Piano originated in Western countries,so a large number of Western cultural elements are used in piano art creation,mainly to present Western humanistic thoughts and spiritual cultural cores to the audience.In recent ...Piano originated in Western countries,so a large number of Western cultural elements are used in piano art creation,mainly to present Western humanistic thoughts and spiritual cultural cores to the audience.In recent years,with the modernization of piano art and culture in China,many Chinese listeners have begun to demand more ethnic and folk piano pieces with Chinese characteristics.In order to meet the audience’s pursuit of modern Chinese piano art,more and more creators are integrating ethnic music elements into modern piano art creation.This article explores the integration significance of ethnic music elements in modern piano art creation and the current situation of Chinese modern piano art creation,and finds that ethnic music elements have positive help in enhancing the novelty,ethnic characteristics,and timeliness of piano art creation.Based on this,this article proposes several strategies for integrating traditional ethnic music elements into modern piano art creation,including adapting traditional ethnic music elements,creating pentatonic tunes,and modifying work titles.The aim is to provide references and inspiration for the development of Chinese piano art creation and culture.展开更多
The continuous reduction of electrolytes by Li metal leads to a poor lifespan of lithium metal batteries(LMBs). Low Coulombic efficiency(CE) and safety concern due to dendrite growth are the challenging issues for LMB...The continuous reduction of electrolytes by Li metal leads to a poor lifespan of lithium metal batteries(LMBs). Low Coulombic efficiency(CE) and safety concern due to dendrite growth are the challenging issues for LMB electrolyte design. Novel electrolytes such as highly concentrated electrolytes(HCEs) have been proposed for improving interphase stability. However, this strategy is currently limited for high cost due to the use of a large amount of lithium salts as well as their high viscosity, reduced ion mobility, and poor wettability. In this work, we propose a new type of electrolyte having a moderate concentration. The electrolyte has the advantage of HCEs as the anion is preferentially reduced to form inorganic solidelectrolyte-interphase(SEI). Such optimization has been confirmed through combined spectroscopic and electrochemical characterizations and supported with the first-principle molecular dynamics simulation. We have shown the intrinsic connections between solution structure and their electrochemical stability. The 2.0 M LiDFOB/PC electrolyte, as predicted by our characterizations and simulations, allows stable charge–discharge of LNMO|Li cells at 5C for more than 1500 cycles. The 2.0 M electrolyte generates a dense layer of SEI containing fluoro-oxoborates, Li_(3)BO_(3), LiF, Li_(2)CO_(3), and some organic species effectively passivating the lithium metal, as confirmed by electron microscopy, X-ray photoelectron spectroscopy,and solid-state nuclear magnetic resonance.展开更多
The Tumen river region including Yanji,Tumen, Longjing and Hunchun cities is situated in the east part of Jilin Province.The region is an important economic exploitation area in the province. The total area is 10, 228...The Tumen river region including Yanji,Tumen, Longjing and Hunchun cities is situated in the east part of Jilin Province.The region is an important economic exploitation area in the province. The total area is 10, 228. 86 km2.There are superior geographical location, rich natural rare, various gemorphological types and less farmaland in the region. The remote sensing technique is adopted in the survey of present landuse. The newest Landsat and CCT data are selected in the survey. Comparing the data obtained from remote sensing survey with the data from land detail investigation we can are that the paddy-field, garden for planting fruits, residential area and factory and mine, traffic land have increased in different extents, especially, the residential area is increased rapidly, but the forest land, grazing land have decreased. The unused land has been used. Land productive potentiality system is a multi-hierarchic comprehensive-complex system of natural economy.Its core is photosynthesis of green vegetation, which is affected by factors such as radiation,temperature, rainfall, soil fertility and management level. According to calculation of productive potentiality, the analysis of carrying capacity for population has ho done and the conclusion is drawn. After 2000,the population growth in the region will be reStricted by lack of are of farmland resources and level of grain production. Existing land and its reserve are can not carry a population more than 150×104.It is estmeted that the grain only depends on transportstion outside to meet the needs of population growth and social development after 2000.展开更多
