Milled form of mesophase pitch-based graphite fibers were coated with a titanium layer using chemical vapor deposition technique and Ti-coated graphite fiber/Cu composites were fabricated by hot-pressing sintering. Th...Milled form of mesophase pitch-based graphite fibers were coated with a titanium layer using chemical vapor deposition technique and Ti-coated graphite fiber/Cu composites were fabricated by hot-pressing sintering. The composites were characterized with X-ray diffraction, scanning/transmission electron microscopies, and by mea- suring thermal properties, including thermal conductivity and coefficient of thermal expansion （CTE）. The results show that the milled fibers are preferentially oriented in a plane perpendicular to the pressing direction, leading to anisotropic thermal properties of the composites. The Ti coating reacted with graphite fiber and formed a continuous and uniform TiC layer. This carbide layer establishes a good metallurgical interracial bonding in the composites, which can improve the thermal properties effectively. When the fiber content ranges from 35 vol% to 50 vol%, the in-plane thermal conductivities of the composites increase from 383 to 407 W.（m.K）-~, and the in-plane CTEs decrease from 9.5 x 10-6 to 6.3 10-6 K-1.展开更多
Since the time step of the traditional finite-difference time-domain(FDTD) method is limited by the small grid size, it is inefficient when dealing with the electromagnetic problems of multi-scale structures.Therefore...Since the time step of the traditional finite-difference time-domain(FDTD) method is limited by the small grid size, it is inefficient when dealing with the electromagnetic problems of multi-scale structures.Therefore, the explicit and unconditionally stable FDTD(US-FDTD) approach has been developed to break through the limitation of Courant–Friedrich–Levy(CFL) condition.However, the eigenvalues and eigenvectors of the system matrix must be calculated before the time iteration in the explicit US-FDTD.Moreover, the eigenvalue decomposition is also time consuming, especially for complex electromagnetic problems in practical application.In addition, compared with the traditional FDTD method, the explicit US-FDTD method is more difficult to introduce the absorbing boundary and plane wave.To solve the drawbacks of the traditional FDTD and the explicit US-FDTD, a new hybrid FDTD algorithm is proposed in this paper.This combines the explicit US-FDTD with the traditional FDTD, which not only overcomes the limitation of CFL condition but also reduces the system matrix dimension, and introduces the plane wave and the perfectly matched layer(PML) absorption boundary conveniently.With the hybrid algorithm, the calculation of the eigenvalues is only required in the fine mesh region and adjacent coarse mesh region.Therefore, the calculation efficiency is greatly enhanced.Furthermore, the plane wave and the absorption boundary introduction of the traditional FDTD method can be directly utilized.Numerical results demonstrate the effectiveness, accuracy, stability, and convenience of this hybrid algorithm.展开更多
Ni-P coated diamond powder was fabricated successfully by using electroless plating.Effects of active solutions,plating time,reaction temperature,and the components of the plating bath on the Ni-P coating were investi...Ni-P coated diamond powder was fabricated successfully by using electroless plating.Effects of active solutions,plating time,reaction temperature,and the components of the plating bath on the Ni-P coating were investigated systematically.Moreover,a study on the thermal stability of Ni-P coated diamond under various atmospheres was performed.The results indicate that Pd atoms absorbed on the diamond surface as active sites can consequently enhance the deposition rate of Ni effectively.The optimized plating bath and reaction conditions improve both the plating speed and the coverage rate of Ni-P electroless plating on the diamond surface.Compared to the diamond substrate,the diamond coated with Ni-P films exhibits very high thermal stability and can be processed up to 900°C in air and 1300°C in protective atmosphere such as H2.展开更多
（38vo1% SiCp ＋ 2vo1% A1203f）/2024 A1 composites were fabricated by pressure infiltration. Graphite powder was introduced as a forming filler in preform preparation, and the effects of the powder size on the microst...（38vo1% SiCp ＋ 2vo1% A1203f）/2024 A1 composites were fabricated by pressure infiltration. Graphite powder was introduced as a forming filler in preform preparation, and the effects of the powder size on the microstructures and mechanical properties of the final com- posites were investigated. The results showed that the composite with 15 μm graphite powder as a forming filler had the maximum tensile strength of 506 MPa, maximum yield strength of 489 MPa, and maximum elongation of 1.2%, which decreased to 490 MPa, 430 MPa, and 0.4%, respectively, on increasing the graphite powder size from 15 to 60 μm. The composite with 60 μm graphite powder showed the highest elastic modulus, and the value decreased from 129 to 113 GPa on decreasing the graphite powder size from 60 to 15 μm. The differences between these properties are related to the different microstructures of the corresponding composites, which determine their failure modes.展开更多
