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Excess Molar Volume, Viscosity and Heat Capacity for the Mixture of 1,2-Propanediol-Water at Different Temperatures 被引量:5
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作者 杨长生 马沛生 +1 位作者 唐多强 靳凤民 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2003年第2期175-180,共6页
Experimental densities, viscosities and heat capacities at different temperatures were presented over the entire mole fraction range for the binary mixture of 1,2-propanediol and water. Density values were used in the... Experimental densities, viscosities and heat capacities at different temperatures were presented over the entire mole fraction range for the binary mixture of 1,2-propanediol and water. Density values were used in the determination of excess molar volumes, VE. At the same time, the excess viscosity was investigated. The values of VE and E were fitted to the Redlich-Kister equation. Good agreement was observed. The excess volumes are negative over the entire range of composition. They show an U-shaped-concentration dependence and decrease in absolute values with increase of temperature. Values of E are negative over the entire range of the composition, and has a trend very similar to that of VE . The analysis shows that at any temperature the specific heat of mixture is a linear function of the composition as x1 > 20%. All the extended lines intersect at one point. An empirical equation is obtained to calculate the specific heat to mixture at any composition and temperature in the experimental range. 展开更多
关键词 VISCOSITY heat capacity DENSITY excess molar volume molecular interaction
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Excess Molar Volume, Viscosity and Heat Capacity for the Binary Mixture of p-Xylene and Acetic Acid at Different Temperatures 被引量:1
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作者 杨长生 马沛生 +2 位作者 唐多强 尹秋响 赵长伟 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2002年第5期604-609,共6页
Experimental densities, viscosities and heat capacities atdifferent temperatures were presented over the entire range of molefraction for the binary mixture of p-xylene and acetic acid. Densityvalues were used in the ... Experimental densities, viscosities and heat capacities atdifferent temperatures were presented over the entire range of molefraction for the binary mixture of p-xylene and acetic acid. Densityvalues were used in the determination of excess molar volumes, V^E.At the same time, the excess viscosity and excess molar heatcapacities were calculated. The values of V^E, η~E and c^E_p werefitted to the Redlich-Kister equation. Good agreements were observed.The excess molar volumes are positive with a large maximum valuelocated in the central concentration range. 展开更多
关键词 VISCOSITY heat capacity DENSITY excess molar volume
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Density and Excess Molar Volume of Binary Mixtures ofp-Xylene+Acetic Acid and o-Xylene+Acetic Acid at Different Temperatures and Pressures
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作者 杨天宇 夏淑倩 +1 位作者 邸志国 马沛生 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2008年第2期247-255,共9页
A new apparatus was designed with a thick-walled glass capillary, electric heater tube with red copper and heat preservation. The thick-walled glass capillary was used for its advantages of resistance to acid corrosio... A new apparatus was designed with a thick-walled glass capillary, electric heater tube with red copper and heat preservation. The thick-walled glass capillary was used for its advantages of resistance to acid corrosion and pressure, and ease of observation. The experimental densities over the entire range of mole fraction for the binary mixture of p-xylene+acetic acid and o-xylene+acetic acid were measured using the new apparatus at temperatures ranging from 313.15K to 473.15K and pressure ranging from 0.20 to 2,0 MPa. The density values were used in the determination of excess molar volumes, W. The Redlich-Kister equation was used to fit the excess molar volume values, and the coefficients and estimate ot the standard error values were presented. The experimental resuits prove that the density measurement apparatus is successful. 展开更多
关键词 DENSITY excess molar volume P-XYLENE O-XYLENE acetic acid
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Excess Molar Volume of Binary Mixtures of Methylheptenone+Alkanols at 298.15 K
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作者 XIAO Xi LI Hao-ran +2 位作者 WANG Cong-min WANG Qi HAN Shi-jun 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2002年第4期427-429,共3页
