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丙烯酸酯乳液在氯乙烯悬浮聚合体系中稳态原位增韧改性 被引量:1
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作者 夏宇正 王熙宁 +4 位作者 石淑先 陈晓农 张作岐 张德龙 徐帅 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2020年第1期37-43,共7页
以丙烯酸丁酯(BA)、丙烯酸乙酯(EA)为单体,通过乳液聚合制备了粒径100 nm左右的均相交联共聚乳液(AC),并将其作为氯乙烯悬浮聚合用接枝改性剂,原位接枝共聚和原位共混进行增韧改性,以制备高抗冲复合聚氯乙烯树脂(AC-PVC)。研究了乳化剂... 以丙烯酸丁酯(BA)、丙烯酸乙酯(EA)为单体,通过乳液聚合制备了粒径100 nm左右的均相交联共聚乳液(AC),并将其作为氯乙烯悬浮聚合用接枝改性剂,原位接枝共聚和原位共混进行增韧改性,以制备高抗冲复合聚氯乙烯树脂(AC-PVC)。研究了乳化剂种类和EA用量对AC乳液稳定性及乳胶粒粒径的影响,模拟了AC乳液在三氯乙烯悬浮聚合体系中的稳定性,并在20 L高压反应釜中进行了氯乙烯悬浮聚合试验,对不同分散剂用量下所得AC-PVC颗粒形态及力学性能进行了表征。结果表明,反应釜粘釜现象明显改善,粗粒径的AC-PVC比例降低,且AC-PVC的抗冲性能显著提高,最高缺口冲击强度可达普通SG-5型PVC树脂的27倍。 展开更多
关键词 丙烯酸酯乳液 悬浮聚合 稳态 原位增韧改性 高抗冲聚氯乙烯
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Nanoindentation Study on Mechanical Properties of Nano-SiO2/Dental Resin Composites 被引量:1
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作者 Chao Zha Jianhua Hu +7 位作者 Ainong Li Shangyu Huang Hanxing Liu Gang Chen Anqi Lei zuoqi zhang Bei Li Zhengzhi Wang 《Journal of Materials Science and Chemical Engineering》 2018年第4期57-64,共8页
The micro/nano-scale indentation tests were performed to explore the performance of bisphenol-α-glycidyl methacrylate (Bis-GMA)/triethylene glycol dimethacrylate (TEGDMA) dental resin composites. The effect of the fi... The micro/nano-scale indentation tests were performed to explore the performance of bisphenol-α-glycidyl methacrylate (Bis-GMA)/triethylene glycol dimethacrylate (TEGDMA) dental resin composites. The effect of the filling content of nano-SiO2 particles on the mechanical properties of the dental composites was studied as well. The experimental results showed that the incorporation of the nano-SiO2 particles at low concentrations (up to 10 wt.%) can apparently increase the hardness and elastic modulus of the dental rein composites. The plasticity index indicates a best elastic recovery capability at a proper amount (4 wt.%) of the nanoparticles. Combined with the infrared spectrum, the mechanical enhancement mechanisms of the dental resin composites were analyzed. 展开更多
关键词 INDENTATION SiO2 Nanoparticles DENTAL RESIN Composites MECHANICAL Properties
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An elastic model for bioinspired design of carbon nanotube bundles
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作者 Xiaoyu Sun zuoqi zhang +1 位作者 Yuanjie Xu Yongwei zhang 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2015年第2期205-215,共11页
Collagen fibers provide a good example of making strong micro-or mesoscale fibers from nanoscale tropocollagen molecules through a staggered and crosslinked organization in a bottom-up manner.Mimicking the architectur... Collagen fibers provide a good example of making strong micro-or mesoscale fibers from nanoscale tropocollagen molecules through a staggered and crosslinked organization in a bottom-up manner.Mimicking the architectural features of collagen fibers has been shown to be a promising approach to develop carbon nanotube(CNT)fibers of high performance.In the present work,an elastic model is developed to describe the load transfer and failure propagation within the bioinspired CNT bundles,and to establish the relations of the mechanical properties of the bundles with a number of geometrical and physical parameters such as the CNT aspect ratio and longitudinal gap,interface cross-link density,and the functionalizationinduced degradation in CNTs,etc.With the model,the stress distributions along the CNT-CNT interface as well as in every individual CNT are well captured,and the failure propagation along the interface and its effects on the mechanical properties of the CNT bundles are predicted.The work may provide useful guidelines for the design of novel CNT fibers in practice. 展开更多
关键词 碳纳米管 弹性模型 仿生设计 纳米管束 胶原纤维 机械性能 故障传播 CNT
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Biomechanical finite element analysis of typical tibiotalar arthrodesis
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作者 Fangbo Bing Chi Wei +4 位作者 Pan Liu Zhenzi Li Yu Deng zuoqi zhang Shaobo Zhu 《Medicine in Novel Technology and Devices》 2021年第3期226-235,共10页
Tibiotalar arthrodesis(TTA)is a common surgical method for post-traumatic arthrosis and primary osteoarthrosis of ankle.Internal screw fixation exhibits such advantages of higher fusion rate and fewer complications th... Tibiotalar arthrodesis(TTA)is a common surgical method for post-traumatic arthrosis and primary osteoarthrosis of ankle.Internal screw fixation exhibits such advantages of higher fusion rate and fewer complications that it has become the mainstream surgical procedure in clinics.However,there are still disputes over the choice of screw type,number and nailing method.In this study,a 3D model of tibiotalar joint was established based on CT data.Two representative types of screws were modeled according to their real objects.Preprocessing was done in Hypermesh 2017,and the finite element simulations of different surgical schemes and postoperative ankle joint movements were performed via Abaqus 2016.The stress distribution in tibiotalar joints and screws,interarticular displacement,and screw deformation were extracted for comparative analyses.The results show that:(1)the three-screw fixation scheme with smaller displacements and higher contact pressure is superior to the two-screw one;(2)the relative displacements of the tibia and talus of full-thread screw under all loads were reduced by approximately 50%compared with those of lag screw,showing better stability;(3)the 60scheme is more favorable for joint fusion and more stable under vertical load,while the 75has the best bending resistance;(4)the stress and strain distributions in screws indicate that the screw break is most likely to happen near its contact region with the bone inlet,the maximum stress reaches 212.2 MPa.This study is of great significance for the selection and optimization of the surgical plan. 展开更多
关键词 Surgical design and optimization Screw type and number Stability Stress and strain analyses Finite element method
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