Manganese-substituted magnetite ferrofluids(FFs)Mnx Fe_(1-x)Fe_(2)O_(4)(x=0–0.8)were prepared in this work through a chemical coprecipitation reaction.The controlled growth of FF nanomaterials for antibacterial activ...Manganese-substituted magnetite ferrofluids(FFs)Mnx Fe_(1-x)Fe_(2)O_(4)(x=0–0.8)were prepared in this work through a chemical coprecipitation reaction.The controlled growth of FF nanomaterials for antibacterial activities is challenging,and therefore,very few reports are available on the topic.This research focuses on stabilizing aqueous FFs with the tetramethylammonium hydroxide surfactant to achieve high homogeneity.Morphological characterization reveals nanoparticles of 5–11 nm formed by the chemical reaction and nanocrystalline nature,as evident from structural investigations.Mn-substituted magnetic FFs are analyzed for their structural,functional,and antibacterial performance according to the Mn-substituent content.Optical studies show a high blue shift for Mn^(2+)-substituted Mnx Fe_(1-x)Fe_(2)O_(4)with the theoretical correlation of optical band gaps with the Mn content.The superparamagnetic nature of substituted FFs causes zero coercivity and remanence,which consequently influence the particle size,cation distribution,and spin canting.The structural and functional performance of the FFs is correlated with the antibacterial activity,finally demonstrating the highest inhibition zone formation for Mnx Fe_(1-x)Fe_(2)O_(4)FFs.展开更多
The present paper covers the unprecedented preparation of stable aqueous Dy-ferrite ferrofluids, whereby colloidal Dy δ Fe 3- δ O4 ultrafine particles were dispersed by using polymeric surfactant PMAA. The stabiliti...The present paper covers the unprecedented preparation of stable aqueous Dy-ferrite ferrofluids, whereby colloidal Dy δ Fe 3- δ O4 ultrafine particles were dispersed by using polymeric surfactant PMAA. The stabilities of the series of the ferrofluids were studied according to the stability indexes. The susceptibility measurements were made with a Farady-type magnetic balance at various temperatures and magnetic field intensities. In terms of Langevin function, the σ versus H/T curves showed that Dy-ferrite ferrofluids exhibited superparamagnetism behavior and the blocking temperatures were in the range from 160 to 200 K. Moreover, the ferrofluids were characterized by means of Infra-red spectroscopy, transmission electron microscopy, X-ray diffraction, and Mssbauer spectroscopy.展开更多
The regular distribution of micro-droplets splitting from thin ferrofluid layer is systematic experimentally investigated, as the layer is placed in a vertical magnetic field. In this work, the field is applied in an ...The regular distribution of micro-droplets splitting from thin ferrofluid layer is systematic experimentally investigated, as the layer is placed in a vertical magnetic field. In this work, the field is applied in an instant manner and a slow manner, respectively; the field strength is linear increased. With instantly raising the field, it is observed that the ferrofluid layer is split into several regularly distributed micro-droplets, and that the number of micro-droplets is linear to the magnetic field strength and the thickness of the liquid layers. When the field is slowly increased, a liquid ring together with several micro-droplets appears from the ferrofluid layer splitting. A spatial drift of the micro-droplets is also observed in the process of increasing the magnetic field. Our results are useful for manipulating the splitting regularities of ferrofluid layers by magnetic field, which may be used in non-contact segmentation, and magnetically manipulated drug carriers for targeting the therapy, etc.展开更多
Thermal overload relays are economic electromechanical protection devices which offers reliable protection for electric motors in the event of overload or phase failure. Presently there are two types of overload relay...Thermal overload relays are economic electromechanical protection devices which offers reliable protection for electric motors in the event of overload or phase failure. Presently there are two types of overload relays which depend on the temperature characteristics of metals to provide protection by tripping the circuit. These relays lack accuracy as they do not activate the trip circuit at any exact specified temperature. In this paper we introduce a new form of thermal over-load relay actuated by ferrofluid. The ferrofluid has a very accurate transition temperature known as curie temperature. It acts as a ferromagnetic material below the curie temperature and loses the property of ferromagnetism above this temperature. By using this property of the fluid we propose an alternative method for more accurate op-eration under overload condition. This relay finds application in the protection system of electrical machines. Thus, in this paper we present a novel and simple technique for protection against thermal overloading using ferrofluid.展开更多
