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Enhanced magnetic anisotropy and high hole mobility in magnetic semiconductor Ga_(1-x-y)Fe_(x)Ni_(y)Sb
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作者 Zhi Deng Hailong Wang +5 位作者 Qiqi Wei Lei Liu Hongli Sun Dong Pan Dahai Wei Jianhua Zhao 《Journal of Semiconductors》 EI CAS CSCD 2024年第1期16-21,共6页
(Ga,Fe)Sb is a promising magnetic semiconductor(MS)for spintronic applications because its Curie temperature(T_(C))is above 300 K when the Fe concentration is higher than 20%.However,the anisotropy constant Ku of(Ga,F... (Ga,Fe)Sb is a promising magnetic semiconductor(MS)for spintronic applications because its Curie temperature(T_(C))is above 300 K when the Fe concentration is higher than 20%.However,the anisotropy constant Ku of(Ga,Fe)Sb is below 7.6×10^(3)erg/cm^(3)when Fe concentration is lower than 30%,which is one order of magnitude lower than that of(Ga,Mn)As.To address this issue,we grew Ga_(1-x-y)Fe_(x)Ni_(y)Sb films with almost the same x(≈24%)and different y to characterize their magnetic and electrical transport properties.We found that the magnetic anisotropy of Ga_(0.76-y)Fe_(0.24)Ni_(y)Sb can be enhanced by increasing y,in which Ku is negligible at y=1.7%but increases to 3.8×10^(5)erg/cm^(3)at y=6.1%(T_(C)=354 K).In addition,the hole mobility(μ)of Ga_(1-x-y)Fe_(x)Ni_(y)Sb reaches 31.3 cm^(2)/(V∙s)at x=23.7%,y=1.7%(T_(C)=319 K),which is much higher than the mobility of Ga_(1-x)Fe_(x)Sb at x=25.2%(μ=6.2 cm^(2)/(V∙s)).Our results provide useful information for enhancing the magnetic anisotropy and hole mobility of(Ga,Fe)Sb by using Ni co-doping. 展开更多
关键词 magnetic semiconductor molecular beam epitaxy Fe-Ni co-doping magnetic anisotropy hole mobility
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High threshold voltage enhancement-mode GaN p-FET with Sirich LPCVD SiN_(x) gate insulator for high hole mobility 被引量:1
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作者 Liyang Zhu Kuangli Chen +5 位作者 Ying Ma Yong Cai Chunhua Zhou Zhaoji Li Bo Zhang Qi Zhou 《Journal of Semiconductors》 EI CAS CSCD 2023年第8期78-86,共9页
In this work,the GaN p-MISFET with LPCVD-SiN_(x) is studied as a gate dielectric to improve device performance.By changing the Si/N stoichiometry of SiN_(x),it is found that the channel hole mobility can be effectivel... In this work,the GaN p-MISFET with LPCVD-SiN_(x) is studied as a gate dielectric to improve device performance.By changing the Si/N stoichiometry of SiN_(x),it is found that the channel hole mobility can be effectively enhanced with Si-rich SiN_(x) gate dielectric,which leads to a respectably improved drive current of GaN p-FET.The record high channel mobility of 19.4 cm2/(V∙s)was achieved in the device featuring an Enhancement-mode channel.Benefiting from the significantly improved channel mobility,the fabricated E-mode GaN p-MISFET is capable of delivering a decent-high current of 1.6 mA/mm,while simultaneously featuring a negative threshold-voltage(VTH)of–2.3 V(defining at a stringent criteria of 10μA/mm).The device also exhibits a well pinch-off at 0 V with low leakage current of 1 nA/mm.This suggests that a decent E-mode operation of the fabricated p-FET is obtained.In addition,the VTH shows excellent stability,while the threshold-voltage hysteresisΔVTH is as small as 0.1 V for a gate voltage swing up to–10 V,which is among the best results reported in the literature.The results indicate that optimizing the Si/N stoichiometry of LPCVD-SiN_(x) is a promising approach to improve the device performance of GaN p-MISFET. 展开更多
关键词 p-channel GaN p-FET LPCVD channel mobility hole mobility ENHANCEMENT-MODE
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Growth of Tellurium Nanobelts on h-BN for p-type Transistors with Ultrahigh Hole Mobility 被引量:2
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作者 Peng Yang Jiajia Zha +12 位作者 Guoyun Gao Long Zheng Haoxin Huang Yunpeng Xia Songcen Xu Tengfei Xiong Zhuomin Zhang Zhengbao Yang Ye Chen Dong-Keun Ki Juin J.Liou Wugang Liao Chaoliang Tan 《Nano-Micro Letters》 SCIE EI CAS CSCD 2022年第7期43-54,共12页
