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Surface Metallization of Glass Fiber(GF)/Polyetheretherketone(PEEK) Composite with Cu Coatings Deposited by Magnetron Sputtering and Electroplating 被引量:1
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作者 钟利 金凡亚 +2 位作者 朱剑豪 TONG Honghui DAN Min 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第1期213-220,共8页
Surface metallization of glass fiber(GF)/polyetheretherketone(PEEK)[GF/PEEK] is conducted by coating copper using electroplating and magnetron sputtering and the properties are determined by X-ray diffraction(XRD), sc... Surface metallization of glass fiber(GF)/polyetheretherketone(PEEK)[GF/PEEK] is conducted by coating copper using electroplating and magnetron sputtering and the properties are determined by X-ray diffraction(XRD), scanning electron microscopy(SEM), and electron backscatter diffraction(EBSD).The coating bonding strength is assessed by pull-out tests and scribing in accordance with GB/T 9286-1998.The results show that the Cu coating with a thickness of 30 μm deposited on GF/PEEK by magnetron sputtering has lower roughness, finer grain size, higher crystallinity, as well as better macroscopic compressive stress,bonding strength, and electrical conductivity than the Cu coating deposited by electroplating. 展开更多
关键词 surface metallization cu coating magnetron sputtering ELECTROPLATING
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The Effect of Na_(2)O/B_(2)O_(3)Composition Ratio on the Structure and Properties of Cu^(+)Doped Luminescent Glass
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作者 LI Bohan FENG Jinyang +3 位作者 FENG Xiaoping ZHAO Xiujian WU Donghua MA Xiao 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第6期1379-1390,共12页
Cu^(+)-doped alkali borosilicate glasses with different Na_(2)O contents were prepared by the melting method,and the effects of different R values(R=Na_(2)O/B_(2)O_(3))on the structure,ion presence state and luminesce... Cu^(+)-doped alkali borosilicate glasses with different Na_(2)O contents were prepared by the melting method,and the effects of different R values(R=Na_(2)O/B_(2)O_(3))on the structure,ion presence state and luminescence properties of Cu^(+)-doped alkali borosilicate glasses were investigated.The analysis by FT-IR and Raman spectroscopy shows that,with the increase of R value of the glass,the[BO_(3)]in the structure of Cu^(+)-doped alkali borosilicate glass transforms into[BO_(4)]and the number of non-bridging oxygen in the glass network appears to be slightly increased.The absorption spectra and EPR analysis reveal that the Cu^(+)content in the glass gradually decreases and the Cu^(2+)content gradually increases as the R value of the glass increases.XPS and PL tests further indicate that the transformation of the octahedral coordination structure of Cu^(+)to the octahedral coordination structure of Cu^(2+)and the cubic coordination structure of Cu^(+)occurs in the glass as the R value of the glass increases.This transformation can effectively reduce the concentration quenching phenomenon of Cu^(+)and improve the fluorescence luminescence intensity of the glass samples.Meanwhile,the samples were found to have luminescence tunability as well as good thermal stability. 展开更多
关键词 R value glass structure cu ion valence LUMINESCENCE
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Ag enhanced CuS nanoflower catalyst coupling dielectric barrier discharge plasma for disinfection performance and mechanism
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作者 Run WANG Man WANG +5 位作者 Zhouling YANG Mingyu WANG Leyi LIU Lu ZHOU Yi ZHANG Yingqi SONG 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第12期99-109,共11页
