In this work,a set of novel Cu2ZnSnS4/Bi2WO6(CZTS/BWO)two-dimensional(2 D)/two-dimensional(2 D)type-Ⅱheterojunctions with different CZTS weight ratios(1%,2%,and 5%)were successfully synthesized via a brief secondary ...In this work,a set of novel Cu2ZnSnS4/Bi2WO6(CZTS/BWO)two-dimensional(2 D)/two-dimensional(2 D)type-Ⅱheterojunctions with different CZTS weight ratios(1%,2%,and 5%)were successfully synthesized via a brief secondary solvothermal process.The successful formation of the heterojunctions was affirmed by characterization methods such as X-ray photoelectron spectroscopy and high-resolution transmission electron microscopy.The photocatalytic activity results showed that the prepared CZTS/BWO heterojunctions had excellent photocatalytic behaviors for organic degradation,especially when the mass fraction of CZTS with respect to BWO in the composite was 2%.Moreover,the addition of hydrogen peroxide(H2O2)could further improve the dye and antibiotic degradation efficiencies.The reinforced photocatalytic and photo-Fenton degradation performance were primarily attributable to the introduction of BWO,which afforded increased active sites,expanded the solar spectral response range,and accelerated the cycle of Cu(Ⅱ)/Cu(Ⅰ);after four cycling times,its catalytic activity did not decrease significantly.In addition,reasonable hypotheses of the photocatalytic and photo-Fenton catalytic mechanisms were formulated.This study is expected to provide a visual approach for designing a novel photo-Fenton catalyst to jointly utilize the photocatalytic and Fenton activities,which can be better applied to the purification of residual organics in wastewater.展开更多
基金supported by the National Natural Science Foundation of China(21663030,21666039)the Open Project of State Key Laboratory of Organic-Inorganic Composites Beijing Key Laboratory,Beijing University of Chemical Technology(oic-201901009)+2 种基金the Project of Science&Technology Office of Shannxi Province(2018TSCXL-NY-02-01,2013K11-08,2013SZS20-P01)Industrial Key Project of Yan’an Science and Technology Bureau(2018KG-04)the Project of Yan’an Science Graduate Innovation Project of Yan’an University(YCX201988)~~
文摘In this work,a set of novel Cu2ZnSnS4/Bi2WO6(CZTS/BWO)two-dimensional(2 D)/two-dimensional(2 D)type-Ⅱheterojunctions with different CZTS weight ratios(1%,2%,and 5%)were successfully synthesized via a brief secondary solvothermal process.The successful formation of the heterojunctions was affirmed by characterization methods such as X-ray photoelectron spectroscopy and high-resolution transmission electron microscopy.The photocatalytic activity results showed that the prepared CZTS/BWO heterojunctions had excellent photocatalytic behaviors for organic degradation,especially when the mass fraction of CZTS with respect to BWO in the composite was 2%.Moreover,the addition of hydrogen peroxide(H2O2)could further improve the dye and antibiotic degradation efficiencies.The reinforced photocatalytic and photo-Fenton degradation performance were primarily attributable to the introduction of BWO,which afforded increased active sites,expanded the solar spectral response range,and accelerated the cycle of Cu(Ⅱ)/Cu(Ⅰ);after four cycling times,its catalytic activity did not decrease significantly.In addition,reasonable hypotheses of the photocatalytic and photo-Fenton catalytic mechanisms were formulated.This study is expected to provide a visual approach for designing a novel photo-Fenton catalyst to jointly utilize the photocatalytic and Fenton activities,which can be better applied to the purification of residual organics in wastewater.
基金National Nature Science Foundation of China(50972107,51172165)Zhejinag Province Key Scientific and Technological Innovations Team of China(2009R50010)+1 种基金Key Foundation of Zhejiang Province Natural Science Foundation of China(Z4110347)Wenzhou Municipal Science and Technology Bureau Key Program(G20090082)
