In this work, Pd–Cu/γ-Al2O3 is prepared by the impregnation method and investigated for selective oxygenization of cyclopentene to cyclopentanone. A series of bimetallic Pd–Cu/γ-Al2O3 nanocatalysts were prepared a...In this work, Pd–Cu/γ-Al2O3 is prepared by the impregnation method and investigated for selective oxygenization of cyclopentene to cyclopentanone. A series of bimetallic Pd–Cu/γ-Al2O3 nanocatalysts were prepared and the structures characterized by XRD, XPS and TEM. We determined that the obtained Pd–Cu/γ-Al2O3（molar ratio Pd：Cu = 5：1） was an efficient catalyst for the oxygenization of cyclopentene to cyclopentanone with 95% selectivity and 85% conversion（100 °C, 1 MPa initial O2 pressure, 7 h）.展开更多
Several γ-Al2O3 supported Pd-Ni bimetallic nanocatalysts （Pd-Ni （x：y）[Al2O3; where x and y represent the mass ratio of Pd and Ni, respectively） were prepared by the impregnation method and used for selective hyd...Several γ-Al2O3 supported Pd-Ni bimetallic nanocatalysts （Pd-Ni （x：y）[Al2O3; where x and y represent the mass ratio of Pd and Ni, respectively） were prepared by the impregnation method and used for selective hydrogenation of cyclopentadiene to cyclopentene. The Pd-NiJAl2O3 samples were confirmed to generate Pd-Ni bimetallic nanoparticles by X-ray diffraction （XRD）, X-ray photoelectron spectroscopy （XPS） and transmission electron microscopy （TEM）. The catalytic activity was assessed in view of the effects of different mass ratios of Pd and Ni, temperature, pressure, etc. Among all the samples, the Pd-Ni （1：1 ）/Al2O3 （PN-1：1 ） catalyst showed extremely high catalytic ability. The conversion of cyclopentadiene and selectivity for cyclopentene can be simultaneously more than 90%.展开更多
基金financial assistance from the National Natural Science Foundation of China (Nos. 21272050, 21371044, 21472033 and 21571047)
文摘In this work, Pd–Cu/γ-Al2O3 is prepared by the impregnation method and investigated for selective oxygenization of cyclopentene to cyclopentanone. A series of bimetallic Pd–Cu/γ-Al2O3 nanocatalysts were prepared and the structures characterized by XRD, XPS and TEM. We determined that the obtained Pd–Cu/γ-Al2O3（molar ratio Pd：Cu = 5：1） was an efficient catalyst for the oxygenization of cyclopentene to cyclopentanone with 95% selectivity and 85% conversion（100 °C, 1 MPa initial O2 pressure, 7 h）.
基金the financial assistance from the National Natural Science Foundation of China (Nos.21272050,21371044,21472033)the Program for New Century Excellent Talents in University of the Chinese Ministry of Education (No.NCET-110627)
文摘Several γ-Al2O3 supported Pd-Ni bimetallic nanocatalysts （Pd-Ni （x：y）[Al2O3; where x and y represent the mass ratio of Pd and Ni, respectively） were prepared by the impregnation method and used for selective hydrogenation of cyclopentadiene to cyclopentene. The Pd-NiJAl2O3 samples were confirmed to generate Pd-Ni bimetallic nanoparticles by X-ray diffraction （XRD）, X-ray photoelectron spectroscopy （XPS） and transmission electron microscopy （TEM）. The catalytic activity was assessed in view of the effects of different mass ratios of Pd and Ni, temperature, pressure, etc. Among all the samples, the Pd-Ni （1：1 ）/Al2O3 （PN-1：1 ） catalyst showed extremely high catalytic ability. The conversion of cyclopentadiene and selectivity for cyclopentene can be simultaneously more than 90%.
