Accurate insight into the heat generation rate(HGR) of lithium-ion batteries(LIBs) is one of key issues for battery management systems to formulate thermal safety warning strategies in advance.For this reason,this pap...Accurate insight into the heat generation rate(HGR) of lithium-ion batteries(LIBs) is one of key issues for battery management systems to formulate thermal safety warning strategies in advance.For this reason,this paper proposes a novel physics-informed neural network(PINN) approach for HGR estimation of LIBs under various driving conditions.Specifically,a single particle model with thermodynamics(SPMT) is first constructed for extracting the critical physical knowledge related with battery HGR.Subsequently,the surface concentrations of positive and negative electrodes in battery SPMT model are integrated into the bidirectional long short-term memory(BiLSTM) networks as physical information.And combined with other feature variables,a novel PINN approach to achieve HGR estimation of LIBs with higher accuracy is constituted.Additionally,some critical hyperparameters of BiLSTM used in PINN approach are determined through Bayesian optimization algorithm(BOA) and the results of BOA-based BiLSTM are compared with other traditional BiLSTM/LSTM networks.Eventually,combined with the HGR data generated from the validated virtual battery,it is proved that the proposed approach can well predict the battery HGR under the dynamic stress test(DST) and worldwide light vehicles test procedure(WLTP),the mean absolute error under DST is 0.542 kW/m^(3),and the root mean square error under WLTP is1.428 kW/m^(3)at 25℃.Lastly,the investigation results of this paper also show a new perspective in the application of the PINN approach in battery HGR estimation.展开更多
Three polyamines(PAs)(spermidine(Spd),spermine(Spm),and putrescine(Put))were used as growth regulators to the marine macroalgae Gracilariopsis lemaneiformis and to female gametophyte and reproductive tissues(cystocarp...Three polyamines(PAs)(spermidine(Spd),spermine(Spm),and putrescine(Put))were used as growth regulators to the marine macroalgae Gracilariopsis lemaneiformis and to female gametophyte and reproductive tissues(cystocarps were constructed),which led to early maturation of cystocarps and spore release.Laboratory cultivation revealed that exogenous PA application accelerated the development of cystocarps,and the mean sporeling growth rate was 20%–50%/d during the initial week of cultivation.The spore count(SC),survival rate(SR),and germination rate(GR)of G.lemaneiformis showed different responses to PA(10-6 mol/L and 10-3 mol/L)treatments under different temperatures(18,26,and 34℃),light intensities(30,60,and 90μmol photons/(m^(2)·s)),salinities(25,30,and 35),and nutrient levels(25꞉2.5,50꞉5.0,and 75꞉7.5μmol/L NH4Cl꞉K2HPO4),and the optimal conditions were 26℃,light intensity of 60μmol/(m^(2)·s),salinity of 35,and nutrient level of 50꞉5.0μmol/L NH4Cl꞉K2HPO4.Under the optimum conditions,the SC per cystocarp increased by 82.38%,and the spore SR and GR increased by 33.07%and 46.44%,respectively.Each experiment lasted for 7 days,with the highest SC on Day 4 and plateauing on Day 7.The results indicate that PAs could promote the early maturation,spore release,survival,and germination of G.lemaneiformis under laboratory conditions.展开更多
The stress path characteristics of surrounding rock in the formation of gob were analyzed and the unloading was solved. Taking Chengchao Iron Mine as the engineering background, the model for analyzing the instability...The stress path characteristics of surrounding rock in the formation of gob were analyzed and the unloading was solved. Taking Chengchao Iron Mine as the engineering background, the model for analyzing the instability of deep gob was established based on the mechanism of stress relief in deep mining.The energy evolution law was analyzed by introducing the local energy release rate index(LERR), and the energy criterion of the instability of surrounding rock was established based on the cusp catastrophe theory. The results show that the evolution equation of the local energy release of the surrounding rock is a quartic function with one unknown and the release rate increases gradually during the mining process.The calculation results show that the gob is stable. The LERR per unit volume of the bottom structure is relatively smaller which means that the stability is better. The LERR distribution showed that there was main energy release in the horizontal direction and energy concentration in the vertical direction which meets the characteristics of deep mining. In summary, this model could effectively calculate the stability of surrounding rock in the formation of gob. The LERR could reflect the dynamic process of energy release,transfer and dissipation and that provided an important reference for the study of the stability of deep mined out area.展开更多
High temperature(HT)during grain filling is one of the most important environmental factors limiting maize yield and grain quality.Nitrogen(N)fertilizer is essential for maintaining normal plant growth and defense aga...High temperature(HT)during grain filling is one of the most important environmental factors limiting maize yield and grain quality.Nitrogen(N)fertilizer is essential for maintaining normal plant growth and defense against environmental stresses.The effects of three N rates and two temperature regimes on the grain yield and quality of fresh waxy maize were studied using the hybrids Suyunuo 5(SYN5)and Yunuo 7(YN7)as materials.N application rates were 1.5,4.5,and 7.5 g plant-1,representing low,moderate,and high N levels(LN,MN,and HN,respectively).Mean day/night temperatures during the grain filling of spring-and summer-sown plants were 27.6/21.0°C and 28.6/20.0°C for ambient temperature(AT)and 35/21.0°C and 35/20.0°C for HT,respectively.On average,HT reduced kernel number,weight,yield,and moisture content by 29.8%,17.9%,38.7%,and 3.3%,respectively.Kernel number,weight,yield,moisture,and starch contents were highest under MN among the three N rates under both temperature regimes.HT reduced grain starch content at all N levels.HT increased grain protein content,which gradually increased with N rate.Mean starch granule size under MN was larger(10.9μm)than that under LN and HN(both 10.4μm)at AT.However,the mean size of starch granules was higher under LN(11.7μm)and lower under MN(11.2μm)at HT.Iodine binding capacity(IBC)was lowest under MN and highest under HN among the three N levels under both temperature regimes.In general,IBC at all N rates was increased by HT.Peak viscosity(PV)was gradually reduced with increasing N rate at AT.In comparison with LN,PV was increased by MN and decreased by HN at HT.Retrogradation percentage gradually increased with N rate at AT,but was lowest under MN among the three N rates at HT.LN+AT and MN+HT produced grain with high pasting viscosity and low retrogradation tendency.MN application could alleviate the negative effects of HT on the grain yield and quality of fresh waxy maize.展开更多
