Thermite films are typical energetic materials(EMs)and have great value in initiating explosive devices.However,research in thermite film preparation is far behind that of research in thermite powders.Electrophoretic ...Thermite films are typical energetic materials(EMs)and have great value in initiating explosive devices.However,research in thermite film preparation is far behind that of research in thermite powders.Electrophoretic deposition(EPD)is an emerging,rapid coating method for film fabrication,including of energetic composite films.In this work,a polytetrafluoroethylene(PTFE)/Al/CuO organic-inorganic hybrid energetic film was successfully obtained using the above method for the first time.The addition of lithocholic acid as a surfactant into the electroplating suspension enabled PTFE to be charged.The combustion and energy release were analyzed by means of a high-speed camera and differential scanning calorimetery(DSC).It was found that the combustion process and energy release of PTFE/Al/CuO were much better than that of Al/CuO.The main reason for the excellent combustion performance of the hybrid PTFE/Al/CuO system was that the oxidability of PTFE accelerated the redox reaction between Al and CuO.The prepared PTFE/Al/CuO film was also employed as ignition material to fire a B-KNO_3 explosive successfully,indicating considerable potential for use as an ignition material in micro-ignitors.This study sheds light on the preparation of fluoropolymer-containing organic-inorganic hybrid energetic films by one-step electrophoretic deposition.展开更多
基金supported by National Natural Science Foundation of China(No.21905032)Natural Science Foundation of the Higher Education Institutions of Anhui Province(No.KJ2019A0687,No.KJ2016A503)+2 种基金High-level Humanities and Social Science Award Cultivation Project of Chaohu University and Innovation(No.kj20zkjp01,No.kj20xqyx02)Entrepreneurship Training Program for Students of National and school level(No.202010380014,X202010380013)Chaohu University for the Start-Up grant(No.KYQD-201907)。
文摘Thermite films are typical energetic materials(EMs)and have great value in initiating explosive devices.However,research in thermite film preparation is far behind that of research in thermite powders.Electrophoretic deposition(EPD)is an emerging,rapid coating method for film fabrication,including of energetic composite films.In this work,a polytetrafluoroethylene(PTFE)/Al/CuO organic-inorganic hybrid energetic film was successfully obtained using the above method for the first time.The addition of lithocholic acid as a surfactant into the electroplating suspension enabled PTFE to be charged.The combustion and energy release were analyzed by means of a high-speed camera and differential scanning calorimetery(DSC).It was found that the combustion process and energy release of PTFE/Al/CuO were much better than that of Al/CuO.The main reason for the excellent combustion performance of the hybrid PTFE/Al/CuO system was that the oxidability of PTFE accelerated the redox reaction between Al and CuO.The prepared PTFE/Al/CuO film was also employed as ignition material to fire a B-KNO_3 explosive successfully,indicating considerable potential for use as an ignition material in micro-ignitors.This study sheds light on the preparation of fluoropolymer-containing organic-inorganic hybrid energetic films by one-step electrophoretic deposition.
