To better understand the role of the-NH_(2)group in adsorption process of phenolic wastewaters,NH_(2)-functionalized MIL-53(Al)composites with activated carbon(NH_(2)-M(Al)@(B)AC)were prepared.The results showed that ...To better understand the role of the-NH_(2)group in adsorption process of phenolic wastewaters,NH_(2)-functionalized MIL-53(Al)composites with activated carbon(NH_(2)-M(Al)@(B)AC)were prepared.The results showed that the-NH_(2)group could increase the mesopore volume for composites,which promotes mass transfer and full utilization of active sites,because hierarchical mesopore structure makes the adsorbent easier to enter the internal adsorption sites.Furthermore,the introduction of the-NH_(2)group can improve the adsorption capacity,decrease the activation energy,and enhance the interaction between the adsorbent and p-nitrophenol,demonstrating that the-NH_(2)group plays a crucial role in the adsorption of p-nitrophenol.The density functional theory calculation results show that the H-bond interaction between the-NH_(2)group in the adsorbent and the-NO_(2)in the p-nitrophenol(adsorption energy of -35.5 kJ·mol^(-1)),and base-acid interaction between the primary-NH_(2)group in the adsorbent and the acidic-OH group in the p-nitrophenol(adsorption energy of -27.3 kJ·mol^(-1))are predominant mechanisms for adsorption in terms of the NH_(2)-functionalized adsorbent.Both NH_(2)-functionalized M(Al)@AC and M(Al)@BAC composites exhibited higher p-nitrophenol adsorption capacity than corresponding nonfunctionalized composites.Among the composites,the NH_(2)-M(Al)@BAC had the highest p-nitrophenol adsorption capacity of 474 mg·g^(-1).展开更多
k holomorphic functions are a type of generation of holomorphic functions.In this paper,a nonlinear boundary value problem for k holomorphic functions is primarily discussed on generalized polycylinders in C^(2).The e...k holomorphic functions are a type of generation of holomorphic functions.In this paper,a nonlinear boundary value problem for k holomorphic functions is primarily discussed on generalized polycylinders in C^(2).The existence of the solution for the problem is studied in detail with the help of the boundary properties of Cauchy type singular integral operators with a k holomorphic kernel.Furthermore,the integral representation for the solution is obtained.展开更多
With the recent development of high entropy materials, an alternative approach to develop advanced functional materials with distinctive properties that show improved values compared to conventional materials has been...With the recent development of high entropy materials, an alternative approach to develop advanced functional materials with distinctive properties that show improved values compared to conventional materials has been provided. The high entropy concept was later successfully transferred to metal fluorides and high entropy fluorides(HEFs) were successfully synthesized. Owing to their high theoretical specific capacities in energy storage applications, HEFs were utilized as cathode materials for lithiumion batteries(LIBs) and their underlying storage mechanisms were investigated. Instead of a step-bystep reduction of each individual metal cation, the HEFs seem to exhibit a single-step reduction process,indicating a solid solution compound instead of merely a mixture of different metal fluorides. It was also observed that the electrochemical behavior of the HEFs depends on each individual incorporated element. Therefore, by altering the elemental composition, new materials that exhibit improved electrochemical properties can be designed. Remarkably, HEFs with seven incorporated metal elements exhibited a better cycling stability as well as a lower hysteresis compared to binary metal fluorides.These findings offer new guidelines for material design and tailoring towards high performance LIBs.展开更多
We mainly discuss the invariance of some subclasses of biholomorphic mappings under the generalized Roper-Suffridge operators on Bergman-Hartogs domains which are based on the unit ball Bn. Using the geometric propert...We mainly discuss the invariance of some subclasses of biholomorphic mappings under the generalized Roper-Suffridge operators on Bergman-Hartogs domains which are based on the unit ball Bn. Using the geometric properties and the distortion results of subclasses of biholomorphic mappings, we obtain the geometric characters of almost spirallike mappings of type β and order α, S_?~*(β, A, B), strong and almost spirallike mappings of type βand order α maintained under the generalized Roper-Suffridge operators on Bergman-Hartogs domains. Sequentially, we conclude that the generalized operators and the known operators preserve the same properties under some conditions. The conclusions generalize some known results.展开更多