The prime objective of the present study is to examine the effect of temperature dependent viscosity μ(T ) on the revolving axi-symmetric laminar boundary layer flow of an incompressible, electrically non-conducting ...The prime objective of the present study is to examine the effect of temperature dependent viscosity μ(T ) on the revolving axi-symmetric laminar boundary layer flow of an incompressible, electrically non-conducting ferrofluid in the presence of a stationary plate subjected to a magnetic field and maintained at a uniform temperature. To serve this purpose, the non-linear coupled partial differential equations are firstly converted into the ordinary differential equations using well-known similarity transformations. The popular finite difference method is employed to discretize the non-linear coupled differential equations. These discretized equations are then solved using the Newton method in MATLAB, for which an initial guess is made with the help of the Flex PDE Solver. Along with the velocity profiles, the effects of temperature dependent viscosity are also examined on the skin friction, the heat transfer, and the boundary layer displacement thickness. The obtained results are presented numerically as well as graphically.展开更多
Rheological properties are the theoretical basis and the key to common problems in ferrofluid applications,therefore they are expected to be adjustable to satisfy different technical requirements through altering the ...Rheological properties are the theoretical basis and the key to common problems in ferrofluid applications,therefore they are expected to be adjustable to satisfy different technical requirements through altering the microstructure of ferrofluid during the process of preparation.In this paper,Four ferrofluid samples with different magnetic particle size were prepared by controlling the concentration of precursor solution during co-precipitation process and the rheological properties of these samples were investigated.These samples exhibited field-controlled rheological properties.Eternal magnetic field would enhance the formation of microstructures,resulting in an increase of viscosity.While with the increase of shear rate,microstructures tended to be destroyed,causing viscosity to decrease.There were two opposing mechanisms of the influence of precursor solution concentration.On one hand,the reduction of the precursor solution concentration would produce primary magnetic particles of smaller size.But on the other hand,the surfactant became insufficient to completely coat the magnetic particles because of an increased specific surface area,causing the magnetic particles to aggregate and form secondary clustering structures which strongly enhanced the magnetoviscous effect and weakened the viscoelastic effect.展开更多
Some of the modern electronic and optoelectronic devices exploit ferrofluids contained in narrow gaps between two material plates. When the width of the gap becomes below a micrometer, the boundary plates are subjecte...Some of the modern electronic and optoelectronic devices exploit ferrofluids contained in narrow gaps between two material plates. When the width of the gap becomes below a micrometer, the boundary plates are subjected to the Casimir force arising from the zero-point and thermal fluctuations of the electromagnetic field. These forces should be taken into account in microdevices with the dimensions decreased to below a micrometer. In this paper, we review recently performed calculations of the attractive Casimir pressure in three-layer systems containing a ferrofluid. We also find the ferrofluidic system where the Casimir pressure is repulsive. This result is obtained in the framework of the fundamental Lifshitz theory of van der Waals and Casimir forces. The conclusion is made that enhanced repulsion due to the presence of a ferrofluid may prevent from sticking of closely spaced elements of a microdevice.展开更多
This study is to numerically test the interfacial instability of ferrofluid flow under the presence of a vacuum magnetic field.The ferrofluid parabolized stability equations(PSEs)are derived from the ferrofluid stabil...This study is to numerically test the interfacial instability of ferrofluid flow under the presence of a vacuum magnetic field.The ferrofluid parabolized stability equations(PSEs)are derived from the ferrofluid stability equations and the Rosensweig equations,and the characteristic values of the ferrofluid PSEs are given to describe the ellipticity of ferrofluid flow.Three numerical models representing specific cases considering with/without a vacuum magnetic field or viscosity are created to mathematically examine the interfacial instability by the computation of characteristic values.Numerical investigation shows strong dependence of the basic characteristic of ferrofluid Rayleigh-Taylor instability(RTI)on viscosity of ferrofluid and independence of the vacuum magnetic field.For the shock wave striking helium bubble,the magnetic field is not able to trigger the symmetry breaking of bubble but change the speed of the bubble movement.In the process of droplet formation from a submerged orifice,the collision between the droplet and the liquid surface causes symmetry breaking.Both the viscosity and the magnetic field exacerbate symmetry breaking.The computational results agree with the published experimental results.展开更多
