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δ-(Al,Fe)OOH的高压相变
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作者 王宝云 肖万生 宋茂双 《高压物理学报》 CAS CSCD 北大核心 2021年第6期50-60,共11页
δ-(Al,Fe)OOH被认为是将水输运到地球核幔边界的可能载体,厘清其在高压下的结构相变与物理性质对于理解深部水循环具有重要意义。利用金刚石压腔和同步辐射X射线衍射,研究了δ-Fe_(0.08)Al_(0.92)OOH(δ-Fe8)的压缩行为。压力-晶胞体积... δ-(Al,Fe)OOH被认为是将水输运到地球核幔边界的可能载体,厘清其在高压下的结构相变与物理性质对于理解深部水循环具有重要意义。利用金刚石压腔和同步辐射X射线衍射,研究了δ-Fe_(0.08)Al_(0.92)OOH(δ-Fe8)的压缩行为。压力-晶胞体积(p-V)曲线表明:δ-Fe8在0~78 GPa经历了氢原子的有序–无序转变和铁的自旋转变。其中氢原子有序–无序转变发生在约9.7 GPa,p-V曲线在相变点出现轻微转折,且轴比a/c和b/c对压力的斜率在相变前后发生反转,空间群由P21nm变为Pnnm。铁自旋转变发生在31.5~39.5 GPa,伴随着约2%的晶胞体积塌缩,属于等结构相变。采用Birch-Murnaghan状态方程分段拟合了p-V曲线,得到了各个结构的状态方程参数。用铁高自旋态和低自旋态理想固溶体模型分析了自旋转变区域的p-V数据,拟合得到低自旋分数随压力变化的关系式。计算结果表明,体弹模量和体波速在自旋转变区域会出现软化行为,说明地球内部富集一定数量的δ-Fe8可能造成中下地幔局部体波低速异常。结合前人研究,给出了δ-(Al,Fe)OOH体系的相变压力与铁含量的线性关系式。 展开更多
关键词 高压 X射线衍射 δ-(Al Fe)OOH 相变 自旋转变
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Experimental Probing on Formation Mechanism of Hydrocarbon in Deep Earth
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作者 Weng Kenan xiao wansheng Zhang Huizi and Wang Benshan(Guangzhou Geochemistry Institute, Academia Sinica, Guangzhou) 《China Oil & Gas》 CAS 1997年第1期39-40,共2页
关键词 Abiogenic HYDROCARBON HIGH temperature HIGH pressure
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Adakitic rocks and destruction of the North China Craton:Evidence from experimental petrology and geochemistry 被引量:35
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作者 XIONG xiaoLin LIU XingCheng +5 位作者 ZHU ZhiMin LI Yuan xiao wansheng SONG MaoShuang ZHANG Sheng WU JinHua 《Science China Earth Sciences》 SCIE EI CAS 2011年第6期858-870,共13页
The general temporal-spatial consistency for the formation of adakitic rocks and lithospheric thinning in northern China provide a window to examine the processes and mechanism for the destruction of the North China C... The general temporal-spatial consistency for the formation of adakitic rocks and lithospheric thinning in northern China provide a window to examine the processes and mechanism for the destruction of the North China Craton.With experimental petrology data,this paper demonstrates that the adakitic rocks in northern China are the products of partial melting of middle-to high-potassic metabasalts at the base of the lower continent crust.Based on the TiO2 solubility model,many adakitic rocks in Dabie,Jiaodong and the northern part of the craton appear to have been saturated with TiO2.This indicates the presence of a Ti-rich accessory phase in their source regions.This phase must be rutile based on the decreasing Nb/La with increasing La/Yb in the adakitic rocks.The adakitic magmas were,thus,derived from a depth of more than 50 km,based on pressures (higher than 1.5 GPa) for the stability of rutile in a metabasalt system.Because present-day crustal thickness is generally only 35 km,we suggest that the destruction of the North China Craton may have led to at least 15 km of thinning or delamination of the crust. 展开更多
关键词 adakitic rocks North China Craton crustal thinning RUTILE experimental petrology
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