In this study,the hydrothermal method was employed to grow submicron CuS on carbon cloth(CC),and the photoreduction method was used to grow Ag nanoparticles on the CuS submicron flowers,thus forming the Ag/CuS/CC cata... In this study,the hydrothermal method was employed to grow submicron CuS on carbon cloth(CC),and the photoreduction method was used to grow Ag nanoparticles on the CuS submicron flowers,thus forming the Ag/CuS/CC catalytic electrode.The application of Ag/CuS/CC electrode-coupled dielectric barrier discharge(DBD)plasma in the disinfection of pathogenic bacteria in water was studied.The Ag/CuS/CC electrode exhibits strong antibacterial activity,and under an external voltage of 30 V,the degradation efficiency of Bacillus subtilis reaches 99.99%within 15 min without regeneration.After five cycles,the inactivation rate of Bacillus subtilis reached 99.99%within 25 min.The practical applicability of the Ag/CuS/CC-coupled DBD system for treating actual wastewater was evaluated,and the changes in biological toxicity were investigated.The results indicate that the prepared Ag/CuS/CC coupled DBD has great potential for safe disinfection of pathogenic bacteria in water through integrated processes. 展开更多
关键词 PLasMA cuS submicron flower active species pathogenic bacteria sterilization mechanism
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Texture and Geochemistry of Multi-stage Hydrothermal Scheelite in the Mamupu Cu-Au-Mo(-W)Deposit,Eastern Tibet:Implications for Tungsten Mineralization in the Yulong Belt
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作者 ZHANG Xiaoxu TANG Juxing +7 位作者 LIN Bin WANG Qin HE Liang YAN Gang SHAO Rui WU Qiang DU Qiu ZHAXI Pingcuo 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2024年第3期701-716,共16页
Multistage tungsten mineralization was recently discovered in the Mamupu copper-polymetallic deposit in the southern Yulong porphyry copper belt(YPCB),Tibet.This study reports the results of cathodoluminescence,trace ... Multistage tungsten mineralization was recently discovered in the Mamupu copper-polymetallic deposit in the southern Yulong porphyry copper belt(YPCB),Tibet.This study reports the results of cathodoluminescence,trace element and Sr isotope analyses of Mamupu scheelite samples,undertaken in order to better constrain the mechanism of W mineralization and the sources of the ore-forming fluids.Three different types of scheelite are identified in the Mamupu deposit:scheelite A(Sch A)mainly occurs in breccias during the prograde stage,scheelite B(Sch B)forms in the chlorite-epidote alteration zone in the retrograde stage,while scheelite C(Sch C)occurs in distal quartz sulfide veins.The extremely high Mo content and negative Eu anomaly in Sch A represent high oxygen fugacity in the prograde stage.Compared with ore-related porphyries,Sch A has a similar REE pattern,but with higher ΣREE,more depleted HREE and slightly lower(^(87)Sr/^(86)Sr)i ratios.These features suggest that Sch A is genetically related to ore-related porphyries,but extensive interaction with carbonate surrounding rocks affects the final REE and Sr isotopic composition.Sch B shows dark(Sch B-I)and light(Sch B-II)domains under CL imaging.From Sch B-I to Sch B-II,LREEs are gradually depleted,with MREEs being gradually enriched.Sch C has the highest LREE/HREE ratio,which indicates that it inherited the geochemical characteristics of fluids after the precipitation of HREE-rich minerals,such as diopside and garnet,in the early prograde stage.The Mo content in Sch B and Sch C gradually decreased,indicating that the oxygen fugacity of the fluids changed from oxidative in the early stages to reductive in the later,the turbulent Eu anomaly in Sch B and Sch C indicating that the Eu anomaly in the Mamupu scheelite is not solely controlled by oxygen fugacity.The extensive interaction of magmatic-hydrothermal fluids and carbonate provides the necessary Ca^(2+)for the precipitation of scheelite in the Mamupu deposit. 展开更多
关键词 SCHEELITE GEOCHEMISTRY Mamupu cu deposit Yulong porphyry copper belt eastern Tibet
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Magmatic-hydrothermal Evolution and Mineralization Mechanisms of the Wangjiazhuang Cu(-Mo)Deposit in the Zouping Volcanic Basin,Shandong Province,China:Constraints from Fluid Inclusions
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作者 SHU Lei YANG Renchao +5 位作者 SHEN Kun YANG Deping MAO Guangzhou LI Min LIU Pengrui MA Xiaodong 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2024年第3期679-700,共22页
