The performances of CO selective oxidation in hydrogen-rich gas over fourcatalytic systems of CuO/ZrO_2, CuO/MnO_2, CuO/CoO and CuO/CeO_2 were compared. The reducibility ofthese catalysts and the effect of CuO and CeO...The performances of CO selective oxidation in hydrogen-rich gas over fourcatalytic systems of CuO/ZrO_2, CuO/MnO_2, CuO/CoO and CuO/CeO_2 were compared. The reducibility ofthese catalysts and the effect of CuO and CeO_2 molar ratio of CuO/CeO_2 catalysts on the activityof selective CO oxidation are investigated by XRD and TPR methods. The results show that thecatalysts with the exception of CuO/ZrO_2 have the interactions between CuO and CoO, CeO_2 or MnO_2,which result in a decrease in the reduction temperature. Among the catalysts studied, CuO/ZrO_2catalyst shows the lowest catalytic activity while CuO/CeO_2 catalyst exhibits the best catalyticperformance. The CuO(10%)/CeO_2 catalyst attains the highest CO conversion and selectivity at 140and 160℃. The addition of 9% H_2O in the reactant feed decreases the activity of CuO/CeO_2 catalystbut increases its CO selectivity.展开更多
The production of benzene directly from methane aromatization under oxygen-free condition is currently a new focus in natural gas utilization. The influence of preparation techniques of the catalysts on their catalyti...The production of benzene directly from methane aromatization under oxygen-free condition is currently a new focus in natural gas utilization. The influence of preparation techniques of the catalysts on their catalytic activities is studied in this paper. The influencing factors include the impregnating method, the calcination temperature, the promoter content and the acidity of the zeolite support. Optimum preparation techniques for the catalysts are obtained through this work.展开更多
基金This work was financially supported by Guangdong Province Natural Science Foundation of China(000435), the Doctoral Program Foundation of the Ministry of Education (20010561003) Guangzhou Municipal Science and Technology Project(2001J1C0211)
文摘The performances of CO selective oxidation in hydrogen-rich gas over fourcatalytic systems of CuO/ZrO_2, CuO/MnO_2, CuO/CoO and CuO/CeO_2 were compared. The reducibility ofthese catalysts and the effect of CuO and CeO_2 molar ratio of CuO/CeO_2 catalysts on the activityof selective CO oxidation are investigated by XRD and TPR methods. The results show that thecatalysts with the exception of CuO/ZrO_2 have the interactions between CuO and CoO, CeO_2 or MnO_2,which result in a decrease in the reduction temperature. Among the catalysts studied, CuO/ZrO_2catalyst shows the lowest catalytic activity while CuO/CeO_2 catalyst exhibits the best catalyticperformance. The CuO(10%)/CeO_2 catalyst attains the highest CO conversion and selectivity at 140and 160℃. The addition of 9% H_2O in the reactant feed decreases the activity of CuO/CeO_2 catalystbut increases its CO selectivity.
文摘The production of benzene directly from methane aromatization under oxygen-free condition is currently a new focus in natural gas utilization. The influence of preparation techniques of the catalysts on their catalytic activities is studied in this paper. The influencing factors include the impregnating method, the calcination temperature, the promoter content and the acidity of the zeolite support. Optimum preparation techniques for the catalysts are obtained through this work.
