The ruthenium hydrido-carbonyl cluster in NaY zeolite,synthesized by the reaction of Ru3(CO)(12)/NaY with hydrogen,was characterized by FTIR,UV-VIS and EXAFS spectroscopies.
Ru111(NH3)6 in the cages of NaX zeolite was converted in the presence of CO+H2 into [Ru6(CO)18]2-, which was characterized by in-situ FTIR, UV-VIS and EXAFS spectroscopies. The material derived from [Ru6(CO)18]2-/NaX ...Ru111(NH3)6 in the cages of NaX zeolite was converted in the presence of CO+H2 into [Ru6(CO)18]2-, which was characterized by in-situ FTIR, UV-VIS and EXAFS spectroscopies. The material derived from [Ru6(CO)18]2-/NaX exhibited high calalytic activity in n-butane hydrogenolysis.展开更多
文摘The ruthenium hydrido-carbonyl cluster in NaY zeolite,synthesized by the reaction of Ru3(CO)(12)/NaY with hydrogen,was characterized by FTIR,UV-VIS and EXAFS spectroscopies.
文摘Ru111(NH3)6 in the cages of NaX zeolite was converted in the presence of CO+H2 into [Ru6(CO)18]2-, which was characterized by in-situ FTIR, UV-VIS and EXAFS spectroscopies. The material derived from [Ru6(CO)18]2-/NaX exhibited high calalytic activity in n-butane hydrogenolysis.