The lack of stable p-type van der Waals(vdW)semiconductors with high hole mobility severely impedes the step of low-dimensional materials entering the industrial circle.Although p-type black phosphorus(bP)and telluriu... The lack of stable p-type van der Waals(vdW)semiconductors with high hole mobility severely impedes the step of low-dimensional materials entering the industrial circle.Although p-type black phosphorus(bP)and tellurium(Te)have shown promising hole mobilities,the instability under ambient conditions of bP and relatively low hole mobility of Te remain as daunting issues.Here we report the growth of high-quality Te nanobelts on atomically flat hexagonal boron nitride(h-BN)for high-performance p-type field-effect transistors(FETs).Importantly,the Te-based FET exhibits an ultrahigh hole mobility up to 1370 cm^(2) V^(−1) s^(−1) at room temperature,that may lay the foundation for the future high-performance p-type 2D FET and metal-oxide-semiconductor(p-MOS)inverter.The vdW h-BN dielectric substrate not only provides an ultra-flat surface without dangling bonds for growth of high-quality Te nanobelts,but also reduces the scattering centers at the interface between the channel material and the dielectric layer,thus resulting in the ultrahigh hole mobility. 展开更多
关键词 Chemical vapor deposition Substrate engineering TELLURIUM Field-effect transistors hole mobility
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Enhanced photoresponsivity and hole mobility of MoTe_2 phototransistors by using an Al_2O_3 high-κ gate dielectric 被引量:5
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作者 Wenjie Chen Renrong Liang +2 位作者 Jing Wang Shuqin Zhang Jun Xu 《Science Bulletin》 SCIE EI CSCD 2018年第15期997-1005,共9页
Molybdenum ditelluride (MoTe2) has been demonstrated great potential in electronic and optoelectronic applications. However, the reported effective hole mobility remains far below its theoretical value. Herein, taki... Molybdenum ditelluride (MoTe2) has been demonstrated great potential in electronic and optoelectronic applications. However, the reported effective hole mobility remains far below its theoretical value. Herein, taking advantage of high-κ screening effect, we have fabricated back-gated MoTe2 transistors on an Al2O3 high-κ dielectric and systematically investigated the electronic and optoelectronic proper- ties. A high current on/off ratio exceeding 106 is achieved in the Al2O3-based MoTe2 transistors, and the hole mobility is demonstrated to be 150 cm2 V^-1 s^-1, compared to 0.2-20 cm^2 V^-1 s^-1 ever obtained from back-gated MoTe2 transistors in the literatures. Moreover, a considerable hole concentration of 1.2 × 10^13 cm 2 is attained in our Al2O3-based MoTe2 transistors owing to the strong gate control capa- bility, leading to a high on-state hole current of 6.1 μA μm^-1. After optimization, our Al2O3-based MoTe2 phototransistor exhibits outstanding photodetective performance, with a high responsivity of 543 AW^-1 and a high photogain of 1,662 at 405 nm light illumination, which are boosted around 419 times compared to the referential SiO2-based control devices. The mechanisms of photoconductivity in the Al2O3-based MoTe2 phototransistors have been analyzed in detail, and the photogating effect is considered to play an important role. This work may provide useful insight to improve carrier mobility in two-dimensional layered semiconductors and open opportunities to facilitate the development of high-performance photodetectors in the future. 展开更多
关键词 MoTe2 High-K dielectric PHOTOTRANSISTORS hole mobility PHOTODETECTORS
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Mn-doped SiGe thin films grown by UHV/CVD with room-temperature ferromagnetism and high hole mobility 被引量:2
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作者 Limeng Shen Xi Zhang +3 位作者 Jiaqi Wang Jianyuan Wang Cheng Li Gang Xiang 《Science China Materials》 SCIE EI CAS CSCD 2022年第10期2826-2832,共7页
In this work,silicon-germanium(SiGe)thin films are epitaxially grown on Ge substrates by ultra-high vacuum chemical vapor deposition and then doped with Mn element by ion-implantation and subsequent rapid thermal anne... In this work,silicon-germanium(SiGe)thin films are epitaxially grown on Ge substrates by ultra-high vacuum chemical vapor deposition and then doped with Mn element by ion-implantation and subsequent rapid thermal annealing(RTA).The characterizations show that the epitaxial SiGe thin films are single-crystalline with uniform tensile strain and then become polycrystalline after the ion implantation and following RTA.The magnetization measurements indicate that the annealed thin films exhibit Mn concentration-dependent ferromagnetism up to 309 K and the X-ray magnetic circular dichroism characterizations reveal the spin and orbital magnetic moments from the substitutional Mn element.To minimize the influence of anomalous Hall effect,magneto-transport measurements at a high magnetic field up to 31 T at 300 K are performed to obtain the hole mobility,which reaches a record-high value of~1230 cm^(2)V^(-1)s^(-1),owing to the crystalline quality and tensile strain-induced energy band modulation of the samples.The first demonstration of Mn-doped SiGe thin films with roomtemperature ferromagnetism and high carrier mobility may pave the way for practical semiconductor spintronic applications. 展开更多