The precipitation behavior of γ′ phase,under various interrupt cooling tests after 1170℃,solution treatment was examined.The results indicate that the size of secondary γ′ precipitates increases with the decrease...The precipitation behavior of γ′ phase,under various interrupt cooling tests after 1170℃,solution treatment was examined.The results indicate that the size of secondary γ′ precipitates increases with the decrease of interrupt temperature,and the shape changes from spherical to butterfly like.The fine tertiary γ′ can form either during the post cool air quenching at high interrupt-temperatures,or during the specified 5℃ min-1cooling.Air quenching at high temperatures cannot suppress further nucleation of tertiary γ′ phase.展开更多
The influence of oxygen content and heat treatment on the evolution of carbides in a powder metallurgy （PM） Ni-base superalloy was characterized. The results reveal that oxygen content has little influence on the pr...The influence of oxygen content and heat treatment on the evolution of carbides in a powder metallurgy （PM） Ni-base superalloy was characterized. The results reveal that oxygen content has little influence on the precipitation of carbides inside the particles. However, under the consolidated state, stable Ti oxides on the particle surface act as nuclei for the precipitation of prior particle boundaries （PPB）. Also, oxygen can diffuse internally along grain boundaries under compressive stress, which favors the precipitation of carbides inside the particles. Therefore, a higher amount of carbides will appear with more oxygen content in the case of consolidated alloys. It is also observed that PPB can be disrupted into discontinuous particles at 1200℃, but this carbide network is hard to be eliminated completely. The combined MC-M23C6 morphology approves the nucleation and growth mechanism of carbide evolution.展开更多
The method of calciothermic reduction of B4C was proposed for preparing CaB6.The phase transition and morphology evolution during the reaction were investigated in detail.The experimental results reveal that Ca first ...The method of calciothermic reduction of B4C was proposed for preparing CaB6.The phase transition and morphology evolution during the reaction were investigated in detail.The experimental results reveal that Ca first reacts with B4C to generate CaB2C2 and CaB6 at a low temperature and that the CaB2C2 subsequently reacts with Ca to produce CaB6 and CaC2 at a high temperature.After the products were leached to remove the byproduct CaC2,pure CaB6 was obtained.The grain size of the prepared CaB6 was 2–3μm,whereas its particle size was 4–13μm;it inherited the particle size of B4C.The residual C content of the product was decreased to 1.03 wt%after the first reaction at 1173 K for 4 h and the second reaction at 1623 K for 4 h.展开更多
Nickel-coated graphite flakes/copper（GN/Cu） composites were fabricated by spark plasma sintering with the surface of graphite flakes（GFs） being modified by Ni–P electroless plating. The effects of the phase trans...Nickel-coated graphite flakes/copper（GN/Cu） composites were fabricated by spark plasma sintering with the surface of graphite flakes（GFs） being modified by Ni–P electroless plating. The effects of the phase transition of the amorphous Ni–P plating and of Ni diffusion into the Cu matrix on the densification behavior, interfacial microstructure, and thermal conductivity（TC） of the GN/Cu composites were systematically investigated. The introduction of Ni–P electroless plating efficiently reduced the densification temperature of uncoated GF/Cu composites from 850 to 650℃ and slightly increased the TC of the X–Y basal plane of the GF/Cu composites with 20 vol%–30 vol% graphite flakes. However, when the graphite flake content was greater than 30 vol%, the TC of the GF/Cu composites decreased with the introduction of Ni–P plating as a result of the combined effect of the improved heat-transfer interface with the transition layer, P generated at the interface, and the diffusion of Ni into the matrix. Given the effect of the Ni content on the TC of the Cu matrix and on the interface thermal resistance, a modified effective medium approximation model was used to predict the TC of the prepared GF/Cu composites.展开更多
