Fluid catalytic cracking (FCC) salty wastewaters, containing quaternary ammonium compounds (QACs), are very difficult to treat by biochemical process. Anoxic/oxic (A/O) biochemical system, based on nitrification and d...Fluid catalytic cracking (FCC) salty wastewaters, containing quaternary ammonium compounds (QACs), are very difficult to treat by biochemical process. Anoxic/oxic (A/O) biochemical system, based on nitrification and denitrification reactions, was used to assess their possible biodegradation. Because of the negative effects of high salt concentration (3%), heavy metals and toxic organic matter on microorganisms’ activities, some techniques consisting of dilution, coagulation and flocculation, and ozonation pretreatments, were gradually tested to evaluate chemical oxygen demand (COD), ammonia-nitrogen (ammonia-N) and total nitrogen (TN) removal rates. In this process of FCC wastewater, starting with university-domesticated sludge, the ammonia-N and TN removal rates were worst. However, when using domesticated SBR’s sludge and operating with five-fold daily diluted influent (thus reducing salt concentration), the ammonia-N removal reached about 57% while the TN removal rate was less than 37% meaning an amelioration of the nitrification process. However, by reducing the dilution factors, these results were inflected after some days of operation, with ammonia-N removal decreasing and TN barely removed meaning a poor nitrification. Even by reducing heavy metals concentration with coagulation/flocculation process, the results never changed. Thereafter, by using ozonation pre-treatment to degrade the detected organic matter of di-tert-butylphenol and certain isoparaffins, COD, ammonia-N and TN removal rates reached 92%, 62% and 61%, respectively. These results showed that the activities of the microorganisms were increased, thus indicating a net denitrification and nitrification reactions improvement.展开更多
Annular centrifugal contactors (ACCs) have many advantages and are recognized as key solvent-extraction equipment for the future reprocessing of spent nuclear fuel (RSNF). To successfully design and operate ACCs for R...Annular centrifugal contactors (ACCs) have many advantages and are recognized as key solvent-extraction equipment for the future reprocessing of spent nuclear fuel (RSNF). To successfully design and operate ACCs for RSNF, it is necessary to understand the hydrodynamic characteristics of the extraction systems in ACCs. The phase ratio (R = Vaq/Vorg, A/O) and liquid holdup volume (V) of the ACC are important hydrodynamic characteristics. In this study, a liquid-fast-separation method was used to systematically investigate the effects of the operational and structural parameters on the V and R (A/O) of a φ20 ACC by using a 30%TBP/kerosene- HNO3 solution system. The results showed that the operational and structural parameters had different effects on the V and R (A/O) of the mixing and separating zones of the ACC, respectively. For the most frequently used structural parameters of the φ20 ACC, when the rotor speed was 3500 r/min, the total flow rate was 2.0 L/h, and the flow ratio (A/O) was 1, the liquid holdup volumes in the mixing zone and rotor were 8.03 and 14.0 mL, respectively, and the phase ratios (A/O) of the mixing zone and separating zone were 0.96 and 1.43, respectively.展开更多
The characteristic of phosphorus removal andappropriate change of the traditional operation modes wereinvestigated in UniFed sequencing batch reactor (SBR)laboratory-scale apparatus (40 L), treating actual domesticwas...The characteristic of phosphorus removal andappropriate change of the traditional operation modes wereinvestigated in UniFed sequencing batch reactor (SBR)laboratory-scale apparatus (40 L), treating actual domesticwastewater with low ratios of C/N (2.57) and C/P (30.18),providing theoretical basis for actual application ofwastewater treatment plant. UniFed SBR system with itsunique operation mode had the distinct superiority ofphosphorus removal. On this occasion, the effect ofvolumetric exchange ratio (VER) and the method ofinfluent introduction for phosphorus removal were studied.When the carbon source became the limiting factor tophosphorus release, the higher the VER, the lower thephosphorus concentration in the effluent. Three differentinfluent patterns, including one-time filling, four-timefilling, and continuous filling with the same quantity ofwastewater could increase the release rate of anaerobicphosphorus from 0.082 to 0.143 mg·P·(L·min)-1. Appropriatechange of the traditional operation modes couldoptimize the efficiency of phosphorus removal. When thefeed/ decant time was extended from 2 h to 4 h, thephosphorous removal efficiency increased from 59.93% to88.45% without any external carbon source. In the mode ofalternation of anoxic-aerobic (A/O) condition, phosphorousremoval efficiency increased from 55.07% to 72.27%clearly. The carbon source in the influent can be usedadequately, and denitrifying phosphorus removal wascarried out in anoxic stage 2 (A2). This mode was optimalfor the treatment of actual domestic wastewater with lowC/N and C/P ratios.展开更多
