Industrially prepared artificial graphite(AG)is attractive for potassium-ion batteries(PIBs),but its rate performance is poor and the production process is energy intensive,so developing an efficient strategy to produ...Industrially prepared artificial graphite(AG)is attractive for potassium-ion batteries(PIBs),but its rate performance is poor and the production process is energy intensive,so developing an efficient strategy to produce novel graphite with low energy consumption and high performance is economically important.Herein,a nanostructured graphite composed of multi-walled carbon nanotubes(MWCNTs)and graphite shells was prepared by one-pot method through low-temperature pyrolysis of iron-based metal-organic framework(MOF)and carbon source.The high graphitization degree of nanostructured graphite makes the initial Coulombic efficiency(ICE)exceed 80%,and the three-dimensional(3D)conductive network ensures a specific capacity of 234 mAh·g^(−1)after 1000 cycles at a high current density of 500 mA·g^(−1).In addition,the typical graphite potassium storage mechanism is also demonstrated by in situ X-ray diffraction(XRD)and in situ Raman spectroscopy,and its practicality is also proved by the voltage of the full cells.This work provides a feasible way to optimize the practical production process of AG and expand its application in energy storage.展开更多
This paper investigates the cooperative output regulation problem of linear multi-agent systems with a linear exogenous system(exo-system).The network topology is described by a directed graph which contains a directe...This paper investigates the cooperative output regulation problem of linear multi-agent systems with a linear exogenous system(exo-system).The network topology is described by a directed graph which contains a directed spanning tree with the exo-system as the root.Aiming at improving the transient performance of the multi-agent systems,a dynamic control law is developed by the composite nonlinear feedback(CNF)control technique.In particular,a distributed dynamic compensator independent of the interaction on the compensator states of agents among the network,is adopted.The solvability condition for the cooperative output regulation problem is obtained using the small-gain theory,which will not be destroyed by adding the nonlinear feedback part of the CNF control law.It is also shown that in the case with the exo-system not diverging exponentially,the small-gain condition can be guaranteed using the low-gain design.Finally,simulation results illustrate that the proposed CNF control law improves the transient performance for the cooperative output regulation of linear multi-agent systems.展开更多
基金the financial support from the National Key Research and Development Program of China(Nos.2022YFB2404300 and 2023YFB3809303)the National Natural Science Foundation of China(Nos.51832004 and 52127816)State Key Laboratory of Advanced Technology for Materials Synthesis and Processing(No.WUT:2022-KF-4).
文摘Industrially prepared artificial graphite(AG)is attractive for potassium-ion batteries(PIBs),but its rate performance is poor and the production process is energy intensive,so developing an efficient strategy to produce novel graphite with low energy consumption and high performance is economically important.Herein,a nanostructured graphite composed of multi-walled carbon nanotubes(MWCNTs)and graphite shells was prepared by one-pot method through low-temperature pyrolysis of iron-based metal-organic framework(MOF)and carbon source.The high graphitization degree of nanostructured graphite makes the initial Coulombic efficiency(ICE)exceed 80%,and the three-dimensional(3D)conductive network ensures a specific capacity of 234 mAh·g^(−1)after 1000 cycles at a high current density of 500 mA·g^(−1).In addition,the typical graphite potassium storage mechanism is also demonstrated by in situ X-ray diffraction(XRD)and in situ Raman spectroscopy,and its practicality is also proved by the voltage of the full cells.This work provides a feasible way to optimize the practical production process of AG and expand its application in energy storage.
基金This work was supported in part by the National Natural Science Foundation of China under Grants 62273285 and 62173283in part by the Natural Science Foundation of Fujian Province of China under Grants 2021J01051.
文摘This paper investigates the cooperative output regulation problem of linear multi-agent systems with a linear exogenous system(exo-system).The network topology is described by a directed graph which contains a directed spanning tree with the exo-system as the root.Aiming at improving the transient performance of the multi-agent systems,a dynamic control law is developed by the composite nonlinear feedback(CNF)control technique.In particular,a distributed dynamic compensator independent of the interaction on the compensator states of agents among the network,is adopted.The solvability condition for the cooperative output regulation problem is obtained using the small-gain theory,which will not be destroyed by adding the nonlinear feedback part of the CNF control law.It is also shown that in the case with the exo-system not diverging exponentially,the small-gain condition can be guaranteed using the low-gain design.Finally,simulation results illustrate that the proposed CNF control law improves the transient performance for the cooperative output regulation of linear multi-agent systems.