Cr-coated diamond/Cu composites were prepared by spark plasma sintering. The effects of sintering pressure, sintering temperature, sintering duration, and Cu powder particle size on the relative density and thermal co...Cr-coated diamond/Cu composites were prepared by spark plasma sintering. The effects of sintering pressure, sintering temperature, sintering duration, and Cu powder particle size on the relative density and thermal conductivity of the composites were investigated in this paper. The influence of these parameters on the properties and microstructures of the composites was also discussed. The results show that the relative density of Cr-coated diamond/Cu reaches ~100% when the composite is gradually compressed to 30 MPa during the heating process. The densification temperature increases from 880 to 915℃ when the diamond content is increased from 45vol% to 60vol%. The densification temperature does not increase further when the content reaches 65vol%. Cu powder particles in larger size are beneficial for increasing the relative density of the composite.展开更多
Herein, graphite was used in the Si-vapor reactive infiltration of diamond/SiC/Si composites to produce composites with various Si C contents. X-ray diffraction was used to determine the phases of the composite, where...Herein, graphite was used in the Si-vapor reactive infiltration of diamond/SiC/Si composites to produce composites with various Si C contents. X-ray diffraction was used to determine the phases of the composite, whereas scanning electron microscopy was used to confirm the Si–C reaction between the silicon, graphite, and diamond and to observe the SiC morphology. Various SiC contents in the composite were observed with graphite addition. Furthermore, the reaction between silicon and graphite(diamond) produced coarse(fine) SiC particles. The generation of a 10-μm-diameter Si–C area on the surface of the diamond was observed. The thermal conductivity(TC) and coefficient of thermal expansion(CTE) of the composite was investigated, where the TC varied from 317–426 W·m^-1·K^-1 with the increase of the SiC volume fraction from 38% to 76% and the corresponding CTE increased from 1.7 × 10^-6 to 3.7 × 10^-6 K^-1, respectively. Furthermore, a critical point for the CTE was found to exist at approximately 250℃, where the composite was under a hydrostatic condition. Finally, the bending strength was found to range from 241 to 341 MPa.展开更多
The angular distribution of gamma-ray burst（GRB）jets is not yet clear.The observed luminosity of GRB 170817A is the lowest among all known short GRBs,which is best explained by the fact that our line of sight is out...The angular distribution of gamma-ray burst（GRB）jets is not yet clear.The observed luminosity of GRB 170817A is the lowest among all known short GRBs,which is best explained by the fact that our line of sight is outside of the jet opening angle,θ_（obs）〉θ_j,whereθ_（obs） is the angle between our line of sight and the jet axis.As inferred by gravitational wave observations,as well as radio and X-ray afterglow modeling of GRB 170817A,it is likely that θ_（obs）~20°–28°.In this work,we quantitatively consider two scenarios of angular energy distribution of GRB ejecta：a top-hat jet and a structured jet with a power law index s.For the top-hat jet model,we get a large θ_j（e.g.,θ_j〉10°）,a rather high local （i.e., z 〈 0.01） short GRB rate ~8–15×10~3 Gpc^（-3）yr~（-1（（estimated to be 90~1850 Gpc^（-3）yr^（-1） in Fong et al.）and an extremely high（on-axis,V（~500 ke V for a typical short GRB）.For the structured jet model,we use θ_（obs） to give limits on s and θ_j for typical on-axis luminosity of a short GRB（e.g.,10^（49）erg s（-1） 1051erg s（-1））,and a low on-axis luminosity case（e.g.,1049erg s（-1））gives more reasonable values of s.The structured jet model is more feasible for GRB170817A than the top-hat jet model due to the rather high local short GRB rate,and the extremely high on-axis E_（peak,0） almost rules out the top-hat jet model.GRB 170817A is likely a low on-axis luminosity GRB（1049erg s（-1））with a structured jet.展开更多
A method which combines electronegativity difference,CALculation of PHAse Diagrams(CALPHAD) and machine learning has been proposed to efficiently screen the high yield strength regions in Co-Cr-Fe-Ni-Mo multi-componen...A method which combines electronegativity difference,CALculation of PHAse Diagrams(CALPHAD) and machine learning has been proposed to efficiently screen the high yield strength regions in Co-Cr-Fe-Ni-Mo multi-component phase diagram.First,the single-phase region at a certain annealing temperature is obtained by combining CALPHAD method and machine learning,to avoid the formation of brittle phases.Then high yield strength points in the single-phase region are selected by electronegativity difference.The yield strength and plastic deformation behavior of the designed Co_(14)Cr_(30)Ni_(50)Mo_(6)alloy are measured to evaluate the proposed method.The validation experiments indicate this method is effective to predict high yield strength points in the whole compositional space.Meanwhile,the interactions between the high density of shear bands and dislocations contribute to the high ductility and good work hardening ability of Co_(14)Cr_(30)Ni_(50)Mo_(6)alloy.The method is helpful and instructive to property-oriented compositional design for multi-principal element alloys.展开更多
