Herein,a novel method for fl uorometric detection of soybean trypsin inhibitor(SBTI)activity based on a water-soluble poly(diphenylacetylene)derivative was reported.Fluorescence quenching of the polymer via p-nitroani...Herein,a novel method for fl uorometric detection of soybean trypsin inhibitor(SBTI)activity based on a water-soluble poly(diphenylacetylene)derivative was reported.Fluorescence quenching of the polymer via p-nitroaniline,produced from the trypsin-catalyzed decomposition of N-benzoyl-DL-arginine-4-nitroanilide hydrochloride(L-BAPA),was well described using the Stern-Volmer equation.SBTI activity was quantitatively assessed based on changes in the fl uorescence intensity of the polymer.This strategy has several advantages,such as high sensitivity and ease of operation.Moreover,its applicability to other biochemical analyses is promising.展开更多
In this study,a MnOx@TiO2 core‐shell catalyst prepared by a two‐step method was used for the low‐temperature selective catalytic reduction of NOx with NH3.The catalyst exhibits high activity,high stability,and exce...In this study,a MnOx@TiO2 core‐shell catalyst prepared by a two‐step method was used for the low‐temperature selective catalytic reduction of NOx with NH3.The catalyst exhibits high activity,high stability,and excellent N2 selectivity.Furthermore,it displays better SO2 and H2O tolerance than its MnOx,TiO2,and MnOx/TiO2 counterparts.The prepared catalyst was characterized systematically by transmission electron microscopy,high‐resolution transmission electron microscopy,X‐ray diffraction,Raman,BET,X‐ray photoelectron spectroscopy,NH3 temperature‐programmed desorption and H2 temperature‐programmed reduction analyses.The optimized MnOx@TiO2 catalyst exhibits an obvious core‐shell structure,where the TiO2 shell is evenly distributed over the MnOx nanorod core.The catalyst also presents abundant mesopores,Lewis‐acid sites,and high redox capability,all of which enhance its catalytic performance.According to the XPS results,the decrease in the number of Mn4+active centers after SO2 poisoning is significantly lower in MnOx@TiO2 than in MnOx/TiO2.The core‐shell structure is hence able to protect the catalytic active sites from H2O and SO2 poisoning.展开更多
This work has been undertaken to study the influences of pH value on the characteristics and activity of photocatalyst by deposition- precipitation method during its preparation process. A series of Pt-modified TiO2 w...This work has been undertaken to study the influences of pH value on the characteristics and activity of photocatalyst by deposition- precipitation method during its preparation process. A series of Pt-modified TiO2 were prepared by deposition-precipitation method at different pH values as well as wet impregnation method, and characterized by XRD, XPS, TEM, UV-Vis and photoluminescence （PL）. It was found that the catalysts had the highest photocatalytic activity for NO conversion when pH value was kept at around 7. And the sample prepared by deposition-precipitation method showed higher activity than that by impregnation method. This was mainly due to their high value in highly-dispersed platinum oxides （PtOx） content on the surface of the catalysts. The results from UV-Vis absorption showed that highest absorbance was obtained for Pt/TiO2 prepared at pH values of around 7. And PL spectra results indicated that the recombination rate of photogenerated electrons and holes of the samples prepared by deposition-precipitation method was lower than that prepared by impregnation method. And in the zeta potential study, the pH values for the isoelectric point of the preparing slurry of 0.05 wt.%Pt/TiO2 and 0.5 wt.%Pt/TiO2 were determined to be 6.5-8.5, which further confirmed the enrichment of PtOx dopants for the catalysts repapered when pH value was around 7.展开更多
The CeO2@TiO2 core-shell nanostructure catalyst prepared by a two-step hydrothermal method was used for selective catalytic reduction （SCR） of NOx with NH3 in this study. The catalyst presented the obvious core-shel...The CeO2@TiO2 core-shell nanostructure catalyst prepared by a two-step hydrothermal method was used for selective catalytic reduction （SCR） of NOx with NH3 in this study. The catalyst presented the obvious core-shell structure, and the shell was amorphous TiO2 which could protect the active center from the SO2 erosion. The catalyst showed high activity and stability, excellent N2 selectivity and superior SO2 resistance and H2O tolerance. Characterizations such as TEM, HR-TEM, XRD, BET, XPS, NH3-TPD, and H2-TPR were carried out. The results indicated that the catalyst had large surface area and the active sites were well dispersed on the surface. The NH3-TPD, H2-TPR and XPS results implied that its increased SCR activity might be due to the enhancement of NH3 chemisorption and the increase of active oxygen species, both of which were conductive to NH3 activation. The excellent catalytic performance suggests that it is a promising candidate for SCR catalyst.展开更多
基金The authors appreciate the support from the Zhe-jiang Province Lingyan Key R&D Project(No.2022C01177)the Zhejiang Administration for Market Regulation Eyas Program Cultiva-tion Project(No.CY2022355).