In this article, we mainly study the invariance of some biholomorphic mappings with special geometric characteristics under the extension operators. First we generalize the Roper-Suffridge extension operators on Bergm...In this article, we mainly study the invariance of some biholomorphic mappings with special geometric characteristics under the extension operators. First we generalize the Roper-Suffridge extension operators on Bergman-Hartogs domains. Then, by the geometric characteristics of subclasses of biholomorphic mappings, we conclude that the modified Roper-Suff ridge operators preserve the properties of S_Ω~*(β,A, B), parabolic and spirallike mappings of type β and order p, strong and almost spirallike mappings of type 0 and orderα as well as almost starlike mappings of complex order λ on Ω_(p1,…,ps,q)^(B^n) under different conditions, respectively. The conclusions provide new approaches to construct these biholomorphic mappings in several complex variables.展开更多
In this article, we extend the well-known Roper-Suffridge operator on Bn+1 and bounded complete Reinhardt domains in Cn+1, then we investigate the properties of the generalized operators. Applying the Loewner theory, ...In this article, we extend the well-known Roper-Suffridge operator on Bn+1 and bounded complete Reinhardt domains in Cn+1, then we investigate the properties of the generalized operators. Applying the Loewner theory, we obtain the mappings constructed by the generalized operators that have parametric representation on Bn+1. In addition, by using the geometric characteristics and the parametric representation of subclasses of spirallike mappings, we conclude that the extended operators preserve the geometric properties of several subclasses of spirallike mappings on Bn+1 and bounded complete Reinhardt domains in Cn+1. The conclusions provide new approaches to construct mappings with special geometric properties in Cn+1.展开更多
Objective:To analyze the efficacy of capecitabine(referred to as Cap)single-agent maintenance therapy in the advanced breast cancer.Methods:The subjects of the study were 50 patients with advanced breast cancer who we...Objective:To analyze the efficacy of capecitabine(referred to as Cap)single-agent maintenance therapy in the advanced breast cancer.Methods:The subjects of the study were 50 patients with advanced breast cancer who were admitted to our hospital between March 2016 and March 2019.They were divided into groups A and B with 25 cases each.The subjects of these two groups were treated conventional method,respectively.And then,Capecitabine maintenance therapy was continued for group A,clinical observation for groups B.Progressionfree survival(PFS)was compared between the two groups.Results:The median PFS was 14.2 months for group A and 8.9 months for group B(P<0.05).The complication rate of group A was 24.0%compared to that of group B was 22.0%(P>0.05).Conclusion:The patients with advanced breast cancer who received Cap maintenance therapy were benefited from better curative effect and controllable complications,which has high promotion value.展开更多
In this paper,the authors extend the Roper-Suffridge operator on the generalized Hartogs domains.They mainly research the properties of the extended operator.By the characteristics of Hartogs domains and the geometric...In this paper,the authors extend the Roper-Suffridge operator on the generalized Hartogs domains.They mainly research the properties of the extended operator.By the characteristics of Hartogs domains and the geometric properties of subclasses of spirallike mappings,they obtain the extended Roper-Suffridge operator preserving almost starlikeness of complex orderλ,almost spirallikeness of typeβand orderα,parabolic spirallikeness of typeβand orderρon the Hartogs domains in different conditions.They conclude that the corresponding extension operator preserves the same geometric invariance on the unit ball B^(n) in C^(n).The conclusions provide a new approach to study these geometric mappings in C^(n).展开更多