关键词 diluted magnetic semiconductor Mn-doped SiGe FERROMAGNETISM hole mobility UHV/CVD
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Hole mobility enhancement in uniaxial stressed Ge dependence on stress and transport direction 被引量:1
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作者 MA JianLi FU ZhiFen +1 位作者 LIU Peng ZHANG HeMing 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2014年第10期1860-1865,共6页
Utilizing a six-band k.p valence band calculations that considered a strained perturbation Hamiltonian, uniaxial stress-induced valence band structure parameters for Ge such as band edge energy shift, split, and effec... Utilizing a six-band k.p valence band calculations that considered a strained perturbation Hamiltonian, uniaxial stress-induced valence band structure parameters for Ge such as band edge energy shift, split, and effective mass were quantitatively evaluated. Based on these valence band parameters, the dependence of hole mobility on uniaxial stress(direction, type, and magnitude) and hole transport direction was theoretical studied. The results show that the hole mobility had a strong dependence on the transport direction and uniaxial stress. The hole mobility enhancement can be found for all transport directions and uniaxial stess configurations, and the hole transport along the [110] direction under the uniaxial [110] compressive stress had the highest mobility compared to other transport directions and stress configurations. 展开更多
关键词 Ge uniaxial stress valence band structure hole mobility
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A physical model of hole mobility for germanium-on-insulator pMOSFETs 被引量:1
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作者 袁文宇 徐静平 +2 位作者 刘璐 黄勇 程智翔 《Journal of Semiconductors》 EI CAS CSCD 2016年第4期50-56,共7页
A physical model of hole mobility for germanium-on-insulator p MOSFETs is built by analyzing all kinds of scattering mechanisms, and a good agreement of the simulated results with the experimental data is achieved, co... A physical model of hole mobility for germanium-on-insulator p MOSFETs is built by analyzing all kinds of scattering mechanisms, and a good agreement of the simulated results with the experimental data is achieved, confirming the validity of this model. The scattering mechanisms involved in this model include acoustic phonon scattering, ionized impurity scattering, surface roughness scattering, coulomb scattering and the scattering caused by Ge film thickness fluctuation. The simulated results show that the coulomb scattering from the interface charges is responsible for the hole mobility degradation in the low-field regime and the surface roughness scattering limits the hole mobility in the high-field regime. In addition, the effects of some factors, e.g. temperature, doping concentration of the channel and the thickness of Ge film, on degradation of the mobility are also discussed using the model, thus obtaining a reasonable range of the relevant parameters. 展开更多
关键词 GeOI pMOSFETs hole mobility scattering mechanisms
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Impacts of additive uniaxial strain on hole mobility in bulk Si and strained-Si p-MOSFETs
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作者 赵硕 郭磊 +2 位作者 王敬 许军 刘志弘 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2009年第10期27-32,共6页
Hole mobility changes under uniaxial and combinational stress in different directions are characterized and analyzed by applying additive mechanical uniaxial stress to bulk Si and SiGe-virtual-substrate-induced strain... Hole mobility changes under uniaxial and combinational stress in different directions are characterized and analyzed by applying additive mechanical uniaxial stress to bulk Si and SiGe-virtual-substrate-induced strained- Si(s-Si)p-MOSFETs(metal-oxide-semiconductor field-effect transistors)along 110 and 100 channel directions. In bulk Si,a mobility enhancement peak is found under uniaxial compressive strain in the low vertical field.The combination of 100 direction uniaxial tensile strain and substrate-induced biaxial tensile strain provides a higher mobility relative to the 110 direction,opposite to the situation in bulk Si.But the combinational strain experiences a gain loss at high field,which means that uniaxial compressive strain may still be a better choice.The mobility enhancement of SiGe-induced strained p-MOSFETs along the 110 direction under additive uniaxial tension is explained by the competition between biaxial and shear stress. 展开更多