The Wangjiazhuang Cu(-Mo)deposit,located within the Zouping volcanic basin in western Shandong Province,China,is unique in this area for having an economic value.In order to expound the metallogenetic characteristics ... The Wangjiazhuang Cu(-Mo)deposit,located within the Zouping volcanic basin in western Shandong Province,China,is unique in this area for having an economic value.In order to expound the metallogenetic characteristics of this porphyry-like hydrothermal deposit,a detailed fluid inclusion study has been conducted,employing the techniques of representative sampling,fluid inclusion petrography,microthermometry,Raman spectroscopy,LA-ICP-MS analysis of single fluid inclusions,as well as cathode fluorescence spectrometer analysis of host mineral quartz.The deposit contains mainly two types of orebodies,i.e.veinlet-dissemination-stockwork orebodies in the K-Si alteration zone and pegmatiticquartz sulfide veins above them.In addition,minor breccia ore occurs locally.Four types of fluid inclusions in the deposit and altered quartz monzonite are identified:L-type one-or two-phase aqueous inclusions,V-type vapor-rich inclusions with V/L ratios greater than 50%-90%,D-type multiphase fluid inclusions containing daughter minerals or solids and S-type silicate-bearing fluid inclusions containing mainly muscovite and biotite.Ore petrography and fluid inclusion study has revealed a three-stage mineralization process,driven by magmatic-hydrothermal fluid activity,as follows.Initially,a hydrothermal fluid,separated from the parent magma,infiltrated into the quartz monzonite,resulting in its extensive K-Si alteration,as indicated by silicate-bearing fluid inclusions trapped in altered quartz monzonite.This is followed by the early mineralization,the formation of quartz veinlets and dissemination-stockwork ores.During the main mineralization stage,due to the participation and mixing of meteoric groundwater with magmatic-sourced hydrothermal fluid,the cooling and phase separation caused deposition of metals from the hydrothermal fluids.As a result,the pegmatitic-quartz sulfide-vein ores formed.In the late mineralization stage,decreasing fluid salinity led to the formation of L-type aqueous inclusions and chalcopyrite-sulfosalt ore.Coexistence of V-type and D-type inclusions and their similar homogenization temperatures with different homogenization modes suggest that phase separation or boiling of the ore-forming fluids took place during the early and the main mineralization stages.The formation P-T conditions of S-type inclusions and the early and the main mineralization stages were estimated as ca.156-182 MPa and 450-650℃,350-450℃,18-35 MPa and 280-380℃,8-15 MPa,respectively,based on the microthermometric data of the fluid inclusions formed at the individual stages. 展开更多
关键词 fluid inclusions fluid immiscibility mineralization mechanisms Wangjiazhuang cu(-Mo)deposit
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A dendritic Cu/Cu_(2)O structure with high curvature enables rapid and efficient reduction of carbon dioxide to C_(2) in an H-cell
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作者 Lei shao Bochen Hu +3 位作者 Jinhui Hao Junjie Jin Weidong Shi Min Chen 《Chinese Journal of Catalysis》 SCIE CAS CSCD 2024年第8期144-153,共10页
Electrocatalytic reduction of CO_(2)(CO_(2)RR)to multicarbon products is an efficient approach for ad-dressing the energy crisis and achieving carbon neutrality.In H-cells,achieving high-current C_(2)products is chall... Electrocatalytic reduction of CO_(2)(CO_(2)RR)to multicarbon products is an efficient approach for ad-dressing the energy crisis and achieving carbon neutrality.In H-cells,achieving high-current C_(2)products is challenging because of the inefficient mass transfer of the catalyst and the presence of the hydrogen evolution reaction(HER).In this study,dendritic Cu/Cu_(2)O with abundant Cu^(0)/Cu^(+)interfaces and numerous dendritic curves was synthesized in a CO_(2)atmosphere,resulting in the high selectivity and current density of the C_(2)products.Dendritic Cu/Cu_(2)O achieved a C_(2)Faradaic efficiency of 69.8%and a C_(2)partial current density of 129.5 mA cm^(-2)in an H-cell.Finite element simulations showed that a dendritic structure with a high curvature generates a strong electric field,leading to a localized CO_(2)concentration.Additionally,DRT analysis showed that a dendritic