The authors propose a new approach to construct subclasses of biholomorphic mappings with special geometric properties in several complex variables. The RoperSuffridge operator on the unit ball B^n in C^n is modified....The authors propose a new approach to construct subclasses of biholomorphic mappings with special geometric properties in several complex variables. The RoperSuffridge operator on the unit ball B^n in C^n is modified. By the analytical characteristics and the growth theorems of subclasses of spirallike mappings, it is proved that the modified Roper-Suffridge operator [Φ_(G,γ)(f)](z) preserves the properties of S_Ω~*(A, B), as well as strong and almost spirallikeness of type β and order α on B^n. Thus, the mappings in S_Ω~*(A, B), as well as strong and almost spirallike mappings, can be constructed through the corresponding functions in one complex variable. The conclusions follow some special cases and contain the elementary results.展开更多
Mitsugumin 53 (MG53), a newly identified muscle-specific protein, is an essential component of the cell membrane repair machinery in skeletal and cardiac muscle. However, the role of MG53 after burns in other tissues ...Mitsugumin 53 (MG53), a newly identified muscle-specific protein, is an essential component of the cell membrane repair machinery in skeletal and cardiac muscle. However, the role of MG53 after burns in other tissues remains unclear. This study aims to investigate the possible roles of MG53 in the protection of the kidney after severe burn injury, and an animal scalding model of 30% of total body surface area (TBSA) was used. Recombinant human MG53 (rhMG53) or bovine serum albumin (BSA) was injected intravenously via the tail vein. Data showed that the mortality in the MG53-treated group was lower than that in control group. Administration of rhMG53 may alleviate histological alterations in renal tubular epithelial cells after burn injury. Renal tubular injury scores and the average optical density score of kidney injury molecule-1 (KIM-1) immunohistochemical staining in the MG53-treated group were significantly lower than those in control group (P < 0.001). Exogenous rhMG53 was found to be located in renal tubular epithelial cells. Numerous polymerase I and transcript release factor (PTRF) were expressed in the mouse kidney after severe scalding. In conclusion, our data indicate that MG53 protein protects the kidney by involving local PTRF after severe burn injury.展开更多
Mercury ion(Hg2+) pollution exists in water, soil, and food. By interacting with the thiol groups in protein, Hg2+ ions can accumulate in ways that cause serious damage to the central nervous system and threaten human...Mercury ion(Hg2+) pollution exists in water, soil, and food. By interacting with the thiol groups in protein, Hg2+ ions can accumulate in ways that cause serious damage to the central nervous system and threaten human health and natural environment. Undoubtedly, Hg2+ ion detection is a significant issue in environment and health monitoring. A variety of sensor platforms for Hg2+ ion detection based on organic molecules, DNA, oligonucleotides, inorganic materials, etc, have been reported. In this paper, an artificial peptide PHg, with a cluster bio-mineralize sequence(CCY) and a multi-charge hydrophilic sequence is designed as a template for the one-step synthesis of a peptide-Au cluster probe. Briefly: the peptide PHg in situ anchors Au ions to form a peptide-Au(I) intermediate and the reaction p H with Na OH is adjusted; after 12 h incubation at room temperature, the peptide PHg-Au nanocluster probe with red fluorescence is obtained. The probe has a super-small core size of approximately 1.26 nm and a maximum emission peak at 650 nm. The presence of Hg2+ ions cause the fluorescence of the probe to greatly decrease. Based on the differences in fluorescence intensity of the PHg-Au nanocluster in the absence and presence of Hg2+ ions, Hg2+ ions could be quantitatively detected in concentrations ranging from 5 nmol/L to 1 ?mol/L. The limit of detection(LOD) is 7.5 nmol/L. Compared with some interference ions such as, K+, Mg2+, Ca2+, Pb2+, Ni2+, Fe3+, and Cu2+, the selectivity was excellent. The sensing of Hg2+ ion is not affected by the chelate agents: EDTA, which imparts a significant advantage in a range of applications. As a result, a simple, sensitive and selective fluorescent assay based on peptide PHg-Au cluster is developed for the detection of Hg2+ ions.展开更多