Penetrative Bénard-Maranagoni convection in micropolar ferromagnetic fluid layer in the presence of a uniform vertical magnetic field has been investigated via internal heating model. The lower boundary is consid...Penetrative Bénard-Maranagoni convection in micropolar ferromagnetic fluid layer in the presence of a uniform vertical magnetic field has been investigated via internal heating model. The lower boundary is considered to be rigid at constant temperature, while the upper boundary free open to the atmosphere is flat and subject to a convective surface boundary condition. The resulting eigenvalue problem is solved numerically by Galerkin method. The stability of the system is found to be dependent on the dimensionless internal heat source strength Ns, magnetic parameter M1, the non-linearity of magnetization parameter M3, coupling parameter N1, spin diffusion parameter N3 and micropolar heat conduction parameter N5. The results show that the onset of ferroconvection is delayed with an increase in N1 and N5 but hastens the onset of ferroconvection with an increase in M1, M3, N3 and Ns. The dimension of ferroconvection cells increases when there is an increase in M3, N1, N5 and Ns and decrease in M1 and N3.展开更多
To analyze the thermal convection of ferrofluid along a flat plate is the persistence of this study. The two-dimensional laminar, steady, incompressible flow past a flat plate subject to convective surface boundary co...To analyze the thermal convection of ferrofluid along a flat plate is the persistence of this study. The two-dimensional laminar, steady, incompressible flow past a flat plate subject to convective surface boundary condition, slip velocity in the presence of radiation has been studied where the magnetic field is applied in the transverse direction to the plate. Two different kinds of magnetic nanoparticles, magnetite Fe3O4 and cobalt ferrite CoFe2O4 are amalgamated within the base fluids water and kerosene. The effects of various physical aspects such as magnetic field, volume fraction, radiation and slip conditions on the flow and heat transfer characteristics are presented graphically and discussed. The effect of various dimensionless parameters on the skin friction coefficient and heat transfer rate are also tabulated. To investigate this particular problem, numerical computations are done using the implicit finite difference method based Keller-Box Method.展开更多
Synthesis of functional iron oxide nanoparticles, well dispersed in aqueous fluids still remains a challenge as its stability requires a delicate balance between electrostatic and magnetic interactions. Templated synt...Synthesis of functional iron oxide nanoparticles, well dispersed in aqueous fluids still remains a challenge as its stability requires a delicate balance between electrostatic and magnetic interactions. Templated synthesis using biomolecules is useful because the biomolecules have their unique arrangement in aqueous systems that enhance stability, commonly called “biomimetic synthesis”. We have developed a one-pot in-situ, low energy process for the synthesis of highly monodispersed, Collagen Functionalized Ferrofluids (CFF) as a templating agent in an aqueous medium. The nanoparticles so obtained were characterized by X-ray diffraction (XRD), dynamic light scattering (DLS), Fourier transform infrared spectroscopy (FTIR). The antibacterial activity in terms of minimum inhibitory concentration (MIC), minimum bactericidal concentration (MBC) and growth inhibition has been assessed against gram positive, Staphylococcus aureus, ATCC 13709 (native strain) and in Escherichia coli, DH5α gram negative bacteria. The cytotoxicity of the CFFs on cancer cell lines human embryonic kidney (HEK), breast adenocarcinoma (MCF-7) and Ehrlich ascitic carcinoma (EAC) have also been investigated. CFFs indicated variable MIC and MBC values against S. aureus and E. coli being minimum for 1.5% CFF (MIC:23.43 μg/ml and 93.75 μg/ml and MBC: 46.87 μg/ml and 187.5 μg/ml). The observed cytotoxicity in mammalian cells indicated the susceptibility of MCF-7 breast cancer cells when compared to HEK cells.展开更多
A kind of ferrofluid containing Fe-Al oxide composite nanometer particles was synthesized. The ferrofluid made of Fe-Al oxide composite nanometer particles which ratio was Fe:Al2O3 = 3:1 and thermally treated at 300&#...A kind of ferrofluid containing Fe-Al oxide composite nanometer particles was synthesized. The ferrofluid made of Fe-Al oxide composite nanometer particles which ratio was Fe:Al2O3 = 3:1 and thermally treated at 300°C showed Faraday effect approximate linearity versus the magnetic field B, and a relatively excellent Faraday effect without saturation in varying 0 - 1.5T magnetic field, which provided a method for synthesizing the ferrofluid of Faraday rotation still continuing in a relatively high magnetic field.展开更多