struc-ture with a high curvature actively adsorbed the surrounding high concentration of CO_(2),enhancing the mass transfer rate and achieving a high current density.During the experiment,the impact of the electronic structure on the performance of the catalyst was investigated by varying the atomic ratio of Cu^(0)/Cu^(+) on the catalyst surface,which resulted in improved ethylene selectivity.Under the optimal atomic ratio of Cu^(0)/Cu^(+),the charge transfer resistance was minimized,and the desorption rate of the intermediates was low,favoring C_(2) generation.Density functional theory calculations indicated that the Cu^(0)/Cu^(+) interfaces exhibited a lower Gibbs free energy for the rate-determining step,enhancing C_(2)H_(4) formation.The Cu/Cu_(2)O catalyst also exhibited a low Cu d-band center,which enhanced the adsorption stability of *CO on the surface and facilitated C_(2)formation.This observa-tion explained the higher yield of C_(2) products at the Cu^(0)/Cu^(+) interface than that of H_(2) under rapid mass transfer.The results of the net present value model showed that the H-cell holds promising industrial prospects,contingent upon it being a catalyst with both high selectivity and high current density.This approach of integrating the structure and composition provides new insights for ad-vancing the CO_(2)RR towards high-current C_(2) products. 展开更多
关键词 Reduction of CO_(2) High current Dendritic structure cu/cu_(2)O H-cell
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Fabrication of Graphene/Cu Composite by Chemical Vapor Deposition and Effects of Graphene Layers on Resultant Electrical Conductivity
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作者 Xinyue Liu Yaling Huang +2 位作者 Yuyao Li Jie Liu Quanfang Chen 《Journal of Harbin Institute of Technology(New Series)》 CAS 2024年第1期16-25,共10页
Graphene(Gr)has unique properties including high electrical conductivity;Thus,graphene/copper(Gr/Cu)composites have attracted increasing attention to replace traditional Cu for electrical applications. However,the pro... Graphene(Gr)has unique properties including high electrical conductivity;Thus,graphene/copper(Gr/Cu)composites have attracted increasing attention to replace traditional Cu for electrical applications. However,the problem of how to control graphene to form desired Gr/Cu composite is not well solved. This paper aims at exploring the best parameters for preparing graphene with different layers on Cu foil by chemical vapor deposition(CVD)method and studying the effects of different layers graphene on Gr/Cu composite’s electrical conductivity. Graphene grown on single-sided and double-sided copper was prepared for Gr/Cu and Gr/Cu/Gr composites. The resultant electrical conductivity of Gr/Cu composites increased with decreasing graphene layers and increasing graphene volume fraction. The Gr/Cu/Gr composite with monolayer graphene owns volume fraction of less than 0.002%,producing the best electrical conductivity up to59.8 ×10^(6)S/m,equivalent to 104.5% IACS and 105.3% pure Cu foil. 展开更多
关键词 chemical vapor deposition(CVD) Gr/cu Gr/cu/Gr graphene layers graphene volume fraction electrical conductivity
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Improvement of ionic conductivity of solid polymer electrolyte based on Cu-Al bimetallic metal-organic framework fabricated through molecular grafting
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作者 Liu-bin SONG Tian-yuan LONG +5 位作者 Min-zhi XIAO Min LIU Ting-ting ZHAO Yin-jie KUANG Lin JIANG Zhong-liang XIAO 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第9期2943-2958,共16页
