A new coordination polymer [Cu2(OH)(nbta)(tib)(H2 O)2]n(1, H3 nbta = 5-nitro-1,2,3-benzenetricarboxylic acid, tib = 1-(4 H-1,2,4-triazol-4-yl)-4-(imidazol-1-yl)benzene) constructed from dimeric Cu(Ⅱ) units has been s...A new coordination polymer [Cu2(OH)(nbta)(tib)(H2 O)2]n(1, H3 nbta = 5-nitro-1,2,3-benzenetricarboxylic acid, tib = 1-(4 H-1,2,4-triazol-4-yl)-4-(imidazol-1-yl)benzene) constructed from dimeric Cu(Ⅱ) units has been synthesized under hydrothermal conditions and structurally characterized by single-crystal X-ray diffraction analysis. The compound crystallizes in monoclinic system, space group I2/c, with a = 17.8474(9), b = 11.7588(6), c = 21.9221(11) ?, β = 104.419(5)°, V = 4455.7(4) ?3 and Z = 8. Compound 1 is a three-dimensional structure constructed from dimeric Cu(Ⅱ) units and presents a 2-nodal(3,5)-connected net. Moreover, the thermal stability and solid UV-Vis absorption spectra have been investigated.展开更多
The doping reaction of polyaniline with camphor sulfonic acid (CSAH) in different organic solvents was studied by UV Vis spectroscopy. The experimental results show that the polaron band of the species was shifted to ...The doping reaction of polyaniline with camphor sulfonic acid (CSAH) in different organic solvents was studied by UV Vis spectroscopy. The experimental results show that the polaron band of the species was shifted to shorter wavelength when polyaniline was doped with CSAH in N methyl 2 pyrrolidione (NMP) solvent, while the red shift of polaron band was observed when it was in N, N dimethylformamide (DMF). It indicates that the influence of different processing solvents on the doping property of polyaniline is greatly different. N methyl 2 pyrrolidione is a good solvent for polyaniline, polyaniline chain is unfolded in it. The interaction of NMP with CSAH is so strong that the resulting product is apt to dedoping, while the solubility of polyaniline in DMF is relatively low and polyaniline chain is in partly folded state. Thus the doping reaction is kinetically disadvantageous but thermodynamically advantageous.展开更多
The adsorption behaviour has been studied using in situ FTIR and UV/Vis spectroscopy,voltammetry,AC impedance and polential step methods.The results show that cytochrome c can be irreversibly adsorbed on the gold surf...The adsorption behaviour has been studied using in situ FTIR and UV/Vis spectroscopy,voltammetry,AC impedance and polential step methods.The results show that cytochrome c can be irreversibly adsorbed on the gold surface in a complete monolayer and the adsorbed layer can mediate the redox reaction of cytochrome c in the solotiorr but not ail adsorbed cytochrome c molecules would play this role.展开更多
RE chlorophyll a complexes (RE=La, Ce, Eu and Y) were synthesized in acetone solution. The UV Vis and FTIR spectra of RE chlorophyll a, chlorophyll a and pheophytin a as well as MCD spectra of chlorophyll a, p...RE chlorophyll a complexes (RE=La, Ce, Eu and Y) were synthesized in acetone solution. The UV Vis and FTIR spectra of RE chlorophyll a, chlorophyll a and pheophytin a as well as MCD spectra of chlorophyll a, pheophytin a and La chlorophyll a were studied. Results show that Soret band splits, Q y(0→0) blue shifts, and the other Q band disappearance occurred in the UV Vis spectra of the RE chlorophyll a complexes. The FTIR spectra of the RE chlorophyll a complexes are similar to that of chlorophyll a, but are distinct from that of pheophytin a. These phenomena indicate that La 3+ , Ce 3+ , Eu 3+ , and Y 3+ coordinate to the porphyrin rings of pheophytin, and RE chlorophyll a complexes are formed. MCD spectrum of La chlorophyll a shows the special bands in Soret band region, which indicated that La chlorophyll a are sandwich structure porphyrin complexes.展开更多