关键词 hole mobility enhancement additive uniaxial strain biaxial strain combinational strain channeldirection
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High Hole Mobility of GaSb Relaxed Epilayer Grown on GaAs Substrate by MOCVD through Interfacial Misfit Dislocations Array
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作者 Wei Zhou Xiang Li +3 位作者 Sujing Xia Jie Yang Wu Tang K.M.Lau 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2012年第2期132-136,共5页
The structural property of GaSb epilayers grown on semi-insulator GaAs (001) substrate by metalorganic chemical vapor deposition (MOCVD) using Triethylgallium (TEGa) and trimethylantimony (TMSb), was investiga... The structural property of GaSb epilayers grown on semi-insulator GaAs (001) substrate by metalorganic chemical vapor deposition (MOCVD) using Triethylgallium (TEGa) and trimethylantimony (TMSb), was investigated by variation of the Sb:Ga (V/Ill) ratio. An optimum V/Ill ratio of 1.4 was determined in our growth conditions. Using transmission electron microscopy (TEM), we found that there was an interracial misfit dislocations (IMF) growth mode in our experiment, in which the large misfit strain between epilayer and substrate is relaxed by periodic 90 deg. IMF array at the hetero-epitaxial interface. The rms roughness of a 300 nm-thick GaSb layer is only 2.7 nm in a 10μm×10μm scan from atomic force microscopy (AFM) result. The best hole density and mobility of 300 nm GaSb epilayer are 5.27xi06 cm-3(1.20×106) and 553 cm2-V-l.s-1 (2340) at RT (77 K) from Hall measurement, respectively. These results indicate that the IMF growth mode can be used in MOCVD epitaxial technology similar to molecular beam epitaxy (MBE) technology to produce the thinner GaSb layer with low density of dislocations and other defects on GaAs substrate for the application of devices. 展开更多
关键词 Interfacial misfit dislocations Metalorganic chemical vapour deposition Misfit dislocation hole mobility
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Hole mobility of strained Si/(001)Si_(1-x)Ge_x
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作者 WANG XiaoYan ZHANG HeMing +2 位作者 MA JianLi WANG GuanYu QU JiangTao 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2012年第1期48-54,共7页
The hole mobility of strained silicon along the <110> orientation on (001) Si1?xGex is obtained by solving collision term in the Boltzmann transport equation. The analytical model is proposed that considers the ... The hole mobility of strained silicon along the <110> orientation on (001) Si1?xGex is obtained by solving collision term in the Boltzmann transport equation. The analytical model is proposed that considers the effect of strain-induced splitting at valence band valleys in silicon, doping dependence and three scattering mechanisms, i.e., ionized impurity scattering, acoustic phonon scattering and non-polar optical phonon scattering. The hole occupancy at top band indicates a non-monotonic variation under biaxial tensile strain at low temperature (77 K). What's more, a non-monotonic variation of hole mobility at room temperature (300 K) is presented. Compared with the room temperature hole mobility, the low temperature hole mobility is affected greatly by ionized impurity scattering at lower impurity concentration. At the same time, the room temperature hole mobility is lower than that of electron with the same germanium content and doping concentration. If the parameters are correctly chosen, the model can also be used to calculate the hole mobility of other crystal faces with arbitrary orientation. So, it lays a useful foundation for strained silicon devices and circuits. 展开更多
关键词 subband hole occupancy scattering model germanium content hole mobility
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Group velocity matters for accurate prediction of phonon-limited carrier mobility
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作者 Qiao-Lin Yang Hui-Xiong Deng +1 位作者 Su-Huai Wei aJun-Wei Luo 《Chinese Physics B》 SCIE EI CAS CSCD 2021年第8期449-455,共7页