We investigate the Taylor-Couette flow of a rotating ferrofluid under the influence of symmetry breaking transverse magnetic field in counter-rotating small-aspect-ratio setup. We find only changing the magnetic field...We investigate the Taylor-Couette flow of a rotating ferrofluid under the influence of symmetry breaking transverse magnetic field in counter-rotating small-aspect-ratio setup. We find only changing the magnetic field strength can drive the dynamics from time-periodic limit-cycle solution to time-independent steady fixed-point solution and vice versa. Thereby both solutions exist in symmetry related offering mode-two symmetry with left-or right-winding characteristics due to finite transverse magnetic field. Furthermore the time-periodic limit-cycle solutions offer alternately stroboscoping both helical left-and right-winding contributions of mode-two symmetry. The Navier-Stokes equations are solved with a second order time splitting method combined with spatial discretization of hybrid finite difference and Galerkin method.展开更多
Based on a lognormal particle size distribution, this paper makes a model analysis on the polydispersity effects on the magnetization behaviour of diluted ferrofluids. Using a modified Langevin relationship for the lo...Based on a lognormal particle size distribution, this paper makes a model analysis on the polydispersity effects on the magnetization behaviour of diluted ferrofluids. Using a modified Langevin relationship for the lognormal dis- persion, it first performs reduced calculations without material parameters. From the results, it is extrapolated that for the ferrofluid of lognormal polydispersion, in comparison with the corresponding monodispersion, the saturation magnetization is enhanced higher by the particle size distribution. It also indicates that in an equivalent magnetic field, the lognormally polydispersed ferrofluid is magnetically saturated faster than the corresponding monodispersion. Along the theoretical extrapolations, the polydispersity effects are evaluated for a typical ferrofluid of magnetite, with a dispersity of σ = 0.20. The results indicate that the lognormal polydispersity leads to a slight increase of the saturation magnetization, but a noticeable increase of the speed to reach the saturation value in an equivalent magnetic field.展开更多
Ferrofluid containing highly conductive polyaniline (PANI) was prepared, in which soluble PANI solutions doped with 10-camphorsulfonic acid (CSA) and dodecyl benzenesulfonic acid (DBSA) were used as the basic solution...Ferrofluid containing highly conductive polyaniline (PANI) was prepared, in which soluble PANI solutions doped with 10-camphorsulfonic acid (CSA) and dodecyl benzenesulfonic acid (DBSA) were used as the basic solution and Fe3O4 nanoparticles (d = 10 nm) as the magnetic material. Moreover, the freestanding films of the resulting ferrofluid can be obtained by an evaporation method. The electrical and magnetic properties of the ferrofiuid or its films can be adjusted through changing the content of PANI and Fe3O4. High saturated magnetization (≈ 30 emu/g) and high conductivity(≈ 250 S/cm) of the composite films can be achieved when the composite film contains 26.6 wt% of Fe3O. In particular, it was found that the composite films exhibit a super-paramagnetic behavior (Hc = 0) attributed to the size of Fe3O4 particles on the nanometer scale.展开更多
The phase transition between a massive dense phase and a diluted superparamagnetic phase has been studied by means of a direct molecular dynamics simulation. The equilibrium structures of the ferrofluid aggregate nucl...The phase transition between a massive dense phase and a diluted superparamagnetic phase has been studied by means of a direct molecular dynamics simulation. The equilibrium structures of the ferrofluid aggregate nucleus are obtained for different values of a temperature and an external magnetic field magnitude. An approximate match of experiment and simulation has been shown for the ferrofluid phase diagram coordinates "field–temperature". The provided phase coexistence curve has an opposite trend comparing to some of known theoretical results. This contradiction has been discussed. For given experimental parameters, it has been concluded that the present results describe more precisely the transition from linear chains to a dense globes phase. The theoretical concepts which provide the opposite binodal curve dependency trend match other experimental conditions: a diluted ferrofluid, a high particle coating rate, a high temperature,and/or a less particles coupling constant value.展开更多
We propose a novel optical intensity modulator based on the combination of a symmetrical metal cladding optical waveguide (SMCW) and ferrofluid, where the ferrofluid is sealed in the waveguide to act as a guiding laye...We propose a novel optical intensity modulator based on the combination of a symmetrical metal cladding optical waveguide (SMCW) and ferrofluid, where the ferrofluid is sealed in the waveguide to act as a guiding layer. The light matter interaction in the ferrofluid film leads to the formation of a regular nanoparticle pattern, which changes the phase match condition of the ultrahigh order modes in return. When two lasers are incident on the same spot of the waveguide chip, experiments illustrate all-optical modulation of one laser beam by adjusting the intensity of the other laser. A possible theoretical explanation may be due to the optical trapping and Soret effect since the phenomenon is considerable only when the control laser is effectively coupled into the waveguide.展开更多