Heterojunction is regarded as a crucial step toward realizing high-performance devices,particularly,forming gradient energy band between heterojunctions benefits self-powered photodetectors.Therefore,in this paper,the...Heterojunction is regarded as a crucial step toward realizing high-performance devices,particularly,forming gradient energy band between heterojunctions benefits self-powered photodetectors.Therefore,in this paper,the synthesis of CsPbI3 nanorods(NRs)and its application as the interfacial layer in high-performance,all-solution-processed self-powered photodetectors are presented.For the bilayer photodetector ITO/ZnO(100 nm)/PbS-TBAI(150 nm)/Au,a responsivity of 3.6 A/W with a specific detectivity of 9.8×10^(12)Jones was obtained under 0.1 mW/cm^(2)white light illumination at zero bias(i.e.in self-powered mode).Meanwhile,the photocurrent was enhanced to an On/Off current ratio of 105 at zero bias with an open circuit voltage of 0.53 V for trilayer photodetector ITO/ZnO(100 nm)/PbSTBAI(150 nm)/CsPbI3(250 nm)/Au,in which the CsPbI3 NRs layer works as the interfacial layer.As a result,a specific detectivity of 4.5×10^(13)Jones with a responsivity of 11.12 A/W was obtained under0.1 mW/cm^(2) white light illumination,as well as the rising/decaying time of 0.57 s/0.41 s with excellent stability and reproducibility upto four weeks in air.The enhanced-performance is ascribed to the mismatch bandgap between PbS-TBAI/CsPbI_(3)interface,which can suppress the carrier recombination and provide efficient transport passages for charge carriers.Thus,it provides a feasible and efficient method for high-performance photodetectors.展开更多
The flow distribution and mixing performance of the laminar flow in the PBT impeller-stirred tank were investigated in this study.The variation along with mixing time of the flow distribution and concentration at the ...The flow distribution and mixing performance of the laminar flow in the PBT impeller-stirred tank were investigated in this study.The variation along with mixing time of the flow distribution and concentration at the selected positions was visualized by means of the CFD and experiment methods.The CFD simulations results had a good agreement with the experimental results.In order to minish the Segregated Regions,the PBT impeller was optimally designed by means of orthogonal factorial experiment with selecting theθ99 mixing time as evaluation criteria.With the aim to increase the mixing efficiency,the optimal design results were obtained with the geometrical parameters of impeller diameter of 0.084 m,discharge angle of 45º,blade width of 0.018 m,and clearance of 0.05 m,and the mixing time of the optimal impeller-stirred flow was about 180 s,so this optimal design PBT impeller is more proper for the agricultural industries.展开更多
基金supported by the National Natural Science Foundation of China(22008134)。
文摘To better understand the role of the-NH_(2)group in adsorption process of phenolic wastewaters,NH_(2)-functionalized MIL-53(Al)composites with activated carbon(NH_(2)-M(Al)@(B)AC)were prepared.The results showed that the-NH_(2)group could increase the mesopore volume for composites,which promotes mass transfer and full utilization of active sites,because hierarchical mesopore structure makes the adsorbent easier to enter the internal adsorption sites.Furthermore,the introduction of the-NH_(2)group can improve the adsorption capacity,decrease the activation energy,and enhance the interaction between the adsorbent and p-nitrophenol,demonstrating that the-NH_(2)group plays a crucial role in the adsorption of p-nitrophenol.The density functional theory calculation results show that the H-bond interaction between the-NH_(2)group in the adsorbent and the-NO_(2)in the p-nitrophenol(adsorption energy of -35.5 kJ·mol^(-1)),and base-acid interaction between the primary-NH_(2)group in the adsorbent and the acidic-OH group in the p-nitrophenol(adsorption energy of -27.3 kJ·mol^(-1))are predominant mechanisms for adsorption in terms of the NH_(2)-functionalized adsorbent.Both NH_(2)-functionalized M(Al)@AC and M(Al)@BAC composites exhibited higher p-nitrophenol adsorption capacity than corresponding nonfunctionalized composites.Among the composites,the NH_(2)-M(Al)@BAC had the highest p-nitrophenol adsorption capacity of 474 mg·g^(-1).
基金the NSF of China(11571089,11871191)the NSF of Henan Province(222300420397)+1 种基金the NSF of Hebei Province(A2022208007)the Key Foundation of Hebei Normal University(L2018Z01)。
文摘k holomorphic functions are a type of generation of holomorphic functions.In this paper,a nonlinear boundary value problem for k holomorphic functions is primarily discussed on generalized polycylinders in C^(2).The existence of the solution for the problem is studied in detail with the help of the boundary properties of Cauchy type singular integral operators with a k holomorphic kernel.Furthermore,the integral representation for the solution is obtained.
