By temperature gradient method under high pressure and high temperature(HPHT),with NiMnCo alloy as the solvent metal,at diamond-stable region of about 5.4 GPa and 1500 K,metastable regrown graphite crystals of differe...By temperature gradient method under high pressure and high temperature(HPHT),with NiMnCo alloy as the solvent metal,at diamond-stable region of about 5.4 GPa and 1500 K,metastable regrown graphite crystals of different morphology were synthesized.With B as an additive incorporated into the NiMnCo-C system,metastable regrown graphite crystals of sphere-like shape were firstly obtained under HPHT.If the growth system does not contain B,sheet-like regrown graphite crystals,most with regular hexagonal morphology,are grown upwards and standing vertically in the metal solvent.When B additive of 1.0 wt pct was added into carbon source(graphite powder),all metastable regrown graphite crystals took on the habit of regular sphere-like morphology,and were grown by a spiral layer growth mechanism.展开更多
Due to elimination of horizontal and vertical tails,flying wing aircraft has poor longitudinal and directional dynamic characteristics.In addition,flying wing aircraft uses drag rudders for yaw control,which tends to ...Due to elimination of horizontal and vertical tails,flying wing aircraft has poor longitudinal and directional dynamic characteristics.In addition,flying wing aircraft uses drag rudders for yaw control,which tends to generate strong three-axis control coupling.To overcome these problems,a flight control law design method that couples the longitudinal axis with the lateraldirectional axes is proposed.First,the three-axis coupled control augmentation structure is specified.In the structure,a‘‘soft/hard"cross-connection method is developed for three-axis dynamic decoupling and longitudinal control response decoupling from the drag rudders;maneuvering turn angular rate estimation and subtraction are used in the yaw axis to improve the directional damping.Besides,feedforward control is adopted to improve the maneuverability and control decoupling performance.Then,detailed design methods for feedback and feedforward control parameters are established using eigenstructure assignment and model following technique.Finally,the proposed design method is evaluated and compared with conventional method by numeric simulations.The influences of control derivatives variation of drag rudders on the method are also analyzed.It is demonstrated that the method can effectively improve the dynamic characteristics of flying wing aircraft,especially the directional damping characteristics,and decouple the longitudinal responses from the drag rudders.展开更多
We present the work about the initiative fabrication of multi-scale hierarchical TiO2-x by our strategy,combining high pressure and high temperature(HPHT)reactive sintering with appropriate ratio of coarse Ti to nanos...We present the work about the initiative fabrication of multi-scale hierarchical TiO2-x by our strategy,combining high pressure and high temperature(HPHT)reactive sintering with appropriate ratio of coarse Ti to nanosized TiO_(2).Ubiquitous lattice defects engineering has also been achieved in our samples by HPHT.The thermoelectric performance was significantly enhanced,and rather low thermal conductivity(1.60 W m^(-1)K^(-1))for titanium oxide was reported here for TiO1.76.Correspondingly,a high dimensionless figure of merit(zT)up to 0.33 at 700℃was realized in it.As far as we know,this value is an enhancement of 43%of the ever best result about nonstoichiometric TiO_(2)and the result is also exciting for oxide thermoelectric materials.The moderate power factor,the significantly reduced thermal conductivity and the remarkable synergy between electrical properties and thermal conductivity are responsible for the excellent thermoelectric performance.We develop a facile strategy for preparing multi-scale hierarchical TiO_(2-x)and its superior ability to optimize thermoelectric performance has been demonstrated here.展开更多
