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基于非亲核电解液构建稳定的镁离子电池
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作者 谢茂玲 王钧 +5 位作者 胡晨吉 郑磊 孔华彬 沈炎宾 陈宏伟 陈立桅 《电化学》 CAS CSCD 北大核心 2022年第3期131-138,共8页
非亲核电解液被认为是新一代可用于镁离子电池的高稳定电解液。但由于电解液容易在镁金属表面产生不传导镁离子的钝化层,导致镁的电化学沉积/溶出过程在该电解液中表现出动力学缓慢、库仑效率较低等缺点。在本研究中,我们通过在非亲核... 非亲核电解液被认为是新一代可用于镁离子电池的高稳定电解液。但由于电解液容易在镁金属表面产生不传导镁离子的钝化层,导致镁的电化学沉积/溶出过程在该电解液中表现出动力学缓慢、库仑效率较低等缺点。在本研究中,我们通过在非亲核电解液中引入二苯二硫醚(PDF)添加剂以实现对镁金属电极的界面调控。研究表明PDF产生的苯基硫醇盐中间体可以紧密结合在镁金属表面,并显著抑制了镁金属表面钝化层的生成。经界面优化后的镁金属电极的沉积-溶出库仑效率高达99.5%,并且表现出显著降低的过电位。利用此电解液,并以镁金属为负极、Mo;S;Se为正极构建的镁离子电池在室温下可稳定循环150周(0.1 C)。这类通过添加剂优化镁金属界面的策略也将有助于推进其他类型的镁离子电解液的实际应用。 展开更多
关键词 镁离子电池 非亲核电解质 电极界面 添加剂 二苯二硫醚
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Active structures integrated with wireless sensor and actuator networks: a bio-inspired control framework 被引量:1
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作者 Peng-cheng YANG yan-bin shen Yao-zhi LUO 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2016年第4期253-272,共20页
One of the main problems in controlling the shape of active structures (AS) is to determine the actuations that drive the structure from the current state to the target state. Model-based methods such as stochastic ... One of the main problems in controlling the shape of active structures (AS) is to determine the actuations that drive the structure from the current state to the target state. Model-based methods such as stochastic search require a known type of load and relatively long computational time, which limits the practical use of AS in civil engineering. Moreover, additive errors may be produced because of the discrepancy between analytic models and real structures. To overcome these limitations, this paper presents a compound system called WAS, which combines AS with a wireless sensor and actuator network (WSAN). A bio-inspired control framework imitating the activity of the nervous systems of animals is proposed for WAS. A typical example is tested for verification. In the example, a triangular tensegrity prism that aims to maintain its original height is integrated with a WSAN that consists of a central controller, three actuators, and three sensors. The result demonstrates the feasibility of the proposed concept and control framework in cases of unknown loads that include different types, distributions, magnitudes, and directions. The proposed control framework can also act as a supplementary means to improve the efficiency and accuracy of control frameworks based on a common stochastic search. 展开更多
关键词 Active structures (AS) Wireless sensor and actuator networks (WSAN) Shape control Bio-inspired control
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Static control method using gradient-genetic algorithm for grillage adaptive beam string structures based on minimal internal force
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作者 yan-bin shen Hao-song SUN +3 位作者 An-dong LEI Xiao-yuan YING Guang YANG Yao-zhi LUO 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2022年第9期721-732,共12页
The grillage adaptive beam string structure(GABSS)is a new type of smart structure that can self-adjust its deformation and internal forces through a group of active struts(actuators)in response to changes in environm... The grillage adaptive beam string structure(GABSS)is a new type of smart structure that can self-adjust its deformation and internal forces through a group of active struts(actuators)in response to changes in environmental conditions.In this paper,an internal force control method based on a gradient–genetic algorithm(GGA)is proposed for the static control of a tensioned structure(especially the GABSS).Specifically,an optimization model of the GABSS is established in which the adjustment values of the actuators are set as the control variables,and the internal force of the beam is set as the objective function.The improved algorithm has the advantage of the global optimization ability of the genetic algorithm and the local search ability of the gradient algorithm.Two examples are provided to illustrate the application of the GGA method.The results show that the proposed method is practical for solving the internal force control problem of the GABSS. 展开更多
关键词 Grillage adaptive beam string structure(GABSS) Gradient-genetic algorithm(GGA) Structural control Adaptive structure Actuator
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