The distribution and verticals variation of geochemical components in the Kasnau-Matasukh lignites of Nagaur Basin, Rajasthan, were investigated using microscopy, proximate and ultimate analyses, Rock-Eval Pyrolysis, ...The distribution and verticals variation of geochemical components in the Kasnau-Matasukh lignites of Nagaur Basin, Rajasthan, were investigated using microscopy, proximate and ultimate analyses, Rock-Eval Pyrolysis, X-ray diffraction and Fourier Transform Infrared analyses, and major/minor/trace element determination. The relationship of elements with ash content and with macerals have also been discussed. These lignites are stratified, black, dominantly composed of huminite group macerals with subordinated amounts of liptinite and inertinite groups. They are classified as type-III kerogen and are mainly gas prone in nature. The concentration （in vol%） of mineral matter is seen to increase towards upper part of seam and so is the concentration （in wt%） of the volatile matter, elemental carbon and sulphur. The common minerals present in these lignitesare mixed clay layer, chlorite, and quartz as identified by X-ray diffraction study. Compared with world average in brown coal, the bulk concentration of Cu is anomalously high in most of the samples while Cd is 2-3 times high and Zn is high in one band. Based on interrelationship, different pyrite forms are noticed to have different preferential enrichment of various elements. The concentration of disseminated pyrite is more than the other pyrite forms and is followed by discrete pyrite grains and massive pyrite.展开更多
The present paper entails the results of the investigations carried out on the lignite deposits of Kachchh Basin. The lignite samples were drawn from five lignite seams from Panandhro lignite field （Seam-I to -V） an...The present paper entails the results of the investigations carried out on the lignite deposits of Kachchh Basin. The lignite samples were drawn from five lignite seams from Panandhro lignite field （Seam-I to -V） and eight lignite seams （Seam-I to -VIII） from the Matanomadh lignite field which are currently operational. The petrographic analysis of the lignites indicates a dominance of huminite group of macerals which is mainly contributed by ulminite-A, ulminite-B, attrinite, densinite, and phlobaphinite. Liptinite （chiefly sporinite, cutinite, resinite, and liptodetrinite） and inertinite （chiefly fusinite, funginite, and inertodetrinite） groups occur in subordinated amount. The mineral matter occurs in moderate concentration. Though sulfur content is high in these lignites, there is no fixed trend of variation of sulfur from bottom seam to top seam. The investigation reveals a flooded forest swamp having high rate of degradation. However, there were a few drier periods indicated by relatively more inertinite macerals. The petrography-based models indicate that the Kachchh lignites of Gujarat evolved in coastal marshy setting under transgressive phase. However, there were few intermittent fluvial activities giving rise to supratidal flood plain. This led to the formation of the associated carbonaceous shales in the basin.展开更多
Lignite samples collected from Vastan, Rajpardi and Tadkeshwar lignite mines of Cambay basin （Gujarat） were subjected to organic petrographic investigations and geochemical analyses and the data, thus generated, is ...Lignite samples collected from Vastan, Rajpardi and Tadkeshwar lignite mines of Cambay basin （Gujarat） were subjected to organic petrographic investigations and geochemical analyses and the data, thus generated, is used to reconstruct the paleodepositional history of these lignite sequences. The lignites of Cambay basin dominantly comprise huminite maceral group （71.6%-86.3%） followed by liptinite （10.1%-19.3%） and inertinite （3.6%-11.0%） maceral groups. The mineral matter varies from 9.0% to 20.0%. The petrography based facies model indicates that these lignites have high values of gelification index （GI） and low tissue preservation index revealing a continuous wet condition in the basin and a relatively slower rate of subsidence during the decay of organic matter. On several occasions, during the formation of seams in Tadkeshwar, Rajpardi and Vastan mines, the value of GI exceeded 10 which indicates a forest permanently flooded and the cause of pronounced degree of degradation. However, few sections in Tadkeshwar seam had relatively drier spells of environmental conditions due to fluctuation in the water table as revealed by moderately high content of inertinite macerals. This is specially indicated by the occurrence of funginite which normally thrives in the upper oxy- genated peatigenic layer and indicates prevalence of oxic conditions during plant deposition. Such conditions prevailed during a transgressive phase but there were intermittent fluvial activities also giving rise to supratidal flood plain as reflected in the form of associated carbonaceous shales in the basin.展开更多