A composite solid electrolyte comprising a Cu-Al bimetallic metal-organic framework(CAB),lithium salt(LiTFSI)and polyethylene oxide(PEO)was fabricated through molecular grafting to enhance the ionic conductivity of th... A composite solid electrolyte comprising a Cu-Al bimetallic metal-organic framework(CAB),lithium salt(LiTFSI)and polyethylene oxide(PEO)was fabricated through molecular grafting to enhance the ionic conductivity of the PEO-based electrolytes.Experimental and molecular dynamics simulation results indicated that the electrolyte with 10 wt.%CAB(PL-CAB-10%)exhibits high ionic conductivity(8.42×10~(-4)S/cm at 60℃),high Li+transference number(0.46),wide electrochemical window(4.91 V),good thermal stability,and outstanding mechanical properties.Furthermore,PL-CAB-10%exhibits excellent cycle stability in both Li-Li symmetric battery and Li/PL-CAB-10%/LiFePO4 asymmetric battery setups.These enhanced performances are primarily attributable to the introduction of the versatile CAB.The abundant metal sites in CAB can react with TFSI~-and PEO through Lewis acid-base interactions,promoting LiTFSI dissociation and improving ionic conductivity.Additionally,regular pores in CAB provide uniformly distributed sites for cation plating during cycling. 展开更多
关键词 polyethylene oxide cu−Al bimetallic metal-organic framework solid lithium metal battery molecular grafting ionic conductivity
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静电纺丝法制备SnSbCuFeZn高熵合金/碳纳米纤维复合负极材料 被引量:1
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作者 辛玉 潘石 +2 位作者 聂淑晴 缪畅 肖围 《矿冶工程》 CAS 北大核心 2024年第4期61-66,共6页
采用静电纺丝技术,结合煅烧工艺,将SnSbCuFeZn高熵合金纳米颗粒均匀地锚定在导电互联的碳纳米纤维中,成功制备了SnSbCuFeZn@CNFs锂离子电池复合负极材料。结果表明,煅烧温度对材料的物相组成和形貌特征有重要影响,且直接影响SnSbCuFeZn... 采用静电纺丝技术,结合煅烧工艺,将SnSbCuFeZn高熵合金纳米颗粒均匀地锚定在导电互联的碳纳米纤维中,成功制备了SnSbCuFeZn@CNFs锂离子电池复合负极材料。结果表明,煅烧温度对材料的物相组成和形貌特征有重要影响,且直接影响SnSbCuFeZn高熵合金纳米颗粒的晶相、尺寸和分布,决定SnSbCuFeZn@CNFs电极的电化学性能。其中SnSbCuFeZn@CNFs-900电极展现出优良综合性能:0.1 A/g时,初始放电比容量达1232.8 mA/g,循环200次后可逆放电比容量保持在786.0 mA/g;1.0 A/g时,循环500次后放电比容量仍有433.8 mA/g;2.0 mV/s扫描速度下,赝电容贡献率高达93.37%。 展开更多
关键词 静电纺丝法 SnsbcuFeZn高熵合金 碳纳米纤维 负极材料 锂离子电池
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GLDA及其组合试剂对土壤中As、Cd、Cu和Pb的提取能力和机制
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作者 陈春发 泮芝伟 +3 位作者 侯建国 冯宏亮 仓龙 王玉军 《土壤》 CAS CSCD 北大核心 2024年第4期841-848,共8页
以重金属复合污染土壤为研究对象,将谷氨酸二乙酸四钠(GLDA)和其他生物可降解络合剂进行组合,研究了单一和组合试剂对土壤中不同重金属的提取效率和影响机制。结果表明:随着试剂与土壤重金属摩尔比的增加,重金属的提取率逐渐增加,最优... 以重金属复合污染土壤为研究对象,将谷氨酸二乙酸四钠(GLDA)和其他生物可降解络合剂进行组合,研究了单一和组合试剂对土壤中不同重金属的提取效率和影响机制。结果表明:随着试剂与土壤重金属摩尔比的增加,重金属的提取率逐渐增加,最优摩尔比为5∶1;草酸(OA)对As、柠檬酸(CA)对Cu的提取能力高于乙二胺四乙酸二钠(EDTA)对As和Cu的提取能力;GLDA在偏酸的条件下对各种重金属的提取能力均较高;通过不同试剂的组合,GLDA和OA在摩尔比为1∶1时对土壤中As、Cu和Pb的提取能力最强,分别为52.4%、75.0%和89.8%,各重金属元素提取能力顺序为Pb>Cu≈Cd>As。而GLDA和CA在摩尔比为5∶1时对土壤中Cd的提取能力最强,为95.7%。提取前后的土壤重金属形态分级表明,GLDA+OA(1∶1)组合试剂降低了绝大多数形态的重金属含量,减少了易迁移和易被生物吸收的弱结合态重金属含量。 展开更多
关键词 谷氨酸二乙酸四钠 生物可降解络合剂 as CD cu PB
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A Comparison of Hydrothermal Aging, SO2 and Propene Poisoning Effects on NH3-SCR over Cu-ZSM-5 and Cu-SAPO-34 Catalysts
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作者 Kouadio Brou Albert Koffi Konan Martin +1 位作者 Zran Van Eric-Simon Horo Kone 《Journal of Materials Science and Chemical Engineering》 2024年第5期10-28,共19页
This study was aimed to investigate the effects of hydrothermal aging, propene and SO<sub>2</sub> poisoning on the ammonia-selective catalytic reduction (NH<sub>3</sub>-SCR) performance of both... This study was aimed to investigate the effects of hydrothermal aging, propene and SO<sub>2</sub> poisoning on the ammonia-selective catalytic reduction (NH<sub>3</sub>-SCR) performance of both Cu-SAPO-34 and Cu-ZSM-5. The catalytic activities of fresh, aged and poisoned samples were tested in ammonia-selective catalytic reduction (NH<sub>3</sub>-SCR) of NO<sub>x</sub> conditions. The XRD, TG and N<sub>2</sub>-desorption results showed that the structures of the Cu-SAPO-34 and Cu-ZSM-5 remained intact after 750˚C hydrothermally aged, SO<sub>2</sub> and propene poisoned. After hydrothermal aging at 750˚C for 12 h, the NO reduction performance of Cu-ZSM-5 was significantly reduced at lower temperatures, while that of Cu-SAPO-34 was less affected. Moreover, Cu-SAPO-34 catalyst showed high NO conversion with SO<sub>2</sub> or propene compared to Cu-ZSM-5. However, Cu-ZSM-5 showed a larger drop in catalytic activity with SO<sub>2</sub> or propene compared to Cu-SAPO-34 catalyst. The H<sub>2</sub>-TPR results showed that Cu<sup>2 </sup> ions could be reduced to Cu<sup> </sup> and Cu<sup>0</sup> for Cu-ZSM-5, while no significant transformation of copper species was observed for Cu-SAPO-34. Meanwhile, the UV-vis DRS results showed that CuO species were formed in Cu-ZSM-5, while little changes were observed for the Cu-SAPO-34. Cu-SAPO-34 showed high sulfur and hydrocarbon poison resistance compared to Cu-ZSM-5. In summary, Cu-SAPO-34 with small-pore zeolite showed higher hydrothermal stability and better hydrocarbon and sulfur poison resistant than Cu-ZSM-5 with medium-pore. 展开更多