Halloysite nanotubes were used as nanocontainers to hold corrosion inhibitors such as Ce^(3+)-Zr^(4+),2-mercaptobenzothiazole and 8-hydroxyquinoline in their lumen.An acid assisted etching of the nanotubes was carried...Halloysite nanotubes were used as nanocontainers to hold corrosion inhibitors such as Ce^(3+)-Zr^(4+),2-mercaptobenzothiazole and 8-hydroxyquinoline in their lumen.An acid assisted etching of the nanotubes was carried out with a view to increase the lumen diameter and thereby,increase the amount of loading of the corrosion inhibitor.The morphology of as-received and etched halloysite nanotubes was ob-served using TEM analysis.The loading of corrosion inhibitors was confirmed using SEM-EDS and BET analysis.Polymeric microcapsules were used as capping agents for the ends of the loaded HNTs following which,they were dispersed into a hybrid sol-gel silica matrix.Dip coating method was used to generate coatings on AZ91D substrates followed by heat treatment at 130℃ for 1 h.The release rate kinetics of corrosion inhibitors from as-received and etched nanotubes was investigated in buffer solutions of 3.5 wt%NaCl at different pH.The release mechanism of corrosion inhibitors from the HNT lumen was validated using various semi-empirical models.Coatings were also evaluated for their corrosion protection ability using electrochemical techniques after exposure to 3.5 wt%NaCl solution for 120 h.Coatings generated using Ce^(3+)-Zr^(4+)loaded into as-received halloysite nanotubes have shown more effective corrosion protection when compared to other corrosion inhibitors after 120 h exposure to the corrosive medium.展开更多
Indium tin oxide （ITO） films were prepared on polyester, Si and glass substrate with relatively high deposition rate of above 0.9 nm/s by DC reactive magnetron sputtering technique at the sputtering pressure of 0.06...Indium tin oxide （ITO） films were prepared on polyester, Si and glass substrate with relatively high deposition rate of above 0.9 nm/s by DC reactive magnetron sputtering technique at the sputtering pressure of 0.06 Pa system, respectively. The dependence of resistivity on deposition parameters, such as deposition rate, target-to-substrate distance （TSD）, oxygen flow rate and sputtering time （thickness）, has been investigated, together with the structural and the optical properties. It was revealed that all ITO films exhibited lattice expansion. The resistivity of ITO thin films shows significant substrate effect: much lower resistivity and broader process window have been reproducibly achieved for the deposition of ITO films onto polyester rather than those prepared on both Si and glass substrates. The films with resistivity of as low as 4.23 ?10-4 Ω.cm and average transmittance of -78% at wavelength of 400-700 nm have been achieved for the films on polyester at room temperature.展开更多
With economic development and rapid urbanization,increases in Gross Domestic Product and population in fastgrowing cities since the turn of the 21st Century have led to increases in energy consumption.Anthropogenic he...With economic development and rapid urbanization,increases in Gross Domestic Product and population in fastgrowing cities since the turn of the 21st Century have led to increases in energy consumption.Anthropogenic heat flux released to the near-surface atmosphere has led to changes in urban thermal environments and severe extreme temperature events.To investigate the effects of energy consumption on urban extreme temperature events,including extreme heat and cold events,a dynamic representation scheme of anthropogenic heat release(AHR)was implemented in the Advanced Research version of the Weather Research and Forecasting(WRF)model,and AHR data were developed based on energy consumption and population density in a case study of Beijing,China.Two simulations during 1999−2017 were then conducted using the developed WRF model with 3-km resolution with and without the AHR scheme.It was shown that the mean temperature increased with the increase in AHR,and more frequent extreme heat events were produced,with an annual increase of 0.02−0.19 days,as well as less frequent extreme cold events,with an annual decrease of 0.26−0.56 days,based on seven extreme temperature indices in the city center.AHR increased the sensible heat flux and led to surface energy budget changes,strengthening the dynamic processes in the atmospheric boundary layer that reduce AHR heating efficiency more in summer than in winter.In addition,it was concluded that suitable energy management might help to mitigate the impact of extreme temperature events in different seasons.展开更多
We simulated the impact of anthropogenic heat release(AHR) on the regional climate in three vast city agglomerations in China using the Weather Research and Forecasting model with nested high-resolution modeling. Base...We simulated the impact of anthropogenic heat release(AHR) on the regional climate in three vast city agglomerations in China using the Weather Research and Forecasting model with nested high-resolution modeling. Based on energy consumption and high-quality land use data, we designed two scenarios to represent no-AHR and current-AHR conditions. By comparing the results of the two numerical experiments, changes of surface air temperature and precipitation due to AHR were quantified and analyzed. We concluded that AHR increases the temperature in these urbanized areas by about 0.5℃– 1℃, and this increase is more pronounced in winter than in other seasons. The inclusion of AHR enhances the convergence of water vapor over urbanized areas. Together with the warming of the lower troposphere and the enhancement of ascending motions caused by AHR, the average convective available potential energy in urbanized areas is increased. Rainfall amounts in summer over urbanized areas are likely to increase and regional precipitation patterns to be altered to some extent.展开更多