Excess molar volume(V E) data on binary liquid mixtures of methylheptenone (MHO) with methanol, ethanol, n-propanol or n-butanol have been determined from the density measurements at 298.15 K and atmospheric pressure... Excess molar volume(V E) data on binary liquid mixtures of methylheptenone (MHO) with methanol, ethanol, n-propanol or n-butanol have been determined from the density measurements at 298.15 K and atmospheric pressure. The values of V E in all the systems over the entire composition range are quantified by the Redlich-Kister equation. The effects of the chain length of alkanols on V E are discussed. 展开更多
关键词 excess molar volume Binary mixtures Methylheptenone ALKANOL DENSITY
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Excess Molar Volumes and Viscosities of Binary Mixture of Diethyl Carbonate+Ethanol at Different Temperatures
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作者 马沛生 李楠楠 《Transactions of Tianjin University》 EI CAS 2005年第2期101-105,共5页
The purpose of this work was to report excess molar volumes and dynamic viscosities of the binary mixture of diethyl carbonate (DEC)+ethanol. Densities and viscosities of the binary mixture of DEC+ethanol at tempera... The purpose of this work was to report excess molar volumes and dynamic viscosities of the binary mixture of diethyl carbonate (DEC)+ethanol. Densities and viscosities of the binary mixture of DEC+ethanol at temperatures 293.15 K—343.15 K and atmospheric pressure were determined over the entire composition range. Densities of the binary mixture of DEC+ethanol were measured by using a vibrating U-shaped sample tube densimeter. Viscosities were determined by using Ubbelohde suspended-level viscometer. Densities are accurate to 1.0×10-5 g·cm-3, and viscosities are reproducible within ±0.003 mPa·s. From these data, excess molar volumes and deviations in viscosity were calculated. Positive excess molar volumes and negative deviations in viscosity for DEC+ethanol system are due to the strong specific interactions.All excess molar vo-(lumes) and deviations in viscosity fit to the Redlich-Kister polynomial equation.The fitting parameters were presented,and the average deviations and standard deviations were also calculated.The errors of correlation are very small.It proves that it is valuable for estimating densities and viscosities of the binary mixture by the correlated equation. 展开更多
关键词 DENSITY VISCOSITY excess molar volume diethyl carbonate ETHANOL
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Excess Molar Volume and Apparent Molar Volume of Binary Mixtures of 2-Methyl-3-buten-2-ol with 1-Alcohol at 298.15K
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作者 刘迪霞 李浩然 +1 位作者 邓东顺 韩世钧 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2002年第4期454-458,共5页
Excess molar volumes (V^E_m) of binary mixtures of2-methyl-3-buten-3-ol [CH_3C(OH)(CH_3)CHCG_2] with four 1-alcohols:methanol, ethanol, 1-propanol and l-butanol at 298.15 K andatmospheric pressure are derived from den... Excess molar volumes (V^E_m) of binary mixtures of2-methyl-3-buten-3-ol [CH_3C(OH)(CH_3)CHCG_2] with four 1-alcohols:methanol, ethanol, 1-propanol and l-butanol at 298.15 K andatmospheric pressure are derived from density measurements with avibrating-tube densimeter. All the excess volumes are negative in thesystems over the entire composition range. The results are correlatedwith the Redlich-Kister equation. The effects of chain length ofl-alcohols on V^E_m are discussed. The apparent molar volumes of2-methyl-3-ol and l-alcohols are calculated respectively. 展开更多
关键词 excess molar volume binary mixture 2-methyl-3-buten-2-ol l-alcohol
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Studies on Lattice Parameter,Molar Volume and Excess Molar Volume of Pb-based a-phase Solid Solution in Pb-Sn-Cd Ternary System
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作者 Liu Hengli (Department of Rock Chemistry, Changchun University of Earth Science, Changchun)Long Xiang, Kang Hongye and Zhao Muyu (Department of Chemistry, Jilin University, Changchun) 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 1990年第4期300-306,共7页