Gallium-based liquid metal,as a high-performance thermal interface material,can improve the performance and service life of electronic equipment.This study focuses on the use of diamond as a thermal conductivity enhan...Gallium-based liquid metal,as a high-performance thermal interface material,can improve the performance and service life of electronic equipment.This study focuses on the use of diamond as a thermal conductivity enhancement phase to improve the thermal conductivity of GaInSn liquid metal and avoid the overflow of liquid metal during application.In this study,diamond/GaInSn composites were prepared by an ultrasonic-assisted wetting method.The thermal conductivity and contact thermal resistance of diamond/GaInSn composites were characterized by the transient method.The morphology and thermal conductivity of diamond/GalnSn composites were investigated when diamond particles of different diameters were added to GaInSn liquid metal.The addition of large-sized diamond particles can effectively improve the thermal conductivity of thermal interface materials (TIMs) but willcause liquid metal to pump out.展开更多
This study was pertained to the effects of Ti coating on diamond surfaces and Si addition into Al matrix on the thermal conductivity（TC） and the coefficient of thermal expansion（CTE） of diamond/Al composites by pr...This study was pertained to the effects of Ti coating on diamond surfaces and Si addition into Al matrix on the thermal conductivity（TC） and the coefficient of thermal expansion（CTE） of diamond/Al composites by pressure infiltration.The fracture surfaces,interface microstructures by metal electro-etching and interfacial thermal conductance of the composites prepared by two methods were compared.The results reveal that Ti coating on diamond surfaces and only12.2 wt% Si addition into Al matrix could both improve the interfacial bonding and increase the TCs of the composites.But the Ti coating layer introduces more interfacial thermal barrier at the diamond/Al interface compared to adding 12.2 wt% Si into Al matrix.The diamond/Al composite with 12.2 wt% Si addition exhibits maximum TC of 534 W·m^-1·K^-1and a very low CTE of 8.9×10^-6K^-1,while the coating Ti-diamond/Al composite has a TC of 514 W·m^-1·K^-1 and a CTE of 11.0×10^-6K^-1.展开更多
To inhibit the graphitization of diamond under high temperature and low pressure, diamond/SiC composites were firstly fabricated by a rapid gaseous Si vacuum reactive infiltration process. The microstructure and graph...To inhibit the graphitization of diamond under high temperature and low pressure, diamond/SiC composites were firstly fabricated by a rapid gaseous Si vacuum reactive infiltration process. The microstructure and graphitization behavior of diamond in the composites under various infiltration temperatures and holding time were investigated. The thermal conductivity of the resul- tant materials was discussed. The results show that the diamond-to-graphite transition is effectively inhibited at temperature of as high as 1600 ℃ under vacuum, and the substantial graphitization starts at 1700 ℃. The microstructure of those ungraphitized samples is uniform and fully densified. The inhibition mechanisms of graphitization include the isolation of the catalysts from diamond by a series of protective layers, high pressure stress applied on diamond by the reaction-bonded SiC, and the moderate gas-solid reaction. For the graphitized samples, the boundary between diamond and SiC is coarse and loose. The graphitization mechanism is considered to be an initial detachment of the bilayers from the diamond surfaces, and subsequently flattening to form graphite. The ungraphitized samples present higher thermal conductivity of about 410 W.m-1.K-1 due to the fine interfacial structure. For the graphitized samples, the thermal conductivity decreases significantly to 285 W.m-1.K-1 as a result of high interfacial thermal resistance.展开更多
TiC-316 L metal matrix composites were successfully printed with an epoxy resin-absolute ethanol system by direct ink writing(DIW) process in this study.Microstructure and fracture morphology of the samples were obser...TiC-316 L metal matrix composites were successfully printed with an epoxy resin-absolute ethanol system by direct ink writing(DIW) process in this study.Microstructure and fracture morphology of the samples were observed by a scanning electron microscope(SEM).Also,the relative density,hardness and transverse rupture strength(TRS) of the sintered samples were tested.The results show that the samples prepared with a new epoxy resin-absolute ethanol system by the DIW process have high solid content of printing slurry,good surface roughness,high relative density and high strength.The solid content of the slurry suitable for DIW was 60 vol%,and the internal diameter of the nozzle was set to 0.4 mm,the printing speed was set to 30 mm·s^(-1),and the layer height was set to 0.36 mm.For the sample with 35 wt% TiC-316 L,the relative density,hardness and TRS of the sintered sample can reach 99.3%,HRA 79.5 and 1438 MPa,respectively.展开更多