In face of climate change catastrophes, understanding the thermal limits and optimal physiological thermal window food crop is of particular urgency. This research aims to evaluate: 1) how physiological performances o...In face of climate change catastrophes, understanding the thermal limits and optimal physiological thermal window food crop is of particular urgency. This research aims to evaluate: 1) how physiological performances of plant will change with increasing chronic and acute heat stress;2) if the examined parameters form a hierarchy in terms of thermal tolerance;and 3) the optimal thermal window and critical temperatures of the examined plants with response to chronic and acute heat stress. Six temperate vegetables were subjected to chronic and acute heat stress and a suite of physiological parameters were evaluated. Dose responses were observed in shoot fresh weight, photosynthetic gas exchange, photosynthetic oxygen evolution, electron transfer rate, photo- and non-photochemical quenching with significant drop in performance as early as 28°C for selected species. Conversely, ratio of variable to maximum fluorescence (F<sub>v</sub>/F<sub>m</sub>) was not affected by heat stress until 46°C in chronic heat stress. Examining the temperature at which a measured parameter’s performance dropped by 50% compared to control (LT<sub>50</sub>), a distinct hierarchy of the indices was observed for Canasta, recombinant inbred line 141, Lactuca serriola and Lactuca sativa (L. “Salinas”): shoot fresh weight, representing the highest integrated level of photosynthesis was the most sensitive to thermal stress (28°C - 30°C), followed by oxygen evolution (35°C - 45°C) while non-photochemical and photochemical quenching which is subcellular function of stress alleviation had a much higher capacity failure temperature (47°C - 60°C). It is expected that F<sub>v</sub>/F<sub>m</sub> ratio, a measurement of sub-cellular structural integrity, will approach that of non-photochemical and photochemical quenching, if not exceeding it. By examining the photosynthetic parameters via their hierarchy of biological organization, it can be inferred that plants like Arugula and recombinant inbred line 192 are already operating near their thermal limit and have less energetic investment into heat stress mediation whereas L. serriola prioritizes thermal tolerance at the expense of photosynthesis efficiency.展开更多
Considering the importance of the prediction of rock burst disasters, and in order to grasp the law of acoustic emission(AE) of coal samples in different dynamic destruction time, the SH-II AE monitoring system was ad...Considering the importance of the prediction of rock burst disasters, and in order to grasp the law of acoustic emission(AE) of coal samples in different dynamic destruction time, the SH-II AE monitoring system was adopted to monitor the failure process of coal samples. The study of the change rule of the AE numbers, energy, ‘b' value and spectrum in the micro crack propagation process of the coal samples shows that as dynamic damage time went by, AE presented high-energy counts and the accumulated counts increased during the compression phase. The AE energy and cumulative counts increased during the elastic stage. The AE blank area increased gradually and the blank lines were more and more obvious in the molding stage. The AE counts and energy showed a trend of decrease in the residual damage phase.AE ‘b' values gradually became sparse, and the large scale cracks percentage compared with micro cracks decreased and the degree of damage decreased. The AE frequency spectrum peak went from the residual damage phase to the molding phase, and finally it was nearly stable, besides the bandwidth of the main frequency is gradually narrowed. Also, the frequency peak changed from single peak frequency to bi-peak frequency and to the single peak frequency. Uniaxial compressive strength is more sensitive than the elastic modulus to dynamic damage time.展开更多
It’s necessary to forecast the shortest spontaneous combustion period for preventing and controlling the coal spontaneous combustion.During the experimental process,a calculating model of the SSCP is established on t...It’s necessary to forecast the shortest spontaneous combustion period for preventing and controlling the coal spontaneous combustion.During the experimental process,a calculating model of the SSCP is established on the basis of the oxidative heat release intensity and thermal capacity at different temperatures.According to the basic parameters of spontaneous combustion,heat of water evaporation and gas desorption,the SSCPs of different coals are further predicted.Finally,this study analyzed the relationships of the SSCP and the judging indexes of the self-ignite tendency.The result shows that the SSCP non-linearly increases with the decrease of dynamic oxygen adsorption and increase of activation energy.Compared with the practical fire situation of mine,this reliable method can meet the actual requirement of mine production.展开更多
In the framework of the finite element method (FEM), a predictionmethod for the heating rate and the skin friction on a body surface is presented byusing the energy and momentum conservation equations respectively. Me...In the framework of the finite element method (FEM), a predictionmethod for the heating rate and the skin friction on a body surface is presented byusing the energy and momentum conservation equations respectively. Meanwhile, abrief analysis is made of the role the weighted functions play in the present work.展开更多