文摘Herein,a novel method for fl uorometric detection of soybean trypsin inhibitor(SBTI)activity based on a water-soluble poly(diphenylacetylene)derivative was reported.Fluorescence quenching of the polymer via p-nitroaniline,produced from the trypsin-catalyzed decomposition of N-benzoyl-DL-arginine-4-nitroanilide hydrochloride(L-BAPA),was well described using the Stern-Volmer equation.SBTI activity was quantitatively assessed based on changes in the fl uorescence intensity of the polymer.This strategy has several advantages,such as high sensitivity and ease of operation.Moreover,its applicability to other biochemical analyses is promising.
文摘In this study,a MnOx@TiO2 core‐shell catalyst prepared by a two‐step method was used for the low‐temperature selective catalytic reduction of NOx with NH3.The catalyst exhibits high activity,high stability,and excellent N2 selectivity.Furthermore,it displays better SO2 and H2O tolerance than its MnOx,TiO2,and MnOx/TiO2 counterparts.The prepared catalyst was characterized systematically by transmission electron microscopy,high‐resolution transmission electron microscopy,X‐ray diffraction,Raman,BET,X‐ray photoelectron spectroscopy,NH3 temperature‐programmed desorption and H2 temperature‐programmed reduction analyses.The optimized MnOx@TiO2 catalyst exhibits an obvious core‐shell structure,where the TiO2 shell is evenly distributed over the MnOx nanorod core.The catalyst also presents abundant mesopores,Lewis‐acid sites,and high redox capability,all of which enhance its catalytic performance.According to the XPS results,the decrease in the number of Mn4+active centers after SO2 poisoning is significantly lower in MnOx@TiO2 than in MnOx/TiO2.The core‐shell structure is hence able to protect the catalytic active sites from H2O and SO2 poisoning.
基金supported by the National Natural Science Foundation of China (No. 50908201)
文摘This work has been undertaken to study the influences of pH value on the characteristics and activity of photocatalyst by deposition- precipitation method during its preparation process. A series of Pt-modified TiO2 were prepared by deposition-precipitation method at different pH values as well as wet impregnation method, and characterized by XRD, XPS, TEM, UV-Vis and photoluminescence （PL）. It was found that the catalysts had the highest photocatalytic activity for NO conversion when pH value was kept at around 7. And the sample prepared by deposition-precipitation method showed higher activity than that by impregnation method. This was mainly due to their high value in highly-dispersed platinum oxides （PtOx） content on the surface of the catalysts. The results from UV-Vis absorption showed that highest absorbance was obtained for Pt/TiO2 prepared at pH values of around 7. And PL spectra results indicated that the recombination rate of photogenerated electrons and holes of the samples prepared by deposition-precipitation method was lower than that prepared by impregnation method. And in the zeta potential study, the pH values for the isoelectric point of the preparing slurry of 0.05 wt.%Pt/TiO2 and 0.5 wt.%Pt/TiO2 were determined to be 6.5-8.5, which further confirmed the enrichment of PtOx dopants for the catalysts repapered when pH value was around 7.
基金financially supported by the National Natural Science Foundation of China(No.51508281)the Natural Science Foundation of Jiangsu Province(No.BK20130907)Research Startup Funds Program for High Level Talent of Nanjing Normal University(No.2013105XGQ0056)
文摘The CeO2@TiO2 core-shell nanostructure catalyst prepared by a two-step hydrothermal method was used for selective catalytic reduction （SCR） of NOx with NH3 in this study. The catalyst presented the obvious core-shell structure, and the shell was amorphous TiO2 which could protect the active center from the SO2 erosion. The catalyst showed high activity and stability, excellent N2 selectivity and superior SO2 resistance and H2O tolerance. Characterizations such as TEM, HR-TEM, XRD, BET, XPS, NH3-TPD, and H2-TPR were carried out. The results indicated that the catalyst had large surface area and the active sites were well dispersed on the surface. The NH3-TPD, H2-TPR and XPS results implied that its increased SCR activity might be due to the enhancement of NH3 chemisorption and the increase of active oxygen species, both of which were conductive to NH3 activation. The excellent catalytic performance suggests that it is a promising candidate for SCR catalyst.