The spin crossover（SCO） compound [Fe（bapbpy）（NCS）2],where bapbpy contains two fused N,N-bis（2-pyridyl）amines,has been studied by DFT/TD-DFT/BS-DFT methods.Several density functionals and basis sets were used i...The spin crossover（SCO） compound [Fe（bapbpy）（NCS）2],where bapbpy contains two fused N,N-bis（2-pyridyl）amines,has been studied by DFT/TD-DFT/BS-DFT methods.Several density functionals and basis sets were used in the calculation to obtain optimized geometries of the compound in the low-（LS） and high-spin（HS） states.The vibrational modes and IR spectra,spin splitting energies,excited states and UV/Vis absorption spectra were obtained.The structural parameters of the calculated isolated complex are in good agreement with the X-ray data.We investigate three dimers of [Fe（bapbpy）（NCS）2] complex for their magnetic properties.It has been found that the complex（1,3） has ferromagnetic character while the others are antiferromagnetic in nature by using a broken symmetry approach in the DFT framework（BS-DFT） with support from the coupling constant values（J） and spin density plots.展开更多
Surface morphology, compositions, microstructure and optical properties of GaN film irradiated by highly charged Kr^(q+)(q = 23, 15, 11) in two geometries to a fluence of 1×10^(15)kr^(q+)/cm^2 were studied using ...Surface morphology, compositions, microstructure and optical properties of GaN film irradiated by highly charged Kr^(q+)(q = 23, 15, 11) in two geometries to a fluence of 1×10^(15)kr^(q+)/cm^2 were studied using AFM,XPS, PL, Raman scattering and UV–visible spectroscopy.The AFM observation shows that the irradiated GaN area is a swollen terrace. The swelling rate increased with the charge state(potential energy). For the same charge state,the swelling rate of tilted incidence was greater than that for normal incidence. The XPS measurements reveal that N deficiency, Ga enrichment and Ga–O and Ga dangling bonds generated on the irradiated GaN surface increased with the charge state, and more N was lost for normal incidence than that for tilted incidence. The UV–Vis results show that the transmittance decreased with increasing charge state. For the same charge state, the transmittance for tilted incidence is higher than that for normal incidence.The PL spectra present that, with increasing charge state,the YL band intensity decreased, with a blueshift in its peak position; while the NBE peak intensity increased firstand then reduced, and a blue luminescence band appeared.A rapid quenching of both the YL and the NEB for normal incidence was observed. Raman spectra display that screw dislocations perhaps were produced near the surface for normal incidence.展开更多
A static optical pressure measurement system and the synthesis of Palladium tetraethyl tetramethyl porphyrin(PdTETMP) are investigated in this paper. UV visible spectrum, surface photovoltage spectrum of PdTETMP and...A static optical pressure measurement system and the synthesis of Palladium tetraethyl tetramethyl porphyrin(PdTETMP) are investigated in this paper. UV visible spectrum, surface photovoltage spectrum of PdTETMP and oxygen quenching phosphorescence of PdTETMP are determined. The results indicate that the photovoltaic respons of PdTETMP decrease as the partial pressure of oxygen rises, which is similar to oxgyen quenching of the phosphorescence of PdTETMP. The data shows, as predicted by Stem Volmer relationship I 0/I=A+Bp/p 0, that a nearly linear relationship between I 0/I versus p/p 0 and the intercept A and slope B are 0.32, 0.67, respectively.展开更多