The relation between the melting point of Portland cement raw meal and its heating rate have been studied. The raw meal was burnt at different heating rate ranging from 10-900℃/min by the following methods: (A) in el...The relation between the melting point of Portland cement raw meal and its heating rate have been studied. The raw meal was burnt at different heating rate ranging from 10-900℃/min by the following methods: (A) in electric resistance furnace; (B) in DTA-TG analyzer with infrared ray focused heating; (C) in high temperature microscope with electron stream heating.展开更多
Thermal manikin plays important roles in simulating thethermal state of human bodies to facilitate the evaluationof thermal comfort properties of various clothing assem-blies.Based on the heat balance principle and an...Thermal manikin plays important roles in simulating thethermal state of human bodies to facilitate the evaluationof thermal comfort properties of various clothing assem-blies.Based on the heat balance principle and analysis ofrelated factors,the heat production rate of manikin isrecommended as an efficient evaluation index.Whereas,its inside heat production which occurs as a result of theexistence of temperature difference between its insidepart and outside surface,should not be ignored.Through a series of theoretical analysis and calculations,a compensative equation is deduced in this paper.展开更多
Mesoporous silica cocoon materials(MSNCs) and MgO doped mesoporous silica cocoons(MgO-MSNCs) with the cocoon-like hierarchical morphology and different alkalinities were synthesized as carriers for acidic drugs. Indom...Mesoporous silica cocoon materials(MSNCs) and MgO doped mesoporous silica cocoons(MgO-MSNCs) with the cocoon-like hierarchical morphology and different alkalinities were synthesized as carriers for acidic drugs. Indomethacin(IMC) was selected as a model drug and loaded into carriers. All materials and the drug-loaded samples were characterized by nitrogen adsorption, FTIR spectroscopy, transmission electron microscopy(TEM), powder X-Ray diffraction(XRD) and differential scanning calorimetry(DSC). The effect of the Mg/Si molar ratio on the kinetics and equilibrium of IMC adsorption on MgO-MSNCs was thoroughly examined, and it was found that the increase in the Mg/Si molar ratio resulted in an increasing IMC adsorption rate due to the increased affinity between alkaline MgO-MSNCs and weak acid IMC. The adsorption kinetics fitted a pseudo second-order model well. The Freundlich isotherm showed a better fit, indicating that the coverage of IMC on the surface of MgO-MSNCs was heterogeneous. The maximum adsorption capacity of adsorbent was calculated by the Langmuir isotherm equation. The Temkin equation provided further support that the IMC adsorption on MgO-MSNCs was dominated by a chemisorption process. MgO-MSNCs also have the advantage of allowing an adjustment of the drug release rate of weak acid drug. The cytotoxicity assay indicated good biocompatibility of MgO-MSNCs. Our research on MgO-MSNCs carriers demonstrated their potential therapeutic benefit for safe and effective management of IMC adsorption and in vitro release.展开更多
Experimental investigations have been devoted to the study of scaling law of coarse-grained dissipation rate structure function for velocity and temperature fluctuation of non-isotropic and inhomogeneous turbulent flo...Experimental investigations have been devoted to the study of scaling law of coarse-grained dissipation rate structure function for velocity and temperature fluctuation of non-isotropic and inhomogeneous turbulent flows at moderate Reynolds number. Much attention has been paid to the case of turbulent boundary layer, which is typically the nonistropic and inhomogeneous trubulence because of the dynamically important existence of organized coherent structure burst process in the near wall region. Longitudinal velocity and temperature have been measured at different vertical positions in turbulent boundary layer over a heated and unheated flat plate in a wind tunnel using hot wire anemometer. The influence of non-isotropy and inhomogeneity and heating the wall on the scaling law of the dissipation rate structure function is studied because of the existence of organized coherent structure burst process in the near wall region. The scaling law of coarse-grained dissipation rate structure function is found to be independent of the mean velocity shear strain and the heating wall boundary condition. The scaling law of the dissipation rate structure function is verified to be in agreement with the hierarchical structure model that has been verified valid for isotropic and homogeneous turbulence.展开更多
In this paper,the fracture problem in non-principal directions of elasticity for a simple layer plate of linear-elastic orthotropic composite materials is studied.The formulae of transformation between characteristic ...In this paper,the fracture problem in non-principal directions of elasticity for a simple layer plate of linear-elastic orthotropic composite materials is studied.The formulae of transformation between characteristic roots,coefficients of elastic compliances in non-principal directions of elasticity and corresponding parameters in principal directions of elasticity are derived.Then,the computing formulae of strain energy release rate under skew-symmetric loading in terms of engineering parameters for principal directions of elasticity are obtained by substituting crack-tip stresses and displacements into the basic formula of the strain energy release rate.展开更多
An interface crack analysis is presented for further understanding the characteristics of the crack-tip field. The conditions under which the energy release rate components would exist are emphasized and the relations...An interface crack analysis is presented for further understanding the characteristics of the crack-tip field. The conditions under which the energy release rate components would exist are emphasized and the relations between energy release rate components and the stress intensity factors are given. Combining with the results of chasical plate theory analysis. a closed-form solution for stress intensity factors in terms of external loading as well as some geometric and material parameters for fairly general composite laminates is derived Then. an analytical solution for energy release rate components is deduced. In order to get energy release rate components under general loading condition. a mode mix parameter, Ω, must be determined separately. A methodology for determining Ω is discussed. Finally. several different kinds of laminates are examined and the results obtained could be used in engineering applications.展开更多