基金financially supported by the National Natural Science Foundation of China(No.51274040)the Fundamental Research Funds for the Central Universities(FRF-TP-10-003B)
文摘Milled form of mesophase pitch-based graphite fibers were coated with a titanium layer using chemical vapor deposition technique and Ti-coated graphite fiber/Cu composites were fabricated by hot-pressing sintering. The composites were characterized with X-ray diffraction, scanning/transmission electron microscopies, and by mea- suring thermal properties, including thermal conductivity and coefficient of thermal expansion （CTE）. The results show that the milled fibers are preferentially oriented in a plane perpendicular to the pressing direction, leading to anisotropic thermal properties of the composites. The Ti coating reacted with graphite fiber and formed a continuous and uniform TiC layer. This carbide layer establishes a good metallurgical interracial bonding in the composites, which can improve the thermal properties effectively. When the fiber content ranges from 35 vol% to 50 vol%, the in-plane thermal conductivities of the composites increase from 383 to 407 W.（m.K）-~, and the in-plane CTEs decrease from 9.5 x 10-6 to 6.3 10-6 K-1.
基金Project supported by the National Natural Science Foundation of China(Grant No.61571348)the Equipment Pre-Research Foundation of China(Grant No.61405180202)
文摘Since the time step of the traditional finite-difference time-domain(FDTD) method is limited by the small grid size, it is inefficient when dealing with the electromagnetic problems of multi-scale structures.Therefore, the explicit and unconditionally stable FDTD(US-FDTD) approach has been developed to break through the limitation of Courant–Friedrich–Levy(CFL) condition.However, the eigenvalues and eigenvectors of the system matrix must be calculated before the time iteration in the explicit US-FDTD.Moreover, the eigenvalue decomposition is also time consuming, especially for complex electromagnetic problems in practical application.In addition, compared with the traditional FDTD method, the explicit US-FDTD method is more difficult to introduce the absorbing boundary and plane wave.To solve the drawbacks of the traditional FDTD and the explicit US-FDTD, a new hybrid FDTD algorithm is proposed in this paper.This combines the explicit US-FDTD with the traditional FDTD, which not only overcomes the limitation of CFL condition but also reduces the system matrix dimension, and introduces the plane wave and the perfectly matched layer(PML) absorption boundary conveniently.With the hybrid algorithm, the calculation of the eigenvalues is only required in the fine mesh region and adjacent coarse mesh region.Therefore, the calculation efficiency is greatly enhanced.Furthermore, the plane wave and the absorption boundary introduction of the traditional FDTD method can be directly utilized.Numerical results demonstrate the effectiveness, accuracy, stability, and convenience of this hybrid algorithm.
基金supported by the National Natural Science Foundation of China (No.50774005)
文摘Ni-P coated diamond powder was fabricated successfully by using electroless plating.Effects of active solutions,plating time,reaction temperature,and the components of the plating bath on the Ni-P coating were investigated systematically.Moreover,a study on the thermal stability of Ni-P coated diamond under various atmospheres was performed.The results indicate that Pd atoms absorbed on the diamond surface as active sites can consequently enhance the deposition rate of Ni effectively.The optimized plating bath and reaction conditions improve both the plating speed and the coverage rate of Ni-P electroless plating on the diamond surface.Compared to the diamond substrate,the diamond coated with Ni-P films exhibits very high thermal stability and can be processed up to 900°C in air and 1300°C in protective atmosphere such as H2.
基金funded by the National Natural Science Foundation of China (Grant No. 51174029 and No. 51374028)National High Technology Research and Development Program of China (No. 2013AA031005)Beijing Higher Education Young Elite Teacher Project (No. YETP0417)
文摘（38vo1% SiCp ＋ 2vo1% A1203f）/2024 A1 composites were fabricated by pressure infiltration. Graphite powder was introduced as a forming filler in preform preparation, and the effects of the powder size on the microstructures and mechanical properties of the final com- posites were investigated. The results showed that the composite with 15 μm graphite powder as a forming filler had the maximum tensile strength of 506 MPa, maximum yield strength of 489 MPa, and maximum elongation of 1.2%, which decreased to 490 MPa, 430 MPa, and 0.4%, respectively, on increasing the graphite powder size from 15 to 60 μm. The composite with 60 μm graphite powder showed the highest elastic modulus, and the value decreased from 129 to 113 GPa on decreasing the graphite powder size from 60 to 15 μm. The differences between these properties are related to the different microstructures of the corresponding composites, which determine their failure modes.
