The ocean accounts for approximately 71%of the total area of the Earth.Whether it is studying the shape of the Earth itself through geodesy or the future development of earth system science,strengthening the construct...The ocean accounts for approximately 71%of the total area of the Earth.Whether it is studying the shape of the Earth itself through geodesy or the future development of earth system science,strengthening the construction of ocean geodesy disciplines and innovating ocean geodetic observation technologies have evident theoretical and practical significance.In recent years,the discipline of ocean geodesy in China has been continuously developing and growing,and notable breakthroughs have been made in ocean satellite geodesy and seafloor geodetic observation technology.Research on ocean geodetic observation models and algorithms has also made great progress.展开更多
The reliability theory has been an important element of the classical geodetic adjustment theory and methods in the linear Gauss-Markov model. Although errors-in-variables(EIV) models have been intensively investigate...The reliability theory has been an important element of the classical geodetic adjustment theory and methods in the linear Gauss-Markov model. Although errors-in-variables(EIV) models have been intensively investigated, little has been done about reliability theory for EIV models. This paper first investigates the effect of a random coefficient matrix A on the conventional geodetic reliability measures as if the coefficient matrix were deterministic. The effects of such geodetic internal and external reliability measures due to the randomness of the coefficient matrix are worked out, which are shown to depend not only on the noise level of the random elements of A but also on the values of parameters. An alternative, linear approximate reliability theory is accordingly developed for use in EIV models. Both the EIV-affected reliability measures and the corresponding linear approximate measures fully account for the random errors of both the coefficient matrix and the observations, though formulated in a slightly different way. Numerical experiments have been carried to demonstrate the effects of errors-in-variables on reliability measures and compared with the conventional Baarda's reliability measures. The simulations have confirmed our theoretical results that the EIV-reliability measures depend on both the noise level of A and the parameter values. The larger the noise level of A, the larger the EIV-affected internal and external reliability measures;the larger the parameters,the larger the EIV-affected internal and external reliability measures.展开更多
Seafloor geodetic network construction involves the development of geodetic station shelter, network configuration design, location selection and layout, surveying strategy, observation model establishment and optimiz...Seafloor geodetic network construction involves the development of geodetic station shelter, network configuration design, location selection and layout, surveying strategy, observation model establishment and optimization, data processing strategy and so on. This paper tries to present main technological problems involved in the seafloor geodetic network construction, and seek the technically feasible solutions. Basic conceptions of developing seafloor geodetic station shelters for shallow sea and deep-sea are described respectively. The overall criteria of seafloor geodetic network construction for submarine navigation and those of network design for crustal motion monitoring are both proposed. In order to enhance application performances of the seafloor geodetic network, the seafloor network configuration should prefer a symmetrical network structure. The sea surface tracking line measurements for determining the seafloor geodetic station position should also adopt an approximately symmetrical configuration, and we recommend circle tracking line observations combined with cross-shaped line(or double cross-shape line) observations for the seafloor positioning mode. As to the offset correction between the Global Navigation Satellite System antenna phase center and the acoustic transducer, it is recommended to combine the calibration through external measurements and model parameter estimation. Besides, it is suggested to correct the sound speed error with a combination of observation value correction and parameterized model correction, and to mainly use the model correction to reduce the influence of acoustic ray error on the seafloor positioning. Following the proposed basic designs, experiments are performed in shallow sea area and deep-sea area respectively. Based on the developed seafloor geodetic shelter and sufficient verification in the shallow sea experiment, a long-term seafloor geodetic station in the deep-sea area of 3000 m depth was established for the first time, and the preliminary positioning result shows that the internal precision of this station is better than 5 cm.展开更多
To develop a convenient method for sensitive and selective determination of Ce3＋ in aqueous phase with complicated matrices, a carbon paste electrode（CPE） modified with ion imprinted polymers（IIPs） were fabricate...To develop a convenient method for sensitive and selective determination of Ce3＋ in aqueous phase with complicated matrices, a carbon paste electrode（CPE） modified with ion imprinted polymers（IIPs） were fabricated. The polymers were prepared by precipitation polymerization using Ce3＋ as template, allyl phenoxyacetate（APA） as monomer, ethylene glycol dimethacrylate（EGDMA） as crosslinker and azobisisobutyronitrile（AIBN） as initiator under the molar ratio of Ce3＋, APA and EGDMA as 1：4：40, respectively. Ce3＋ was detected directly by differential pulse adsorptive stripping voltammetry（DPASV） and its oxidation peak appears at about 0.93 V. All parameters affecting the sensor＇s response are optimized and a calibration curve is plotted at a linear range of 1.0 × 10^（-6）-1.0 x 10^（-5） mol/L and 1.0×10^（-5）-2.0 × 10^（-4）mol/L with the detection limit of 1.5 × 10^（-7） mol/L. All other rare earth ions have no interference with the determination of Ce^（3＋） even at a concentration 500 times higher than that of Ce^（3＋）.This sensor was successfully applied to determination of Ce^（3＋） in two catalyst sample solutions with RSD≤3.3%（n = 5）and recoveries in the range of 99.2%-106.5% at our optimal conditions.展开更多
基金National Natural Science Foundation of China(No.41931076)Laoshan Laboratory(No.LSKJ202205105)+1 种基金National Key R&D Program of China(No.2020YFB0505802)State Key Laboratory of Geo-information Engineering(No.SKLGIE2020-M-1-1)。
文摘The ocean accounts for approximately 71%of the total area of the Earth.Whether it is studying the shape of the Earth itself through geodesy or the future development of earth system science,strengthening the construction of ocean geodesy disciplines and innovating ocean geodetic observation technologies have evident theoretical and practical significance.In recent years,the discipline of ocean geodesy in China has been continuously developing and growing,and notable breakthroughs have been made in ocean satellite geodesy and seafloor geodetic observation technology.Research on ocean geodetic observation models and algorithms has also made great progress.
