Sorbitol,triethanolamine,sodium benzoate,boric acid,and sodium carbonate were mixed to prepare a waterborne rust inhibitor.A temperature and humidity accelerated corrosion test was applied to investigate the corrosion...Sorbitol,triethanolamine,sodium benzoate,boric acid,and sodium carbonate were mixed to prepare a waterborne rust inhibitor.A temperature and humidity accelerated corrosion test was applied to investigate the corrosion behaviour of waterborne rust inhibitor coated Q235 steel and original Q235 steel,which was carried out in a temperature and humidity test chamber(WSHW-1000)at a temperature of 80℃and humidity of 95%.Compared with the original Q235,waterborne rust inhibitor coated Q235 has better resistance to corrosion in hot and humid ambient conditions.Electrochemical impedance spectroscopy and potentiodynamic polarization were measured with a three-electrode cell in 3.5%NaCl aqueous solution on a CHI760E potentiostat/galvanostat.Molecular dynamics was simulated to verify the synergistic corrosion inhibitory mechanism of sodium carbonate and triethanolamine.The test shows that the prepared waterborne rust inhibitor can reduce the tendency of Q235 to corrosion and can also effectively reduce the corrosion rate.展开更多
In Northeast China during the winter, severe snowstorms can occur resulting in both societal and economic damage. In this paper, we explore an effective technique for the seasonal prediction of heavy snow activity, wh...In Northeast China during the winter, severe snowstorms can occur resulting in both societal and economic damage. In this paper, we explore an effective technique for the seasonal prediction of heavy snow activity, where previous synoptic studies have failed. We employ a year-to-year increment approach and ultimately identify four predictors, x1 to x4 . x1 is the area-averaged soil moisture over the northern part of Northeast China in the preceding month of September and represents the role of land processes. x2 represents the role of sea-air interactions in winter, x3 the preceding summer Mascarene High related to the winter SST over the tropical western Pacific, and x4 is the low-level the thermal condition over Northeast China from the previous year that oppose current year. Cross-validation tests for both 1963-2011 and independent hindcasts between 1983-2010 are performed to validate the prediction ability of our technique. The cross validation test results for 1963-2011 reveal a high correlation coefficient of 0.86 (0.77) between the predicted and observed year-to-year increment of the number of snow days. The model also predicts well the independent hindcast for the years 1983-2011. Therefore, this study provides an effective climate prediction model for Northeast China's heavy snow activities and thus requires preliminary application in operational settings.展开更多
Based on the evaluation of state-of-the-art coupled ocean-atmosphere general circulation models （CGCMs） from the ENSEMBLES （Ensemble-based Predictions of Climate Changes and Their Impacts） and DEME- TER （Developm...Based on the evaluation of state-of-the-art coupled ocean-atmosphere general circulation models （CGCMs） from the ENSEMBLES （Ensemble-based Predictions of Climate Changes and Their Impacts） and DEME- TER （Development of a European Multimodel Ensemble System for Seasonal to Interannual Prediction） projects, it is found that the prediction of the South China Sea summer monsoon （SCSSM） has improved since the late 1970s. These CGCMs show better skills in prediction of the atmospheric circulation and precipitation within the SCSSM domain during 1979-2005 than that during 1960-1978. Possible reasons for this improvement are investigated. First, the relationship between the SSTs over the tropical Pacific, North Pacific and tropical Indian Ocean, and SCSSM has intensified since the late 1970s. Meanwhile, the SCSSM-related SSTs, with their larger amplitude of interannual variability, have been better predicted. Moreover, the larger amplitude of the interannual variability of the SCSSM and improved initializations for CGCMs after the late 1970s contribute to the better prediction of the SCSSM. In addition, considering that the CGCMs have certain limitations in SCSSM rainfall prediction, we applied the year-to-year increment approach to these CGCMs from the DEMETER and ENSEMBLES projects to improve the prediction of SCSSM rainfall before and after the late 1970s.展开更多
基金Funded by Key Scientific Research Projects Plan of Henan Higher Education Institutions(No.19A460025)National Natural Science Foundation of China(No.51809127)。
文摘Sorbitol,triethanolamine,sodium benzoate,boric acid,and sodium carbonate were mixed to prepare a waterborne rust inhibitor.A temperature and humidity accelerated corrosion test was applied to investigate the corrosion behaviour of waterborne rust inhibitor coated Q235 steel and original Q235 steel,which was carried out in a temperature and humidity test chamber(WSHW-1000)at a temperature of 80℃and humidity of 95%.Compared with the original Q235,waterborne rust inhibitor coated Q235 has better resistance to corrosion in hot and humid ambient conditions.Electrochemical impedance spectroscopy and potentiodynamic polarization were measured with a three-electrode cell in 3.5%NaCl aqueous solution on a CHI760E potentiostat/galvanostat.Molecular dynamics was simulated to verify the synergistic corrosion inhibitory mechanism of sodium carbonate and triethanolamine.The test shows that the prepared waterborne rust inhibitor can reduce the tendency of Q235 to corrosion and can also effectively reduce the corrosion rate.