This study deals with the stagnation point flow of ferrofluid over a flat plate with non-linear slip boundary condition in the presence of homogeneous-heterogeneous reactions.Three kinds of ferroparticles,namely,magne...This study deals with the stagnation point flow of ferrofluid over a flat plate with non-linear slip boundary condition in the presence of homogeneous-heterogeneous reactions.Three kinds of ferroparticles,namely,magnetite(Fe_3O_4),cobalt ferrite(CoFe_2O_4) and manganese zinc ferrite(Mn-ZnFe_2O_4) are taken into account with water and kerosene as conventional base fluids.The developed model of homogeneous-heterogeneous reactions in boundary layer flow with equal and unequal diffusivities for reactant and autocatalysis is considered.The governing partial differential equations are converted into system of non-linear ordinary differential equations by mean of similarity transformations.These ordinary differential equations are integrated numerically using shooting method.The effects of pertinent parameters on velocity and concentration profiles are presented graphically and discussed.We found that in the presence of Fe_3O_4-kerosene and CoFe_2O_4-kerosene,velocity profiles increase for large values of α and β whereas there is a decrement in concentration profiles with increasing values of if and K_s.Furthermore,the comparison between non-magnetic(A1_2O_3) and magnetic Fe_3O_4 nanoparticles is given in tabular form.展开更多
基金the financial assistance provided by the Indian Council of Medical Research in the form of a research associate (No.5/3/8/95/ITR F/2020)。
文摘Manganese-substituted magnetite ferrofluids(FFs)Mnx Fe_(1-x)Fe_(2)O_(4)(x=0–0.8)were prepared in this work through a chemical coprecipitation reaction.The controlled growth of FF nanomaterials for antibacterial activities is challenging,and therefore,very few reports are available on the topic.This research focuses on stabilizing aqueous FFs with the tetramethylammonium hydroxide surfactant to achieve high homogeneity.Morphological characterization reveals nanoparticles of 5–11 nm formed by the chemical reaction and nanocrystalline nature,as evident from structural investigations.Mn-substituted magnetic FFs are analyzed for their structural,functional,and antibacterial performance according to the Mn-substituent content.Optical studies show a high blue shift for Mn^(2+)-substituted Mnx Fe_(1-x)Fe_(2)O_(4)with the theoretical correlation of optical band gaps with the Mn content.The superparamagnetic nature of substituted FFs causes zero coercivity and remanence,which consequently influence the particle size,cation distribution,and spin canting.The structural and functional performance of the FFs is correlated with the antibacterial activity,finally demonstrating the highest inhibition zone formation for Mnx Fe_(1-x)Fe_(2)O_(4)FFs.
基金Supported by the National Natural Science Foundation of China(No.2 97730 14)
文摘The present paper covers the unprecedented preparation of stable aqueous Dy-ferrite ferrofluids, whereby colloidal Dy δ Fe 3- δ O4 ultrafine particles were dispersed by using polymeric surfactant PMAA. The stabilities of the series of the ferrofluids were studied according to the stability indexes. The susceptibility measurements were made with a Farady-type magnetic balance at various temperatures and magnetic field intensities. In terms of Langevin function, the σ versus H/T curves showed that Dy-ferrite ferrofluids exhibited superparamagnetism behavior and the blocking temperatures were in the range from 160 to 200 K. Moreover, the ferrofluids were characterized by means of Infra-red spectroscopy, transmission electron microscopy, X-ray diffraction, and Mssbauer spectroscopy.
基金Funded by the National Natural Science Foundation of China(No.51077006)
文摘The regular distribution of micro-droplets splitting from thin ferrofluid layer is systematic experimentally investigated, as the layer is placed in a vertical magnetic field. In this work, the field is applied in an instant manner and a slow manner, respectively; the field strength is linear increased. With instantly raising the field, it is observed that the ferrofluid layer is split into several regularly distributed micro-droplets, and that the number of micro-droplets is linear to the magnetic field strength and the thickness of the liquid layers. When the field is slowly increased, a liquid ring together with several micro-droplets appears from the ferrofluid layer splitting. A spatial drift of the micro-droplets is also observed in the process of increasing the magnetic field. Our results are useful for manipulating the splitting regularities of ferrofluid layers by magnetic field, which may be used in non-contact segmentation, and magnetically manipulated drug carriers for targeting the therapy, etc.
