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Saturated hydraulic conductivity of compacted bentonite-sand mixtures before and after gas migration in artificial seawater
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作者 Yasutaka Watanabe shingo yokoyama +2 位作者 Misato Shimbashi Yoichi Yamamoto Takahiro Goto 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2023年第1期216-226,共11页
To understand the self-healing property of an engineered barrier for radioactive waste disposal,the hydraulic conductivity of compacted bentoniteesand mixtures saturated with artificial seawater(SW)before and after ga... To understand the self-healing property of an engineered barrier for radioactive waste disposal,the hydraulic conductivity of compacted bentoniteesand mixtures saturated with artificial seawater(SW)before and after gas migration was examined.Na-and Ca-bentonites were mixed with fine sand at a ratio of 70%bentonite in dry weight.Two aspects were considered during the experiment:the hydraulic conductivity of the specimen that was resaturated after gas migration and the distribution of water content immediately after gas migration to study gas migration pathways.The gas migrated through the entire cross-section of the specimen,and gas breakthrough occurred in the equilibrium swelling pressure range approximately.Subsequently,the gas flow rate reached a sufficient large value when the gas pressure was approximately twice the equilibrium axial pressure(the sum of swelling and confining pressures),which excluded the back pressure.Although the gas migration pathway was not visible when the specimen was observed immediately after gas migration,the water content distribution showed that several parts of the specimen with lower water content were connected in the direction of gas migration.After resaturation,the change in permeability was within a limited rangedtwo to three times larger than that before gas migration for each type of bentonite in SW.This slight change suggests that gas migration creates a pore structure that cannot be sealed via crystalline swelling of montmorillonite in SW,even if highly compacted bentonite is used under a constant-volume condition. 展开更多
关键词 BENTONITE Gas migration Hydraulic conductivity Seawater(SW) SELF-HEALING
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热液合成板状高结晶度三八面体蒙脱石
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作者 Hirohisa YAMADA Kenji TAMURA +1 位作者 shingo yokoyama Yujiro WATANABE 《地质学报》 EI CAS CSCD 北大核心 2006年第4期616-616,共1页
关键词 钠基蒙脱石 高结晶度 热液合成 八面体 板状 产物结构 颗粒大小 热液条件 化学组成 合成温度
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Hydrothermal Formation of Lath-Shaped Trioctahedral Smectite with High Crystallinity
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作者 Hirohisa YAMADA Kenji TAMURA +1 位作者 shingo yokoyama Yujiro WATANABE 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2006年第2期290-295,共6页
塑造板条、高度水晶的 trioctahedral 绿土在热水的条件下面被综合。有 stoichiometrically 使脱水的 Na-smectitecompositions 的熄灭的眼镜在(a) 被对待为 1 和 11 天的 500 deg C 和 100 MPa;并且(b) 为 7 天的 300 deg C 和 100MP... 塑造板条、高度水晶的 trioctahedral 绿土在热水的条件下面被综合。有 stoichiometrically 使脱水的 Na-smectitecompositions 的熄灭的眼镜在(a) 被对待为 1 和 11 天的 500 deg C 和 100 MPa;并且(b) 为 7 天的 300 deg C 和 100MPa。产品的 crystallinity 和颗粒大小依赖于热水的处理的开始的玻璃,合成温度和持续时间的化学成分。Thehigh 结构的订和产品的大尺寸从清晰度 ofXRD 山峰被证实;并且在控制相对湿度下面的水和行为。传播电子显微镜学也为产品的颗粒大小的描述被执行。Particlesizes 从 ca 变化。10 nm 到由改变开始的材料的化学成分的一些 nm。产品与最高结构的订和最大的尺寸是 Si_4O_(11 ) 玻璃在 500 deg C 和 100 MPa 对待 1 天的获得的 fromNa_(0.33 )(Mg_(1.83 )AI_(0.67 )) 。Theobtained 结果也以热水的条件在高度水晶的 trioctahedral 绿土的形成证实了元稳定性和组合相关性。 展开更多
关键词 热液合成 蒙脱石 结晶结构 结晶度 水合作用
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