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Research on the Impact of New and Renewable Energy Replacing Fossil Energy Resource under Constraint of Carbon Emissions 被引量:3
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作者 Zhao Lixiang Yang Chuxiao 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2019年第4期58-67,共10页
For studying new and renewable energy as a substitute for fossil energy in primary energy consumption and its impact on carbon emissions to cope with economic uncertainties, a multi-sector DSGE model was employed to s... For studying new and renewable energy as a substitute for fossil energy in primary energy consumption and its impact on carbon emissions to cope with economic uncertainties, a multi-sector DSGE model was employed to simulate the dynamic impact on carbon emissions and macroeconomic development. The structural adjustment of energy consumption and the carbon emissions mitigation policy were considered in the model. The simulation results showed that using new and renewable energy instead of fossil energy is an optimal choice for the firms to comply with the regulations of carbon emission mitigation policy. Structural adjustment of energy consumption is the best route to achieve the dual goal of economic development and carbon emission reduction. Unexpected sharp fall in free carbon quota has a negative impact on the economy. 展开更多
关键词 new and renewable energy traditional fossil energy energy substitution carbon emission reduction
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Major biological events and fossil energy formation: On the development of energy science under the earth system framework 被引量:2
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作者 PAN Songqi ZOU Caineng +8 位作者 LI Yong JING Zhenhua LIU Entao YUAN Ming ZHANG Guosheng YANG Zhi WU Songtao QIU Zhen LIU Hanlin 《Petroleum Exploration and Development》 CSCD 2021年第3期581-594,共14页
In geological history, one major life explosion and five mass extinction events occurred. These major biological and environmental events affected the evolution of the Earth ecosystem and controlled the formation of o... In geological history, one major life explosion and five mass extinction events occurred. These major biological and environmental events affected the evolution of the Earth ecosystem and controlled the formation of organic-rich strata. The life explosion occurred in Cambrian and the five mass extinction events happened at the end of Ordovician, Late Devonian, end of Permian, end of Triassic, and end of Cretaceous, respectively. They are corresponded to the formation of multiple suites of organic-rich strata globally, which are crucial to the formation, evolution and distribution of the fossil energy on Earth. China’s energy is characterized by "unlimited new energy, rich in coal but insufficient in oil and gas ", and it is determined to rely on new energy sources to achieve " energy independence " and carbon neutrality. From the perspective of the Earth system evolution, we investigate the multiple relationships between energy and Earth, energy and environment, as well as energy and human beings, and carry out comprehensive research on energy. Energy science refers to the science of studying the various energy sources formation and distribution, evaluation and selection, production and utilization, orderly replacement, development prospects, etc. in temporal and spatial scales based on the evolution of the Earth system. The connotation of energy science includes three core contents:(1) The relationship between the Earth and energy, including the formation of energy in the Earth system and the feedback of energy consumption to the Earth’s climate and environment;(2) The relationship between the Earth environment and the human beings, including the Earth environment breeding human beings and human activities transforming the earth environment;(3) The relationship between the energy and the human beings, including the development of energy technology by human beings and the progress of human society driven by energy utilization. The energy science focuses on the formation and development of fossil energy, development and orderly replacement of new energy, exploration and utilization of energy in deep earth and deep space, and energy development strategy and planning. The proposal of energy science is of great significance for improving the discipline system, promoting energy development, clarifying the development direction of energy transition, driving the carbon neutral geology research and constructing a habitable Earth. 展开更多
关键词 life explosion mass extinction carbon neutral fossil energy new energy energy development strategy earth habitability energy science
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Development and prospects of degradable magnesium alloys for structural and functional applications in the fields of environment and energy