基金supported by the Science and Technology Project of Beijing (No. D09080300510901)National High Technology Research and Development Pro-gram of China (No. 2012AA03A514)
文摘The precipitation behavior of γ′ phase,under various interrupt cooling tests after 1170℃,solution treatment was examined.The results indicate that the size of secondary γ′ precipitates increases with the decrease of interrupt temperature,and the shape changes from spherical to butterfly like.The fine tertiary γ′ can form either during the post cool air quenching at high interrupt-temperatures,or during the specified 5℃ min-1cooling.Air quenching at high temperatures cannot suppress further nucleation of tertiary γ′ phase.
基金supported by the Science and Technology Planning Foundation of Beijing (No.D09080300510901)the National Natural Science Foundation of China (No.51104007)
文摘The influence of oxygen content and heat treatment on the evolution of carbides in a powder metallurgy （PM） Ni-base superalloy was characterized. The results reveal that oxygen content has little influence on the precipitation of carbides inside the particles. However, under the consolidated state, stable Ti oxides on the particle surface act as nuclei for the precipitation of prior particle boundaries （PPB）. Also, oxygen can diffuse internally along grain boundaries under compressive stress, which favors the precipitation of carbides inside the particles. Therefore, a higher amount of carbides will appear with more oxygen content in the case of consolidated alloys. It is also observed that PPB can be disrupted into discontinuous particles at 1200℃, but this carbide network is hard to be eliminated completely. The combined MC-M23C6 morphology approves the nucleation and growth mechanism of carbide evolution.
基金financially supported by the Fundamental Research Funds for the Central Universities of China (No. FRF-GF-17-B41)
文摘The method of calciothermic reduction of B4C was proposed for preparing CaB6.The phase transition and morphology evolution during the reaction were investigated in detail.The experimental results reveal that Ca first reacts with B4C to generate CaB2C2 and CaB6 at a low temperature and that the CaB2C2 subsequently reacts with Ca to produce CaB6 and CaC2 at a high temperature.After the products were leached to remove the byproduct CaC2,pure CaB6 was obtained.The grain size of the prepared CaB6 was 2–3μm,whereas its particle size was 4–13μm;it inherited the particle size of B4C.The residual C content of the product was decreased to 1.03 wt%after the first reaction at 1173 K for 4 h and the second reaction at 1623 K for 4 h.
基金financially supported by the National Natural Science Foundation of China (No. 51374028)Fundamental Research Funds for the Central Universities (FRF-GF-17-B37)
文摘Nickel-coated graphite flakes/copper（GN/Cu） composites were fabricated by spark plasma sintering with the surface of graphite flakes（GFs） being modified by Ni–P electroless plating. The effects of the phase transition of the amorphous Ni–P plating and of Ni diffusion into the Cu matrix on the densification behavior, interfacial microstructure, and thermal conductivity（TC） of the GN/Cu composites were systematically investigated. The introduction of Ni–P electroless plating efficiently reduced the densification temperature of uncoated GF/Cu composites from 850 to 650℃ and slightly increased the TC of the X–Y basal plane of the GF/Cu composites with 20 vol%–30 vol% graphite flakes. However, when the graphite flake content was greater than 30 vol%, the TC of the GF/Cu composites decreased with the introduction of Ni–P plating as a result of the combined effect of the improved heat-transfer interface with the transition layer, P generated at the interface, and the diffusion of Ni into the matrix. Given the effect of the Ni content on the TC of the Cu matrix and on the interface thermal resistance, a modified effective medium approximation model was used to predict the TC of the prepared GF/Cu composites.
基金financially supported by the National Natural Science Foundation of China (No. 51374028)
文摘Cr-coated diamond/Cu composites were prepared by spark plasma sintering. The effects of sintering pressure, sintering temperature, sintering duration, and Cu powder particle size on the relative density and thermal conductivity of the composites were investigated in this paper. The influence of these parameters on the properties and microstructures of the composites was also discussed. The results show that the relative density of Cr-coated diamond/Cu reaches ~100% when the composite is gradually compressed to 30 MPa during the heating process. The densification temperature increases from 880 to 915℃ when the diamond content is increased from 45vol% to 60vol%. The densification temperature does not increase further when the content reaches 65vol%. Cu powder particles in larger size are beneficial for increasing the relative density of the composite.