First-principles approaches have recently been developed to replace the phenomenological modeling approaches with adjustable parameters for calculating carrier mobilities in semiconductors.However,in addition to the h... First-principles approaches have recently been developed to replace the phenomenological modeling approaches with adjustable parameters for calculating carrier mobilities in semiconductors.However,in addition to the high computational cost,it is still a challenge to obtain accurate mobility for carriers with a complex band structure,e.g.,hole mobility in common semiconductors.Here,we present a computationally efficient approach using isotropic and parabolic bands to approximate the anisotropy valence bands for evaluating group velocities in the first-principles calculations.This treatment greatly reduces the computational cost in two ways:relieves the requirement of an extremely denseκmesh to obtain a smooth change in group velocity,and reduces the 5-dimensional integral to 3-dimensional integral.Taking Si and SiC as two examples,we find that this simplified approach reproduces the full first-principles calculation for mobility.If we use experimental effective masses to evaluate the group velocity,we can obtain hole mobility in excellent agreement with experimental data over a wide temperature range.These findings shed light on how to improve the first-principles calculations towards predictive carrier mobility in high accuracy. 展开更多
关键词 electron-phonon interaction phonon-limited hole mobility Boltzmann transport equation
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1D p-type molecular-based coordination polymer semiconductor with ultrahigh mobility
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作者 Chenhui Yu Xinxu Zhu +2 位作者 Kefeng Li Guan-E Wang Gang Xu 《Science Bulletin》 SCIE EI CAS CSCD 2024年第17期2705-2711,共7页
One-dimensional(1D)semiconductor nanostructures exhibit exceptional performance in mitigating short-channel effects and ensuring low power consumption.However,the scarcity of high-mobility ptype 1D materials impedes f... One-dimensional(1D)semiconductor nanostructures exhibit exceptional performance in mitigating short-channel effects and ensuring low power consumption.However,the scarcity of high-mobility ptype 1D materials impedes further advancement.Molecular-based materials offer high designability in structure and properties,making them a promising candidate for 1D p-type semiconductor materials.A molecular-based 1D p-type material was developed under the guidance of coordination chemistry.Cu-HT(HT is the abbreviation of p-hydroxy thiophenol)combines the merits of highly orbital overlap between Cu and S,fully covered surface modification with phenol functional groups,and unique cuprophilic(Cu-Cu)interactions.As such,Cu-HT has a remarkable hole mobility of 27.2 cm2V-1s-1,which is one of the highest reported values for 1D molecular-based materials to date and even surpass those of commonly used amorphous silicon as well as the majority of 1D inorganic materials.This achievement underscores the significant potential of coordination polymers in optimizing carrier transport and represents a major advancement in the synthesis of high-performance,1D p-type semiconductor materials.?2024 Science China Press.Published by Elsevier B.V.and Science China Press.All rights are reserved. 展开更多
关键词 Molecular-basedmaterials hole mobility COORDINATIONPOLYMER FIELD-EFFECTTRANSISTORS
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Hole-Transporting Materials with Rational Combination of Pyridine and Dibenzo[a,c]phenazine as Electron Acceptor for Dopant-Free Perovskite Solar Cells
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作者 Weidong Ling Fei Wu +3 位作者 Wentao Yuan Linna Zhu Qianqian Li Zhen Li 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2024年第10期1100-1106,共7页
Perovskite solar cells(PSCs)have been proven to be a promising option for photovoltaic conversion.With the aim to achieve efficient and stable PSCs,it is essential to explore dopant-free hole-transporting materials(HT... Perovskite solar cells(PSCs)have been proven to be a promising option for photovoltaic conversion.With the aim to achieve efficient and stable PSCs,it is essential to explore dopant-free hole-transporting materials(HTMs)with high hole mobility.Herein,HTMs bearing electron donor(D)-electron acceptor(A)-electron donor(D)structures have been constructed with strong intramolecular charge transfer(ICT)effect,based on rational combination of dibenzo[a,c]phenazine and pyridine as electronic acceptors and anchoring groups to perovskite layer.Accordingly,high hole mobility(7.31×10^(-5) cm^(2)·V^(-1)·s^(-1))and photoelectric conversion efficiency(20.45%)have been achieved by dopant-free DPyP-based PSC.It afforded an efficient way to design HTMs with high hole mobility by adjustment of molecular configurations and electronic property of conjugated systems. 展开更多
关键词 Perovskite solar cell Charge transfer Donor-acceptor systems Energy conversion hole mobility
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Comparative studies of Ge and Si p-channel metal-oxide-semiconductor field-effect-transistors with HfSiON dielectric and TaN metal gate 被引量:1
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作者 胡爱斌 徐秋霞 《Chinese Physics B》 SCIE EI CAS CSCD 2010年第5期524-529,共6页