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作者 Yuanding Huang Yaping Zhang +4 位作者 Jiangfeng Song Fusheng Pan Regine Willumeit-Römer Karl Ulrich Kainer Norbert Hort 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2023年第11期3926-3947,共22页
Magnesium and its alloys have such advantages with lightweight, high specific strength, good damping, high castability and machinability,which make them an attractive choice for applications where weight reduction is ... Magnesium and its alloys have such advantages with lightweight, high specific strength, good damping, high castability and machinability,which make them an attractive choice for applications where weight reduction is important, such as in the aerospace and automotive industries.However, their practical applications are still limited because of their poor corrosion resistance, low high temperature strength and ambient formability. Based on such their property shortcomings, recently degradable magnesium alloys were developed for broadening their potential applications. Considering the degradable Mg alloys for medical applications were well reviewed, the present review put an emphasis on such degradable magnesium alloys for structural and functional applications, especially the applications in the environmental and energy fields. Their applications as fracture ball in fossil energy, sacrificial anode, washing ball, and as battery anodes, transient electronics, were summarized. The roles of alloying elements in magnesium and the design concept of such degradable magnesium alloys were discussed. The existing challenges for extending their future applications are explored. 展开更多
关键词 Magnesium alloys ALLOYING Structural applications Degradation Mechanical property Corrosion property fossil and hydrogen energy Fracture ball Battery anode Transient electronics Hydrogen energy
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Comparison of energy consumption and economic performance of organic and conventional soybean production——A case study from Jilin Province, China 被引量:1
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作者 ZHANG Li-wei Til Feike +2 位作者 Jirko Holst Christa Hoffmann Reiner Doluschitz 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2015年第8期1561-1572,共12页
Modern agriculture heavily depends on energy consumption, especially fossil energy, but intensive energy input increases the production cost for producers and results in environmental pollution.Organic agricultural pr... Modern agriculture heavily depends on energy consumption, especially fossil energy, but intensive energy input increases the production cost for producers and results in environmental pollution.Organic agricultural production is considered a more sustainable system, but there is lack of scientific research on the energy consumption between organic and conventional systems in China.The analysis and comparison of energy use between the two systems would help decision-makers to establish economic, effective and efficient agricultural production.Thus, the objectives of the present study are to analyze energy inputs, outputs, energy efficiency, and economic benefits between organic and conventional soybean(Glycine max(L.) Merrill) production.A total of 24 organic farmers and 24 conventional farmers in Jilin Province, China, were chosen for investigation in 2010 production year.Total energy input was 71.55 GJ ha–1 and total energy output was 96.18 GJ ha–1 in the organic system, resulting in an energy efficiency(output/input) of 1.34.Total energy input was 9.37 GJ ha–1 and total energy output was 113.4 GJ ha–1 in the conventional system, resulting in the energy efficiency of 12.1.The huge discrepancy in energy inputs and respective efficiencies lies in the several times higher nutrient inputs in the organic compared to the conventional production system.Finally, the production costs ha–1 were 33% higher, and the net income ha–1 25% lower in the organic compared to the conventional soybean production system.It is recommended to improve fertilizer management in organic production to improve its energetic and economic performance. 展开更多
关键词 energy consumption fossil energy economic benefit organic agriculture soybean production Jilin Province China
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Understanding inter-term fossil energy consumption pathways in China based on sustainable development goals
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作者 Xiaoxiao Zhou Fangyuan Xie +2 位作者 Hui Li Chenbin Zheng Xin Zhao 《Geoscience Frontiers》 SCIE CAS 2024年第3期272-283,共12页