关键词 Hydrothermal Aging Propene and SO2Poisoning Ammonia-Selective Catalytic Reduction(NH3-SCR) cu-SAPO-34 cu-ZSM-5
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添加Sb对Sn-9Zn-3Bi/Cu钎料接头显微组织及力学性能的影响
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作者 涂文斌 吴鸿燕 +3 位作者 梅琪 王韩冰 吴吉洋 颜文俊 《电子元件与材料》 CAS 北大核心 2024年第9期1154-1160,1166,共8页
采用钎料合金化研究添加Sb对Sn-9Zn-3Bi无铅焊点组织、熔点特性、润湿性、金属间化合物(IMC)厚度和剪切强度的影响。结果表明:钎料的熔点随Sb含量的增加而略微上升,钎料的铺展面积随Sb含量的增加从50.3 mm^(2)降低至36.6 mm^(2);添加Sb... 采用钎料合金化研究添加Sb对Sn-9Zn-3Bi无铅焊点组织、熔点特性、润湿性、金属间化合物(IMC)厚度和剪切强度的影响。结果表明:钎料的熔点随Sb含量的增加而略微上升,钎料的铺展面积随Sb含量的增加从50.3 mm^(2)降低至36.6 mm^(2);添加Sb虽然没有改变焊点处钎料基体和界面IMC的显微组织类型,但细化了焊点显微组织,且焊点界面处的IMC厚度从18.6μm降低至16.8μm。随着钎料中Sb含量从0增加到1.5%(质量分数),Sn-9Zn-3Bi/Cu接头剪切强度从22.7 MPa增加到29.8 MPa,剪切强度的提高是显微组织细化、固溶强化及界面处IMC厚度降低共同作用的结果。 展开更多
关键词 无铅钎料 sb 显微组织 剪切强度
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Cu含量以及Cu/Mg比对Al-Si-Cu-Mg合金组织和力学性能的影响
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作者 顾琪 周鹏飞 《铸造》 CAS 2024年第2期180-186,共7页
研究了Cu含量和Cu/Mg比对Al-Si-Cu-Mg合金组织和力学性能的影响。结果表明Al-Si-Cu-Mg合金凝固组织是否形成Mg_(2)Si、Q-Al_(5)Cu_(2)Mg_(8)Si_(6)以及θ-Al_(2)Cu取决于Cu含量以及Cu/Mg比。当Cu/Mg比相对低时形成Mg_(2)Si中间相,而Cu/M... 研究了Cu含量和Cu/Mg比对Al-Si-Cu-Mg合金组织和力学性能的影响。结果表明Al-Si-Cu-Mg合金凝固组织是否形成Mg_(2)Si、Q-Al_(5)Cu_(2)Mg_(8)Si_(6)以及θ-Al_(2)Cu取决于Cu含量以及Cu/Mg比。当Cu/Mg比相对低时形成Mg_(2)Si中间相,而Cu/Mg比高时则倾向于生成Q-Al_(5)Cu_(2)Mg_(8)Si_(6)和θ-Al_(2)Cu相。当Cu/Mg比相同时,高Cu含量和高Mg含量都会促进Q相θ相的形成。通过观察T6热处理后的组织发现Cu含量以及Cu/Mg比控制了初生相的溶解以及析出相的形成,从而影响合金的强度与韧性。通过控制Cu含量及Cu/Mg比使Al-9Si-2Cu-0.5Mg合金中析出较少数量的初生相,再通过热处理析出大量的Q′强化相,使合金具有较高的强度和相对适中的伸长率。 展开更多
关键词 Al-Si-cu-Mg cu含量 cu/Mg比 组织 力学性能
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Corrosion behavior of 2A97 Al-Cu-Li alloys in different thermomechanical conditions by quasi-in-situ analysis
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作者 You Lü Xiang-zhe MENG +2 位作者 Yan-yan LI Ze-hua DONG Xin-xin ZHANG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第9期2772-2786,共15页
As a promising material in the aircraft industry,2A97 Al-Cu-Li alloy exhibits high corrosion susceptibility that may limit its application.In the present work,to illustrate the influences of precipitate and grain-stor... As a promising material in the aircraft industry,2A97 Al-Cu-Li alloy exhibits high corrosion susceptibility that may limit its application.In the present work,to illustrate the influences of precipitate and grain-stored energy on localized corrosion evolution in 2A97 Al-Cu-Li alloy,cold working and artificial aging were carried out to produce 2A97 Al-Cu-Li alloys under different thermomechanical conditions.Quasi-in-situ analysis,traditional immersion test and electrochemical measurement were then conducted to examine the corrosion behavior of 2A97 alloys.It is revealed that precipitate significantly affects Cu enrichment at corrosion fronts,which determines corrosion susceptibility of alloys,whereas grain-stored energy distribution is closely associated with localized corrosion propagation.It is also indicated that quasi-in-situ analysis exhibits a consistent corrosion evolution with traditional immersion tests,which is regarded as a proper method to explore localized corrosion mechanisms by providing local microstructural information with enhanced time and spatial resolutions. 展开更多
关键词 Al−cu−Li alloy corrosion behavior quasi-in situ analysis grain-stored energy thermomechanical treatment
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Hydrogen production performance of the non⁃platinum⁃based MoS_(2)/CuS cathode in microbial electrolytic cells
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作者 HAO Pingping LI Fangfang +5 位作者 WANG Yawen LI Houfen ZHANG Xiao LI Rui WANG Lei LIU Jianxin 《无机化学学报》 SCIE CAS CSCD 北大核心 2024年第9期1811-1824,共14页