Ge and Si p-channel metal-oxide-semiconductor field-effect-transistors (p-MOSFETs) with hafnium silicon oxynitride (HfSiON) gate dielectric and tantalum nitride (TAN) metal gate are fabricated. Self-isolated rin... Ge and Si p-channel metal-oxide-semiconductor field-effect-transistors (p-MOSFETs) with hafnium silicon oxynitride (HfSiON) gate dielectric and tantalum nitride (TAN) metal gate are fabricated. Self-isolated ring-type transistor structures with two masks are employed. W/TaN metal stacks are used as gate electrode and shadow masks of source/drain implantation separately. Capacitance-voltage curve hysteresis of Ge metal-oxide-semiconductor (MOS) capacitors may be caused by charge trapping centres in GeOx (1 〈 x 〈 2). Effective hole mobilities of Ge and Si transistors are extracted by using a channel conductance method. The peak hole mobilities of Si and Ge transistors are 33.4 cm2/(V.s) and 81.0 cm2/(V.s), respectively. Ge transistor has a hole mobility 2.4 times higher than that of Si control sample. 展开更多
关键词 Ge substrate TRANSISTOR HFSION hole mobility
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Unipolar p-type monolayer WSe_(2) field-effect transistors with high current density and low contact resistance enabled by van der Waals contacts
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作者 Miaomiao Li Xinyu Zhang +5 位作者 Zimei Zhang Gang Peng Zhihong Zhu Jia Li Shiqiao Qin Mengjian Zhu 《Nano Research》 SCIE EI CSCD 2024年第11期10162-10169,共8页
High-performance field-effect transistors (FETs) based on atomically thin two-dimensional (2D) semiconductors have demonstrated great promise in post-Moore integrated circuits. However, unipolar p-type 2D semiconducto... High-performance field-effect transistors (FETs) based on atomically thin two-dimensional (2D) semiconductors have demonstrated great promise in post-Moore integrated circuits. However, unipolar p-type 2D semiconductor transistors yet remain challenging and suffer from low saturation current density (less than 10 µA·µm^(−1)) and high contact resistance (larger than 100 kΩ·µm), mainly limited by the Schottky barrier induced by the mismatch of the work-functions and the Fermi level pinning at the metal contact interfaces. Here, we overcome these two obstacles through van der Waals (vdW) integration of high work-function metal palladium (Pd) as the contacts onto monolayer WSe2 grown by chemical vapor deposition (CVD) method. We demonstrate unipolar p-type monolayer WSe2 FETs with superior device performance: room temperature on-state current density exceeding 100 µA·µm^(−1), contact resistance of 12 kΩ·µm, on/off ratio over 107, and field-effect hole mobility of ~ 103 cm2·V^(−1)·s^(−1). Electrical transport measurements reveal that the Fermi level pinning effect is completely effectively eliminated in monolayer WSe2 with vdW Pd contacts, leading to a Schottky barrier-free Ohmic contact at the metal-semiconductor junctions. Combining the advantages of large-scale vdW contact strategy and CVD growth, our results pave the way for wafer-scale fabrication of complementary-metal-oxide-semiconductor (CMOS) logic circuits based on atomically thin 2D semiconductors. 展开更多
关键词 two-dimensional(2D)field-effect transistors(FETs) monolayer WSe2 van der Waals(vdW)contact on-state current hole mobility
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Impact of 〈100〉Channel Direction for High Mobility p-MOSFETs on Biaxial Strained Silicon
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作者 顾玮莹 梁仁荣 +1 位作者 张侃 许军 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2008年第10期1893-1897,共5页
Biaxial strain technology is a promising way to improve the mobility of both electrons and holes, while (100) channel direction appears as to be an effective booster of hole mobility in particular. In this work, the... Biaxial strain technology is a promising way to improve the mobility of both electrons and holes, while (100) channel direction appears as to be an effective booster of hole mobility in particular. In this work, the impact of biaxial strain together with (100) channel orientation on hole mobility is explored. The biaxial strain was incorporated by the growth of a relaxed SiGe buffer layer,serving as the template for depositing a Si layer in a state of biaxial tensile strain. The channel orientation was implemented with a 45^o rotated design in the device layout,which changed the channel direction from (110) to (100) on Si (001) surface. The maximum hole mobility is enhanced by 30% due to the change of channel direction from (110) to (100) on the same strained Si (s-Si) p-MOSFETs,in addition to the mobility enhancement of 130% when comparing s-Si pMOS to bulk Si pMOS both along (110) channels. Discussion and analysis are presented about the origin of the mobility enhancement by channel orientation along with biaxial strain in this work. 展开更多