Sustainable development goals(SDGs)and fossil energy are the core elements of almost all major challenges and opportunities for achieving social development.Particularly,energy sustainability has become one of the piv... Sustainable development goals(SDGs)and fossil energy are the core elements of almost all major challenges and opportunities for achieving social development.Particularly,energy sustainability has become one of the pivotal drivers of China’s economy.This study constructed a comprehensive evaluation index system for the provincial-level sustainable development of fossil energy in China covering three major dimensions(socio-economic,resource,and environmental).Moreover,a set of criteria for measuring the SDGs of fossil energy at the national level in China was developed.Based on the provincial panel data collected from 30 provinces from 2010 through 2019,a spatial econometric model was applied to empirically evaluate the effects of SDGs on fossil energy consumption.The results showed that the SDGs not only promote the reduction of fossil energy consumption with substantial negative spatial spillover effects,but also revealed differences between northern and southern China.To promote the early achievement of sustainable fossil energy development in China,the transformation and upgradation of fossil energy systems should be conducted early and inter-regional cooperation should be strengthened according to local conditions to jointly achieve the SDGs. 展开更多
关键词 Sustainable development goals fossil energy consumption Spatial Durbin model Spillover effects
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The path to carbon neutrality in China:A paradigm shift in fossil resource utilization 被引量:1
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作者 Yong Jin Shanying Hu +2 位作者 Zhenye Zhang Bing Zhu Dingrong Bai 《Resources Chemicals and Materials》 2022年第1期129-135,共7页
The Paris Agreement has set the goal of carbon neutrality to cope with global climate change.China has pledged to achieve carbon neutrality by 2060,which will strategically change everything in our society.As the main... The Paris Agreement has set the goal of carbon neutrality to cope with global climate change.China has pledged to achieve carbon neutrality by 2060,which will strategically change everything in our society.As the main source of carbon emissions,the consumption of fossil energy is the most profoundly affected by carbon neutrality.This work presents an analysis of how China can achieve its goal of carbon neutrality based on its status of fossil energy utilization.The significance of transforming fossils from energy to resource utilization in the future is addressed,while the development direction and key technologies are discussed. 展开更多
关键词 Carbon neutralization fossil energy Resource utilization Carbon dioxide Climate change
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Develop hydroenergy resources and protect earth environment
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作者 Lu Youmei 《Engineering Sciences》 EI 2009年第2期32-34,63,共4页
Energy is a driving force behind the progress of human civilization. Mainly depend on the current human society of non-renewable fossil energy sources, such as coal and oil, its increasing demand. Gradually reduce the... Energy is a driving force behind the progress of human civilization. Mainly depend on the current human society of non-renewable fossil energy sources, such as coal and oil, its increasing demand. Gradually reduce the reserves, the contradiction between supply and demand becoming increasingly prominent. With the process of human history has moved forward with the depletion of fossil energy will eventually be unable to sustainable use. The total hydropower resources are limited, but it is renewable, clean energy, its energy is infinite. Therefore, the full use of limited water resources and slow down the depletion of fossil energy process, is to improve and protect the earth’s ecology and environment, one of the most realistic measures. 展开更多
关键词 water resources fossil energy hydropower construction protect earth environment
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Whole petroleum system and ordered distribution pattern of conventional and unconventional oil and gas reservoirs 被引量:21
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作者 Cheng-Zao Jia Xiong-Qi Pang Yan Song 《Petroleum Science》 SCIE EI CAS CSCD 2023年第1期1-19,共19页
The classical source-to-trap petroleum system concept only considers the migration and accumulation of conventional oil and gas in traps driven dominantly by buoyance in a basin,although revised and improved,even some... The classical source-to-trap petroleum system concept only considers the migration and accumulation of conventional oil and gas in traps driven dominantly by buoyance in a basin,although revised and improved,even some new concepts as composite petroleum system,total petroleum system,total composite petroleum system,were proposed,but they do not account for the vast unconventional oil and gas reservoirs within the system,which is not formed and distributed in traps dominantly by buoyancedriven.Therefore,the petroleum system concept is no longer adequate in dealing with all the oil and gas accumulations in a basin where significant amount of the unconventional oil and gas resources are present in addition to the conventional oil and gas accumulations.This paper looked into