文摘Thermal overload relays are economic electromechanical protection devices which offers reliable protection for electric motors in the event of overload or phase failure. Presently there are two types of overload relays which depend on the temperature characteristics of metals to provide protection by tripping the circuit. These relays lack accuracy as they do not activate the trip circuit at any exact specified temperature. In this paper we introduce a new form of thermal over-load relay actuated by ferrofluid. The ferrofluid has a very accurate transition temperature known as curie temperature. It acts as a ferromagnetic material below the curie temperature and loses the property of ferromagnetism above this temperature. By using this property of the fluid we propose an alternative method for more accurate op-eration under overload condition. This relay finds application in the protection system of electrical machines. Thus, in this paper we present a novel and simple technique for protection against thermal overloading using ferrofluid.
文摘The prime objective of the present study is to examine the effect of temperature dependent viscosity μ(T ) on the revolving axi-symmetric laminar boundary layer flow of an incompressible, electrically non-conducting ferrofluid in the presence of a stationary plate subjected to a magnetic field and maintained at a uniform temperature. To serve this purpose, the non-linear coupled partial differential equations are firstly converted into the ordinary differential equations using well-known similarity transformations. The popular finite difference method is employed to discretize the non-linear coupled differential equations. These discretized equations are then solved using the Newton method in MATLAB, for which an initial guess is made with the help of the Flex PDE Solver. Along with the velocity profiles, the effects of temperature dependent viscosity are also examined on the skin friction, the heat transfer, and the boundary layer displacement thickness. The obtained results are presented numerically as well as graphically.
基金National Natural Science Foundation of China(Grant Nos.51927810,51735006,U1837206)Beijing Municipal Natural Science Foundation of China(Grant No.3182013).
文摘Rheological properties are the theoretical basis and the key to common problems in ferrofluid applications,therefore they are expected to be adjustable to satisfy different technical requirements through altering the microstructure of ferrofluid during the process of preparation.In this paper,Four ferrofluid samples with different magnetic particle size were prepared by controlling the concentration of precursor solution during co-precipitation process and the rheological properties of these samples were investigated.These samples exhibited field-controlled rheological properties.Eternal magnetic field would enhance the formation of microstructures,resulting in an increase of viscosity.While with the increase of shear rate,microstructures tended to be destroyed,causing viscosity to decrease.There were two opposing mechanisms of the influence of precursor solution concentration.On one hand,the reduction of the precursor solution concentration would produce primary magnetic particles of smaller size.But on the other hand,the surfactant became insufficient to completely coat the magnetic particles because of an increased specific surface area,causing the magnetic particles to aggregate and form secondary clustering structures which strongly enhanced the magnetoviscous effect and weakened the viscoelastic effect.
文摘Some of the modern electronic and optoelectronic devices exploit ferrofluids contained in narrow gaps between two material plates. When the width of the gap becomes below a micrometer, the boundary plates are subjected to the Casimir force arising from the zero-point and thermal fluctuations of the electromagnetic field. These forces should be taken into account in microdevices with the dimensions decreased to below a micrometer. In this paper, we review recently performed calculations of the attractive Casimir pressure in three-layer systems containing a ferrofluid. We also find the ferrofluidic system where the Casimir pressure is repulsive. This result is obtained in the framework of the fundamental Lifshitz theory of van der Waals and Casimir forces. The conclusion is made that enhanced repulsion due to the presence of a ferrofluid may prevent from sticking of closely spaced elements of a microdevice.
基金the National Natural Science Foundation of China(No.11971411)the Research Foundation of Education Bureau of Hunan Province of China(No.18A067)。
文摘This study is to numerically test the interfacial instability of ferrofluid flow under the presence of a vacuum magnetic field.The ferrofluid parabolized stability equations(PSEs)are derived from the ferrofluid stability equations and the Rosensweig equations,and the characteristic values of the ferrofluid PSEs are given to describe the ellipticity of ferrofluid flow.Three numerical models representing specific cases considering with/without a vacuum magnetic field or viscosity are created to mathematically examine the interfacial instability by the computation of characteristic values.Numerical investigation shows strong dependence of the basic characteristic of ferrofluid Rayleigh-Taylor instability(RTI)on viscosity of ferrofluid and independence of the vacuum magnetic field.For the shock wave striking helium bubble,the magnetic field is not able to trigger the symmetry breaking of bubble but change the speed of the bubble movement.In the process of droplet formation from a submerged orifice,the collision between the droplet and the liquid surface causes symmetry breaking.Both the viscosity and the magnetic field exacerbate symmetry breaking.The computational results agree with the published experimental results.