文摘The distribution and verticals variation of geochemical components in the Kasnau-Matasukh lignites of Nagaur Basin, Rajasthan, were investigated using microscopy, proximate and ultimate analyses, Rock-Eval Pyrolysis, X-ray diffraction and Fourier Transform Infrared analyses, and major/minor/trace element determination. The relationship of elements with ash content and with macerals have also been discussed. These lignites are stratified, black, dominantly composed of huminite group macerals with subordinated amounts of liptinite and inertinite groups. They are classified as type-III kerogen and are mainly gas prone in nature. The concentration （in vol%） of mineral matter is seen to increase towards upper part of seam and so is the concentration （in wt%） of the volatile matter, elemental carbon and sulphur. The common minerals present in these lignitesare mixed clay layer, chlorite, and quartz as identified by X-ray diffraction study. Compared with world average in brown coal, the bulk concentration of Cu is anomalously high in most of the samples while Cd is 2-3 times high and Zn is high in one band. Based on interrelationship, different pyrite forms are noticed to have different preferential enrichment of various elements. The concentration of disseminated pyrite is more than the other pyrite forms and is followed by discrete pyrite grains and massive pyrite.
文摘The present paper entails the results of the investigations carried out on the lignite deposits of Kachchh Basin. The lignite samples were drawn from five lignite seams from Panandhro lignite field （Seam-I to -V） and eight lignite seams （Seam-I to -VIII） from the Matanomadh lignite field which are currently operational. The petrographic analysis of the lignites indicates a dominance of huminite group of macerals which is mainly contributed by ulminite-A, ulminite-B, attrinite, densinite, and phlobaphinite. Liptinite （chiefly sporinite, cutinite, resinite, and liptodetrinite） and inertinite （chiefly fusinite, funginite, and inertodetrinite） groups occur in subordinated amount. The mineral matter occurs in moderate concentration. Though sulfur content is high in these lignites, there is no fixed trend of variation of sulfur from bottom seam to top seam. The investigation reveals a flooded forest swamp having high rate of degradation. However, there were a few drier periods indicated by relatively more inertinite macerals. The petrography-based models indicate that the Kachchh lignites of Gujarat evolved in coastal marshy setting under transgressive phase. However, there were few intermittent fluvial activities giving rise to supratidal flood plain. This led to the formation of the associated carbonaceous shales in the basin.
文摘Lignite samples collected from Vastan, Rajpardi and Tadkeshwar lignite mines of Cambay basin （Gujarat） were subjected to organic petrographic investigations and geochemical analyses and the data, thus generated, is used to reconstruct the paleodepositional history of these lignite sequences. The lignites of Cambay basin dominantly comprise huminite maceral group （71.6%-86.3%） followed by liptinite （10.1%-19.3%） and inertinite （3.6%-11.0%） maceral groups. The mineral matter varies from 9.0% to 20.0%. The petrography based facies model indicates that these lignites have high values of gelification index （GI） and low tissue preservation index revealing a continuous wet condition in the basin and a relatively slower rate of subsidence during the decay of organic matter. On several occasions, during the formation of seams in Tadkeshwar, Rajpardi and Vastan mines, the value of GI exceeded 10 which indicates a forest permanently flooded and the cause of pronounced degree of degradation. However, few sections in Tadkeshwar seam had relatively drier spells of environmental conditions due to fluctuation in the water table as revealed by moderately high content of inertinite macerals. This is specially indicated by the occurrence of funginite which normally thrives in the upper oxy- genated peatigenic layer and indicates prevalence of oxic conditions during plant deposition. Such conditions prevailed during a transgressive phase but there were intermittent fluvial activities also giving rise to supratidal flood plain as reflected in the form of associated carbonaceous shales in the basin.
