The primary cause of the decrease in thermal conductivity of conventional thermal conductive magnesium alloys is electron scattering brought on by solute atoms.However,the impact of phase interface on thermal conducti...The primary cause of the decrease in thermal conductivity of conventional thermal conductive magnesium alloys is electron scattering brought on by solute atoms.However,the impact of phase interface on thermal conductivity of magnesium alloys is usually disregarded.This study has developed a Mg-Si-Zn-Cu alloy with high thermal conductivity that is distinguished by having a very low solute atom content and a significant number of phase interfaces.The thermal conductivity of the Mg^(-1).38Si-0.5Zn-0.5Cu alloy raises from its untreated value of 133.2 W/(m·K)to 142.2 W/(m·K),which is 91%of the thermal conductivity of pure Mg.This is accomplished by subjecting the alloy to both 0.8wt%Ce modification and T6 heat treatment.The morphology of eutectic Mg_(2)Si phase is changed by Ce modification and heat treatment,and as a result,the scattering of electrons at the Mg_(2)Si/Mg interface is reduced,resulting in increase of the alloy’s thermal conductivity.展开更多
In this paper, the effects of pouring temperature of magnesium melt, preheating temperature of the barrel of the screw mixer, and shear rate on the solidified microstructures of semi-solid slurry were investigated by ...In this paper, the effects of pouring temperature of magnesium melt, preheating temperature of the barrel of the screw mixer, and shear rate on the solidified microstructures of semi-solid slurry were investigated by a mechanical stirring semi-solid process. The appropriate processing parameters of slurry preparation were obtained, and the mold filling ability of semi-solid slurry for thin-walled casting was examined. Results indicate that the solid volume fraction of non-dendritic microstructure increases with a decrease in pouring temperature of magnesium melt and the barrel preheating temperature of the screw mixer. Also the grain size of primary α-phase is reduced. Furthermore, the solid volume fraction of semi-solid nondendritic structure decreases with an increase of shear rate. The fine and round granular microstructure with 30~50 μm in size of semi-solid AZ91D magnesium alloy was presented. Finally, a 1.0 mm thin-walled casting with a clear contour and good soundness was successfully made by semi-solid rheo-diecasting.展开更多
In this work, an efficient process by diluting the nano-SiCp/Al composite granules in the molten matrix under ultrasonic vibration(UV) was developed to prepare metal matrix nano-composites(MMNCs).Millimeter-sized ...In this work, an efficient process by diluting the nano-SiCp/Al composite granules in the molten matrix under ultrasonic vibration(UV) was developed to prepare metal matrix nano-composites(MMNCs).Millimeter-sized composite granules with high content of SiC particle(8 wt%) were specially fabricated by dry high-energy ball milling(HBM) without process control agent, and then remelted and diluted in molten Al alloy under UV. The MMNCs melt was finally squeeze cast under a squeeze pressure of 200 MPa, Microstructure of the composite granules during dry HBM was investigated, and the effect of UV on microstructure and mechanical properties of the MMNCs was discussed. The results indicate that nano-SiC particles are uniformly distributed in the nano-SiCp/Al composite granules, which are covered by vestures of pure Al. During diluting, nano-SiC particles released from the composite granules are quickly dispersed in the molten matrix by UV within 4 min. Microstructure of MMNCs is significantly refined under UV and squeeze casting, eutectic Si phase modified to fine islands with an average length of 1.4 μm. Tensile strength of the squeeze cast MMNCs with 1 wt% of nano-SiC particles is 269 MPa, which is improved by 25% compared with the A356 alloy matrix.展开更多
In this research, the in situ Si and Fe-rich particles reinforced Al matrix composites were fabricated by rheocasting (RC) process assisted with ultrasonic vibration (USV). After USV treatment, the polygonal prima...In this research, the in situ Si and Fe-rich particles reinforced Al matrix composites were fabricated by rheocasting (RC) process assisted with ultrasonic vibration (USV). After USV treatment, the polygonal primary Si crystals were refined into particles with average diameter of about 15-23 μm, and the fraction of primary Si declined to about 5.4-6.5 vol%. The coarse plate-like δ-Al4(Fe,Mn)Si2 phase was transformed into fine particles with average diameter of about 17-20 μm, and the fraction of particle-like Fe-bearing particles is about 3.6-5.3 vol%. The ultimate tensile strength of the RC composites increases with the increase of Fe content at 350 ℃. The increase of the elevated temperature strength of the composites is mainly attributed to the refinement of δ-Al4((Fe,Mn)Si2 phase and the increase of the volume fraction of the Fe-bearing compounds. Compared with the composites without USV, the RC composites assisted with USV have thinner mechanical mixing layer in wear test, which corresponds to smaller wear rate.展开更多
基金supported by NationalNatural Science Foundation of China(52175321).
