In this study, variation in the frequency of thermal discomfort days over China during the period of 1961-2014,including heat discomfort days(HDDs) and cold discomfort days(CDDs), and the influence of external forcing...In this study, variation in the frequency of thermal discomfort days over China during the period of 1961-2014,including heat discomfort days(HDDs) and cold discomfort days(CDDs), and the influence of external forcings on it are discussed. HDDs are the conditions of overheating and overhumidity(represented by humidity index), and CDDs reflect the dangers from cold temperatures and winds(represented by wind chill index). Observations show significant increases(decreases) in the frequency of HDDs(CDDs) over China from 1961 to 2014, with clear regional distinctions. The historical ALL and greenhouse gas(GHG) simulations can sufficiently reproduce the spatial patterns of the observational trend in the frequency of both HDDs and CDDs over China. Further, the impacts of GHG and anthropogenic forcings on the HDDs(CDDs) are detectable over China, except for central and eastern China, based on the optimal fingerprinting method. GHG forcing is identified as a dominant factor for the observational changes in the frequency of HDDs over southern China;GHG and anthropogenic forcings have dominant effects on the variation in the frequency of CDDs over southwestern China. Although trends in the frequency of HDDs and CDDs in historical aerosol forcing simulations seems to be opposite to observations, an aerosol signal fails to be detected. Natural forcing contributes to the observational variation in the frequency of HDDs over northwestern China. In addition, the future projections of thermal discomfort days indicate that Chinese residents will face more threats of heat discomfort and fewer threats of cold discomfort in the future under global warming.展开更多
3 D highly ordered silver nanoparticles(AgNPs) coated silica photonic crystal beads(Ag/SPCBs) were prepared and exploited as a novel surface enhanced Raman scattering(SERS) substrate.The monodisperse and size-controll...3 D highly ordered silver nanoparticles(AgNPs) coated silica photonic crystal beads(Ag/SPCBs) were prepared and exploited as a novel surface enhanced Raman scattering(SERS) substrate.The monodisperse and size-controlled SPCBs were prepared via self-assembly of silica nanoparticles process using a simple microfluidic device.Then the Ag/SPCBs were easily obtained by in situ growth of AgNPs onto the NH_(2)-modified SPCBs.Field emitting scanning electron microscopy(SEM) and energy dispersive X-ray spectrometry(EDX) were used to characterize the Ag/SPCBs.The effect of silica nanoparticle size and AgNO_(3) concentration on the SERS performance of the resultant Ag/SPCBs substrate were discussed in detail.The results indicate that the Ag/SPCBs have highest SERS signals when silica nanoparticle size is250 nm and AgNO_(3) concentration is 0.8 mg/mL.Using malachite green(MG) as model analyte,the Ag/SPCBs substrate displayed a high sensitivity and a wide linear range for MG.The well-designed Ag/SPCBs show high uniformity and excellent reproducibility,and can be used as an effective SERS substrate for sensitive assay application.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.41991283 and 42005014)College Students’Enterprise and Entrepreneurship Education Program of NUIST(Grant No.201910300095Y)。
文摘In this study, variation in the frequency of thermal discomfort days over China during the period of 1961-2014,including heat discomfort days(HDDs) and cold discomfort days(CDDs), and the influence of external forcings on it are discussed. HDDs are the conditions of overheating and overhumidity(represented by humidity index), and CDDs reflect the dangers from cold temperatures and winds(represented by wind chill index). Observations show significant increases(decreases) in the frequency of HDDs(CDDs) over China from 1961 to 2014, with clear regional distinctions. The historical ALL and greenhouse gas(GHG) simulations can sufficiently reproduce the spatial patterns of the observational trend in the frequency of both HDDs and CDDs over China. Further, the impacts of GHG and anthropogenic forcings on the HDDs(CDDs) are detectable over China, except for central and eastern China, based on the optimal fingerprinting method. GHG forcing is identified as a dominant factor for the observational changes in the frequency of HDDs over southern China;GHG and anthropogenic forcings have dominant effects on the variation in the frequency of CDDs over southwestern China. Although trends in the frequency of HDDs and CDDs in historical aerosol forcing simulations seems to be opposite to observations, an aerosol signal fails to be detected. Natural forcing contributes to the observational variation in the frequency of HDDs over northwestern China. In addition, the future projections of thermal discomfort days indicate that Chinese residents will face more threats of heat discomfort and fewer threats of cold discomfort in the future under global warming.
基金the financial support from National Natural Science Foundation of China(Nos.21575125,81870033 and 21475116)333 Project and Qinglan Project of Jiangsu Province,Natural Science Foundation of Jiangsu Province(No.BK20191434)+4 种基金Six Talent Peaks Project of Jiangsu Province for Zhanjun Yang and Juan LiHigh-end Talent Support Program of Yangzhou University for Zhanjun Yang and Juan LiPriority Academic Program Development of Jiangsu Higher Education Institution(PAPD)Project for Science and Technology of Yangzhou(No.YZ2020068)Open Research Fund of State Key Laboratory of Analytical Chemistry for Life Science(No.SKLACLS1915)。
文摘3 D highly ordered silver nanoparticles(AgNPs) coated silica photonic crystal beads(Ag/SPCBs) were prepared and exploited as a novel surface enhanced Raman scattering(SERS) substrate.The monodisperse and size-controlled SPCBs were prepared via self-assembly of silica nanoparticles process using a simple microfluidic device.Then the Ag/SPCBs were easily obtained by in situ growth of AgNPs onto the NH_(2)-modified SPCBs.Field emitting scanning electron microscopy(SEM) and energy dispersive X-ray spectrometry(EDX) were used to characterize the Ag/SPCBs.The effect of silica nanoparticle size and AgNO_(3) concentration on the SERS performance of the resultant Ag/SPCBs substrate were discussed in detail.The results indicate that the Ag/SPCBs have highest SERS signals when silica nanoparticle size is250 nm and AgNO_(3) concentration is 0.8 mg/mL.Using malachite green(MG) as model analyte,the Ag/SPCBs substrate displayed a high sensitivity and a wide linear range for MG.The well-designed Ag/SPCBs show high uniformity and excellent reproducibility,and can be used as an effective SERS substrate for sensitive assay application.