Bulk materials Ba_(8)Ga_(16)In_(x)Ge_(30-x)(x=0.5,1.0,1.5)were prepared by High-Pressure and High-Temperature(HPHT)method and the crystal structure has been confirmed by X-ray diffraction and cell refinement.The actua...Bulk materials Ba_(8)Ga_(16)In_(x)Ge_(30-x)(x=0.5,1.0,1.5)were prepared by High-Pressure and High-Temperature(HPHT)method and the crystal structure has been confirmed by X-ray diffraction and cell refinement.The actual In composition was much lower than the starting composition,and lattice constants increased with the increase of substitution.As the temperature increased,the Seebeck coefficient and electrical resistivity increased first and then decreased,while the thermal conductivity was the opposite,which leads to significant enhancement on thermoelectric properties of the clathrates.The substitution of indium elements decreased the seebeck coefficient and electrical resistivity,and also changed the microstructure of the compounds.A minimum thermal conductivity of 0.84Wm^(-1)1K^(-1)was obtained,and a good ZT value of 0.52 was achieved.The grain boundaries and lattice defects generated by high pressure can effectively scatter phonons of different frequencies,which reduce the lattice thermal conductivity.展开更多
Polycrystalline Cu_(2)Se bulk materials were synthesized by high-pressure and high-temperature(HPHT)technique.The effects of synthetic temperature and pressure on the thermoelectric properties of Cu_(2)Se materials we...Polycrystalline Cu_(2)Se bulk materials were synthesized by high-pressure and high-temperature(HPHT)technique.The effects of synthetic temperature and pressure on the thermoelectric properties of Cu_(2)Se materials were investigated.The results indicate that both synthetic temperature and pressure determine the microstructure and thermoelectric performance of Cu2Se compounds.The increase of synthetic temperature can effectively enhance the electrical conductivity and decrease the lattice thermal conductivity.A two-fold improvement in the power factor is obtained at synthetic temperature of 1000℃ compared to that obtained at room temperature.All b-Cu2Se samples exhibit low and temperatureindependent lattice thermal conductivity ranging from 0.3 to 0.5 Wm^(-1)K^(-1) due to the intrinsic superionic feature and the abundant lattice defects produced at high pressure.A maximum zT of 1.19 at 723 K was obtained for the sample synthesized at 3 GPa and 1000℃.These findings indicate that HPHT technology is an efficient approach to synthesize Cu_(2)Se-based bulk materials.展开更多
基金supported by the National Natural Science Foundation of China under grant No.50172018the Foundation of He nan Educational Committee undergrant No.2009A430014the Open Research Fund Program of State Key Laboratory of Superhard Materials of Jilin University under grant No.200801
文摘By temperature gradient method under high pressure and high temperature(HPHT),with NiMnCo alloy as the solvent metal,at diamond-stable region of about 5.4 GPa and 1500 K,metastable regrown graphite crystals of different morphology were synthesized.With B as an additive incorporated into the NiMnCo-C system,metastable regrown graphite crystals of sphere-like shape were firstly obtained under HPHT.If the growth system does not contain B,sheet-like regrown graphite crystals,most with regular hexagonal morphology,are grown upwards and standing vertically in the metal solvent.When B additive of 1.0 wt pct was added into carbon source(graphite powder),all metastable regrown graphite crystals took on the habit of regular sphere-like morphology,and were grown by a spiral layer growth mechanism.
基金supported by the Fundamental Research Funds for the Central Universities of China(No.:YWF-19-BJ-J-322)。
文摘Due to elimination of horizontal and vertical tails,flying wing aircraft has poor longitudinal and directional dynamic characteristics.In addition,flying wing aircraft uses drag rudders for yaw control,which tends to generate strong three-axis control coupling.To overcome these problems,a flight control law design method that couples the longitudinal axis with the lateraldirectional axes is proposed.First,the three-axis coupled control augmentation structure is specified.In the structure,a‘‘soft/hard"cross-connection method is developed for three-axis dynamic decoupling and longitudinal control response decoupling from the drag rudders;maneuvering turn angular rate estimation and subtraction are used in the yaw axis to improve the directional damping.Besides,feedforward control is adopted to improve the maneuverability and control decoupling performance.Then,detailed design methods for feedback and feedforward control parameters are established using eigenstructure assignment and model following technique.Finally,the proposed design method is evaluated and compared with conventional method by numeric simulations.The influences of control derivatives variation of drag rudders on the method are also analyzed.It is demonstrated that the method can effectively improve the dynamic characteristics of flying wing aircraft,especially the directional damping characteristics,and decouple the longitudinal responses from the drag rudders.