基金the financial support received from the China Scholarship Council(CSC)MERAGEM graduate school and the Ministry of Science,Research and Arts of the State of Baden-Wu rttemberg for funding research+4 种基金the support of the German Research Foundation(DFG)project(SE 1407/4-2)the support of the En ABLES,a project funded by the European Union’s Horizon 2020 research and innovation program under grant agreement(730957)the support of Epi Store project under grant agreement(101017709)the Centre for Electrochemical Energy Storage Ulm-Karlsruhe(CELEST)the support from the Karlsruhe Nano Micro Facility(KNMF)。
文摘With the recent development of high entropy materials, an alternative approach to develop advanced functional materials with distinctive properties that show improved values compared to conventional materials has been provided. The high entropy concept was later successfully transferred to metal fluorides and high entropy fluorides(HEFs) were successfully synthesized. Owing to their high theoretical specific capacities in energy storage applications, HEFs were utilized as cathode materials for lithiumion batteries(LIBs) and their underlying storage mechanisms were investigated. Instead of a step-bystep reduction of each individual metal cation, the HEFs seem to exhibit a single-step reduction process,indicating a solid solution compound instead of merely a mixture of different metal fluorides. It was also observed that the electrochemical behavior of the HEFs depends on each individual incorporated element. Therefore, by altering the elemental composition, new materials that exhibit improved electrochemical properties can be designed. Remarkably, HEFs with seven incorporated metal elements exhibited a better cycling stability as well as a lower hysteresis compared to binary metal fluorides.These findings offer new guidelines for material design and tailoring towards high performance LIBs.
基金supported by NSF of China(11271359,11471098)Science and Technology Research Projects of Henan Provincial Education Department(17A110041)Scientific Research and Innovation Fund Projects of Zhoukou Normal University(ZKNUA201805)
文摘We mainly discuss the invariance of some subclasses of biholomorphic mappings under the generalized Roper-Suffridge operators on Bergman-Hartogs domains which are based on the unit ball Bn. Using the geometric properties and the distortion results of subclasses of biholomorphic mappings, we obtain the geometric characters of almost spirallike mappings of type β and order α, S_?~*(β, A, B), strong and almost spirallike mappings of type βand order α maintained under the generalized Roper-Suffridge operators on Bergman-Hartogs domains. Sequentially, we conclude that the generalized operators and the known operators preserve the same properties under some conditions. The conclusions generalize some known results.
基金supported by NSF of China(11271359,11471098)Science and Technology Research Projects of Henan Provincial Education Department(19B110016)Scientific Research Innovation Fund Project of Zhoukou Normal University(ZKNUA201805)
文摘In this article, we mainly study the invariance of some biholomorphic mappings with special geometric characteristics under the extension operators. First we generalize the Roper-Suffridge extension operators on Bergman-Hartogs domains. Then, by the geometric characteristics of subclasses of biholomorphic mappings, we conclude that the modified Roper-Suff ridge operators preserve the properties of S_Ω~*(β,A, B), parabolic and spirallike mappings of type β and order p, strong and almost spirallike mappings of type 0 and orderα as well as almost starlike mappings of complex order λ on Ω_(p1,…,ps,q)^(B^n) under different conditions, respectively. The conclusions provide new approaches to construct these biholomorphic mappings in several complex variables.
基金supported by NSF of China(11271359,11471098)Science and Technology Research Projects of Henan Provincial Education Department(19B110016)+1 种基金Scientific Research Innovation Fund Project of Zhoukou Normal University(ZKNUA201805)Scientific Research Fund of High Level Talents of Zhoukou Normal University(ZKNUC2019004).
文摘In this article, we extend the well-known Roper-Suffridge operator on Bn+1 and bounded complete Reinhardt domains in Cn+1, then we investigate the properties of the generalized operators. Applying the Loewner theory, we obtain the mappings constructed by the generalized operators that have parametric representation on Bn+1. In addition, by using the geometric characteristics and the parametric representation of subclasses of spirallike mappings, we conclude that the extended operators preserve the geometric properties of several subclasses of spirallike mappings on Bn+1 and bounded complete Reinhardt domains in Cn+1. The conclusions provide new approaches to construct mappings with special geometric properties in Cn+1.
