Zabuye Salt Lake(ZSL)in Xizang is the only saline lake in the world with natural crystalline lithium carbonate.As it is an important lithium production base in China,any changes of this lake are concerning.Global clim...Zabuye Salt Lake(ZSL)in Xizang is the only saline lake in the world with natural crystalline lithium carbonate.As it is an important lithium production base in China,any changes of this lake are concerning.Global climate change(CC)has affected the hydrological conditions of glaciers,lakes,and ecosystems in the Tibetan Plateau(TP).With the aim of monitoring dynamic hydrological changes in ZSL and Lunggar Glaciers(LG)to identify factors governing lake changes,and to estimate the potential damage to grasslands and salt pans,Landsat remote sensing(RS)and meteorological data were used to do a series of experiments and analysis.Firstly,according to the spectral characteristics(SC),salt lake,glaciers,grasslands,and salt pans around the salt lake were extracted by band calculation(BC).Secondly,basin and water areas of the expanded lake were estimated using a shuttle radar topography mission(SRTM)digital elevation model(DEM).Thirdly,comprehensive analyses of lake and glacier area changes,and regional meteorological factors(annual average temperature,annual precipitation,and evaporation)were performed,and the results show that ZSL expanded at a rate of 5.28 km^(2)/a,it is likely to continue expanding.Expansion was closely related to the large-scale melting of a glacier caused by rising temperatures.Continued lake expansion(LE)will exert different effects on surrounding grasslands and salt pans,7.84 km^(2)of grassland and 2.7 km^(2)of salt pan will be submerged with every meter of water increase in the lake.Similar prediction methods was used to monitor other lakes on the TP.Mami Co,Selin Co,and Chaerhan salt lakes all expanded at different rates,and may potentially cause different levels of potential harm to surrounding grasslands and roads.Our study contributes to salt lake research and demonstrates the superiority of RS technology for monitoring saline lakes.展开更多
The multispectral commercial satellite-WorldView-3(WV-3) has the highest spatial, spectral and radiation resolutions among the satellites currently and can generate good data in the shortwave infrared(SWIR). The study...The multispectral commercial satellite-WorldView-3(WV-3) has the highest spatial, spectral and radiation resolutions among the satellites currently and can generate good data in the shortwave infrared(SWIR). The study area is located in the Pobei area of Xinjiang Uygur Autonomous Region, which is rich in mineral resources. The spectral analyses of some typical altered hydroxy-bearing, iron-bearing, and carbonate-bearing minerals could establish several Principal Component Analysis(PCA) models and mineral indices, using the visible and near infrared(VNIR) and the shortwave infrared(SWIR) subsystems of WV-3 data. In addition, the Spectral Angle Method and the spectrum index tool of ENVI software were used to extract the relevant alteration information. The WV-3 data is well suited for identifying hydroxy-bearing alteration with rich SWIR bands which distinguish Al-OH-bearing from MgOH-bearing alteration. Hence, this study provides a basis for the prediction of mineral resources in the Pobei area and sets the foundation for WV-3 data to be used as an important tool in extracting alteration information and prospecting practices.展开更多
Fractal and multi-fractal content area method finds application in a wide variety of geological,geochemical and geophysical fields.In this study,the fractal content-gradient method was used on1:10,000 scale to delinea...Fractal and multi-fractal content area method finds application in a wide variety of geological,geochemical and geophysical fields.In this study,the fractal content-gradient method was used on1:10,000 scale to delineate geochemical anomalies associated with copper mineralization.Analysis of geochemical data from the Yangla super large Cu-Pb-Zn polymetallic ore district using the fractal content-gradient method,combined with other geological data from this area,indicates that oreprospecting in the ore district should focus on Cu as the main metal and Pb-Zn and Au as the auxiliary metals.The types of deposits include(in chronological order) re-formed sedimentary exhalative(SEDEX),skarns,porphyries,and hydrothermal vein-type deposits.Three ore-prospecting targets are divided on a S-N basis:(1) the Qulong exploration area,in which the targets are porphyry-type Cu deposits;(2) the Zongya exploration area,where the targets are porphyry-type Cu and hydrothermal vein-type Cu-Pb polymetallic deposits;and(3) the Zarelongma exploration area,characterized mainly skarn-type "Yangla-style" massive sulfide Cu-Pb deposits.Our study demonstrates that the fractal content-gradient method is convenient,simple,rapid,and direct for delineating geochemical anomalies and for outlining potential exploration targets.展开更多