MoS_(2)/CuS composite catalysts were successfully synthesized using a one-step hydrothermal method with sodium molybdate dihydrate,thiourea,oxalic acid,and copper nitrate trihydrate as raw materials.The hydrogen pro-d... MoS_(2)/CuS composite catalysts were successfully synthesized using a one-step hydrothermal method with sodium molybdate dihydrate,thiourea,oxalic acid,and copper nitrate trihydrate as raw materials.The hydrogen pro-duction performance of MoS_(2)/CuS prepared with different molar ratios of Mo to Cu precursors(n_(Mo)∶n_(Cu))as cathodic catalysts was investigated in the two-chamber microbial electrolytic cell(MEC).X-ray diffraction(XRD),X-ray pho-toelectron spectroscopy(XPS),scanning electron microscopy(SEM),transmission electron microscope(TEM),linear scanning voltammetry(LSV),electrochemical impedance analysis(EIS),and cyclic voltammetry(CV)were used to characterize the synthesized catalysts for testing and analyzing the hydrogen-producing performance.The results showed that the hydrogen evolution performance of MoS_(2)/CuS-20%(nMo∶nCu=5∶1)was better than that of platinum(Pt)mesh,and the hydrogen production rate of MoS_(2)/CuS-20%as a cathode in MEC was(0.2031±0.0237)m^(3)_(H_(2))·m^(-3)·d^(-1) for 72 h at an applied voltage of 0.8 V,which was slightly higher than that of Pt mesh of(0.1886±0.0134)m^(3)_(H_(2))·m^(-3)·d^(-1).The addition of a certain amount of CuS not only regulates the electron transfer ability of MoS_(2) but also increases the density of active sites. 展开更多
关键词 microbial electrolysis cell hydrogen evolution reaction MoS_(2)/cuS composite catalyst Pt mesh
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Effect of cold rolling deformation on microstructure evolution and mechanical properties of spray formed Al−Zn−Mg−Cu−Cr alloys
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作者 Cai-he FAN Yi-hui LI +4 位作者 Qin WU Ling OU Ze-yi HU Yu-meng NI Jian-jun YANG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第8期2442-2454,共13页
The impact of cold rolling deformation,which was introduced after solid solution and before aging treatment,on microstructure evolution and mechanical properties of the as-extruded spray formed Al−9.8Zn−2.3Mg−1.73Cu−0... The impact of cold rolling deformation,which was introduced after solid solution and before aging treatment,on microstructure evolution and mechanical properties of the as-extruded spray formed Al−9.8Zn−2.3Mg−1.73Cu−0.13Cr(wt.%)alloy,was investigated.SEM,TEM,and EBSD were used to analyze the microstructures,and tensile tests were conducted to assess mechanical properties.The results indicate that the D1-T6 sample,subjected to 25%cold rolling deformation,exhibits finer grains(3.35μm)compared to the D0-T6 sample(grain size of 4.23μm)without cold rolling.Cold rolling refines the grains that grow in solution treatment.Due to the combined effects of finer and more dispersed precipitates,higher dislocation density and smaller grains,the yield strength and ultimate tensile strength of the D1-T6 sample can reach 663 and 737 MPa,respectively.In comparison to the as-extruded and D0-T6 samples,the yield strength of the D1-T6 sample increases by 415 and 92 MPa,respectively. 展开更多
关键词 Al−Zn−Mg−cu alloy spray forming microstructure evolution mechanical properties strengthening mechanism
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Influence of thermomechanical treatment on recrystallization and softening resistance of Cu-6.5Fe-0.3Mg alloy
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作者 Zhen-xia LIU Da-wei YUAN +5 位作者 Xin LUO Lan-hao WANG Jin-shui CHEN Hui-ming CHEN Xiang-peng XIAO Bin YANG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第9期2900-2917,共18页
The recrystallization and softening resistance of a Cu-6.5Fe-0.3Mg(mass fraction,%)alloy prepared by Process 1(cold rolling heat treatment)and Process 2(hot/cold rolling heat treatment)were studied using Vickers hardn... The recrystallization and softening resistance of a Cu-6.5Fe-0.3Mg(mass fraction,%)alloy prepared by Process 1(cold rolling heat treatment)and Process 2(hot/cold rolling heat treatment)were studied using Vickers hardness tests,tensile tests,scanning electron microscopy and transmission electron microscopy.The softening temperature,hardness and tensile strength of the alloy prepared by Process 2 were 110°C,HV 15 and 114 MPa higher,respectively,than those of the alloy prepared by Process 1 after aging at 300°C.The recrystallization activation energy of the alloys prepared by Process 1 and Process 2 were 72.83 and 98.11 kJ/mol,respectively.The pinning effects of the precipitates of the two alloys on grain boundaries and dislocations were basically the same.The softening mechanism was mainly attributed to the loss of dislocation strengthening.The higher Fe fiber density inhibited the average free migration path of dislocations and grain boundary migration in the alloy,which was the main reason for higher softening temperature of the alloy prepared by Process 2. 展开更多