文摘Objective:To analyze the efficacy of capecitabine(referred to as Cap)single-agent maintenance therapy in the advanced breast cancer.Methods:The subjects of the study were 50 patients with advanced breast cancer who were admitted to our hospital between March 2016 and March 2019.They were divided into groups A and B with 25 cases each.The subjects of these two groups were treated conventional method,respectively.And then,Capecitabine maintenance therapy was continued for group A,clinical observation for groups B.Progressionfree survival(PFS)was compared between the two groups.Results:The median PFS was 14.2 months for group A and 8.9 months for group B(P<0.05).The complication rate of group A was 24.0%compared to that of group B was 22.0%(P>0.05).Conclusion:The patients with advanced breast cancer who received Cap maintenance therapy were benefited from better curative effect and controllable complications,which has high promotion value.
基金supported by the National Natural Science Foundation of China(No.11871191)the Natural Science Foundation of Henan Province(No.222300420397)+1 种基金the Key Program of Hebei Normal University(No.L2018Z01)the Scientific Research Fund of High Level Talents of Zhoukou Normal University(No.ZKNUC2019004)。
文摘In this paper,the authors extend the Roper-Suffridge operator on the generalized Hartogs domains.They mainly research the properties of the extended operator.By the characteristics of Hartogs domains and the geometric properties of subclasses of spirallike mappings,they obtain the extended Roper-Suffridge operator preserving almost starlikeness of complex orderλ,almost spirallikeness of typeβand orderα,parabolic spirallikeness of typeβand orderρon the Hartogs domains in different conditions.They conclude that the corresponding extension operator preserves the same geometric invariance on the unit ball B^(n) in C^(n).The conclusions provide a new approach to study these geometric mappings in C^(n).
基金supported by the National Natural Science Foundation of China(Nos.11271359,11471098)the Joint Funds of the National Natural Science Foundation of China(No.U1204618)the Science and Technology Research Projects of Henan Provincial Education Department(Nos.14B110015,14B110016)
文摘The authors propose a new approach to construct subclasses of biholomorphic mappings with special geometric properties in several complex variables. The RoperSuffridge operator on the unit ball B^n in C^n is modified. By the analytical characteristics and the growth theorems of subclasses of spirallike mappings, it is proved that the modified Roper-Suffridge operator [Φ_(G,γ)(f)](z) preserves the properties of S_Ω~*(A, B), as well as strong and almost spirallikeness of type β and order α on B^n. Thus, the mappings in S_Ω~*(A, B), as well as strong and almost spirallike mappings, can be constructed through the corresponding functions in one complex variable. The conclusions follow some special cases and contain the elementary results.
基金China's NSFC grants (81027004,81372082, 30571922) to JW and GL, "863" grants (2012AA020504)to JW. Also we sincerely thank Jianjie Ma for selfless assistance to this work
文摘Mitsugumin 53 (MG53), a newly identified muscle-specific protein, is an essential component of the cell membrane repair machinery in skeletal and cardiac muscle. However, the role of MG53 after burns in other tissues remains unclear. This study aims to investigate the possible roles of MG53 in the protection of the kidney after severe burn injury, and an animal scalding model of 30% of total body surface area (TBSA) was used. Recombinant human MG53 (rhMG53) or bovine serum albumin (BSA) was injected intravenously via the tail vein. Data showed that the mortality in the MG53-treated group was lower than that in control group. Administration of rhMG53 may alleviate histological alterations in renal tubular epithelial cells after burn injury. Renal tubular injury scores and the average optical density score of kidney injury molecule-1 (KIM-1) immunohistochemical staining in the MG53-treated group were significantly lower than those in control group (P < 0.001). Exogenous rhMG53 was found to be located in renal tubular epithelial cells. Numerous polymerase I and transcript release factor (PTRF) were expressed in the mouse kidney after severe scalding. In conclusion, our data indicate that MG53 protein protects the kidney by involving local PTRF after severe burn injury.