The lattice parameters a and the molar volumes Km of Pb-based a-phase solid solutions in the Pb-Sn-Cd ternary system were determined by means of X-ray diffraction. The lattice parameters a vary linearly with the molar... The lattice parameters a and the molar volumes Km of Pb-based a-phase solid solutions in the Pb-Sn-Cd ternary system were determined by means of X-ray diffraction. The lattice parameters a vary linearly with the molar fractions, the molar volumes show a positive deviation from the ideal solution behaviour, and the contribution of the solute Cd to the excess molar volumes V is much larger than that of the solute Sn. According to Vegard' s law orsub-regular solution model, the relationship between the experimental data of a or Vm andthe compositions of alloy is obtained by the mathematic regressive method, the prediction precisions of the both formulae are within the limits of experiment error. 展开更多
关键词 Alloy solid solution Lattice parameter molar volume excess molar volume
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Densities and excess molar volumes of mixtures containing diesel,biodiesel and alkanols at temperatures from 288.15 to 313.15 K
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作者 Sunita Malik Poonam Jangra Darolia +1 位作者 S.K.Garg V.K.Sharma 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2021年第6期198-207,共10页
The present work is focusing on the synthesization and physico-chemical properties of Jatropha curcas biodiesel with diesel and alcohols.The densities of binary diesel(2)+1-alkanols(C_(3) or C_(4))(3)and ternary Jatro... The present work is focusing on the synthesization and physico-chemical properties of Jatropha curcas biodiesel with diesel and alcohols.The densities of binary diesel(2)+1-alkanols(C_(3) or C_(4))(3)and ternary Jatropha curcas biodiesel(1)+diesel(2)+1-alkanols(C_(3)or C_(4))(3)blends have been reported over full range of composition at temperatures within range 288.15 to 313.15 K.Also densities of Jatropha curcas biodiesel(1)+diesel or 1-alkanols(C_(3) or C_(4))(2)blends have been measured at 313.15 K.Excess molar volumes,V^E,V^E_(123)of binary and ternary blends were calculated from the measured data and the derived properties were correlated to composition using Redlich-Kister equation.A reasonable agreement was found between the measured and estimated values.Further,densities and excess molar volumes data were reasoned to discuss molecular interactions taking into consideration effect of composition and temperature. 展开更多
关键词 Jatropha curcas biodiesel DIESEL ALCOHOLS Blends Density excess molar volumes
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Excess Molar Volumes and Viscosities for Binary Mixtures of 1-Alkoxypropan-2-ols with 1-Butanol, and 2-Butanol at 298.15 K and Atmospheric Pressure
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作者 PAL, Amalendu GABA, Rekha 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2007年第12期1781-1789,共9页
Excess molar volumes Vm^E and kinematic viscosities v have been measured as a function of composition for binary mixtures of propylene glycol monomethyl ether (1-methoxy-2-propanol), MeOCH2CH(OH)Me, propylene glyc... Excess molar volumes Vm^E and kinematic viscosities v have been measured as a function of composition for binary mixtures of propylene glycol monomethyl ether (1-methoxy-2-propanol), MeOCH2CH(OH)Me, propylene glycol monoethyl ether (1-ethoxy-2-propanol), EtOCH2CH(OH)Me, propylene glycol monopropyl ether (1-propoxy-2-propanol), PrOCH2CH(OH)Me, propylene glycol monobutyl ether (1-butoxy-2-propanol), BuOCH2CH(OH)Me, and propylene glycol tert-butyl ether (1-tert-butoxy-2-propanol), t-BuOCH2CH(OH)Me with 1-butanol, and 2-butanol, at 298.15 K and atmospheric pressure. The excess molar volumes are negative across the entire range of composition for all the systems with 1-butanol, and positive for the systems 2-butanol+ 1-methoxy-2-propanol, and +1-propoxy-2-propanol, negative for the systems 2-butanol+1-butoxy-2-propanol, and change sign for the systems 2-butanol+ 1-ethoxy-2-propanol, and + 1-tert-butoxy-2-propanol. From the experimental data, the deviation in dynamic viscosity η from ∑χiηi has been calculated. Both excess molar volumes and viscosity deviations have been correlated using a Redlich-Kister type polynomial equation by the method of least-squares for the estimation of the binary coefficients and the standard errors. 展开更多
关键词 excess molar volumes binary mixtures alkoxypropanols
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A Prediction of the Excess Partial Molar Free Energies of MgCl_2 in the KCI-MgCl_2-LiCl Molten Salt System Containing MgCl_2 below 0.5 from Thermodynamic Properties of Binary Systems 被引量:1
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作者 Quanru ZHANG, Yuangao LI and Zheng FANG (Department of Chemistry, Central South University of Technology, Changsha 410083, China) 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2000年第1期85-87,共3页