文摘Penetrative Bénard-Maranagoni convection in micropolar ferromagnetic fluid layer in the presence of a uniform vertical magnetic field has been investigated via internal heating model. The lower boundary is considered to be rigid at constant temperature, while the upper boundary free open to the atmosphere is flat and subject to a convective surface boundary condition. The resulting eigenvalue problem is solved numerically by Galerkin method. The stability of the system is found to be dependent on the dimensionless internal heat source strength Ns, magnetic parameter M1, the non-linearity of magnetization parameter M3, coupling parameter N1, spin diffusion parameter N3 and micropolar heat conduction parameter N5. The results show that the onset of ferroconvection is delayed with an increase in N1 and N5 but hastens the onset of ferroconvection with an increase in M1, M3, N3 and Ns. The dimension of ferroconvection cells increases when there is an increase in M3, N1, N5 and Ns and decrease in M1 and N3.
文摘To analyze the thermal convection of ferrofluid along a flat plate is the persistence of this study. The two-dimensional laminar, steady, incompressible flow past a flat plate subject to convective surface boundary condition, slip velocity in the presence of radiation has been studied where the magnetic field is applied in the transverse direction to the plate. Two different kinds of magnetic nanoparticles, magnetite Fe3O4 and cobalt ferrite CoFe2O4 are amalgamated within the base fluids water and kerosene. The effects of various physical aspects such as magnetic field, volume fraction, radiation and slip conditions on the flow and heat transfer characteristics are presented graphically and discussed. The effect of various dimensionless parameters on the skin friction coefficient and heat transfer rate are also tabulated. To investigate this particular problem, numerical computations are done using the implicit finite difference method based Keller-Box Method.
文摘Synthesis of functional iron oxide nanoparticles, well dispersed in aqueous fluids still remains a challenge as its stability requires a delicate balance between electrostatic and magnetic interactions. Templated synthesis using biomolecules is useful because the biomolecules have their unique arrangement in aqueous systems that enhance stability, commonly called “biomimetic synthesis”. We have developed a one-pot in-situ, low energy process for the synthesis of highly monodispersed, Collagen Functionalized Ferrofluids (CFF) as a templating agent in an aqueous medium. The nanoparticles so obtained were characterized by X-ray diffraction (XRD), dynamic light scattering (DLS), Fourier transform infrared spectroscopy (FTIR). The antibacterial activity in terms of minimum inhibitory concentration (MIC), minimum bactericidal concentration (MBC) and growth inhibition has been assessed against gram positive, Staphylococcus aureus, ATCC 13709 (native strain) and in Escherichia coli, DH5α gram negative bacteria. The cytotoxicity of the CFFs on cancer cell lines human embryonic kidney (HEK), breast adenocarcinoma (MCF-7) and Ehrlich ascitic carcinoma (EAC) have also been investigated. CFFs indicated variable MIC and MBC values against S. aureus and E. coli being minimum for 1.5% CFF (MIC:23.43 μg/ml and 93.75 μg/ml and MBC: 46.87 μg/ml and 187.5 μg/ml). The observed cytotoxicity in mammalian cells indicated the susceptibility of MCF-7 breast cancer cells when compared to HEK cells.
文摘A kind of ferrofluid containing Fe-Al oxide composite nanometer particles was synthesized. The ferrofluid made of Fe-Al oxide composite nanometer particles which ratio was Fe:Al2O3 = 3:1 and thermally treated at 300°C showed Faraday effect approximate linearity versus the magnetic field B, and a relatively excellent Faraday effect without saturation in varying 0 - 1.5T magnetic field, which provided a method for synthesizing the ferrofluid of Faraday rotation still continuing in a relatively high magnetic field.
文摘We investigate the Taylor-Couette flow of a rotating ferrofluid under the influence of symmetry breaking transverse magnetic field in counter-rotating small-aspect-ratio setup. We find only changing the magnetic field strength can drive the dynamics from time-periodic limit-cycle solution to time-independent steady fixed-point solution and vice versa. Thereby both solutions exist in symmetry related offering mode-two symmetry with left-or right-winding characteristics due to finite transverse magnetic field. Furthermore the time-periodic limit-cycle solutions offer alternately stroboscoping both helical left-and right-winding contributions of mode-two symmetry. The Navier-Stokes equations are solved with a second order time splitting method combined with spatial discretization of hybrid finite difference and Galerkin method.