In order to broaden the absorption range of graphitic carbon nitride,one of the common methods is to couple the well-known photosensitizer porphyrin with graphitic carbon nitride through van der Waals weak in teractio...In order to broaden the absorption range of graphitic carbon nitride,one of the common methods is to couple the well-known photosensitizer porphyrin with graphitic carbon nitride through van der Waals weak in teractions.To date,to combine porphyrin with graphitic carbon nitridethrough covalent in teractions has not been settled.In this work,through rational molecular design,we successfully in corporated porphyrininto the matrixes of graphitic carbon nitride by covale nt bonding via on expot thermal copolymerization.The resulta nt material not only can wide nthe absorption range but also possess the enlarged specific surface area and construction intramolecular heterojunctions which can contributeto improve electron-holes separation efficiency.The resultant photocatalyst exhibited enhanced H2 production rate(7.6 mmol·g^-1·h^-1)and withthe apparent quantum efficiency(AQE)of 13.3%at 450 nm.At the same time,this method opens a way to fabricate graphitic carb on nitridenano sheets via bottom-up strategy.展开更多
Nanoparticle photosensitizers possess technical advantages for photocatalytic reactions due to enhanced light harvesting and efficient charge transport.Here we report synthesis of semiconductor nanoparticles through c...Nanoparticle photosensitizers possess technical advantages for photocatalytic reactions due to enhanced light harvesting and efficient charge transport.Here we report synthesis of semiconductor nanoparticles through covalent coupling and assembly of metalloporphyrin with condensed carbon nitride.The resultant nanoparticles consist of light harvesting component from the condensed carbon nitride and photocatalytic sites from the metalloporphyrins.This synergetic particle system effectively initiates efficient charge separation and transport and exhibits excellent photocatalytic activity for CO2 reduction.The CO production rate can reach up to 57μmol/(g·h)with a selectivity of 79%over competing H2 evolution.Controlled experiments demonstrate that the combination of light harvesting with photocatalytic activity via covalent assembly is crucial for the high photocatalytic activity.Due to effective charge separation and transfer,the resultant nanoparticle photocatalysts show exceptional photo stability against photo-corrosion under light irradiation,enabling for long-term utilization.This research opens a new way for the development of stable,effective nanoparticle photocatalysts using naturally abundant porphyrin pigments.展开更多
基金Supported by the Academician Workstation Projects of the Institute of Mineral Resources,Chinese Academy of Geological Sciences(Nos.HE 2205,HE 2206,KK 2012)the National Natural Science Foundation of China(No.42172332)+1 种基金the China Geological Survey Project(No.DD 20221684)the Basic Research Projects of the Institute of Mineral Resources,Chinese Academy of Geological Sciences(No.KK 2102)。
文摘Zabuye Salt Lake(ZSL)in Xizang is the only saline lake in the world with natural crystalline lithium carbonate.As it is an important lithium production base in China,any changes of this lake are concerning.Global climate change(CC)has affected the hydrological conditions of glaciers,lakes,and ecosystems in the Tibetan Plateau(TP).With the aim of monitoring dynamic hydrological changes in ZSL and Lunggar Glaciers(LG)to identify factors governing lake changes,and to estimate the potential damage to grasslands and salt pans,Landsat remote sensing(RS)and meteorological data were used to do a series of experiments and analysis.Firstly,according to the spectral characteristics(SC),salt lake,glaciers,grasslands,and salt pans around the salt lake were extracted by band calculation(BC).Secondly,basin and water areas of the expanded lake were estimated using a shuttle radar topography mission(SRTM)digital elevation model(DEM).Thirdly,comprehensive analyses of lake and glacier area changes,and regional meteorological factors(annual average temperature,annual precipitation,and evaporation)were performed,and the results show that ZSL expanded at a rate of 5.28 km^(2)/a,it is likely to continue expanding.Expansion was closely related to the large-scale melting of a glacier caused by rising temperatures.Continued lake expansion(LE)will exert different effects on surrounding grasslands and salt pans,7.84 km^(2)of grassland and 2.7 km^(2)of salt pan will be submerged with every meter of water increase in the lake.Similar prediction methods was used to monitor other lakes on the TP.Mami Co,Selin Co,and Chaerhan salt lakes all expanded at different rates,and may potentially cause different levels of potential harm to surrounding grasslands and roads.Our study contributes to salt lake research and demonstrates the superiority of RS technology for monitoring saline lakes.