and analyzed the distribution characteristics of conventional and unconventional oil/gas reservoirs and their differences and correlations in petroliferous basins in China and North America,and then proposed whole petroleum system(WPS)concept,the WPS is defined as a natural system that encompasses all the conventional and unconventional oil and gas,reservoirs and resources originated from organic matter in source rocks,the geological elements and processes involving the formation,evolution,and distribution of these oil and gas,reservoirs and resources.It is found in the WPS that there are three kinds of hydrocarbons dynamic fields,three kinds of original hydrocarbons,three kinds of reservoir rocks,and the coupling of these three essential elements lead to the basic ordered distribution model of shale oil/gas reservoirs contacting or interbeded with tight oil/gas reservoirs and separated conventional oil/gas reservoirs from source rocks upward,which is expressed as“S\T-C”.Abnormal conditions lead to other three special ordered distribution models:The first is that with shale oil/gas reservoirs separated from tight oil/gas reservoirs.The second is that with two direction ordered distributions from source upward and downward.The third is with lateral distribution from source outside. 展开更多
关键词 Conventional and unconventional oil and gas Petroleum system Whole petroleum system Hydrocarbon reservoirs ordered distribution model fossil energy
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Buoyance-driven hydrocarbon accumulation depth and its implication for unconventional resource prediction 被引量:25
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作者 Xiongqi Pang Chengzao Jia +6 位作者 Wenyang Wang Zhangxin Chen Maowen Li Fujie Jiang Tao Hu Ke Wang Yingxun Wang 《Geoscience Frontiers》 SCIE CAS CSCD 2021年第4期93-109,共17页
The discovery of unconventional hydrocarbon resources since the late 20th century changed geologists’understanding of hydrocarbon migration and accumulations and provides a solution to energy shortage.In 2016,unconve... The discovery of unconventional hydrocarbon resources since the late 20th century changed geologists’understanding of hydrocarbon migration and accumulations and provides a solution to energy shortage.In 2016,unconventional oil production in the USA accounted for 41%of the total oil production;and unconventional natural gas production in China accounted for 35%of total gas production,showing strong growth momentum of unconventional hydrocarbons explorations.Unconventional hydrocarbons generally coexist with conventional petroleum resources;they sometimes distribute in a separate system,not coexisting with a conventional system.Identification and prediction of unconventional resources and their potentials are prominent challenges for geologists.This study analyzed the results of 12,237 drilling wells in six representative petroliferous basins in China and studied the correlations and differences between conventional and unconventional hydrocarbons by comparing their geological features.Migration and accumulation of conventional hydrocarbon are caused dominantly by buoyance.Wepropose a concept of buoyance-driven hydrocarbon accumulation depth to describe the deepest hydrocarbon accumulation depth driven dominantly by buoyance;beyond this depth the buoyance becomes unimportant for hydrocarbon accumulation.We found that the buoyance-driven hydrocarbon accumulation depth in petroliferous basins controls the different oil/gas reservoirs distribution and resource potentials.Hydrocarbon migration and accumulations above this depth is dominated by buoyancy,forming conventional reservoirs in traps with high porosity and permeability,while hydrocarbon migration and accumulation below this depth is dominated by non-buoyancy forces(mainly refers to capillary force,hydrocarbon volumeexpansion force,etc.),forming unconventional reservoirs in tight layers.The buoyance-driven hydrocarbon accumulation depths in six basins in China range from 1200mto 4200 m,which become shallowerwith increasing geothermal gradient,decreasing particle size of sandstone reservoir layers,or an uplift in the whole petroliferous basin.The predicted unconventional resource potential belowthe buoyance-driven hydrocarbon accumulation depth in six basins in China is more than 15.71×10^(9) t oil equivalent,among them 4.71×10^(9) t reserves have been proved.Worldwide,94%of 52,926 oil and gas reservoirs in 1186 basins are conventional reservoirs and only 6%of them are unconventional reservoirs.These 94%conventional reservoirs show promising exploration prospects in the deep area below buoyance-driven hydrocarbon accumulation depth. 展开更多
关键词 Nature energy fossil energy Oil and gas resources Conventional hydrocarbon reservoirs Unconventional hydrocarbon reservoirs Buoyance-driven hydrocarbon accumulation DEPTH
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Recent developments in high-performance Nafion membranes for hydrogen fuel cells applications 被引量:1