A blue poly(azure B) film has been synthesized using repeated potential cycling between -0.25 and 1.10 V (versus SCE). The electrolytic solution consisted of 2.5 mmol dm(-3) azure B, 0.5 mol dm(-3) NaCl and 0.2 mol dm...A blue poly(azure B) film has been synthesized using repeated potential cycling between -0.25 and 1.10 V (versus SCE). The electrolytic solution consisted of 2.5 mmol dm(-3) azure B, 0.5 mol dm(-3) NaCl and 0.2 mol dm(-3) NaH2PO4 at the pH range of 2.0 to 11.0. The in situ visible spectrum during electrolysis of azure B shows that the intensity at 740 nm peak increases with increasing numbers of potential cycles, which is attributable to the formation of poly(azure B). The wavelength of its corresponding absorption peak is 98 nm longer than that of azure B. The polymerization rate is strongly affected by pH values. The anodic peak potential and cathodic peak potential of the poly(azure B) in a solution of pH 3.0 are not affected by increasing the scan rate from 25 to 600 mV s(-1). Poly(azure B) has good electrochemical reversibility and fast charge transfer characteristic in the pH range of 2.0 and 11.0. The conductivity of poly(azure B) is 1.5 x 10(-4) S cm(-1) According to the differences between FTIR spectra of poly(azure B) and azure B, an electrochemical polymerization mechanism of azure B is proposed in this paper.展开更多
基金supported by the National Natural Science Foundation of China(21401097)
文摘A new coordination polymer [Cu2(OH)(nbta)(tib)(H2 O)2]n(1, H3 nbta = 5-nitro-1,2,3-benzenetricarboxylic acid, tib = 1-(4 H-1,2,4-triazol-4-yl)-4-(imidazol-1-yl)benzene) constructed from dimeric Cu(Ⅱ) units has been synthesized under hydrothermal conditions and structurally characterized by single-crystal X-ray diffraction analysis. The compound crystallizes in monoclinic system, space group I2/c, with a = 17.8474(9), b = 11.7588(6), c = 21.9221(11) ?, β = 104.419(5)°, V = 4455.7(4) ?3 and Z = 8. Compound 1 is a three-dimensional structure constructed from dimeric Cu(Ⅱ) units and presents a 2-nodal(3,5)-connected net. Moreover, the thermal stability and solid UV-Vis absorption spectra have been investigated.
文摘The doping reaction of polyaniline with camphor sulfonic acid (CSAH) in different organic solvents was studied by UV Vis spectroscopy. The experimental results show that the polaron band of the species was shifted to shorter wavelength when polyaniline was doped with CSAH in N methyl 2 pyrrolidione (NMP) solvent, while the red shift of polaron band was observed when it was in N, N dimethylformamide (DMF). It indicates that the influence of different processing solvents on the doping property of polyaniline is greatly different. N methyl 2 pyrrolidione is a good solvent for polyaniline, polyaniline chain is unfolded in it. The interaction of NMP with CSAH is so strong that the resulting product is apt to dedoping, while the solubility of polyaniline in DMF is relatively low and polyaniline chain is in partly folded state. Thus the doping reaction is kinetically disadvantageous but thermodynamically advantageous.
文摘The adsorption behaviour has been studied using in situ FTIR and UV/Vis spectroscopy,voltammetry,AC impedance and polential step methods.The results show that cytochrome c can be irreversibly adsorbed on the gold surface in a complete monolayer and the adsorbed layer can mediate the redox reaction of cytochrome c in the solotiorr but not ail adsorbed cytochrome c molecules would play this role.
文摘RE chlorophyll a complexes (RE=La, Ce, Eu and Y) were synthesized in acetone solution. The UV Vis and FTIR spectra of RE chlorophyll a, chlorophyll a and pheophytin a as well as MCD spectra of chlorophyll a, pheophytin a and La chlorophyll a were studied. Results show that Soret band splits, Q y(0→0) blue shifts, and the other Q band disappearance occurred in the UV Vis spectra of the RE chlorophyll a complexes. The FTIR spectra of the RE chlorophyll a complexes are similar to that of chlorophyll a, but are distinct from that of pheophytin a. These phenomena indicate that La 3+ , Ce 3+ , Eu 3+ , and Y 3+ coordinate to the porphyrin rings of pheophytin, and RE chlorophyll a complexes are formed. MCD spectrum of La chlorophyll a shows the special bands in Soret band region, which indicated that La chlorophyll a are sandwich structure porphyrin complexes.
