of freezing time,the content of amylose decreased,while the content of various amylopectin increased and the conformation of polysaccharide changed.Starch deterioration is different under different frozen storage conditions.The deterioration mechanism of frozen dough can be evaluated by variety of starch characteristics during freezing process,which is of great guiding significance to the improvement of frozen dough technology. 展开更多
关键词 Frozen dough Starch structure Poor quality Improved dough technology
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Novel heating technologies to improve fermentation efficiency and quality in wheat products:A short review
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作者 Zhen Wang Jihong Huang +5 位作者 sen ma Xiaoxi Wang Binghua Sun Fengcheng Wang Li Li Qingdan Bao 《Grain & Oil Science and Technology》 2021年第2期81-87,共7页
Identifying novel processing methods is an important research direction in the field of food engineering.Fermented flour products have been popular all over the world for a long time because of their unique flavor and... Identifying novel processing methods is an important research direction in the field of food engineering.Fermented flour products have been popular all over the world for a long time because of their unique flavor and texture.Whether for yeast or sourdough,the accurate temperature control is essential for the fermentation process.Some novel heating methods have shown potential in the processing of fermented flour products.Microwave heating(MWH),radiofrequency heating(RFH),and ohmic heating(OH)are undoubtedly the most promising heating methods.MWH affects the fermentation time of the dough by affecting the water molecules in the dough,and may also improve the fermentation quality of wholewheat flour products.RFH contributes to the control of harmful substances in the fermentation process and has shown potential for the production of sourdough bread.OH has superiority in accurately controlling the temperature,enzymes,microorganisms,etc.in the fermentation process,and it is beneficial to shortening the fermentation time.Researchers have applied these heating methods with different properties to different uses.This article summarized the application and potential of these three novel heating methods in the production of fermented flour products.The application scenarios and parameter settings of novel heating technologies in dough fermentation process need further research.It is reasonable to believe that novel heating methods can become an important tool to improve the efficiency of dough fermentation and the quality of fermented dough in the future. 展开更多
关键词 Microwave heating Radiofrequency heating Ohmic heating Novel heating technology of fermentation
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Effects of milling methods on rheological properties of fermented and non-fermented dough
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作者 Xiaoling Tian Binghua Sun +3 位作者 Xiaoxi Wang sen ma Li Li Xiaojie Qian 《Grain & Oil Science and Technology》 2020年第3期77-86,共10页
The rheological properties of wheat flour are very important for the production of bakery products,and the milling methods greatly influence the rheological properties.In this paper,we measured the particle size distr... The rheological properties of wheat flour are very important for the production of bakery products,and the milling methods greatly influence the rheological properties.In this paper,we measured the particle size distributions,damaged starch contents,granular morphology,and pasting properties of the wheat flour,also carried out the uniaxial elongation test,the texture profile analysis,and rheological properties of the dough to evaluate effects of two milling methods,i.e.impact mill(IM)and hammer mill(HM),on the rheological properties of wheat flour and dough.The results showed that milling methods had no significant effects on flour pasting temperature(except the flour H3 obtained by HM grinding three times)and springiness of dough.Flour samples milled by IM had a lower damaged starch content,higher trough viscosity,higher final viscosity and higher values of setback compared to samples processed by HM.After repeated milling of IM,the damaged starch content of the endosperm granules could be controlled below 1%(P<0.05).There was a gap between H1 and H2 in the elastic modulus value of the non-fermented dough group,and the difference increased after fermentation,which was more obvious in the values of viscosity modulus.The more the milling times,the greater the elastic and viscosity modulus of dough of flour processed by both IM and HM. 展开更多
关键词 Milling methods Particle size distribution Fermented dough Rheological properties
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Parallelizing maximum likelihood classification (MLC) for supervised image classification by pipelined thread approach through high-level synthesis (HLS) on FPGA cluster 被引量:1
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作者 sen ma Xuan Shi David Andrews 《Big Earth Data》 EI 2018年第2期144-158,共15页
High spectral,spatial,vertical and temporal resolution data are increasingly available and result in the serious challenge to pro-cess big remote-sensing images effectively and efficiently.This article introduced how ... High spectral,spatial,vertical and temporal resolution data are increasingly available and result in the serious challenge to pro-cess big remote-sensing images effectively and efficiently.This article introduced how to conduct supervised image classification by implementing maximum likelihood classification(MLC)over big image data on a field programmable gate array(FPGA)cloud.By comparing our prior work of implementing MLC on conventional cluster of multicore computers and graphics processing unit,it can be concluded that FPGAs can achieve the best performance in comparison to conventional CPU cluster and K40 GPU,and are more energy efficient.The proposed pipelined thread approach can be extended to other image-processing solutions to handle big data in the future. 展开更多
关键词 FPGA maximum likelihood classification parallel computing
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Combination of photodynamic therapy and stimulator of interferon genes(STING)agonist inhibits colorectal tumor growth and recurrence
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作者 Yang Hao sen ma +7 位作者 Zili Gu Alireza Haghparast Timo Schomann Zhenfeng Yu Yuanyuan He Xiaoxv Dong Luis J Cruz Peter ten Dijke 《Cancer Communications》 SCIE 2023年第4期513-518,共6页
Dear Editor,Great progress has been made in the clinical use of photodynamic therapy(PDT)for the treatment of patients with superficial tumors[1].However,cancer recurrence and metastasis have limited the application o... Dear Editor,Great progress has been made in the clinical use of photodynamic therapy(PDT)for the treatment of patients with superficial tumors[1].However,cancer recurrence and metastasis have limited the application of PDT in the treatment of solid tumors and advanced cancers.In this context,combining PDT with other complementary immunotherapy regimens may overcome these limitations of PDT[2]. 展开更多
关键词 STIMULATOR SUPERFICIAL clinical
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