基金supported by the National Natural Science Foundation of China, Project No. 42174045under National Key Research and Development Program of China, Project No.2020YFB0505805the National Natural Science Foundation of China, Project No. 41874012。
文摘The reliability theory has been an important element of the classical geodetic adjustment theory and methods in the linear Gauss-Markov model. Although errors-in-variables(EIV) models have been intensively investigated, little has been done about reliability theory for EIV models. This paper first investigates the effect of a random coefficient matrix A on the conventional geodetic reliability measures as if the coefficient matrix were deterministic. The effects of such geodetic internal and external reliability measures due to the randomness of the coefficient matrix are worked out, which are shown to depend not only on the noise level of the random elements of A but also on the values of parameters. An alternative, linear approximate reliability theory is accordingly developed for use in EIV models. Both the EIV-affected reliability measures and the corresponding linear approximate measures fully account for the random errors of both the coefficient matrix and the observations, though formulated in a slightly different way. Numerical experiments have been carried to demonstrate the effects of errors-in-variables on reliability measures and compared with the conventional Baarda's reliability measures. The simulations have confirmed our theoretical results that the EIV-reliability measures depend on both the noise level of A and the parameter values. The larger the noise level of A, the larger the EIV-affected internal and external reliability measures;the larger the parameters,the larger the EIV-affected internal and external reliability measures.
基金supported by National Key Research and Development Program of China (Grant No. 2016YFB0501700)National Natural Science Foundation of China (Grant Nos. 41931076, 41874016 & 61801137)。
文摘Seafloor geodetic network construction involves the development of geodetic station shelter, network configuration design, location selection and layout, surveying strategy, observation model establishment and optimization, data processing strategy and so on. This paper tries to present main technological problems involved in the seafloor geodetic network construction, and seek the technically feasible solutions. Basic conceptions of developing seafloor geodetic station shelters for shallow sea and deep-sea are described respectively. The overall criteria of seafloor geodetic network construction for submarine navigation and those of network design for crustal motion monitoring are both proposed. In order to enhance application performances of the seafloor geodetic network, the seafloor network configuration should prefer a symmetrical network structure. The sea surface tracking line measurements for determining the seafloor geodetic station position should also adopt an approximately symmetrical configuration, and we recommend circle tracking line observations combined with cross-shaped line(or double cross-shape line) observations for the seafloor positioning mode. As to the offset correction between the Global Navigation Satellite System antenna phase center and the acoustic transducer, it is recommended to combine the calibration through external measurements and model parameter estimation. Besides, it is suggested to correct the sound speed error with a combination of observation value correction and parameterized model correction, and to mainly use the model correction to reduce the influence of acoustic ray error on the seafloor positioning. Following the proposed basic designs, experiments are performed in shallow sea area and deep-sea area respectively. Based on the developed seafloor geodetic shelter and sufficient verification in the shallow sea experiment, a long-term seafloor geodetic station in the deep-sea area of 3000 m depth was established for the first time, and the preliminary positioning result shows that the internal precision of this station is better than 5 cm.
基金Project supported by the National Natural Science Foundation of China(21465025)the Doctoral Fund of Ministry of Education of China(20125301110005)the Science Foundation of Yunnan Province(2017FB012)
文摘To develop a convenient method for sensitive and selective determination of Ce3＋ in aqueous phase with complicated matrices, a carbon paste electrode（CPE） modified with ion imprinted polymers（IIPs） were fabricated. The polymers were prepared by precipitation polymerization using Ce3＋ as template, allyl phenoxyacetate（APA） as monomer, ethylene glycol dimethacrylate（EGDMA） as crosslinker and azobisisobutyronitrile（AIBN） as initiator under the molar ratio of Ce3＋, APA and EGDMA as 1：4：40, respectively. Ce3＋ was detected directly by differential pulse adsorptive stripping voltammetry（DPASV） and its oxidation peak appears at about 0.93 V. All parameters affecting the sensor＇s response are optimized and a calibration curve is plotted at a linear range of 1.0 × 10^（-6）-1.0 x 10^（-5） mol/L and 1.0×10^（-5）-2.0 × 10^（-4）mol/L with the detection limit of 1.5 × 10^（-7） mol/L. All other rare earth ions have no interference with the determination of Ce^（3＋） even at a concentration 500 times higher than that of Ce^（3＋）.This sensor was successfully applied to determination of Ce^（3＋） in two catalyst sample solutions with RSD≤3.3%（n = 5）and recoveries in the range of 99.2%-106.5% at our optimal conditions.
基金supported by the National Natural Science Foundation of China (41776038 and 41821004)the International Cooperation Project of Indo-Pacific Ocean Environment Variation and Air-Sea Interaction (GASI-IPOVAI-05)。