基金Supported by the Natural Science Foundation of Shandong Province(No.Y2006B43)
文摘The spin crossover（SCO） compound [Fe（bapbpy）（NCS）2],where bapbpy contains two fused N,N-bis（2-pyridyl）amines,has been studied by DFT/TD-DFT/BS-DFT methods.Several density functionals and basis sets were used in the calculation to obtain optimized geometries of the compound in the low-（LS） and high-spin（HS） states.The vibrational modes and IR spectra,spin splitting energies,excited states and UV/Vis absorption spectra were obtained.The structural parameters of the calculated isolated complex are in good agreement with the X-ray data.We investigate three dimers of [Fe（bapbpy）（NCS）2] complex for their magnetic properties.It has been found that the complex（1,3） has ferromagnetic character while the others are antiferromagnetic in nature by using a broken symmetry approach in the DFT framework（BS-DFT） with support from the coupling constant values（J） and spin density plots.
基金supported by the National Natural Science Foundation of China(Nos.11675231,91426304 and 11105191)the National Magnetic Confinement Fusion Program(No.2011GB108003)the National Basic Research Program of China(No.2010CB832904)
文摘Surface morphology, compositions, microstructure and optical properties of GaN film irradiated by highly charged Kr^(q+)(q = 23, 15, 11) in two geometries to a fluence of 1×10^(15)kr^(q+)/cm^2 were studied using AFM,XPS, PL, Raman scattering and UV–visible spectroscopy.The AFM observation shows that the irradiated GaN area is a swollen terrace. The swelling rate increased with the charge state(potential energy). For the same charge state,the swelling rate of tilted incidence was greater than that for normal incidence. The XPS measurements reveal that N deficiency, Ga enrichment and Ga–O and Ga dangling bonds generated on the irradiated GaN surface increased with the charge state, and more N was lost for normal incidence than that for tilted incidence. The UV–Vis results show that the transmittance decreased with increasing charge state. For the same charge state, the transmittance for tilted incidence is higher than that for normal incidence.The PL spectra present that, with increasing charge state,the YL band intensity decreased, with a blueshift in its peak position; while the NBE peak intensity increased firstand then reduced, and a blue luminescence band appeared.A rapid quenching of both the YL and the NEB for normal incidence was observed. Raman spectra display that screw dislocations perhaps were produced near the surface for normal incidence.
文摘A static optical pressure measurement system and the synthesis of Palladium tetraethyl tetramethyl porphyrin(PdTETMP) are investigated in this paper. UV visible spectrum, surface photovoltage spectrum of PdTETMP and oxygen quenching phosphorescence of PdTETMP are determined. The results indicate that the photovoltaic respons of PdTETMP decrease as the partial pressure of oxygen rises, which is similar to oxgyen quenching of the phosphorescence of PdTETMP. The data shows, as predicted by Stem Volmer relationship I 0/I=A+Bp/p 0, that a nearly linear relationship between I 0/I versus p/p 0 and the intercept A and slope B are 0.32, 0.67, respectively.
基金This work was supported by the National Natural Science Foundation of China (No. 20074027).
文摘A blue poly(azure B) film has been synthesized using repeated potential cycling between -0.25 and 1.10 V (versus SCE). The electrolytic solution consisted of 2.5 mmol dm(-3) azure B, 0.5 mol dm(-3) NaCl and 0.2 mol dm(-3) NaH2PO4 at the pH range of 2.0 to 11.0. The in situ visible spectrum during electrolysis of azure B shows that the intensity at 740 nm peak increases with increasing numbers of potential cycles, which is attributable to the formation of poly(azure B). The wavelength of its corresponding absorption peak is 98 nm longer than that of azure B. The polymerization rate is strongly affected by pH values. The anodic peak potential and cathodic peak potential of the poly(azure B) in a solution of pH 3.0 are not affected by increasing the scan rate from 25 to 600 mV s(-1). Poly(azure B) has good electrochemical reversibility and fast charge transfer characteristic in the pH range of 2.0 and 11.0. The conductivity of poly(azure B) is 1.5 x 10(-4) S cm(-1) According to the differences between FTIR spectra of poly(azure B) and azure B, an electrochemical polymerization mechanism of azure B is proposed in this paper.