The use of supported Co-based catalysts is widespread in various catalytic reactions due to their unique structures.The structural sensitivity of these catalysts is closely linked to their particle size and crystal fo...The use of supported Co-based catalysts is widespread in various catalytic reactions due to their unique structures.The structural sensitivity of these catalysts is closely linked to their particle size and crystal form.Consequently,comprehending the structure–activity relationship requires the development of well-defined Co-based catalysts.Herein,we employed a colloidal wet chemical process and a heterogeneous nucleation method to prepare well-defined Co-based catalysts supported by inert carbon nanospheres.The nanospheres’surface possesses abundant functional groups that efficiently capture metal complexes and facilitate the nucleation and growth of CoO nanoparticles.By adjusting the Co source concentration,solvent molar ratio,and nucleation growth kinetics,we successfully prepared CoO/carbon sphere(CS)catalysts with different particle sizes and crystal forms.The influence of metallic face-centered cubic(fcc)-Co^(0) particle size in the range of 6.6–17.6 nm on the performance of Fischer–Tropsch synthesis(FTS)using well-defined CoO/CS catalysts has been investigated.The result demonstrated that the turnover frequency(TOF)remained constant for CoO/CS catalysts with metallic fcc-Co^(0) particle size larger than 7.7 nm.However,both the selectivity and the activity changed for CoO/CS catalysts with smaller particles(<7.7 nm).Significantly,when metallic fcc-Co^(0) particle size was reduced from 17.6 to 7.7 nm,the cobalt time yield increased to 6.7μmolCO·gCo^(-1)·s^(-1),indicating improved catalytic activity.At the same time,the CH_(4) selectivity decreased to 4.9%,suggesting a higher preference for hydrocarbon production.These findings demonstrate the importance of particle size in Co catalyzed Fischer–Tropsch synthesis.The use of well-defined CoO/CS catalysts offers valuable insights into the structure–activity relationship,leading to a better understanding of Co catalyzed Fischer–Tropsch synthesis.展开更多
The binding between NL-101, a novel nitrogen mustard anti-cancer drug, with amino acids and peptides has been investigated by high performance liquid chromatography electrospray tandem mass spectrometry(HPLC/ESI-MS/MS...The binding between NL-101, a novel nitrogen mustard anti-cancer drug, with amino acids and peptides has been investigated by high performance liquid chromatography electrospray tandem mass spectrometry(HPLC/ESI-MS/MS). This study offers supporting data of the interaction among drug and amino acids and peptides, which could potentially explain the cytotoxic and mutagenic effects of the drug. Collision-induced dissociation(CID) experiment demonstrated that under the same collision energy, the amino group combined with NL-101 adducts are sensitive and often produce more fragment ions; the carboxyl group combined with NL-101 adducts are hard to break and display fewer fragment ions. In addition, when other group(like sulfhydryl group) of amino acids binds to NL-101, CID spectra show different fragmentation pattern. These differences could display structural information about the drug adducts and be utilized as location of the authentic binding sites.展开更多
The effect of gold nanoparticle-decorated molybdenum sulfide(AuNP-MoS2)nanocomposites on amyloid-β-40(Aβ40)aggregation was investigated.The interesting discovery was that the effect of AuNPMoS2 nanocomposites on Aβ...The effect of gold nanoparticle-decorated molybdenum sulfide(AuNP-MoS2)nanocomposites on amyloid-β-40(Aβ40)aggregation was investigated.The interesting discovery was that the effect of AuNPMoS2 nanocomposites on Aβ40 aggregation was contradictory.Low concentration of AuNP-MoS2 nanocomposites could enhance the nucleus formation of Aβ40 peptides and accelerate Aβ40 fibrils aggregation.However,although high concentration of AuNP-MoS2 nanocomposites could enhance the nucleus formation of Aβ40 peptides,it eventually inhibited Aβ40 aggregation process.It might be attributed to the interaction between AuNP-MoS2 nanocomposites and Aβ40 peptides.For low concentration of AuNP-MoS2 nanocomposites,it was acted as nuclei,resulting in the acceleration of the nucleation process.However,the structural flexibility of Aβ40 peptides was limited as the concentration of AuNP-MoS2 nanocomposites was increased,resulting in the inhibition of Aβ40aggregation.These findings suggested that AuNP-MoS2 nanocomposites might have a great potential to design new multifunctional material for future treatment of amyloid-related diseases.展开更多
文摘Piano originated in Western countries,so a large number of Western cultural elements are used in piano art creation,mainly to present Western humanistic thoughts and spiritual cultural cores to the audience.In recent years,with the modernization of piano art and culture in China,many Chinese listeners have begun to demand more ethnic and folk piano pieces with Chinese characteristics.In order to meet the audience’s pursuit of modern Chinese piano art,more and more creators are integrating ethnic music elements into modern piano art creation.This article explores the integration significance of ethnic music elements in modern piano art creation and the current situation of Chinese modern piano art creation,and finds that ethnic music elements have positive help in enhancing the novelty,ethnic characteristics,and timeliness of piano art creation.Based on this,this article proposes several strategies for integrating traditional ethnic music elements into modern piano art creation,including adapting traditional ethnic music elements,creating pentatonic tunes,and modifying work titles.The aim is to provide references and inspiration for the development of Chinese piano art creation and culture.