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作者 Li-Yu Zhu Yu-Cheng Li +3 位作者 Jing Liu Jing He Lu-Ying Wang Jian-Du Lei 《Petroleum Science》 SCIE CAS CSCD 2022年第3期1371-1381,共11页
As a promising alternative to petroleum fossil energy,polymer electrolyte membrane fuel cell has drawn considerable attention due to its low pollution emission,high energy density,portability,and long operation times.... As a promising alternative to petroleum fossil energy,polymer electrolyte membrane fuel cell has drawn considerable attention due to its low pollution emission,high energy density,portability,and long operation times.Proton exchange membrane(PEM)like Nafion plays an essential role as the core of fuel cell.A good PEM must have satisfactory performance such as high proton conductivity,excellent mechanical strength,electrochemical stability,and suitable for making membrane electrode assemblies(MEA).However,performance degradation and high permeability remain the main shortcomings of Nafion.Therefore,the development of a new PEM with better performance in some special conditions is greatly desired.In this review,we aim to summarize the latest achievements in improving the Nafion performance that works well under elevated temperature or methanol-fueled systems.The methods described in this article can be divided into some categories,utilizing hydrophilic inorganic material,metal-organic frameworks,nanocomposites,and ionic liquids.In addition,the mechanism of proton conduction in Nafion membranes is discussed.These composite membranes exhibit some desirable characteristics,but the development is still at an early stage.In the future,revolutionary approaches are needed to accelerate the application of fuel cells and promote the renewal of energy structure. 展开更多
关键词 fossil energy Fuel cell Proton exchange membrane Proton conductivity Inorganic fillers
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The Role of Enthalpy of Reaction in the Process of Global Warming: What Can We Learn from Basic Thermodynamics*
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作者 Wolfram Vogelsberger 《Advances in Chemical Engineering and Science》 2021年第1期77-90,共14页
An increase of carbon dioxide content accompanied by an increase of the temperature is observed in the atmosphere during the last 200 years. This behaviour can be explained by examination of correlations between tree ... An increase of carbon dioxide content accompanied by an increase of the temperature is observed in the atmosphere during the last 200 years. This behaviour can be explained by examination of correlations between tree generally accepted data sets of the recent past, world population, carbon dioxide content in the atmosphere, and rise of global temperature as function of time. No return to climate situations from hundred thousand of years before present is necessary. The world climate is a dynamic equilibrium between all energy generating processes on earth, especially sun energy, and the radiation of energy into space. Since approx. 200 years the dynamic equilibrium is changed additionally by means of fossil energy carriers, whose depots were put on in passed geological epochs, a climatic disturbance was produced. It is shown that the consumption of energy per year by the mankind can warm up the atmosphere by about one degree. This quantity cannot be neglected in climatic calculations;therefore it is the cause of mankind made warming of the atmosphere. The qualitative analyses presented here have shown that the use of so-called renewable energy sources does not necessarily lead to the avoidance of global warming. It can be expected that some techniques will have no or even small effect. Especially the model calculations to the operation of wind turbines and its influence on the temperature of the atmosphere show that it is difficult to estimate their influence and cannot be foreknown. 展开更多
关键词 Reaction Enthalpy Global Temperature fossil energy Carriers Climatic Disturbance
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Employment of mud-pulse generator for improvement of efficiency of a wellbore producing in complex mining and geological conditions
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作者 Bibinur Akhymbayeva 《Petroleum Research》 EI 2024年第1期92-97,共6页
In this study,the employment of mud-pulse generators to improve the efficiency of wellbores under complex mining and geological conditions is examined.A systemic analysis is made of the primary theoretical basis of th... In this study,the employment of mud-pulse generators to improve the efficiency of wellbores under complex mining and geological conditions is examined.A systemic analysis is made of the primary theoretical basis of the study.The benefits of a mud-pulse generator(a high-impulse hydraulic hammer)for wellbore production are stated based on the presented theoretical basis.The results not only show the benefits of mud-pulse generator employment but also provide an analysis of methods that can be used to improve the high-impulse hydraulic hammer efficiency.The acquired results have a substantial practical value not only for specialists,who research,develop,and manage wellbore operations,but also for engineers,who improve the process and modernize existing wellbores,and other experts in the field of wellbore production. 展开更多
