The conversion of rapeseed straw into biochar not only effectively mitigates pollution from traditional straw burning but also aligns with China’s sustainable agricultural development goals. A significant quantity of...The conversion of rapeseed straw into biochar not only effectively mitigates pollution from traditional straw burning but also aligns with China’s sustainable agricultural development goals. A significant quantity of rapeseed stalks is frequently burned in fields, leading to severe air pollution characterized by black smoke and residue, resulting in a substantial waste of straw resources. To address this issue, rapeseed straw form Nanchi Village, Puzhen Town, Hanzhong City, Shaanxi Province, was utilized as a precursor and KOH was employed as an activator to produce porous activated carbon by pyrolysis. Scanning electron microscopy (SEM), elemental analyzer, infrared spectroscopy, specific surface area analysis, and other instruments were employed to characterize the porous activated carbon produced under various temperature gradients and activator concentrations. The microelement composition, structure, specific surface area, and pore size of biochar produced under varying conditions were analyzed to determine the optimal preparation parameters. Furthermore, the adsorption efficiency for tetracycline in wastewater was evaluated using a three-factor, three-level orthogonal experimental design. The results showed that the interior of the activated carbon was porous, while the exterior contained oxygenated functional groups that facilitated the adsorption of nitrogen, phosphorus, and other elements. The optimal carbonization temperature and KOH concentration for activated carbon were determined to be 400°C and 0.5, respectively. The optimal adsorption conditions were identified as pH value of 7, an initial tetracycline concentration of 30 mg/L, a biochar dosage of 0.2 g, an adsorption time of 60 min, and a removal rate of 98.53%. The factors influencing the adsorption of tetracycline onto rapeseed straw biochar were ranked as initial tetracycline concentration>adsorption reaction time>biochar dasage. The findings will provide valuable references for research on biochar performance and the treatment of tetracycline contamination in water.展开更多
Optimization of water and fertilizer coupling management approaches could not only increase apple yield and quality,but also reduce the potential negative impacts of such management activities on the environment.The a...Optimization of water and fertilizer coupling management approaches could not only increase apple yield and quality,but also reduce the potential negative impacts of such management activities on the environment.The aim of the present study was to determine the optimal water-nitrogen(WN)coupling management strategy in an apple orchard in the Weibei Dryland,Shaanxi Province,China,under limited irrigation.A randomized complete block design was adopted to test the effects of three drip irrigation levels(W1,300 m^(3)/hm^(2);W2,600 m^(3)/hm^(2);W3,900 m^(3)/hm^(2))and four N application levels(N0,0 kg/hm^(2);N1,200 kg/hm^(2);N2,400 kg/hm^(2);and N3,600 kg/hm^(2))on N distribution in the 0-100 cm soil profile.Apple yield and economic benefits under different treatments were also evaluated over a three-year period(2012-2014).Compared with the N0W1 treatment,soil N contents were higher and exhibited distinct trends in the soil profile under other treatments.Overall,total N contents exhibited a downward trend from the surface to the subsurface layers(0.11-2.34 g/kg);however,the total N contents of the lower soil layer increased with an increase in irrigation amount.NO_(3)-N contents were the lowest in the 40-60 cm soil layer and then increased with an increase in soil depth.The highest NO_(3)-N contents of different soil layers were observed under the N3W3 treatment,ranging from 124.7 mg/kg(0-20 cm)to 90.9 mg/kg(80-100 cm).NH_(4)^(+)-N contents were low(<10 mg/kg),mainly accumulating in the surface layer and decreasing toward the deeper layers>20 cm.Different water-N coupling treatments also increased apple yield by 7.30%-41.62%when compared with the N0W1 treatment.The highest apple yield(three-year mean:41.01 t/hm^(2))was observed under the N2W2 treatment,with an output value of 237900 RMB yuan/hm^(2) and a net income of 232000 RMB yuan/hm^(2).Considering fruit yield,partial productivity of N fertilizer,and economic and environmental benefits,the N2W2 treatment is the optimal water-N fertilizer coupling drip irrigation scheme for apple production in the study area and other similar dryland areas.展开更多
基金supported by the Key Research and Development Program of Shaanxi Province,China(Grant No.2024NC-YBXM-258,2023-YBNY-272)the Scientific Research Project of City-University Co-construction of Shaanxi Province for State Key Laboratory of Qinba Bio-Resource and Ecological Environment(Grant No.SXC-2108,SXJ-2304).