基金financial support from the National Natural Science Foundation of China (21922410)the Zhejiang Provincial Natural Science Foundation (R19B050003 and LQ21B030006)+2 种基金the Scientific Research Fund of Zhejiang Provincial Education Department (Y201839549)the Zhejiang University K.P. Chao’s High Technology Development Foundation (2018RC009)the Postdoctoral Science Foundation of Zhejiang Province (ZJ2020079)。
文摘The continuous reduction of electrolytes by Li metal leads to a poor lifespan of lithium metal batteries(LMBs). Low Coulombic efficiency(CE) and safety concern due to dendrite growth are the challenging issues for LMB electrolyte design. Novel electrolytes such as highly concentrated electrolytes(HCEs) have been proposed for improving interphase stability. However, this strategy is currently limited for high cost due to the use of a large amount of lithium salts as well as their high viscosity, reduced ion mobility, and poor wettability. In this work, we propose a new type of electrolyte having a moderate concentration. The electrolyte has the advantage of HCEs as the anion is preferentially reduced to form inorganic solidelectrolyte-interphase(SEI). Such optimization has been confirmed through combined spectroscopic and electrochemical characterizations and supported with the first-principle molecular dynamics simulation. We have shown the intrinsic connections between solution structure and their electrochemical stability. The 2.0 M LiDFOB/PC electrolyte, as predicted by our characterizations and simulations, allows stable charge–discharge of LNMO|Li cells at 5C for more than 1500 cycles. The 2.0 M electrolyte generates a dense layer of SEI containing fluoro-oxoborates, Li_(3)BO_(3), LiF, Li_(2)CO_(3), and some organic species effectively passivating the lithium metal, as confirmed by electron microscopy, X-ray photoelectron spectroscopy,and solid-state nuclear magnetic resonance.
文摘The Tumen river region including Yanji,Tumen, Longjing and Hunchun cities is situated in the east part of Jilin Province.The region is an important economic exploitation area in the province. The total area is 10, 228. 86 km2.There are superior geographical location, rich natural rare, various gemorphological types and less farmaland in the region. The remote sensing technique is adopted in the survey of present landuse. The newest Landsat and CCT data are selected in the survey. Comparing the data obtained from remote sensing survey with the data from land detail investigation we can are that the paddy-field, garden for planting fruits, residential area and factory and mine, traffic land have increased in different extents, especially, the residential area is increased rapidly, but the forest land, grazing land have decreased. The unused land has been used. Land productive potentiality system is a multi-hierarchic comprehensive-complex system of natural economy.Its core is photosynthesis of green vegetation, which is affected by factors such as radiation,temperature, rainfall, soil fertility and management level. According to calculation of productive potentiality, the analysis of carrying capacity for population has ho done and the conclusion is drawn. After 2000,the population growth in the region will be reStricted by lack of are of farmland resources and level of grain production. Existing land and its reserve are can not carry a population more than 150×104.It is estmeted that the grain only depends on transportstion outside to meet the needs of population growth and social development after 2000.