The thermodynamical properties of MgCl_2 in KCI-MgCl_2-LiCl molten electrolytes containing MgCl_2 below 0.5 (mole fraction, the same below) have been determined from the interchange energies of two binary systems KCI... The thermodynamical properties of MgCl_2 in KCI-MgCl_2-LiCl molten electrolytes containing MgCl_2 below 0.5 (mole fraction, the same below) have been determined from the interchange energies of two binary systems KCI-MgCl_2 and LiCI-MgCl_2, by means of a model on the assumptions that the electrolytes in the solution are treated as independent particles instead of their ion forms and the interchange energy between the component pair KCI-LiCl is ignored when compared with those of component pairs KCl-MgCl_2 and MgCl_2-LiCl. The interchange energies, wKCl-MgCl_2 and wMgcCl_2-Licl, are obtained as-70000 and -13800 J.mol-1, from the corresponding binary solutions, respectively. 展开更多
关键词 KCI Free A Prediction of the excess Partial molar Free Energies of MgCl2 in the KCI-MgCl2-LiCl Molten Salt System Containing MgCl2 below 0.5 from Thermodynamic Properties of Binary Systems LICL
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Density, Viscosity, and Excess Properties for Binary Mixture of Diethylene Glycol Monoethyl Ether + Water from 293.15 to 333.15 K at Atmospheric Pressure 被引量:5
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作者 李新学 徐国民 +1 位作者 王彦伟 胡一江 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2009年第6期1009-1013,共5页
Densities and viscosities were measured as a function of composition for binary liquid mixture of diethylerie glycol monoethyl ether [CH3CH2O(CH2)2O(CH2)2OH] + water from 293.15 to 333.15 K at atmospheric pressur... Densities and viscosities were measured as a function of composition for binary liquid mixture of diethylerie glycol monoethyl ether [CH3CH2O(CH2)2O(CH2)2OH] + water from 293.15 to 333.15 K at atmospheric pressure, with a capillary pycnometer and Ubbelohde capillary viscometer respectively. From the experimental data, the excess molar volume V^E, viscosity deviation △η, and the excess energy of activation for viscous flow △G^*E were calculated. These data were correlated by the Redlich-Kister type equations to obtain the coefficients and standard deviations. The results showed a strong molecular interaction between diethylene glycol monoethyl ether and water. 展开更多
关键词 DENSITY VISCOSITY diethylene glycol monoethyl ether binary mixture excess molar volume viscosity deviation
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Ultrasonic, Volumetric and Isentropic Compressibility of Binary Mixtures of 1,4-Dioxane with Primary Alcohols at 303.15 K
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作者 Seema Agarwal Dhirendra Kumar Sharma 《Open Journal of Physical Chemistry》 2021年第3期168-181,共14页
Density, viscosity and sound velocity of six binary liquid mixtures of methanol, ethanol, propanol, butanol, hexanol and octanol with 1,4-dioxane have been measured over the entire range of composition at temperature ... Density, viscosity and sound velocity of six binary liquid mixtures of methanol, ethanol, propanol, butanol, hexanol and octanol with 1,4-dioxane have been measured over the entire range of composition at temperature 303.15K. From the experimental densities, viscosities and sound velocity, the excess molar volume (<i>V<sup>E</sup></i>), deviation in viscosity (Δ<i>η</i>) and deviation in isentropic compressibility (Δ<i>K<sub>S</sub></i>) have been calculated. The results have been used to discuss the nature and strength of intermolecular interactions in these mixtures. 展开更多
关键词 DENSITY VISCOSITY Sound Velocity excess molar volume Viscosity Deviation Isentropic Compressibility Binary Mixtures ALCOHOLS
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Experimental data and modeling for excess enthalpies of 2-Pentanol with n-alkanes(C7–C9) at T =(293.15, 298.15 and 303.15) K
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作者 Dongwei Wei Mengying Li +1 位作者 Jing Ma Baohe Wang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2020年第6期1661-1669,共9页
Excess molar enthalpies,H^E,for the binary mixtures of 2-pentanol with n-alkanes(n-heptane,n-octane,and nnonane)have been determined at three different temperatures T=(293.15,298.15 and 303.15)K and normal atmospheric... Excess molar enthalpies,H^E,for the binary mixtures of 2-pentanol with n-alkanes(n-heptane,n-octane,and nnonane)have been determined at three different temperatures T=(293.15,298.15 and 303.15)K and normal atmospheric pressure over the entire composition range using a Calvet microcalorimeter.All mixtures show endothermic mixing with the maximum values of the excess enthalpies occurring in the n-alkane-rich region.The H^Edata are smoothed using Redlich–Kister equation.The applicability of the Treszczanowicz–Benson,ERAS,Renon–Prausnitz and Chen–Bagley models to correlate H^Eof studied mixtures is tested,and the agreement between experimental and theoretical results is satisfactory.Each model includes a self-association equilibrium constant that represents hydrogen bonding and an adjustable parameter that reflects physical interactions. 展开更多