基金supported by the National Basic Research Program of China (2009CB421406)the Knowledge Innovation Key Program of the Chinese Academy of Sciences (KZCX2-YW-QN202)Strategic Technological Program of Chinese Academy of Sciences (XDA05090426)
文摘In Northeast China during the winter, severe snowstorms can occur resulting in both societal and economic damage. In this paper, we explore an effective technique for the seasonal prediction of heavy snow activity, where previous synoptic studies have failed. We employ a year-to-year increment approach and ultimately identify four predictors, x1 to x4 . x1 is the area-averaged soil moisture over the northern part of Northeast China in the preceding month of September and represents the role of land processes. x2 represents the role of sea-air interactions in winter, x3 the preceding summer Mascarene High related to the winter SST over the tropical western Pacific, and x4 is the low-level the thermal condition over Northeast China from the previous year that oppose current year. Cross-validation tests for both 1963-2011 and independent hindcasts between 1983-2010 are performed to validate the prediction ability of our technique. The cross validation test results for 1963-2011 reveal a high correlation coefficient of 0.86 (0.77) between the predicted and observed year-to-year increment of the number of snow days. The model also predicts well the independent hindcast for the years 1983-2011. Therefore, this study provides an effective climate prediction model for Northeast China's heavy snow activities and thus requires preliminary application in operational settings.
基金Supported by the National Natural Science Foundation of China(41421004,41325018,and 41575079)State Administration for Foreign Expert Affairs of the Chinses Academy of Sciences(CAS/SAFEA)
文摘Based on the evaluation of state-of-the-art coupled ocean-atmosphere general circulation models （CGCMs） from the ENSEMBLES （Ensemble-based Predictions of Climate Changes and Their Impacts） and DEME- TER （Development of a European Multimodel Ensemble System for Seasonal to Interannual Prediction） projects, it is found that the prediction of the South China Sea summer monsoon （SCSSM） has improved since the late 1970s. These CGCMs show better skills in prediction of the atmospheric circulation and precipitation within the SCSSM domain during 1979-2005 than that during 1960-1978. Possible reasons for this improvement are investigated. First, the relationship between the SSTs over the tropical Pacific, North Pacific and tropical Indian Ocean, and SCSSM has intensified since the late 1970s. Meanwhile, the SCSSM-related SSTs, with their larger amplitude of interannual variability, have been better predicted. Moreover, the larger amplitude of the interannual variability of the SCSSM and improved initializations for CGCMs after the late 1970s contribute to the better prediction of the SCSSM. In addition, considering that the CGCMs have certain limitations in SCSSM rainfall prediction, we applied the year-to-year increment approach to these CGCMs from the DEMETER and ENSEMBLES projects to improve the prediction of SCSSM rainfall before and after the late 1970s.