基金financially supported by the National Key R&D Program of China (Nos. 2016YFB0301402 and 2016YFB0301400)the National Natural Science Foundation of China (No. 51274040)
文摘Herein, graphite was used in the Si-vapor reactive infiltration of diamond/SiC/Si composites to produce composites with various Si C contents. X-ray diffraction was used to determine the phases of the composite, whereas scanning electron microscopy was used to confirm the Si–C reaction between the silicon, graphite, and diamond and to observe the SiC morphology. Various SiC contents in the composite were observed with graphite addition. Furthermore, the reaction between silicon and graphite(diamond) produced coarse(fine) SiC particles. The generation of a 10-μm-diameter Si–C area on the surface of the diamond was observed. The thermal conductivity(TC) and coefficient of thermal expansion(CTE) of the composite was investigated, where the TC varied from 317–426 W·m^-1·K^-1 with the increase of the SiC volume fraction from 38% to 76% and the corresponding CTE increased from 1.7 × 10^-6 to 3.7 × 10^-6 K^-1, respectively. Furthermore, a critical point for the CTE was found to exist at approximately 250℃, where the composite was under a hydrostatic condition. Finally, the bending strength was found to range from 241 to 341 MPa.
基金supported by the National Natural Science Foundation of China (NSFC, Grant Nos. 11633007 and 11661161010)supported by NSFC (Grant No. 11673078)
文摘The angular distribution of gamma-ray burst（GRB）jets is not yet clear.The observed luminosity of GRB 170817A is the lowest among all known short GRBs,which is best explained by the fact that our line of sight is outside of the jet opening angle,θ_（obs）〉θ_j,whereθ_（obs） is the angle between our line of sight and the jet axis.As inferred by gravitational wave observations,as well as radio and X-ray afterglow modeling of GRB 170817A,it is likely that θ_（obs）~20°–28°.In this work,we quantitatively consider two scenarios of angular energy distribution of GRB ejecta：a top-hat jet and a structured jet with a power law index s.For the top-hat jet model,we get a large θ_j（e.g.,θ_j〉10°）,a rather high local （i.e., z 〈 0.01） short GRB rate ~8–15×10~3 Gpc^（-3）yr~（-1（（estimated to be 90~1850 Gpc^（-3）yr^（-1） in Fong et al.）and an extremely high（on-axis,V（~500 ke V for a typical short GRB）.For the structured jet model,we use θ_（obs） to give limits on s and θ_j for typical on-axis luminosity of a short GRB（e.g.,10^（49）erg s（-1） 1051erg s（-1））,and a low on-axis luminosity case（e.g.,1049erg s（-1））gives more reasonable values of s.The structured jet model is more feasible for GRB170817A than the top-hat jet model due to the rather high local short GRB rate,and the extremely high on-axis E_（peak,0） almost rules out the top-hat jet model.GRB 170817A is likely a low on-axis luminosity GRB（1049erg s（-1））with a structured jet.
基金supported by the National Natural Science Foundation of China (Grant No.51701061)the Natural Science Foundation of Hebei Province (Grant Nos.E2019202059, E2020202124)the foundation strengthening program (Grant No. 2019-JCJQ-142)。
文摘A method which combines electronegativity difference,CALculation of PHAse Diagrams(CALPHAD) and machine learning has been proposed to efficiently screen the high yield strength regions in Co-Cr-Fe-Ni-Mo multi-component phase diagram.First,the single-phase region at a certain annealing temperature is obtained by combining CALPHAD method and machine learning,to avoid the formation of brittle phases.Then high yield strength points in the single-phase region are selected by electronegativity difference.The yield strength and plastic deformation behavior of the designed Co_(14)Cr_(30)Ni_(50)Mo_(6)alloy are measured to evaluate the proposed method.The validation experiments indicate this method is effective to predict high yield strength points in the whole compositional space.Meanwhile,the interactions between the high density of shear bands and dislocations contribute to the high ductility and good work hardening ability of Co_(14)Cr_(30)Ni_(50)Mo_(6)alloy.The method is helpful and instructive to property-oriented compositional design for multi-principal element alloys.
