Ruled surfaces found in engineering parts are often blended with a constraint surface,like the blade surface and hub surface of a centrifugal impeller.It is significant to accurately machine these ruled surfaces in fl...Ruled surfaces found in engineering parts are often blended with a constraint surface,like the blade surface and hub surface of a centrifugal impeller.It is significant to accurately machine these ruled surfaces in flank milling with interference-free and fairing tool path,while current models in fulfilling these goals are complex and rare.In this paper,a tool path planning method with optimal cutter locations(CLs)is proposed for 5-axis flank milling of ruled surfaces under multiple geometric constraints.To be specific,a concise three-point contact tool positioning model is firstly developed for a cylindrical cutter.Different tool orientations arise when varying the three contact positions and a tool orientation pool with acceptable cutter-surface deviation is constructed using a meta-heuristic algorithm.Fairing angular curves are derived from candidates in this pool,and then curve registration for cutter tip point on each determined tool axis is performed in respect of interference avoidance and geometric smoothness.On this basis,an adaptive interval determination model is developed for deviation control of interpolated cutter locations.This model is designed to be independent of the CL optimization process so that multiple CLs can be planned simultaneously with parallel computing technique.Finally,tests are performed on representative surfaces and the results show the method has advantages over previous meta-heuristic tool path planning approaches in both machining accuracy and computation time,and receives the best comprehensive performance compared to other multi-constrained methods when machining an impeller.展开更多
Nowadays,free-form surfaces have been widely used in various industrial fields.They are usually machined by CNC machine tools,but recently have also begun to be manufactured by industrial robotic arm manipulators,than...Nowadays,free-form surfaces have been widely used in various industrial fields.They are usually machined by CNC machine tools,but recently have also begun to be manufactured by industrial robotic arm manipulators,thanks to low cost,large operation reaching space and high machining flexibility of robot.So far,various methodologies have been proposed to improve efficiency and quality of free-form surface machining,thus this paper aims at providing a state-ofthe-art review on research advances in free-form surface machining.In this review,tool path generation,feedrate scheduling in Cartesian space and trajectory planning in joint space are focused for both CNC machining and robot machining,and their research statues,existing difficulties and key issues are discussed in detail.Finally,the feasible routes,breakthrough points and future development trend are also expounded.展开更多
In this paper, a multi-delay milling system considering helix angle and run-out effects is firstly established. An exponential cutting force model is used to model the interaction between a work-piece and a cutting to...In this paper, a multi-delay milling system considering helix angle and run-out effects is firstly established. An exponential cutting force model is used to model the interaction between a work-piece and a cutting tool, and a new approach is presented for accurately calibrating exponential cutting force coefficients and cutter run-out parameters. Furthermore, based on an implicit multi-step Adams formula and an improved precise time-integration algorithm, a novel stability prediction method is proposed to predict the stability of the system. The involved time delay term and periodic coefficient term are integrated as a comprehensive state term in the integral response which is approximated by the Adams formula. Then, a Floquet transition matrix with an arbitraryorder form is constructed by using a series of matrix multiplication, and the stability of the system is determined by the Floquet theory. Compared to classical semi-discretization methods and fulldiscretization methods, the developed method shows a good performance in convergence, efficiency,accuracy, and multi-order complexity. A series of cutting tests is further carried out to validate the practicability and effectiveness of the proposed method. The results show that the calibration process needs a time of less than 5 min, and the stability prediction method is effective.展开更多
AstereodivergentPd/Cucatalyst systemforasymmetric desymmetric alkylation of allylic geminal dicarboxylates has been developed,which was successfully applied to the asymmetric synthesis of β-hydroxycarbonylmotifs bear...AstereodivergentPd/Cucatalyst systemforasymmetric desymmetric alkylation of allylic geminal dicarboxylates has been developed,which was successfully applied to the asymmetric synthesis of β-hydroxycarbonylmotifs bearing a versatile carbon-carbon double bond in an enantio-and diastereodivergent manner.A wide scope of substrates including challenging alkylsubstituted,2-substituted,and3,3′-disubstitutedallylic species are compatible with this catalytic system,delivering the substituted products in high to excellent yieldsandwith excellent diastereo-(upto>20:1 dr)and enantioselectivities(up to>99%ee).Furthermore,the mechanism of this dual Pd/Cu catalytic system including:(1)the desymmetrization process ofgeminal dicarboxylates;(2)the origin of regioselectivity(branched or linear);(3)the enantio-and diastereoselectivity observed by changing the combinations of two chiral metal catalysts,have been carefully investigated by theoretical calculations.展开更多
A Lewis acid-catalyzed[4+2]cycloaddition of 3-alkyl-2-vinylindoles withβ,γ-unsaturatedα-ketoesters has been established in the presence of Sc(OTf)3,which afforded a series of indole-containing pyran derivatives in ...A Lewis acid-catalyzed[4+2]cycloaddition of 3-alkyl-2-vinylindoles withβ,γ-unsaturatedα-ketoesters has been established in the presence of Sc(OTf)3,which afforded a series of indole-containing pyran derivatives in generally good yields(up to 90%yield)with excellent diastereoselectivities(up to >95:5 dr)under mild conditions.This approach not only enriches the chemistry of 3-alkyl-2-vinylindoles,but also has provided an atom-economic method for the synthesis of indole-containing pyran derivatives with potential bioactivity.展开更多
基金supported by the National Natural Science Foundation of China(Nos.U22A20202 and 52205516)the China Postdoctoral Science Foundation(No.2022 M720641)。
文摘Ruled surfaces found in engineering parts are often blended with a constraint surface,like the blade surface and hub surface of a centrifugal impeller.It is significant to accurately machine these ruled surfaces in flank milling with interference-free and fairing tool path,while current models in fulfilling these goals are complex and rare.In this paper,a tool path planning method with optimal cutter locations(CLs)is proposed for 5-axis flank milling of ruled surfaces under multiple geometric constraints.To be specific,a concise three-point contact tool positioning model is firstly developed for a cylindrical cutter.Different tool orientations arise when varying the three contact positions and a tool orientation pool with acceptable cutter-surface deviation is constructed using a meta-heuristic algorithm.Fairing angular curves are derived from candidates in this pool,and then curve registration for cutter tip point on each determined tool axis is performed in respect of interference avoidance and geometric smoothness.On this basis,an adaptive interval determination model is developed for deviation control of interpolated cutter locations.This model is designed to be independent of the CL optimization process so that multiple CLs can be planned simultaneously with parallel computing technique.Finally,tests are performed on representative surfaces and the results show the method has advantages over previous meta-heuristic tool path planning approaches in both machining accuracy and computation time,and receives the best comprehensive performance compared to other multi-constrained methods when machining an impeller.