文摘The primary cause of the decrease in thermal conductivity of conventional thermal conductive magnesium alloys is electron scattering brought on by solute atoms.However,the impact of phase interface on thermal conductivity of magnesium alloys is usually disregarded.This study has developed a Mg-Si-Zn-Cu alloy with high thermal conductivity that is distinguished by having a very low solute atom content and a significant number of phase interfaces.The thermal conductivity of the Mg^(-1).38Si-0.5Zn-0.5Cu alloy raises from its untreated value of 133.2 W/(m·K)to 142.2 W/(m·K),which is 91%of the thermal conductivity of pure Mg.This is accomplished by subjecting the alloy to both 0.8wt%Ce modification and T6 heat treatment.The morphology of eutectic Mg_(2)Si phase is changed by Ce modification and heat treatment,and as a result,the scattering of electrons at the Mg_(2)Si/Mg interface is reduced,resulting in increase of the alloy’s thermal conductivity.
文摘In this paper, the effects of pouring temperature of magnesium melt, preheating temperature of the barrel of the screw mixer, and shear rate on the solidified microstructures of semi-solid slurry were investigated by a mechanical stirring semi-solid process. The appropriate processing parameters of slurry preparation were obtained, and the mold filling ability of semi-solid slurry for thin-walled casting was examined. Results indicate that the solid volume fraction of non-dendritic microstructure increases with a decrease in pouring temperature of magnesium melt and the barrel preheating temperature of the screw mixer. Also the grain size of primary α-phase is reduced. Furthermore, the solid volume fraction of semi-solid nondendritic structure decreases with an increase of shear rate. The fine and round granular microstructure with 30~50 μm in size of semi-solid AZ91D magnesium alloy was presented. Finally, a 1.0 mm thin-walled casting with a clear contour and good soundness was successfully made by semi-solid rheo-diecasting.
基金financially supported by the National Natural Science Foundation of China (Grant No. 51574129)
文摘In this work, an efficient process by diluting the nano-SiCp/Al composite granules in the molten matrix under ultrasonic vibration(UV) was developed to prepare metal matrix nano-composites(MMNCs).Millimeter-sized composite granules with high content of SiC particle(8 wt%) were specially fabricated by dry high-energy ball milling(HBM) without process control agent, and then remelted and diluted in molten Al alloy under UV. The MMNCs melt was finally squeeze cast under a squeeze pressure of 200 MPa, Microstructure of the composite granules during dry HBM was investigated, and the effect of UV on microstructure and mechanical properties of the MMNCs was discussed. The results indicate that nano-SiC particles are uniformly distributed in the nano-SiCp/Al composite granules, which are covered by vestures of pure Al. During diluting, nano-SiC particles released from the composite granules are quickly dispersed in the molten matrix by UV within 4 min. Microstructure of MMNCs is significantly refined under UV and squeeze casting, eutectic Si phase modified to fine islands with an average length of 1.4 μm. Tensile strength of the squeeze cast MMNCs with 1 wt% of nano-SiC particles is 269 MPa, which is improved by 25% compared with the A356 alloy matrix.
基金financially supported by the National Basic Research Program of China (No.2012CB619600)the Fundamental Research Funds for the Central Universities (No.2014QNRC003)
文摘In this research, the in situ Si and Fe-rich particles reinforced Al matrix composites were fabricated by rheocasting (RC) process assisted with ultrasonic vibration (USV). After USV treatment, the polygonal primary Si crystals were refined into particles with average diameter of about 15-23 μm, and the fraction of primary Si declined to about 5.4-6.5 vol%. The coarse plate-like δ-Al4(Fe,Mn)Si2 phase was transformed into fine particles with average diameter of about 17-20 μm, and the fraction of particle-like Fe-bearing particles is about 3.6-5.3 vol%. The ultimate tensile strength of the RC composites increases with the increase of Fe content at 350 ℃. The increase of the elevated temperature strength of the composites is mainly attributed to the refinement of δ-Al4((Fe,Mn)Si2 phase and the increase of the volume fraction of the Fe-bearing compounds. Compared with the composites without USV, the RC composites assisted with USV have thinner mechanical mixing layer in wear test, which corresponds to smaller wear rate.