Comparative investigations were carried out of the effect of heat treatment regimes Jor steelGC-4（40CrMnSiMoVA）on its crack propagating rates,from corrosion fatigue,（da/dN）<sub>CF</sub>,or stress corro...Comparative investigations were carried out of the effect of heat treatment regimes Jor steelGC-4（40CrMnSiMoVA）on its crack propagating rates,from corrosion fatigue,（da/dN）<sub>CF</sub>,or stress corrosion cracking,（da/dt）<sub>SCC</sub>,in media with various constituentsand pH values.Both（da/dN）<sub>CF</sub> and（da/dt）<sub>SCC</sub> accelerate with the increase of yield stressof the steel,yet the former is far less than the later.In comparison with media,the（da/dt）<sub>SCC</sub> in distilled water is slightly greater than that in 3.5% NaCl solution,and the（da/dN）<sub>CF</sub> in distilled water is far less than that in 3.5% NaCl solution.With the pH valueincreasing in 3.5% NaCl solution,the（da/dN）<sub>CF</sub> lowers down and the（da/dt）<sub>SCC</sub> speedsup.An explanation was also proposed with concept of the cyclic hardening and softening atcrack tip,as well as the crack closure and occluded cell effect.展开更多
基金funded by the Artificial Intelligence Technology Project of Xi’an Science and Technology Bureau in China(No.21RGZN0014)。
文摘Accurate insight into the heat generation rate(HGR) of lithium-ion batteries(LIBs) is one of key issues for battery management systems to formulate thermal safety warning strategies in advance.For this reason,this paper proposes a novel physics-informed neural network(PINN) approach for HGR estimation of LIBs under various driving conditions.Specifically,a single particle model with thermodynamics(SPMT) is first constructed for extracting the critical physical knowledge related with battery HGR.Subsequently,the surface concentrations of positive and negative electrodes in battery SPMT model are integrated into the bidirectional long short-term memory(BiLSTM) networks as physical information.And combined with other feature variables,a novel PINN approach to achieve HGR estimation of LIBs with higher accuracy is constituted.Additionally,some critical hyperparameters of BiLSTM used in PINN approach are determined through Bayesian optimization algorithm(BOA) and the results of BOA-based BiLSTM are compared with other traditional BiLSTM/LSTM networks.Eventually,combined with the HGR data generated from the validated virtual battery,it is proved that the proposed approach can well predict the battery HGR under the dynamic stress test(DST) and worldwide light vehicles test procedure(WLTP),the mean absolute error under DST is 0.542 kW/m^(3),and the root mean square error under WLTP is1.428 kW/m^(3)at 25℃.Lastly,the investigation results of this paper also show a new perspective in the application of the PINN approach in battery HGR estimation.
基金Supported by the National Key R&D Program of China(No.2018YFD0901502)the Ningbo Key R&D Science and Technology Program(Nos.2019B10009,2021Z114)the Natural Science Foundation of Zhejiang Province(Nos.LY19C190003,LQ20C190002)。
文摘Three polyamines(PAs)(spermidine(Spd),spermine(Spm),and putrescine(Put))were used as growth regulators to the marine macroalgae Gracilariopsis lemaneiformis and to female gametophyte and reproductive tissues(cystocarps were constructed),which led to early maturation of cystocarps and spore release.Laboratory cultivation revealed that exogenous PA application accelerated the development of cystocarps,and the mean sporeling growth rate was 20%–50%/d during the initial week of cultivation.The spore count(SC),survival rate(SR),and germination rate(GR)of G.lemaneiformis showed different responses to PA(10-6 mol/L and 10-3 mol/L)treatments under different temperatures(18,26,and 34℃),light intensities(30,60,and 90μmol photons/(m^(2)·s)),salinities(25,30,and 35),and nutrient levels(25꞉2.5,50꞉5.0,and 75꞉7.5μmol/L NH4Cl꞉K2HPO4),and the optimal conditions were 26℃,light intensity of 60μmol/(m^(2)·s),salinity of 35,and nutrient level of 50꞉5.0μmol/L NH4Cl꞉K2HPO4.Under the optimum conditions,the SC per cystocarp increased by 82.38%,and the spore SR and GR increased by 33.07%and 46.44%,respectively.Each experiment lasted for 7 days,with the highest SC on Day 4 and plateauing on Day 7.The results indicate that PAs could promote the early maturation,spore release,survival,and germination of G.lemaneiformis under laboratory conditions.
基金provided by the National Natural Science Foundation of China(No.5137403)the Fundamental Research Funds for the Central Universities(No.FRF-TP-15-042A1)
文摘The stress path characteristics of surrounding rock in the formation of gob were analyzed and the unloading was solved. Taking Chengchao Iron Mine as the engineering background, the model for analyzing the instability of deep gob was established based on the mechanism of stress relief in deep mining.The energy evolution law was analyzed by introducing the local energy release rate index(LERR), and the energy criterion of the instability of surrounding rock was established based on the cusp catastrophe theory. The results show that the evolution equation of the local energy release of the surrounding rock is a quartic function with one unknown and the release rate increases gradually during the mining process.The calculation results show that the gob is stable. The LERR per unit volume of the bottom structure is relatively smaller which means that the stability is better. The LERR distribution showed that there was main energy release in the horizontal direction and energy concentration in the vertical direction which meets the characteristics of deep mining. In summary, this model could effectively calculate the stability of surrounding rock in the formation of gob. The LERR could reflect the dynamic process of energy release,transfer and dissipation and that provided an important reference for the study of the stability of deep mined out area.