基金supported by the National Natural Science Foundation of China(Nos.22072184,22372199,and 21972170)the Young Top-notch Talent Cultivation Program of Hubei Provincethe Fundamental Research Funds for the Central Universities of South-Central Minzu University(No.CZZ23005).
文摘The use of supported Co-based catalysts is widespread in various catalytic reactions due to their unique structures.The structural sensitivity of these catalysts is closely linked to their particle size and crystal form.Consequently,comprehending the structure–activity relationship requires the development of well-defined Co-based catalysts.Herein,we employed a colloidal wet chemical process and a heterogeneous nucleation method to prepare well-defined Co-based catalysts supported by inert carbon nanospheres.The nanospheres’surface possesses abundant functional groups that efficiently capture metal complexes and facilitate the nucleation and growth of CoO nanoparticles.By adjusting the Co source concentration,solvent molar ratio,and nucleation growth kinetics,we successfully prepared CoO/carbon sphere(CS)catalysts with different particle sizes and crystal forms.The influence of metallic face-centered cubic(fcc)-Co^(0) particle size in the range of 6.6–17.6 nm on the performance of Fischer–Tropsch synthesis(FTS)using well-defined CoO/CS catalysts has been investigated.The result demonstrated that the turnover frequency(TOF)remained constant for CoO/CS catalysts with metallic fcc-Co^(0) particle size larger than 7.7 nm.However,both the selectivity and the activity changed for CoO/CS catalysts with smaller particles(<7.7 nm).Significantly,when metallic fcc-Co^(0) particle size was reduced from 17.6 to 7.7 nm,the cobalt time yield increased to 6.7μmolCO·gCo^(-1)·s^(-1),indicating improved catalytic activity.At the same time,the CH_(4) selectivity decreased to 4.9%,suggesting a higher preference for hydrocarbon production.These findings demonstrate the importance of particle size in Co catalyzed Fischer–Tropsch synthesis.The use of well-defined CoO/CS catalysts offers valuable insights into the structure–activity relationship,leading to a better understanding of Co catalyzed Fischer–Tropsch synthesis.
基金supported by the National Natural Science Foundation of China (Nos. 21327010, 21372199)
文摘The binding between NL-101, a novel nitrogen mustard anti-cancer drug, with amino acids and peptides has been investigated by high performance liquid chromatography electrospray tandem mass spectrometry(HPLC/ESI-MS/MS). This study offers supporting data of the interaction among drug and amino acids and peptides, which could potentially explain the cytotoxic and mutagenic effects of the drug. Collision-induced dissociation(CID) experiment demonstrated that under the same collision energy, the amino group combined with NL-101 adducts are sensitive and often produce more fragment ions; the carboxyl group combined with NL-101 adducts are hard to break and display fewer fragment ions. In addition, when other group(like sulfhydryl group) of amino acids binds to NL-101, CID spectra show different fragmentation pattern. These differences could display structural information about the drug adducts and be utilized as location of the authentic binding sites.
基金the National Natural Science Foundation of China(Nos.21375034,21675047 and 21735002)Natural Science Foundation for Distinguished Young Scholars of Hunan Province(No.2016JJ1008)。
文摘The effect of gold nanoparticle-decorated molybdenum sulfide(AuNP-MoS2)nanocomposites on amyloid-β-40(Aβ40)aggregation was investigated.The interesting discovery was that the effect of AuNPMoS2 nanocomposites on Aβ40 aggregation was contradictory.Low concentration of AuNP-MoS2 nanocomposites could enhance the nucleus formation of Aβ40 peptides and accelerate Aβ40 fibrils aggregation.However,although high concentration of AuNP-MoS2 nanocomposites could enhance the nucleus formation of Aβ40 peptides,it eventually inhibited Aβ40 aggregation process.It might be attributed to the interaction between AuNP-MoS2 nanocomposites and Aβ40 peptides.For low concentration of AuNP-MoS2 nanocomposites,it was acted as nuclei,resulting in the acceleration of the nucleation process.However,the structural flexibility of Aβ40 peptides was limited as the concentration of AuNP-MoS2 nanocomposites was increased,resulting in the inhibition of Aβ40aggregation.These findings suggested that AuNP-MoS2 nanocomposites might have a great potential to design new multifunctional material for future treatment of amyloid-related diseases.