基金Project supported by the Shanghai Leading Academic Discipline Project of China (Grant No. B107)
文摘Based on a lognormal particle size distribution, this paper makes a model analysis on the polydispersity effects on the magnetization behaviour of diluted ferrofluids. Using a modified Langevin relationship for the lognormal dis- persion, it first performs reduced calculations without material parameters. From the results, it is extrapolated that for the ferrofluid of lognormal polydispersion, in comparison with the corresponding monodispersion, the saturation magnetization is enhanced higher by the particle size distribution. It also indicates that in an equivalent magnetic field, the lognormally polydispersed ferrofluid is magnetically saturated faster than the corresponding monodispersion. Along the theoretical extrapolations, the polydispersity effects are evaluated for a typical ferrofluid of magnetite, with a dispersity of σ = 0.20. The results indicate that the lognormal polydispersity leads to a slight increase of the saturation magnetization, but a noticeable increase of the speed to reach the saturation value in an equivalent magnetic field.
基金This project was supported by 973 Program of China.
文摘Ferrofluid containing highly conductive polyaniline (PANI) was prepared, in which soluble PANI solutions doped with 10-camphorsulfonic acid (CSA) and dodecyl benzenesulfonic acid (DBSA) were used as the basic solution and Fe3O4 nanoparticles (d = 10 nm) as the magnetic material. Moreover, the freestanding films of the resulting ferrofluid can be obtained by an evaporation method. The electrical and magnetic properties of the ferrofiuid or its films can be adjusted through changing the content of PANI and Fe3O4. High saturated magnetization (≈ 30 emu/g) and high conductivity(≈ 250 S/cm) of the composite films can be achieved when the composite film contains 26.6 wt% of Fe3O. In particular, it was found that the composite films exhibit a super-paramagnetic behavior (Hc = 0) attributed to the size of Fe3O4 particles on the nanometer scale.
基金support with the graphical design of the "FFANS" web page
文摘The phase transition between a massive dense phase and a diluted superparamagnetic phase has been studied by means of a direct molecular dynamics simulation. The equilibrium structures of the ferrofluid aggregate nucleus are obtained for different values of a temperature and an external magnetic field magnitude. An approximate match of experiment and simulation has been shown for the ferrofluid phase diagram coordinates "field–temperature". The provided phase coexistence curve has an opposite trend comparing to some of known theoretical results. This contradiction has been discussed. For given experimental parameters, it has been concluded that the present results describe more precisely the transition from linear chains to a dense globes phase. The theoretical concepts which provide the opposite binodal curve dependency trend match other experimental conditions: a diluted ferrofluid, a high particle coating rate, a high temperature,and/or a less particles coupling constant value.
基金supported by the National Natural Science Foundation of China (Grant Nos. 11274091 and 11274092)the Fundamental Research Funds for the Central Universities of Hohai University, China (Grant No. 2011B11014)
文摘We propose a novel optical intensity modulator based on the combination of a symmetrical metal cladding optical waveguide (SMCW) and ferrofluid, where the ferrofluid is sealed in the waveguide to act as a guiding layer. The light matter interaction in the ferrofluid film leads to the formation of a regular nanoparticle pattern, which changes the phase match condition of the ultrahigh order modes in return. When two lasers are incident on the same spot of the waveguide chip, experiments illustrate all-optical modulation of one laser beam by adjusting the intensity of the other laser. A possible theoretical explanation may be due to the optical trapping and Soret effect since the phenomenon is considerable only when the control laser is effectively coupled into the waveguide.
文摘This study deals with the stagnation point flow of ferrofluid over a flat plate with non-linear slip boundary condition in the presence of homogeneous-heterogeneous reactions.Three kinds of ferroparticles,namely,magnetite(Fe_3O_4),cobalt ferrite(CoFe_2O_4) and manganese zinc ferrite(Mn-ZnFe_2O_4) are taken into account with water and kerosene as conventional base fluids.The developed model of homogeneous-heterogeneous reactions in boundary layer flow with equal and unequal diffusivities for reactant and autocatalysis is considered.The governing partial differential equations are converted into system of non-linear ordinary differential equations by mean of similarity transformations.These ordinary differential equations are integrated numerically using shooting method.The effects of pertinent parameters on velocity and concentration profiles are presented graphically and discussed.We found that in the presence of Fe_3O_4-kerosene and CoFe_2O_4-kerosene,velocity profiles increase for large values of α and β whereas there is a decrement in concentration profiles with increasing values of if and K_s.Furthermore,the comparison between non-magnetic(A1_2O_3) and magnetic Fe_3O_4 nanoparticles is given in tabular form.