基金partially supported by the National Natural Science Foundation of China(Nos.91948203,51975097)the National Key Research and Development Project(No.2020YFA0713702)to Dalian University of Technology。
文摘Nowadays,free-form surfaces have been widely used in various industrial fields.They are usually machined by CNC machine tools,but recently have also begun to be manufactured by industrial robotic arm manipulators,thanks to low cost,large operation reaching space and high machining flexibility of robot.So far,various methodologies have been proposed to improve efficiency and quality of free-form surface machining,thus this paper aims at providing a state-ofthe-art review on research advances in free-form surface machining.In this review,tool path generation,feedrate scheduling in Cartesian space and trajectory planning in joint space are focused for both CNC machining and robot machining,and their research statues,existing difficulties and key issues are discussed in detail.Finally,the feasible routes,breakthrough points and future development trend are also expounded.
基金co-supported by the National Natural Science Foundation of China (Nos.51525501,11290143,and 51621064)the Science Challenging Program of China (No.JCKY2016212A506-0102)
文摘In this paper, a multi-delay milling system considering helix angle and run-out effects is firstly established. An exponential cutting force model is used to model the interaction between a work-piece and a cutting tool, and a new approach is presented for accurately calibrating exponential cutting force coefficients and cutter run-out parameters. Furthermore, based on an implicit multi-step Adams formula and an improved precise time-integration algorithm, a novel stability prediction method is proposed to predict the stability of the system. The involved time delay term and periodic coefficient term are integrated as a comprehensive state term in the integral response which is approximated by the Adams formula. Then, a Floquet transition matrix with an arbitraryorder form is constructed by using a series of matrix multiplication, and the stability of the system is determined by the Floquet theory. Compared to classical semi-discretization methods and fulldiscretization methods, the developed method shows a good performance in convergence, efficiency,accuracy, and multi-order complexity. A series of cutting tests is further carried out to validate the practicability and effectiveness of the proposed method. The results show that the calibration process needs a time of less than 5 min, and the stability prediction method is effective.
基金supported by the National Natural Science Foundation of China(nos.21620102003,21831005,21901158,and 21991112)the Shanghai Sailing Program(no.19YF1421900)+3 种基金Shanghai Municipal Education Commission(no.201701070002E00030)National Key R&D Program of China(no.2018YFE0126800)the Science and Technology Commission of Shanghai Municipality(no.19JC1430100)Zhiyuan Scholar Program(no.ZIRC2020-04).
文摘AstereodivergentPd/Cucatalyst systemforasymmetric desymmetric alkylation of allylic geminal dicarboxylates has been developed,which was successfully applied to the asymmetric synthesis of β-hydroxycarbonylmotifs bearing a versatile carbon-carbon double bond in an enantio-and diastereodivergent manner.A wide scope of substrates including challenging alkylsubstituted,2-substituted,and3,3′-disubstitutedallylic species are compatible with this catalytic system,delivering the substituted products in high to excellent yieldsandwith excellent diastereo-(upto>20:1 dr)and enantioselectivities(up to>99%ee).Furthermore,the mechanism of this dual Pd/Cu catalytic system including:(1)the desymmetrization process ofgeminal dicarboxylates;(2)the origin of regioselectivity(branched or linear);(3)the enantio-and diastereoselectivity observed by changing the combinations of two chiral metal catalysts,have been carefully investigated by theoretical calculations.
基金This work was supported by National Natural Science Foundation of China(No.21772069)Natural Science Foundation of Jiangsu Province(No.BK20201018)+1 种基金Undergraduate Students Project of Jiangsu Province(No.202010320050Z)High-level Innovative and Entrepreneurial Talents Introduction Plan of Jiangsu Province,and Natural Science Foundation of JSNU(No.19XSRX010).
文摘A Lewis acid-catalyzed[4+2]cycloaddition of 3-alkyl-2-vinylindoles withβ,γ-unsaturatedα-ketoesters has been established in the presence of Sc(OTf)3,which afforded a series of indole-containing pyran derivatives in generally good yields(up to 90%yield)with excellent diastereoselectivities(up to >95:5 dr)under mild conditions.This approach not only enriches the chemistry of 3-alkyl-2-vinylindoles,but also has provided an atom-economic method for the synthesis of indole-containing pyran derivatives with potential bioactivity.