基金financially supported by the National Basic Research Program of China(2013CB932703)the National Natural Science Foundation of China(21390414,31300827,31271072)
文摘Mercury ion(Hg2+) pollution exists in water, soil, and food. By interacting with the thiol groups in protein, Hg2+ ions can accumulate in ways that cause serious damage to the central nervous system and threaten human health and natural environment. Undoubtedly, Hg2+ ion detection is a significant issue in environment and health monitoring. A variety of sensor platforms for Hg2+ ion detection based on organic molecules, DNA, oligonucleotides, inorganic materials, etc, have been reported. In this paper, an artificial peptide PHg, with a cluster bio-mineralize sequence(CCY) and a multi-charge hydrophilic sequence is designed as a template for the one-step synthesis of a peptide-Au cluster probe. Briefly: the peptide PHg in situ anchors Au ions to form a peptide-Au(I) intermediate and the reaction p H with Na OH is adjusted; after 12 h incubation at room temperature, the peptide PHg-Au nanocluster probe with red fluorescence is obtained. The probe has a super-small core size of approximately 1.26 nm and a maximum emission peak at 650 nm. The presence of Hg2+ ions cause the fluorescence of the probe to greatly decrease. Based on the differences in fluorescence intensity of the PHg-Au nanocluster in the absence and presence of Hg2+ ions, Hg2+ ions could be quantitatively detected in concentrations ranging from 5 nmol/L to 1 ?mol/L. The limit of detection(LOD) is 7.5 nmol/L. Compared with some interference ions such as, K+, Mg2+, Ca2+, Pb2+, Ni2+, Fe3+, and Cu2+, the selectivity was excellent. The sensing of Hg2+ ion is not affected by the chelate agents: EDTA, which imparts a significant advantage in a range of applications. As a result, a simple, sensitive and selective fluorescent assay based on peptide PHg-Au cluster is developed for the detection of Hg2+ ions.
基金partially funded by the project of State Key Laboratory of Transducer Technology(SKT1404)the project of the Key Laboratory of Photoelectronic Imaging Technology and System(2017OEIOF02)Beijing Institute of Technology,Ministry of Education of Chinathe project of the Key R&D projects of the Ministry of Science and Technology(SQ2019YFB220038)。
文摘Heterojunction is regarded as a crucial step toward realizing high-performance devices,particularly,forming gradient energy band between heterojunctions benefits self-powered photodetectors.Therefore,in this paper,the synthesis of CsPbI3 nanorods(NRs)and its application as the interfacial layer in high-performance,all-solution-processed self-powered photodetectors are presented.For the bilayer photodetector ITO/ZnO(100 nm)/PbS-TBAI(150 nm)/Au,a responsivity of 3.6 A/W with a specific detectivity of 9.8×10^(12)Jones was obtained under 0.1 mW/cm^(2)white light illumination at zero bias(i.e.in self-powered mode).Meanwhile,the photocurrent was enhanced to an On/Off current ratio of 105 at zero bias with an open circuit voltage of 0.53 V for trilayer photodetector ITO/ZnO(100 nm)/PbSTBAI(150 nm)/CsPbI3(250 nm)/Au,in which the CsPbI3 NRs layer works as the interfacial layer.As a result,a specific detectivity of 4.5×10^(13)Jones with a responsivity of 11.12 A/W was obtained under0.1 mW/cm^(2) white light illumination,as well as the rising/decaying time of 0.57 s/0.41 s with excellent stability and reproducibility upto four weeks in air.The enhanced-performance is ascribed to the mismatch bandgap between PbS-TBAI/CsPbI_(3)interface,which can suppress the carrier recombination and provide efficient transport passages for charge carriers.Thus,it provides a feasible and efficient method for high-performance photodetectors.
基金This study was financially supported by the National Special Fund Program for Major Scientific Instruments and Equipment Development(2011YQ160002)Open Research Fund Program of Hubei Provincial Key Laboratory of Chemical Equipment Intensification and Intrinsic Safety(2015KA03).
文摘The flow distribution and mixing performance of the laminar flow in the PBT impeller-stirred tank were investigated in this study.The variation along with mixing time of the flow distribution and concentration at the selected positions was visualized by means of the CFD and experiment methods.The CFD simulations results had a good agreement with the experimental results.In order to minish the Segregated Regions,the PBT impeller was optimally designed by means of orthogonal factorial experiment with selecting theθ99 mixing time as evaluation criteria.With the aim to increase the mixing efficiency,the optimal design results were obtained with the geometrical parameters of impeller diameter of 0.084 m,discharge angle of 45º,blade width of 0.018 m,and clearance of 0.05 m,and the mixing time of the optimal impeller-stirred flow was about 180 s,so this optimal design PBT impeller is more proper for the agricultural industries.