关键词 fossil energy sources High-pulse hydraulic hammer Wellbore production technology The efficiency of wellbore usage Hydro-impulse systems
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Stepwise multiple regression method of greenhouse gas emission modeling in the energy sector in Poland 被引量:4
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作者 Alicja Kolasa-Wiecek 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2015年第4期47-54,共8页
The energy sector in Poland is the source of 81% of greenhouse gas(GHG) emissions. Poland,among other European Union countries, occupies a leading position with regard to coal consumption. Polish energy sector activ... The energy sector in Poland is the source of 81% of greenhouse gas(GHG) emissions. Poland,among other European Union countries, occupies a leading position with regard to coal consumption. Polish energy sector actively participates in efforts to reduce GHG emissions to the atmosphere, through a gradual decrease of the share of coal in the fuel mix and development of renewable energy sources. All evidence which completes the knowledge about issues related to GHG emissions is a valuable source of information. The article presents the results of modeling of GHG emissions which are generated by the energy sector in Poland. For a better understanding of the quantitative relationship between total consumption of primary energy and greenhouse gas emission, multiple stepwise regression model was applied. The modeling results of CO2 emissions demonstrate a high relationship(0.97) with the hard coal consumption variable. Adjustment coefficient of the model to actual data is high and equal to 95%. The backward step regression model, in the case of CH4 emission, indicated the presence of hard coal(0.66), peat and fuel wood(0.34), solid waste fuels, as well as other sources(- 0.64) as the most important variables. The adjusted coefficient is suitable and equals R2= 0.90. For N2 O emission modeling the obtained coefficient of determination is low and equal to 43%. A significant variable influencing the amount of N2 O emission is the peat and wood fuel consumption. 展开更多
关键词 Greenhouse gases Burning of fossil fuels energy sector Backward stepwise regression modeling
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Carbon capture and storage in the USA:the role of US innovation leadership in climate-technology commercialization 被引量:2
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作者 Lee Beck 《Clean Energy》 EI 2020年第1期2-11,共10页
To limit global warming and mitigate climate change,the global economy needs to decarbonize and reduce emissions to net-zero by mid-century.The asymmetries of the global energy system necessitate the deployment of a s... To limit global warming and mitigate climate change,the global economy needs to decarbonize and reduce emissions to net-zero by mid-century.The asymmetries of the global energy system necessitate the deployment of a suite of decarbonization technologies and an all-of-the-above approach to deliver the steep CO_(2)-emissions reductions necessary.Carbon capture and storage(CCS)technologies that capture CO_(2) from industrial and power-plant point sources as well as the ambient air and store them underground are largely seen as needed to address both the flow of emissions being released and the stock of CO_(2) already in the atmosphere.Despite the pressing need to commercialize the technologies,their large-scale deployment has been slow.Initial deployment,however,could lead to near-term cost reduction and technology proliferation,and lowering of the overall system cost of decarbonization.As of November 2019,more than half of global large-scale CCS facilities are in the USA,thanks to a history of sustained government support for the technologies.Recently,the USA has seen a raft of new developments on the policy and project side signaling a reinvigorated push to commercialize the technology.Analysing these recent developments using a policy-priorities framework for CCS commercialization developed by the Global CCS Institute,the paper assesses the USA’s position to lead large-scale deployment of CCS technologies to commercialization.It concludes that the USA is in a prime position due to the political economic characteristics of its energy economy,resource wealth and innovation-driven manufacturing sector. 展开更多
关键词 carbon capture CCUS energy and environment energy system and policy fossil energy hydrogen and fuel cell
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Integrating the ISO 14034 standard as a platform for carbon capture and utilization technology performance evaluation 被引量:1