基金supported by the “Iron and manganese resources investigation projection” from the Chinese Academy of Geological Sciences(Grant No.12120115037901)
文摘The multispectral commercial satellite-WorldView-3(WV-3) has the highest spatial, spectral and radiation resolutions among the satellites currently and can generate good data in the shortwave infrared(SWIR). The study area is located in the Pobei area of Xinjiang Uygur Autonomous Region, which is rich in mineral resources. The spectral analyses of some typical altered hydroxy-bearing, iron-bearing, and carbonate-bearing minerals could establish several Principal Component Analysis(PCA) models and mineral indices, using the visible and near infrared(VNIR) and the shortwave infrared(SWIR) subsystems of WV-3 data. In addition, the Spectral Angle Method and the spectrum index tool of ENVI software were used to extract the relevant alteration information. The WV-3 data is well suited for identifying hydroxy-bearing alteration with rich SWIR bands which distinguish Al-OH-bearing from MgOH-bearing alteration. Hence, this study provides a basis for the prediction of mineral resources in the Pobei area and sets the foundation for WV-3 data to be used as an important tool in extracting alteration information and prospecting practices.
基金supported by the fund"Metallogenic Geodynamic Background,Process and Quantitative Evaluation of Super Large Fe-Cu Polymetallic Deposits,Qinghai Qimantag Area"(Grant No.1212011220929)from Beijing Key Laboratory of Land Resources Information Research and Development,China University of Geosciences,Beijing
文摘Fractal and multi-fractal content area method finds application in a wide variety of geological,geochemical and geophysical fields.In this study,the fractal content-gradient method was used on1:10,000 scale to delineate geochemical anomalies associated with copper mineralization.Analysis of geochemical data from the Yangla super large Cu-Pb-Zn polymetallic ore district using the fractal content-gradient method,combined with other geological data from this area,indicates that oreprospecting in the ore district should focus on Cu as the main metal and Pb-Zn and Au as the auxiliary metals.The types of deposits include(in chronological order) re-formed sedimentary exhalative(SEDEX),skarns,porphyries,and hydrothermal vein-type deposits.Three ore-prospecting targets are divided on a S-N basis:(1) the Qulong exploration area,in which the targets are porphyry-type Cu deposits;(2) the Zongya exploration area,where the targets are porphyry-type Cu and hydrothermal vein-type Cu-Pb polymetallic deposits;and(3) the Zarelongma exploration area,characterized mainly skarn-type "Yangla-style" massive sulfide Cu-Pb deposits.Our study demonstrates that the fractal content-gradient method is convenient,simple,rapid,and direct for delineating geochemical anomalies and for outlining potential exploration targets.
文摘In order to broaden the absorption range of graphitic carbon nitride,one of the common methods is to couple the well-known photosensitizer porphyrin with graphitic carbon nitride through van der Waals weak in teractions.To date,to combine porphyrin with graphitic carbon nitridethrough covalent in teractions has not been settled.In this work,through rational molecular design,we successfully in corporated porphyrininto the matrixes of graphitic carbon nitride by covale nt bonding via on expot thermal copolymerization.The resulta nt material not only can wide nthe absorption range but also possess the enlarged specific surface area and construction intramolecular heterojunctions which can contributeto improve electron-holes separation efficiency.The resultant photocatalyst exhibited enhanced H2 production rate(7.6 mmol·g^-1·h^-1)and withthe apparent quantum efficiency(AQE)of 13.3%at 450 nm.At the same time,this method opens a way to fabricate graphitic carb on nitridenano sheets via bottom-up strategy.
基金E B.acknowledges the support from the National Natural Science Foundation of China(Nos.21771055 and U1604139)Zhongyuan high level talents special support plan(No.204200510010)Scientific and Technological Innovation Team in University of Henan Province(No.20IRTSTHN001).
文摘Nanoparticle photosensitizers possess technical advantages for photocatalytic reactions due to enhanced light harvesting and efficient charge transport.Here we report synthesis of semiconductor nanoparticles through covalent coupling and assembly of metalloporphyrin with condensed carbon nitride.The resultant nanoparticles consist of light harvesting component from the condensed carbon nitride and photocatalytic sites from the metalloporphyrins.This synergetic particle system effectively initiates efficient charge separation and transport and exhibits excellent photocatalytic activity for CO2 reduction.The CO production rate can reach up to 57μmol/(g·h)with a selectivity of 79%over competing H2 evolution.Controlled experiments demonstrate that the combination of light harvesting with photocatalytic activity via covalent assembly is crucial for the high photocatalytic activity.Due to effective charge separation and transfer,the resultant nanoparticle photocatalysts show exceptional photo stability against photo-corrosion under light irradiation,enabling for long-term utilization.This research opens a new way for the development of stable,effective nanoparticle photocatalysts using naturally abundant porphyrin pigments.