基金supported by the National Key Research and Development Program of China(2016YFD0300109,2018YFD0200703)the National Natural Science Foundation of China(31771709)+2 种基金Jiangsu Agriculture Science and Technology Innovation Fund(CX[19]3056)the Priority Academic Program Development of Jiangsu Higher Education InstitutionsHigh-end Talent Support Program of Yangzhou University。
文摘High temperature(HT)during grain filling is one of the most important environmental factors limiting maize yield and grain quality.Nitrogen(N)fertilizer is essential for maintaining normal plant growth and defense against environmental stresses.The effects of three N rates and two temperature regimes on the grain yield and quality of fresh waxy maize were studied using the hybrids Suyunuo 5(SYN5)and Yunuo 7(YN7)as materials.N application rates were 1.5,4.5,and 7.5 g plant-1,representing low,moderate,and high N levels(LN,MN,and HN,respectively).Mean day/night temperatures during the grain filling of spring-and summer-sown plants were 27.6/21.0°C and 28.6/20.0°C for ambient temperature(AT)and 35/21.0°C and 35/20.0°C for HT,respectively.On average,HT reduced kernel number,weight,yield,and moisture content by 29.8%,17.9%,38.7%,and 3.3%,respectively.Kernel number,weight,yield,moisture,and starch contents were highest under MN among the three N rates under both temperature regimes.HT reduced grain starch content at all N levels.HT increased grain protein content,which gradually increased with N rate.Mean starch granule size under MN was larger(10.9μm)than that under LN and HN(both 10.4μm)at AT.However,the mean size of starch granules was higher under LN(11.7μm)and lower under MN(11.2μm)at HT.Iodine binding capacity(IBC)was lowest under MN and highest under HN among the three N levels under both temperature regimes.In general,IBC at all N rates was increased by HT.Peak viscosity(PV)was gradually reduced with increasing N rate at AT.In comparison with LN,PV was increased by MN and decreased by HN at HT.Retrogradation percentage gradually increased with N rate at AT,but was lowest under MN among the three N rates at HT.LN+AT and MN+HT produced grain with high pasting viscosity and low retrogradation tendency.MN application could alleviate the negative effects of HT on the grain yield and quality of fresh waxy maize.
文摘Halloysite nanotubes were used as nanocontainers to hold corrosion inhibitors such as Ce^(3+)-Zr^(4+),2-mercaptobenzothiazole and 8-hydroxyquinoline in their lumen.An acid assisted etching of the nanotubes was carried out with a view to increase the lumen diameter and thereby,increase the amount of loading of the corrosion inhibitor.The morphology of as-received and etched halloysite nanotubes was ob-served using TEM analysis.The loading of corrosion inhibitors was confirmed using SEM-EDS and BET analysis.Polymeric microcapsules were used as capping agents for the ends of the loaded HNTs following which,they were dispersed into a hybrid sol-gel silica matrix.Dip coating method was used to generate coatings on AZ91D substrates followed by heat treatment at 130℃ for 1 h.The release rate kinetics of corrosion inhibitors from as-received and etched nanotubes was investigated in buffer solutions of 3.5 wt%NaCl at different pH.The release mechanism of corrosion inhibitors from the HNT lumen was validated using various semi-empirical models.Coatings were also evaluated for their corrosion protection ability using electrochemical techniques after exposure to 3.5 wt%NaCl solution for 120 h.Coatings generated using Ce^(3+)-Zr^(4+)loaded into as-received halloysite nanotubes have shown more effective corrosion protection when compared to other corrosion inhibitors after 120 h exposure to the corrosive medium.
文摘Indium tin oxide （ITO） films were prepared on polyester, Si and glass substrate with relatively high deposition rate of above 0.9 nm/s by DC reactive magnetron sputtering technique at the sputtering pressure of 0.06 Pa system, respectively. The dependence of resistivity on deposition parameters, such as deposition rate, target-to-substrate distance （TSD）, oxygen flow rate and sputtering time （thickness）, has been investigated, together with the structural and the optical properties. It was revealed that all ITO films exhibited lattice expansion. The resistivity of ITO thin films shows significant substrate effect: much lower resistivity and broader process window have been reproducibly achieved for the deposition of ITO films onto polyester rather than those prepared on both Si and glass substrates. The films with resistivity of as low as 4.23 ?10-4 Ω.cm and average transmittance of -78% at wavelength of 400-700 nm have been achieved for the films on polyester at room temperature.
基金This work was supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDA23090102)the National Natural Science Foundation of China(Grant No.41830967)+2 种基金the Key Research Program of Frontier Sciences,Chinese Academy of Sciences(Grant No.QYZDY-SSW-DQC012)the National Key Research and Development Program of China(Grant Nos.2018YFC1506602 and 2020YFA0608203)We also thank the National Meteorological Information Center,China Meteorological Administration,for data support.
文摘With economic development and rapid urbanization,increases in Gross Domestic Product and population in fastgrowing cities since the turn of the 21st Century have led to increases in energy consumption.Anthropogenic heat flux released to the near-surface atmosphere has led to changes in urban thermal environments and severe extreme temperature events.To investigate the effects of energy consumption on urban extreme temperature events,including extreme heat and cold events,a dynamic representation scheme of anthropogenic heat release(AHR)was implemented in the Advanced Research version of the Weather Research and Forecasting(WRF)model,and AHR data were developed based on energy consumption and population density in a case study of Beijing,China.Two simulations during 1999−2017 were then conducted using the developed WRF model with 3-km resolution with and without the AHR scheme.It was shown that the mean temperature increased with the increase in AHR,and more frequent extreme heat events were produced,with an annual increase of 0.02−0.19 days,as well as less frequent extreme cold events,with an annual decrease of 0.26−0.56 days,based on seven extreme temperature indices in the city center.AHR increased the sensible heat flux and led to surface energy budget changes,strengthening the dynamic processes in the atmospheric boundary layer that reduce AHR heating efficiency more in summer than in winter.In addition,it was concluded that suitable energy management might help to mitigate the impact of extreme temperature events in different seasons.