基金financially supported by Beijing Natural Science Foundation (No.2224105)the Science and Technology Innovation Fund of GRINM (No.12366)。
文摘Gallium-based liquid metal,as a high-performance thermal interface material,can improve the performance and service life of electronic equipment.This study focuses on the use of diamond as a thermal conductivity enhancement phase to improve the thermal conductivity of GaInSn liquid metal and avoid the overflow of liquid metal during application.In this study,diamond/GaInSn composites were prepared by an ultrasonic-assisted wetting method.The thermal conductivity and contact thermal resistance of diamond/GaInSn composites were characterized by the transient method.The morphology and thermal conductivity of diamond/GalnSn composites were investigated when diamond particles of different diameters were added to GaInSn liquid metal.The addition of large-sized diamond particles can effectively improve the thermal conductivity of thermal interface materials (TIMs) but willcause liquid metal to pump out.
基金financially supported by the National Natural Science Foundation of China (No.51274040)the Fundamental Research Funds for the Central Universities (No.FRF-TP-10-003B)
文摘This study was pertained to the effects of Ti coating on diamond surfaces and Si addition into Al matrix on the thermal conductivity（TC） and the coefficient of thermal expansion（CTE） of diamond/Al composites by pressure infiltration.The fracture surfaces,interface microstructures by metal electro-etching and interfacial thermal conductance of the composites prepared by two methods were compared.The results reveal that Ti coating on diamond surfaces and only12.2 wt% Si addition into Al matrix could both improve the interfacial bonding and increase the TCs of the composites.But the Ti coating layer introduces more interfacial thermal barrier at the diamond/Al interface compared to adding 12.2 wt% Si into Al matrix.The diamond/Al composite with 12.2 wt% Si addition exhibits maximum TC of 534 W·m^-1·K^-1and a very low CTE of 8.9×10^-6K^-1,while the coating Ti-diamond/Al composite has a TC of 514 W·m^-1·K^-1 and a CTE of 11.0×10^-6K^-1.
基金financially supported by the National Natural Science Foundation of China(No.51274040)the State Basic Research Development Program of China(No.2011CB606306)the Fundamental Research Funds for the Central Universities(No.FRF-TP-10-003B)
文摘To inhibit the graphitization of diamond under high temperature and low pressure, diamond/SiC composites were firstly fabricated by a rapid gaseous Si vacuum reactive infiltration process. The microstructure and graphitization behavior of diamond in the composites under various infiltration temperatures and holding time were investigated. The thermal conductivity of the resul- tant materials was discussed. The results show that the diamond-to-graphite transition is effectively inhibited at temperature of as high as 1600 ℃ under vacuum, and the substantial graphitization starts at 1700 ℃. The microstructure of those ungraphitized samples is uniform and fully densified. The inhibition mechanisms of graphitization include the isolation of the catalysts from diamond by a series of protective layers, high pressure stress applied on diamond by the reaction-bonded SiC, and the moderate gas-solid reaction. For the graphitized samples, the boundary between diamond and SiC is coarse and loose. The graphitization mechanism is considered to be an initial detachment of the bilayers from the diamond surfaces, and subsequently flattening to form graphite. The ungraphitized samples present higher thermal conductivity of about 410 W.m-1.K-1 due to the fine interfacial structure. For the graphitized samples, the thermal conductivity decreases significantly to 285 W.m-1.K-1 as a result of high interfacial thermal resistance.
基金financially supported by Heyuan Science and Technology Project(No.HEKE 000781)the Science and Technology Projects of Guangdong Province(No.2016B090914001)Jihua Laboratory Project“Additive Manufacturing for Difficulty-to-Machine Materials”(No.X190061UZ190)。
文摘TiC-316 L metal matrix composites were successfully printed with an epoxy resin-absolute ethanol system by direct ink writing(DIW) process in this study.Microstructure and fracture morphology of the samples were observed by a scanning electron microscope(SEM).Also,the relative density,hardness and transverse rupture strength(TRS) of the sintered samples were tested.The results show that the samples prepared with a new epoxy resin-absolute ethanol system by the DIW process have high solid content of printing slurry,good surface roughness,high relative density and high strength.The solid content of the slurry suitable for DIW was 60 vol%,and the internal diameter of the nozzle was set to 0.4 mm,the printing speed was set to 30 mm·s^(-1),and the layer height was set to 0.36 mm.For the sample with 35 wt% TiC-316 L,the relative density,hardness and TRS of the sintered sample can reach 99.3%,HRA 79.5 and 1438 MPa,respectively.