文摘Fluid catalytic cracking (FCC) salty wastewaters, containing quaternary ammonium compounds (QACs), are very difficult to treat by biochemical process. Anoxic/oxic (A/O) biochemical system, based on nitrification and denitrification reactions, was used to assess their possible biodegradation. Because of the negative effects of high salt concentration (3%), heavy metals and toxic organic matter on microorganisms’ activities, some techniques consisting of dilution, coagulation and flocculation, and ozonation pretreatments, were gradually tested to evaluate chemical oxygen demand (COD), ammonia-nitrogen (ammonia-N) and total nitrogen (TN) removal rates. In this process of FCC wastewater, starting with university-domesticated sludge, the ammonia-N and TN removal rates were worst. However, when using domesticated SBR’s sludge and operating with five-fold daily diluted influent (thus reducing salt concentration), the ammonia-N removal reached about 57% while the TN removal rate was less than 37% meaning an amelioration of the nitrification process. However, by reducing the dilution factors, these results were inflected after some days of operation, with ammonia-N removal decreasing and TN barely removed meaning a poor nitrification. Even by reducing heavy metals concentration with coagulation/flocculation process, the results never changed. Thereafter, by using ozonation pre-treatment to degrade the detected organic matter of di-tert-butylphenol and certain isoparaffins, COD, ammonia-N and TN removal rates reached 92%, 62% and 61%, respectively. These results showed that the activities of the microorganisms were increased, thus indicating a net denitrification and nitrification reactions improvement.
基金supported by the Program for Changjiang Scholars and Innovative Research Team in University of Ministry of Education of China(No.IRT13026)the National 863 Program for Nuclear Fuel Cycling and Nuclear Safety Technology Project(No.2009AA050703)
文摘Annular centrifugal contactors (ACCs) have many advantages and are recognized as key solvent-extraction equipment for the future reprocessing of spent nuclear fuel (RSNF). To successfully design and operate ACCs for RSNF, it is necessary to understand the hydrodynamic characteristics of the extraction systems in ACCs. The phase ratio (R = Vaq/Vorg, A/O) and liquid holdup volume (V) of the ACC are important hydrodynamic characteristics. In this study, a liquid-fast-separation method was used to systematically investigate the effects of the operational and structural parameters on the V and R (A/O) of a φ20 ACC by using a 30%TBP/kerosene- HNO3 solution system. The results showed that the operational and structural parameters had different effects on the V and R (A/O) of the mixing and separating zones of the ACC, respectively. For the most frequently used structural parameters of the φ20 ACC, when the rotor speed was 3500 r/min, the total flow rate was 2.0 L/h, and the flow ratio (A/O) was 1, the liquid holdup volumes in the mixing zone and rotor were 8.03 and 14.0 mL, respectively, and the phase ratios (A/O) of the mixing zone and separating zone were 0.96 and 1.43, respectively.
基金This work was supported by the Joint Research Fund for Overseas Natural Science Foundation of China(Grant No.50628808)State Key Laboratory of Urban Water Resource and Environment(HIT)(No.QAK200802)Academic Human Resources Development in Institutions of Higher Learning Under the Jurisdiction of Beijing Municipality(No.PHR20090502)。
文摘The characteristic of phosphorus removal andappropriate change of the traditional operation modes wereinvestigated in UniFed sequencing batch reactor (SBR)laboratory-scale apparatus (40 L), treating actual domesticwastewater with low ratios of C/N (2.57) and C/P (30.18),providing theoretical basis for actual application ofwastewater treatment plant. UniFed SBR system with itsunique operation mode had the distinct superiority ofphosphorus removal. On this occasion, the effect ofvolumetric exchange ratio (VER) and the method ofinfluent introduction for phosphorus removal were studied.When the carbon source became the limiting factor tophosphorus release, the higher the VER, the lower thephosphorus concentration in the effluent. Three differentinfluent patterns, including one-time filling, four-timefilling, and continuous filling with the same quantity ofwastewater could increase the release rate of anaerobicphosphorus from 0.082 to 0.143 mg·P·(L·min)-1. Appropriatechange of the traditional operation modes couldoptimize the efficiency of phosphorus removal. When thefeed/ decant time was extended from 2 h to 4 h, thephosphorous removal efficiency increased from 59.93% to88.45% without any external carbon source. In the mode ofalternation of anoxic-aerobic (A/O) condition, phosphorousremoval efficiency increased from 55.07% to 72.27%clearly. The carbon source in the influent can be usedadequately, and denitrifying phosphorus removal wascarried out in anoxic stage 2 (A2). This mode was optimalfor the treatment of actual domestic wastewater with lowC/N and C/P ratios.