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作者 Tim Hansen Kevin McCabe +1 位作者 Bill Chatterton Michael Leitch 《Clean Energy》 EI 2021年第4期600-610,共11页
Independent testing and verification of emerging technologies are vital parts of the technology-commercialization process.With the rapid development of carbon capture and utilization(CCU)technologies,where existing st... Independent testing and verification of emerging technologies are vital parts of the technology-commercialization process.With the rapid development of carbon capture and utilization(CCU)technologies,where existing standards and certifications do not exist,independent verification approaches and guidelines can provide a means to obtain credible information for an emerging market.The ISO 14034:2016-Environmental Management:Environmental Technology Verification(ETV)standard can serve as a foundational platform to ensure the consistency,quality and credibility of data on CCU technology performance,enabling direct comparisons between technologies and reducing risk to decision-makers regarding potential investment,future deployment and ultimate impacts of CCU innovations.Applying the fundamental principles of ISO 14034 to the evaluation of nine finalist CCU technologies competing in the NRG COSIA Carbon XPRIZE ensured that data used to evaluate competitors was of high quality,consistent across technologies and met the information needs of the XPRIZE and competition judges responsible for selecting winners.The approaches outlined here,including verification parameters and verification tasks for both XPRIZE-specific technology evaluations and full CCU technology evaluation by an accredited entity in conformance with the ISO 14034 standard,provide insight into the potential benefits-methodological consistency,high-quality data,independent oversight,methodological flexibility and broad applicability-and limitations-technology readiness and applicability,verification and instrumentation costs and lack of specificity-of the approach in an application for the evaluation of emerging technologies.Further application of the ISO 14034 standard and principles,developed through a consensus approach that incorporates other developing guidelines,can drive consistency and credibility for technology-performance evaluations across the CCU sector,ultimately leading to reduced risk and improved market access for new innovations. 展开更多
关键词 carbon capture CCUS chemical engineering COAL energy and environment fossil energy
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Effect of additives on mercury partitioning in wet-limestone flue-gas desulfurization
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作者 Ida Masoomi Barna Heidel +1 位作者 Marc Oliver Schmid Gunter Scheffknecht 《Clean Energy》 EI 2020年第2期132-141,共10页
The wet-flue-gas desulfurization(FGD)process plays an important role in removing water-soluble flue-gas components such as sulphur dioxide(SO_(2))and oxidized mercury compounds.Under the reducing environment of the FG... The wet-flue-gas desulfurization(FGD)process plays an important role in removing water-soluble flue-gas components such as sulphur dioxide(SO_(2))and oxidized mercury compounds.Under the reducing environment of the FGD,there is the possibility of re-emission of the already absorbed mercury(Hg)to the gas phase,which may be diminished by the utilization of specific additives.In this study,the effect of two different additives on Hg re-emission from the aqueous phase and Hg partitioning in gypsum and filtrate of a lab-scale wet-limestone FGD is investigated.Furthermore,the behaviour of additives in the presence of different halides is studied.The studied additives are TMT 15■as a sulphidic precipitating agent,which forms non-soluble mercury compounds,and activated lignite(AL)as a carbon-based sorbent,which adsorbs Hg compounds from the aqueous phase.TMT 15■has no significant effect on SO_(2) absorption;on the other hand,addition of AL improves the SO_(2)-removal efficiency by up to 30%.Using both additives,Hg re-emission is suppressed in all the experimented cases except for AL in the absence of halides,in which Hg re-emission shows no change.Thus,the need to form nucleophilic oxidized mercury compounds in the slurry for the adsorption of oxidized mercury on AL can be concluded.Usage of both additives improves Hg retention in the slurry to different extents.It is shown that,for the additive-free slurries,the Hg-adsorption capacity of the solid fraction of the slurry is the limiting parameter.Moreover,the utilization of both additives results in a significant increase in the Hg concentration of solid fraction.The correlation between redox potential and partitioning of Hg in the slurry is presented by comparing the change in the redox potential of slurries when additives are used. 展开更多
关键词 fossil energy flue-gas cleaning flue-gas desulfurization MERCURY ADDITIVES
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