关键词 excess molar enthalpy 2-Pentanol N-ALKANE Redlich–Kister equation Correlation
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Densities, Viscosities and Related Properties for Binary Mixtures of Sulfolane + p-Xylene, Sulfolane + Ethylbenzene in the Temperature Range from 303.15K to 353.15K
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作者 杨长生 马沛生 周清 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2004年第4期537-542,共6页
Densities and viscosities of the binary systems of sulfolane + ethylbenzene, sulfolane + p-xylene have been experimentally determined in temperature interval 303.15-353.15 K and at atmospheric pressure for the whole c... Densities and viscosities of the binary systems of sulfolane + ethylbenzene, sulfolane + p-xylene have been experimentally determined in temperature interval 303.15-353.15 K and at atmospheric pressure for the whole composition range. The excess molar volumes and viscosity deviations were computed. The computed quantities have been fitted to Redlich-Kister equation. Excess molar volumes and viscosity deviation show a systematic change with increasing temperature. Two mixtures exhibit negative excess volumes with a minimum which occurs approximately at x = 0.5. The effect of the size, shape and interaction of components on excess molar volumes and viscosity deviations is discussed. 展开更多
关键词 density VISCOSITY excess molar volume SULFOLANE
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Densities of methanol+trimethyl phosphate binary mixtures from (293.15 to 333.15)K and viscosities of trimethyl phosphate from (283.15 to 373.15)K
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作者 王利生 田娜娜 范传雷 《Journal of Beijing Institute of Technology》 EI CAS 2011年第2期267-271,共5页
Densities of methanol+trimethyl phosphate binary mixtures were measured over a temperature range of (293.15 to 333.15)K at atmospheric pressure. From these data, excess molar volume(VE) was calculated. Viscositie... Densities of methanol+trimethyl phosphate binary mixtures were measured over a temperature range of (293.15 to 333.15)K at atmospheric pressure. From these data, excess molar volume(VE) was calculated. Viscosities of trimethyl phosphate were also measured over a temperature range of (283.15 to 373.15)K and the data were fitted to the Andrade equation. The density data were fitted to a second-order polynomial. The excess molar volumes were fitted to the Redlich-Kister equation using a nonlinear regression method. Results show that the density and viscosity gradually decreases with the increase of temperature. 展开更多
关键词 trimethyl phosphate DENSITY VISCOSITY excess molar volume
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Density and surface tension of binary mixtures of 1-ethyl-3-methylimdazolium nitrate with alcohols
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作者 Feng Yun Zhao Li Ya Liang +1 位作者 Jian Ying Wang Yong Qi Hu 《Chinese Chemical Letters》 SCIE CAS CSCD 2012年第11期1295-1298,共4页
New experimental data of densities and surface tensions are presented for the binary mixtures of the ionic liquid 1-ethyl-3- methyl imidazolium nitrate ([EMIM]NO3) with methanol and ethanol. Measurements were perfor... New experimental data of densities and surface tensions are presented for the binary mixtures of the ionic liquid 1-ethyl-3- methyl imidazolium nitrate ([EMIM]NO3) with methanol and ethanol. Measurements were performed at 298.15 K and atmospheric pressure, covering the whole composition range. Excess molar volumes VE and the surface tension deviations 8y have been determined. For the excess molar volumes of binary mixture, there is a region of negative VE at low IL mole fraction, passing through a minimum and then VE increases and becomes positive, showing maximum at higher IL mole fraction. It is shown that the surface tension deviations ~y of [EMIM]NO3 + methanol system are positive but those of [EMIM]NO3 + ethanol system are negative over the entire mole fraction range. 展开更多
关键词 Ionic liquid DENSITY Surface tension excess molar volume
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