文摘The conversion of rapeseed straw into biochar not only effectively mitigates pollution from traditional straw burning but also aligns with China’s sustainable agricultural development goals. A significant quantity of rapeseed stalks is frequently burned in fields, leading to severe air pollution characterized by black smoke and residue, resulting in a substantial waste of straw resources. To address this issue, rapeseed straw form Nanchi Village, Puzhen Town, Hanzhong City, Shaanxi Province, was utilized as a precursor and KOH was employed as an activator to produce porous activated carbon by pyrolysis. Scanning electron microscopy (SEM), elemental analyzer, infrared spectroscopy, specific surface area analysis, and other instruments were employed to characterize the porous activated carbon produced under various temperature gradients and activator concentrations. The microelement composition, structure, specific surface area, and pore size of biochar produced under varying conditions were analyzed to determine the optimal preparation parameters. Furthermore, the adsorption efficiency for tetracycline in wastewater was evaluated using a three-factor, three-level orthogonal experimental design. The results showed that the interior of the activated carbon was porous, while the exterior contained oxygenated functional groups that facilitated the adsorption of nitrogen, phosphorus, and other elements. The optimal carbonization temperature and KOH concentration for activated carbon were determined to be 400°C and 0.5, respectively. The optimal adsorption conditions were identified as pH value of 7, an initial tetracycline concentration of 30 mg/L, a biochar dosage of 0.2 g, an adsorption time of 60 min, and a removal rate of 98.53%. The factors influencing the adsorption of tetracycline onto rapeseed straw biochar were ranked as initial tetracycline concentration>adsorption reaction time>biochar dasage. The findings will provide valuable references for research on biochar performance and the treatment of tetracycline contamination in water.
基金financially supported by the Key Research and Development Program of Shaanxi Province,China(Grant No.2019NY-202)the Research Foundation of Education Bureau of Shaanxi Province,China(Grant No.19JS012)the Scientific Research Project of City-University Co-construction of Shaanxi Province for State Key Laboratory of Qinba Bio-Resource and Ecological Environment(SXC-2108).
文摘Optimization of water and fertilizer coupling management approaches could not only increase apple yield and quality,but also reduce the potential negative impacts of such management activities on the environment.The aim of the present study was to determine the optimal water-nitrogen(WN)coupling management strategy in an apple orchard in the Weibei Dryland,Shaanxi Province,China,under limited irrigation.A randomized complete block design was adopted to test the effects of three drip irrigation levels(W1,300 m^(3)/hm^(2);W2,600 m^(3)/hm^(2);W3,900 m^(3)/hm^(2))and four N application levels(N0,0 kg/hm^(2);N1,200 kg/hm^(2);N2,400 kg/hm^(2);and N3,600 kg/hm^(2))on N distribution in the 0-100 cm soil profile.Apple yield and economic benefits under different treatments were also evaluated over a three-year period(2012-2014).Compared with the N0W1 treatment,soil N contents were higher and exhibited distinct trends in the soil profile under other treatments.Overall,total N contents exhibited a downward trend from the surface to the subsurface layers(0.11-2.34 g/kg);however,the total N contents of the lower soil layer increased with an increase in irrigation amount.NO_(3)-N contents were the lowest in the 40-60 cm soil layer and then increased with an increase in soil depth.The highest NO_(3)-N contents of different soil layers were observed under the N3W3 treatment,ranging from 124.7 mg/kg(0-20 cm)to 90.9 mg/kg(80-100 cm).NH_(4)^(+)-N contents were low(<10 mg/kg),mainly accumulating in the surface layer and decreasing toward the deeper layers>20 cm.Different water-N coupling treatments also increased apple yield by 7.30%-41.62%when compared with the N0W1 treatment.The highest apple yield(three-year mean:41.01 t/hm^(2))was observed under the N2W2 treatment,with an output value of 237900 RMB yuan/hm^(2) and a net income of 232000 RMB yuan/hm^(2).Considering fruit yield,partial productivity of N fertilizer,and economic and environmental benefits,the N2W2 treatment is the optimal water-N fertilizer coupling drip irrigation scheme for apple production in the study area and other similar dryland areas.
