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A numerical simulation method of natural fragment formation and injury to human thorax
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作者 yuan-yuan ju Lei Zhang +3 位作者 Di-Ke Ruan Cheng Xu Ming Hu Ren-Rong Long 《Chinese Journal of Traumatology》 CAS CSCD 2020年第5期258-264,共7页
Objective:Fragment injury is a type of blast injury that is becoming more and more common in military campaigns and terrorist attacks.Numerical simulation methods investigating the formation of natural fragments and i... Objective:Fragment injury is a type of blast injury that is becoming more and more common in military campaigns and terrorist attacks.Numerical simulation methods investigating the formation of natural fragments and injuries to biological targets are expected to be developed.Methods:A cylindrical warhead model was established and the formation process of natural fragments was simulated using the approach of tied nodes with failure through the explicit finite element(FE)software of LS-DYNA.The interaction between the detonation product and the warhead shell was simulated using the fluidestructure interaction algorithm.A method to simulate the injury of natural fragments to a biological target was presented by transforming Lagrange elements into smooth particle hydrodynamics(SPH)particles after the natural fragments were successfully formed.A computational model of the human thorax was established to simulate the injury induced by natural fragments by the node-to-surface contact algorithm with erosion.Results:The discontinuous velocities of the warhead shell at different locations resulted in the formation of natural fragments with different sizes.The velocities of natural fragments increased rapidly at the initial stage and slowly after the warhead shell fractured.The initial velocities of natural fragments at the central part of the warhead shell were the largest,whereas those at both ends of the warhead shell were the smallest.The natural fragments resulted in bullet holes that were of the same shape as that of the fragments but slightly larger in size than the fragments in the human thorax after they penetrated through.Stress waves propagated in the ribs and enhanced the injury to soft tissues;additionally,ballistic pressure waves ahead of the natural fragments were also an injury factor to the soft tissues.Conclusion:The proposed method is effective in simulating the formation of natural fragments and their injury to biological targets.Moreover,this method will be beneficial for simulating the combined injuries of natural fragments and shock waves to biological targets. 展开更多
关键词 Finite element analysis Fragment injury Human thorax Fluidestructure interaction Smooth particle hydrodynamics
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介孔核结构聚合物胶束的制备及其在汞离子检测中的应用 被引量:1
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作者 鞠媛媛 韩广达 +1 位作者 陆燕 赵汉英 《高分子学报》 SCIE CAS CSCD 北大核心 2018年第8期1081-1088,共8页
通过可逆加成-断裂链转移聚合(RAFT)和原子转移自由基聚合(ATRP)设计合成了具有p H响应性和还原响应性的双亲性聚合物分子刷,聚聚(乙二醇)单甲醚甲基丙烯酸酯-block-(聚甲基丙烯酸叔丁酯-graft-聚甲基丙烯酸N,N-二甲氨基乙酯)(POEGMA-b-... 通过可逆加成-断裂链转移聚合(RAFT)和原子转移自由基聚合(ATRP)设计合成了具有p H响应性和还原响应性的双亲性聚合物分子刷,聚聚(乙二醇)单甲醚甲基丙烯酸酯-block-(聚甲基丙烯酸叔丁酯-graft-聚甲基丙烯酸N,N-二甲氨基乙酯)(POEGMA-b-(Pt BMA-g-PDMAEMA)),其中侧链PDMAEMA与主链通过二硫键相连.运用核磁共振氢谱(1H-NMR)和凝胶渗透色谱(GPC)表征了聚合物的结构、分子量及分子量分布.在碱性条件下,聚合物分子刷自组装成以POEGMA为壳,Pt BMA和PDMAEMA为核的多组分胶束.由于Pt BMA和PDMAEMA互不相容,在核中形成微相分离,体积分数较大的Pt BMA形成连续相,体积分数较小的PDMAEMA形成分散相.调节p H至酸性条件后,分散相PDMAEMA由坍陷变为伸展状态,从胶束的核中溶解出来.加入还原剂断开侧链PDMAEMA与主链相连的二硫键,制得孔内壁含有巯基的介孔核结构聚合物胶束.利用透射电镜(TEM)和动态光散射(DLS)表征了胶束的形貌和粒径.通过TEM结果得出介孔核结构聚合物胶束的孔径大小约为2 nm.利用巯基对氯金酸的还原作用和对金纳米粒子的稳定作用,制得孔内修饰金纳米粒子的介孔核结构聚合物胶束.利用巯基和溴的点击反应,制得孔内修饰聚噻吩衍生物的介孔核结构聚合物胶束,其对Hg^(2+)检测表现出较高的灵敏度和特异性. 展开更多
关键词 多分组胶束 介孔核结构聚合物胶束 巯基化学 Hg^2+检测
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