关键词 P-MOSFET strained Si channel direction hole mobility enhancement
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Efficiency enhancement of fluorescent blue organic light-emitting diodes using doped hole transport and emissive layers
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作者 Nam Ho Kim You-Hyun Kim +4 位作者 Ju-An Yoon Seung Ⅱ Yoo Kok Wai Cheah Furong Zhu Woo Young Kim 《Chinese Optics Letters》 SCIE EI CAS CSCD 2016年第4期86-90,共5页
The electroluminescent characteristics of blue organic light-emitting diodes (BOLEDs) fabricated with doped charge carrier transport layers are analyzed. The fluorescent blue dopant BCzVBi is doped in an emissive la... The electroluminescent characteristics of blue organic light-emitting diodes (BOLEDs) fabricated with doped charge carrier transport layers are analyzed. The fluorescent blue dopant BCzVBi is doped in an emissive layer, hole transport layer (HTL) and electron transport layer (ETL), respectively, to optimize the probability of ex- citon generation in the BOLEDs. The luminance and luminous efficiency of BOLEDs made with BCzVBi-doped HTL and ETL increase by 22% and 17% from 11,683 cd/m2 at 8.5 V and 6.08 cd/A at 4.0 V to 14,264 cd/m2 at 8.5 V and 7.13 cd/A at 4.0 V while CIE coordinates of (0.15, 0.15) of both types of BOLEDs remained unchanged. The electron mobility of BCzVBi is estimated to be 1.02 × 10-5 cm2/Vs by TOF. 展开更多
关键词 Carrier transport Doping (additives) Efficiency Electron transport properties Fluorescence hole mobility Light emission Light emitting diodes
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D^(6h)Symmetric Radical Donor-Acceptor Nanographene Modulated Interfacial Carrier Transfer for High-Performance Perovskite Solar Cells
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作者 Can Wang Yifeng Gao +10 位作者 Zhen-Lin Qiu Ping-Ping Sun Naoyuki Shibayama Zilong Zhang Qiu Xiong Fangbin Ren Shui-Yang Lien Lusheng Liang Jiaoxia Zhang Yuan-Zhi Tan Peng Gao 《CCS Chemistry》 CSCD 2023年第9期2159-2170,共12页
Imbalanced charge-carrier extraction remains an issue aggravating interfacial charge accumulation and recombination.More hopping transport channels could accelerate the extraction of charge.Here,we demonstrated an eff... Imbalanced charge-carrier extraction remains an issue aggravating interfacial charge accumulation and recombination.More hopping transport channels could accelerate the extraction of charge.Here,we demonstrated an effective“bridging interface”strategy between the perovskite/2,2′,7,7′-tetrakis(N,N-di-pmethoxyphenylamine)-9,9′-spirobifluorene(spiro-OMeTAD)that modulates interfacial charge transfer and improves hole mobility using radical-containing donor-acceptor nanographenes(D-A NGs)possessing electron-deficient perchlorinated NGs and electron-rich aniline derivatives.The fully delocalized backbone of nanographene formed a conjugated bridge for intermolecular charge transfer and generated stable radical cations,verified by electron spin resonance.Lamellar andπ-πstacking orientation of D-A NGs also provided advantageous hopping transport channels.Besides favorable charge transfer within D-A NGs,systematic explorations indicated a strong interface coupling and noticeable charge transfer across the D-A NGs and perovskite interface,where electrons would flow from D-A NGs to perovskite,and holes would flow from perovskite to D-A NGs.Moreover,the hole mobility of spiro-OMeTAD was also enhanced because the D-A NGs would diffuse into the spiro-OMeTAD layer.As a result,planar n-i-p perovskite solar cellsmodified byD-ANG-OMe/D-ANG-tBudeliveredchampion power conversion efficiencies(PCEs)of 23.25%and 23.51%,respectively. 展开更多
关键词 perovskite solar cell RADICALS donor-acceptor nanographene hole mobility interfacial charge transfer
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Electrodeposited transparent PEDOT for inverted perovskite solar cells:improved charge transport and catalytic performances 被引量:3
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作者 Cong-Tan Zhu Ying Yang +4 位作者 Fei-Yu Lin Yuan Luo Shu-Peng Ma Liu Zhu Xue-Yi Guo 《Rare Metals》 SCIE EI CAS CSCD 2021年第9期2402-2414,共13页