基金supported by the Strategic Priority Research Program-Climate Change: Carbon Budget and Relevant Issues of the Chinese Academy of Sciences (Grant No. XDA05090000)the National Key Program for Developing Basic Sciences of China (Grant No. 2009CB421401)+1 种基金the Special Fund for Meteorological Scientific Research in Public Interest (Grant No. GYHY201106028)the Knowledge Innovation Program of the Chinese Academy of Sciences (Grant No. KZCX2-EW-202)
文摘We simulated the impact of anthropogenic heat release(AHR) on the regional climate in three vast city agglomerations in China using the Weather Research and Forecasting model with nested high-resolution modeling. Based on energy consumption and high-quality land use data, we designed two scenarios to represent no-AHR and current-AHR conditions. By comparing the results of the two numerical experiments, changes of surface air temperature and precipitation due to AHR were quantified and analyzed. We concluded that AHR increases the temperature in these urbanized areas by about 0.5℃– 1℃, and this increase is more pronounced in winter than in other seasons. The inclusion of AHR enhances the convergence of water vapor over urbanized areas. Together with the warming of the lower troposphere and the enhancement of ascending motions caused by AHR, the average convective available potential energy in urbanized areas is increased. Rainfall amounts in summer over urbanized areas are likely to increase and regional precipitation patterns to be altered to some extent.
文摘In face of climate change catastrophes, understanding the thermal limits and optimal physiological thermal window food crop is of particular urgency. This research aims to evaluate: 1) how physiological performances of plant will change with increasing chronic and acute heat stress;2) if the examined parameters form a hierarchy in terms of thermal tolerance;and 3) the optimal thermal window and critical temperatures of the examined plants with response to chronic and acute heat stress. Six temperate vegetables were subjected to chronic and acute heat stress and a suite of physiological parameters were evaluated. Dose responses were observed in shoot fresh weight, photosynthetic gas exchange, photosynthetic oxygen evolution, electron transfer rate, photo- and non-photochemical quenching with significant drop in performance as early as 28°C for selected species. Conversely, ratio of variable to maximum fluorescence (F<sub>v</sub>/F<sub>m</sub>) was not affected by heat stress until 46°C in chronic heat stress. Examining the temperature at which a measured parameter’s performance dropped by 50% compared to control (LT<sub>50</sub>), a distinct hierarchy of the indices was observed for Canasta, recombinant inbred line 141, Lactuca serriola and Lactuca sativa (L. “Salinas”): shoot fresh weight, representing the highest integrated level of photosynthesis was the most sensitive to thermal stress (28°C - 30°C), followed by oxygen evolution (35°C - 45°C) while non-photochemical and photochemical quenching which is subcellular function of stress alleviation had a much higher capacity failure temperature (47°C - 60°C). It is expected that F<sub>v</sub>/F<sub>m</sub> ratio, a measurement of sub-cellular structural integrity, will approach that of non-photochemical and photochemical quenching, if not exceeding it. By examining the photosynthetic parameters via their hierarchy of biological organization, it can be inferred that plants like Arugula and recombinant inbred line 192 are already operating near their thermal limit and have less energetic investment into heat stress mediation whereas L. serriola prioritizes thermal tolerance at the expense of photosynthesis efficiency.
基金This work was jointly supported by the National Key Basic Research and Development Project of China under Grant No.2004CB418304the National Natural Science Foundation of China under Grant Nos.40505016,40575030 and 40233031.
基金provided by the National Natural Science Foundation of China (No.51374097)the Science Foundation General Projects of Chinese Postgraduate (No.2014M561384)Key Project of Science and Technology Research of Department of Education in Heilongjiang Province (No.12541z009)
文摘Considering the importance of the prediction of rock burst disasters, and in order to grasp the law of acoustic emission(AE) of coal samples in different dynamic destruction time, the SH-II AE monitoring system was adopted to monitor the failure process of coal samples. The study of the change rule of the AE numbers, energy, ‘b' value and spectrum in the micro crack propagation process of the coal samples shows that as dynamic damage time went by, AE presented high-energy counts and the accumulated counts increased during the compression phase. The AE energy and cumulative counts increased during the elastic stage. The AE blank area increased gradually and the blank lines were more and more obvious in the molding stage. The AE counts and energy showed a trend of decrease in the residual damage phase.AE ‘b' values gradually became sparse, and the large scale cracks percentage compared with micro cracks decreased and the degree of damage decreased. The AE frequency spectrum peak went from the residual damage phase to the molding phase, and finally it was nearly stable, besides the bandwidth of the main frequency is gradually narrowed. Also, the frequency peak changed from single peak frequency to bi-peak frequency and to the single peak frequency. Uniaxial compressive strength is more sensitive than the elastic modulus to dynamic damage time.
基金supported by China National Science Foundation of China (Nos.51074158 and 51304189)the Youth Science and Research Fund of China University of Mining and Technology of China (No.2009A006)
文摘It’s necessary to forecast the shortest spontaneous combustion period for preventing and controlling the coal spontaneous combustion.During the experimental process,a calculating model of the SSCP is established on the basis of the oxidative heat release intensity and thermal capacity at different temperatures.According to the basic parameters of spontaneous combustion,heat of water evaporation and gas desorption,the SSCPs of different coals are further predicted.Finally,this study analyzed the relationships of the SSCP and the judging indexes of the self-ignite tendency.The result shows that the SSCP non-linearly increases with the decrease of dynamic oxygen adsorption and increase of activation energy.Compared with the practical fire situation of mine,this reliable method can meet the actual requirement of mine production.
基金The project supported by the National Natural Science Foundation of China (19889210)
文摘In the framework of the finite element method (FEM), a predictionmethod for the heating rate and the skin friction on a body surface is presented byusing the energy and momentum conservation equations respectively. Meanwhile, abrief analysis is made of the role the weighted functions play in the present work.
文摘The relation between the melting point of Portland cement raw meal and its heating rate have been studied. The raw meal was burnt at different heating rate ranging from 10-900℃/min by the following methods: (A) in electric resistance furnace; (B) in DTA-TG analyzer with infrared ray focused heating; (C) in high temperature microscope with electron stream heating.
