In a shale gas and oil reservoir,hydrocarbon fluids are stored in organic nanopores with sizes on the order of~1-100 nm.The adsorption,selectivity,and phase behavior of hydrocarbons in the nanopores are crucial for es...In a shale gas and oil reservoir,hydrocarbon fluids are stored in organic nanopores with sizes on the order of~1-100 nm.The adsorption,selectivity,and phase behavior of hydrocarbons in the nanopores are crucial for estimating the gas-in-place and predicting the productivity.In this study,to understand the characteristics of the phase behavior of multicomponent hydrocarbon systems in shale reservoirs,the phase behavior of a CH_(4)/n-C_(4)H_(10)binary mixture in graphite nanopores was investigated by Grand Ca-nonical Monte Carlo(GCMC)molecular simulation.The method for determining the dew-point pressure and bubble-point pressure in the nanopores was explored.The condensation phenomenon was observed owing to the difference in the adsorption selectivities of the hydrocarbon molecules on the nanopore surfaces,and hence the dew-point pressure(and bubble-point pressure)of hydrocarbon mixtures in the nanopores significantly shifted.The GCMC simulations reproduced both the higher and lower bubble-point pressures in nanopores in previous studies.This work highlights the crucial role of the selec-tivity in the phase behavior of hydrocarbons in nanopores.展开更多
基金the Promotion of Science(JSPS)for a Grant-in-Aid for Scientific Research A(No.24246148)a Grant-in-Aid for Scientific Research C(No.17K06988).
文摘In a shale gas and oil reservoir,hydrocarbon fluids are stored in organic nanopores with sizes on the order of~1-100 nm.The adsorption,selectivity,and phase behavior of hydrocarbons in the nanopores are crucial for estimating the gas-in-place and predicting the productivity.In this study,to understand the characteristics of the phase behavior of multicomponent hydrocarbon systems in shale reservoirs,the phase behavior of a CH_(4)/n-C_(4)H_(10)binary mixture in graphite nanopores was investigated by Grand Ca-nonical Monte Carlo(GCMC)molecular simulation.The method for determining the dew-point pressure and bubble-point pressure in the nanopores was explored.The condensation phenomenon was observed owing to the difference in the adsorption selectivities of the hydrocarbon molecules on the nanopore surfaces,and hence the dew-point pressure(and bubble-point pressure)of hydrocarbon mixtures in the nanopores significantly shifted.The GCMC simulations reproduced both the higher and lower bubble-point pressures in nanopores in previous studies.This work highlights the crucial role of the selec-tivity in the phase behavior of hydrocarbons in nanopores.