The acidic, corrosive effect of sodium polystyrene sulfonate(PSS) in poly 3,4-ethylenedioxythiophene:sodium polystyrene sulfonate(PEDOT:PSS) limits the stability of inverted perovskite solar cells(PSCs) based on the I... The acidic, corrosive effect of sodium polystyrene sulfonate(PSS) in poly 3,4-ethylenedioxythiophene:sodium polystyrene sulfonate(PEDOT:PSS) limits the stability of inverted perovskite solar cells(PSCs) based on the ITO/PEDOT:PSS/perovskite/PCBM/BCP/Ag structure. In this work, a poly 3,4-ethylenedioxythiophene(PEDOT) hole transport layer(HTL) with high hole mobility and good catalytic performance was prepared by electrochemical cyclic voltammetry(CV) method for inverted PSCs. By controlling the CV cycles(from 1 to 5 cycles) and EDOT monomer solution concentration(from0.5 to 2.0 mmol·L^(-1)) of electrochemical deposition, the thickness, morphology, optical and electrochemical properties of PEDOT could be accurately adjusted. The optimal photovoltaic performance with current density(J_(sc)) of 22.19 mA·cm^(-2), open circuit voltage(V_(oc)) of 0.94 V, fill factor(FF) of 0.65 and photoelectric conversion efficiency of 13.56% was obtained when deposition of PEDOT with 1 CV cycle and EDOT concentration of 0.5 mmol·L^(-1). At this point, the perovskite showed good crystallization,optimal optical, charge transport and recombination performance, resulting in better V_(oc)and photoelectric conversion efficiency(PCE) compared to the devices with higher CV cycle numbers and 3,4-ethylenedioxythiophene(EDOT) concentration. For comparison with spin-coated PEDOT:PSS, the device with electrodeposited PEDOT showed improved J_(sc)and comparable V_(oc), which may result from its better charge transport and catalytic ability.The device with spin-coated PEDOT:PSS showed photoelectric conversion efficiency of 12.25%, which was lower than that based on electrodeposited PEDOT(13.56%) with1 CV cycles and 0.5 mmol·L^(-1) EDOT concentration. And the device with electrodeposited PEDOT as HTLs showed more excellent air stability. In ambient air((32 ± 5) ℃ and RH: 70% ± 20%), it still maintained more than 80%of the initial photoelectric conversion efficiency after1000 h. In comparison, the photoelectric conversion efficiency of the device with PEDOT:PSS decreased to 20% of the initial value after storage for 500 h. From this study, a facial and low-cost way to prepare PEDOT HTL with high performances that better than the traditional PEDOT:PSS has been explored, which is expected to eliminate the acidic, corrosive effect of PSS in PEDOT:PSS. 展开更多
关键词 Electrochemically cyclic voltammetry Inverted perovskite solar cells Electrodeposited PEDOT hole mobility Tafel analysis
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Stoichiometric effect on electrical and near-infrared photodetection properties of full-composition-range GaAs1−xSbx nanowires 被引量:1
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作者 Jiamin Sun Mingming Han +15 位作者 Meng Peng Lei Zhang Dong Liu Chengcheng Miao Jiafu Ye Zhiyong Pang Longbing He Hailu Wang Qing Li Peng Wang Lin Wang Xiaoshuang Chen Chongxin Shan Litao Sun Weida Hu Zai-xing Yang 《Nano Research》 SCIE EI CSCD 2021年第11期3961-3968,共8页
As one of the most important narrow bandgap ternary semiconductors, GaAs1−xSbx nanowires (NWs) have attracted extensive attention recently, due to the superior hole mobility and the tunable bandgap, which covers the w... As one of the most important narrow bandgap ternary semiconductors, GaAs1−xSbx nanowires (NWs) have attracted extensive attention recently, due to the superior hole mobility and the tunable bandgap, which covers the whole near-infrared (NIR) region, for technological applications in next-generation high-performance electronics and NIR photodetection. However, it is still a challenge to the synthesis of high-quality GaAs1−xSbx NWs across the entire range of composition, resulting in the lack of correlation investigation among stoichiometry, microstructure, electronics, and NIR photodetection. Here, we demonstrate the success growth of high-quality GaAs1−xSbx NWs with full composition range by adopting a simple and low-cost surfactant-assisted solid source chemical vapor deposition method. All of the as-prepared NWs are uniform, smooth, and straight, without any phase segregation in all stoichiometric compositions. The lattice constants of each NW composition have been well correlated with the chemical stoichiometry and confirmed by high-resolution transmission electron microscopy, X-ray diffraction, and Raman spectrum. Moreover, with the increase of Sb concentration, the hole mobility of the as-fabricated field-effect-transistors and the responsivity and detectivity of the as-fabricated NIR photodetectors increase accordingly. All the results suggest a careful stoichiometric design is required for achieving optimal NW device performances. 展开更多
关键词 GaAs1−xSbx nanowire stoichiometry effect full-composition-range field-effect hole mobility near-infrared photodetection
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