基金This work was supported by the National Natural Science Foundation of China(Grant No.51171070)the Project of Jilin Science and Technology Development Plan(20170101045JC)Graduate Innovation Fund of Jilin University(Project No.2016065).
文摘We present the work about the initiative fabrication of multi-scale hierarchical TiO2-x by our strategy,combining high pressure and high temperature(HPHT)reactive sintering with appropriate ratio of coarse Ti to nanosized TiO_(2).Ubiquitous lattice defects engineering has also been achieved in our samples by HPHT.The thermoelectric performance was significantly enhanced,and rather low thermal conductivity(1.60 W m^(-1)K^(-1))for titanium oxide was reported here for TiO1.76.Correspondingly,a high dimensionless figure of merit(zT)up to 0.33 at 700℃was realized in it.As far as we know,this value is an enhancement of 43%of the ever best result about nonstoichiometric TiO_(2)and the result is also exciting for oxide thermoelectric materials.The moderate power factor,the significantly reduced thermal conductivity and the remarkable synergy between electrical properties and thermal conductivity are responsible for the excellent thermoelectric performance.We develop a facile strategy for preparing multi-scale hierarchical TiO_(2-x)and its superior ability to optimize thermoelectric performance has been demonstrated here.
基金This workwas financially supported by National Natural Science Foundation of China(51171070)the Project of Jilin Science and Technology Development Plan(20170101045JC).
文摘Bulk materials Ba_(8)Ga_(16)In_(x)Ge_(30-x)(x=0.5,1.0,1.5)were prepared by High-Pressure and High-Temperature(HPHT)method and the crystal structure has been confirmed by X-ray diffraction and cell refinement.The actual In composition was much lower than the starting composition,and lattice constants increased with the increase of substitution.As the temperature increased,the Seebeck coefficient and electrical resistivity increased first and then decreased,while the thermal conductivity was the opposite,which leads to significant enhancement on thermoelectric properties of the clathrates.The substitution of indium elements decreased the seebeck coefficient and electrical resistivity,and also changed the microstructure of the compounds.A minimum thermal conductivity of 0.84Wm^(-1)1K^(-1)was obtained,and a good ZT value of 0.52 was achieved.The grain boundaries and lattice defects generated by high pressure can effectively scatter phonons of different frequencies,which reduce the lattice thermal conductivity.
基金the National Natural Science Foundation of China(No.11704340,11804305 and 51171070)the Project of Jilin Science and Technology Development Plan(Project No.20170101045JC)+1 种基金the China Postdoctoral Science Foundation(No.2017M620303 and 2017M622360)the Key Research Project of Higher Education Institution of Henan Province(No.19A140006).
文摘Polycrystalline Cu_(2)Se bulk materials were synthesized by high-pressure and high-temperature(HPHT)technique.The effects of synthetic temperature and pressure on the thermoelectric properties of Cu_(2)Se materials were investigated.The results indicate that both synthetic temperature and pressure determine the microstructure and thermoelectric performance of Cu2Se compounds.The increase of synthetic temperature can effectively enhance the electrical conductivity and decrease the lattice thermal conductivity.A two-fold improvement in the power factor is obtained at synthetic temperature of 1000℃ compared to that obtained at room temperature.All b-Cu2Se samples exhibit low and temperatureindependent lattice thermal conductivity ranging from 0.3 to 0.5 Wm^(-1)K^(-1) due to the intrinsic superionic feature and the abundant lattice defects produced at high pressure.A maximum zT of 1.19 at 723 K was obtained for the sample synthesized at 3 GPa and 1000℃.These findings indicate that HPHT technology is an efficient approach to synthesize Cu_(2)Se-based bulk materials.