关键词 cu−6.5Fe−0.3Mg alloy hot rolling recrystallization activation energy softening mechanism dislocation strengthening
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叶面阻控剂对大白菜Cu、Pb、Cd、As含量及产量的影响
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作者 熊艳竹 孙秀梅 +7 位作者 鲁海燕 杨浚雯 李群仙 杨跃民 李平 李惠吉 赵娟丽 杜彩艳 《云南农业科技》 2024年第2期42-44,共3页
土壤重金属污染已成为威胁农产品安全和人类健康的重要问题。为了验证喷施叶面阻控剂降低As-Cu复合污染土壤上大白菜重金属铜(Cu)、铅(Pb)、镉(Cd)、砷(As)的污染效应,在弥勒市选取有代表性的农田,通过田间试验研究了硅肥、铁肥、锌肥... 土壤重金属污染已成为威胁农产品安全和人类健康的重要问题。为了验证喷施叶面阻控剂降低As-Cu复合污染土壤上大白菜重金属铜(Cu)、铅(Pb)、镉(Cd)、砷(As)的污染效应,在弥勒市选取有代表性的农田,通过田间试验研究了硅肥、铁肥、锌肥、硒肥对As-Cu复合污染土壤上的大白菜Cu,Pb,Cd,As含量及大白菜产量的影响。结果表明,与对照相比,喷施叶面阻控剂均有效降低了大白菜可食用部位Cu、Pb、Cd、As含量,降幅分别为13.32%~36.15%、25.31%~52.39%、14.75%~29.27%、33.55%~45.68%。喷施不同叶面阻控剂有效增加了大白菜产量,增幅为0.10%~3.20%,其中以喷施硅肥处理的白菜产量最高。综合不同阻控剂降低大白菜可食用部位Cu、Pb、Cd、As含量及对大白菜的增产效应,在本试验条件下,在以硅肥的喷施效果最佳。 展开更多
关键词 叶面阻控剂 大白菜 cu PB CD as
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Mechanism study of Cu(Ⅱ) adsorption from acidic wastewater by ultrasonic-modified municipal solid waste incineration fly ash
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作者 Shunda lin Yang Lu +3 位作者 Lin Zheng Ling Long Xuguang Jiang Jianhua Yan 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第3期157-165,共9页
High concentrations of copper ions(Cu(Ⅱ)) in water will pose health risks to humans and the ecological environment. Therefore, this study aims to utilize ultrasonic-cured modified municipal solid waste incineration(M... High concentrations of copper ions(Cu(Ⅱ)) in water will pose health risks to humans and the ecological environment. Therefore, this study aims to utilize ultrasonic-cured modified municipal solid waste incineration(MSWI) fly ash for Cu(Ⅱ) adsorption to achieve the purpose of “treating waste by waste.” The effects of p H, adsorption time, initial concentration, and temperature on the modified MSWI fly ash’s adsorption efficiency were systematically studied in this article. The adsorption performance of the modified MSWI fly ash can be enhanced by the ultrasonic modification. At pH = 2, 3 and 4, the adsorption capacity of the modified MSWI fly ash for Cu(Ⅱ) increased by 2.7, 1.9 and 1.2 times, respectively. Furthermore, it was suggested that the adsorption process of the modified MSWI fly ash can be better simulated by the pseudo-second-order kinetic model, with a maximum adsorption capacity calculated by the Langmuir model of 24.196 mg.g-1. Additionally, the adsorption process is spontaneous,endothermic, and chemisorption-dominated from the thermodynamic studies(ΔH and ΔS > 0, ΔG < 0).Finally, the enhanced adsorption performance of the modified MSWI fly ash for Cu(Ⅱ) may be attributed to electrostatic interaction and chelation effects. 展开更多
关键词 ULTRasOUND MSWI fly ash cu(Ⅱ) WasTEWATER ADSORPTION
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As_(2)O_(3)与Cu-ZSM-5催化剂的相互作用机理
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作者 张欢 史一林 +4 位作者 刘梁 王晨星 孙瑞彬 贾里 金燕 《中国环境科学》 EI CAS CSCD 北大核心 2024年第4期2003-2010,共8页
基于密度泛函理论计算了NO和As_(2)O_(3)在Cu-ZSM-5表面的吸附性能.通过确立As_(2)O_(3)在Cu-ZSM-5表面的最佳吸附位点,对As3+在其活性位点吸附的反应路径进行研究,计算As在催化剂上的吸附反应活化能垒和决速步骤,揭示As_(2)O_(3)与活... 基于密度泛函理论计算了NO和As_(2)O_(3)在Cu-ZSM-5表面的吸附性能.通过确立As_(2)O_(3)在Cu-ZSM-5表面的最佳吸附位点,对As3+在其活性位点吸附的反应路径进行研究,计算As在催化剂上的吸附反应活化能垒和决速步骤,揭示As_(2)O_(3)与活性位点Cu-O-Cu的成键机制和相互作用机理.结果表明,NO和As_(2)O_(3)都以非氧端吸附在Cu-ZSM-5活性位点Cu-O-Cu的晶格氧位,吸附能分别为-218.515kJ/mol和-206.422kJ/mol,吸附过程中有电荷转移且发生了强烈的相互作用.As_(2)O_(3)在Cu-ZSM-5活性位点Cu-O-Cu的晶格氧上的氧化过程分两步进行,As^(3+)作为Lewis碱与Lewis酸中心的Cu-O-Cu发生非均相氧化反应,第一阶段的氧化产物As_(2)O_(4)在相邻的活性位点上发生二次氧化反应,生成的As_(2)O_(5)成为As^(3+)吸附后的主要存在形式.其中,生成As_(2)O_(4)的反应阶段需要跨越242.75kJ/mol的能垒,成为整个氧化进程的决速步骤. 展开更多
关键词 cu-ZSM-5 as_(2)O_(3) 吸附 氧化反应 能垒
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