文摘Thermal manikin plays important roles in simulating thethermal state of human bodies to facilitate the evaluationof thermal comfort properties of various clothing assem-blies.Based on the heat balance principle and analysis ofrelated factors,the heat production rate of manikin isrecommended as an efficient evaluation index.Whereas,its inside heat production which occurs as a result of theexistence of temperature difference between its insidepart and outside surface,should not be ignored.Through a series of theoretical analysis and calculations,a compensative equation is deduced in this paper.
基金supported by the National Basic Research Pro-gram of China(973 Program)(No.2015CB932100)National Natural Science Foundation of China(No.81473165)Liaoning Provincial Key Laboratory of Drug Preparation De-sign&Evaluation of Liaoning Provincial Education Depart-ment(No.LZ2015068)
文摘Mesoporous silica cocoon materials(MSNCs) and MgO doped mesoporous silica cocoons(MgO-MSNCs) with the cocoon-like hierarchical morphology and different alkalinities were synthesized as carriers for acidic drugs. Indomethacin(IMC) was selected as a model drug and loaded into carriers. All materials and the drug-loaded samples were characterized by nitrogen adsorption, FTIR spectroscopy, transmission electron microscopy(TEM), powder X-Ray diffraction(XRD) and differential scanning calorimetry(DSC). The effect of the Mg/Si molar ratio on the kinetics and equilibrium of IMC adsorption on MgO-MSNCs was thoroughly examined, and it was found that the increase in the Mg/Si molar ratio resulted in an increasing IMC adsorption rate due to the increased affinity between alkaline MgO-MSNCs and weak acid IMC. The adsorption kinetics fitted a pseudo second-order model well. The Freundlich isotherm showed a better fit, indicating that the coverage of IMC on the surface of MgO-MSNCs was heterogeneous. The maximum adsorption capacity of adsorbent was calculated by the Langmuir isotherm equation. The Temkin equation provided further support that the IMC adsorption on MgO-MSNCs was dominated by a chemisorption process. MgO-MSNCs also have the advantage of allowing an adjustment of the drug release rate of weak acid drug. The cytotoxicity assay indicated good biocompatibility of MgO-MSNCs. Our research on MgO-MSNCs carriers demonstrated their potential therapeutic benefit for safe and effective management of IMC adsorption and in vitro release.
基金Foundation items:the National Natural Science Foundation of China(10002011,19732005)the National Climbing Project(970211021)
文摘Experimental investigations have been devoted to the study of scaling law of coarse-grained dissipation rate structure function for velocity and temperature fluctuation of non-isotropic and inhomogeneous turbulent flows at moderate Reynolds number. Much attention has been paid to the case of turbulent boundary layer, which is typically the nonistropic and inhomogeneous trubulence because of the dynamically important existence of organized coherent structure burst process in the near wall region. Longitudinal velocity and temperature have been measured at different vertical positions in turbulent boundary layer over a heated and unheated flat plate in a wind tunnel using hot wire anemometer. The influence of non-isotropy and inhomogeneity and heating the wall on the scaling law of the dissipation rate structure function is studied because of the existence of organized coherent structure burst process in the near wall region. The scaling law of coarse-grained dissipation rate structure function is found to be independent of the mean velocity shear strain and the heating wall boundary condition. The scaling law of the dissipation rate structure function is verified to be in agreement with the hierarchical structure model that has been verified valid for isotropic and homogeneous turbulence.
文摘In this paper,the fracture problem in non-principal directions of elasticity for a simple layer plate of linear-elastic orthotropic composite materials is studied.The formulae of transformation between characteristic roots,coefficients of elastic compliances in non-principal directions of elasticity and corresponding parameters in principal directions of elasticity are derived.Then,the computing formulae of strain energy release rate under skew-symmetric loading in terms of engineering parameters for principal directions of elasticity are obtained by substituting crack-tip stresses and displacements into the basic formula of the strain energy release rate.
文摘An interface crack analysis is presented for further understanding the characteristics of the crack-tip field. The conditions under which the energy release rate components would exist are emphasized and the relations between energy release rate components and the stress intensity factors are given. Combining with the results of chasical plate theory analysis. a closed-form solution for stress intensity factors in terms of external loading as well as some geometric and material parameters for fairly general composite laminates is derived Then. an analytical solution for energy release rate components is deduced. In order to get energy release rate components under general loading condition. a mode mix parameter, Ω, must be determined separately. A methodology for determining Ω is discussed. Finally. several different kinds of laminates are examined and the results obtained could be used in engineering applications.
文摘Comparative investigations were carried out of the effect of heat treatment regimes Jor steelGC-4（40CrMnSiMoVA）on its crack propagating rates,from corrosion fatigue,（da/dN）<sub>CF</sub>,or stress corrosion cracking,（da/dt）<sub>SCC</sub>,in media with various constituentsand pH values.Both（da/dN）<sub>CF</sub> and（da/dt）<sub>SCC</sub> accelerate with the increase of yield stressof the steel,yet the former is far less than the later.In comparison with media,the（da/dt）<sub>SCC</sub> in distilled water is slightly greater than that in 3.5% NaCl solution,and the（da/dN）<sub>CF</sub> in distilled water is far less than that in 3.5% NaCl solution.With the pH valueincreasing in 3.5% NaCl solution,the（da/dN）<sub>CF</sub> lowers down and the（da/dt）<sub>SCC</sub> speedsup.An explanation was also proposed with concept of the cyclic hardening and softening atcrack tip,as well as the crack closure and occluded cell effect.
