Efficient third-order nonlinearities of the Zinc Oxide and Al-doped Zinc Oxide were studied by Third Harmonic Generation (Third Harmonic Generation) Maker fringes to establish the effect Aluminum of Aluminum doping (A...Efficient third-order nonlinearities of the Zinc Oxide and Al-doped Zinc Oxide were studied by Third Harmonic Generation (Third Harmonic Generation) Maker fringes to establish the effect Aluminum of Aluminum doping (Al-doping) on the cubic nonlinearities. Adding the Al-dopant to the Zinc Oxide crystal structure results in changes that affect the optical and nonlinear characteristics. Presented results indicate that the magnitude of X<sup>(3)</sup> was enhanced at single experimental wavelengths;however, across the broadband experimental spectrum, the effect of Al-doping remained relatively constant. The observed enhancement of third-order nonlinearity was purely from the bound electronic response. The observation is attributed to increased charge carriers and spontaneous polarization in the Zinc Oxide and Al-doped Zinc Oxide crystal structure.展开更多
With the pulsed laser deposition （PLD） method, amorphous 80GeS2-15Ga2S3-5CdS chalcogenide film was deposited on glassy substrate. Obvious second harmonic generation （SHG） was observed in the ultraviolet （UV）-pol...With the pulsed laser deposition （PLD） method, amorphous 80GeS2-15Ga2S3-5CdS chalcogenide film was deposited on glassy substrate. Obvious second harmonic generation （SHG） was observed in the ultraviolet （UV）-polarized film and the SHG intensity increased with the increase in single pulse energy and irradiation time. Through Raman spectra and transmission spectra, the mechanism of SHG was studied. The experimental results demonstrated that effective electron traps and hole traps were generated in the UV- polarized film. The energy of electrons and holes was using up due to the collision with other particles and crystal fields during their movement and finally they were captured by the traps and fixed, which made the electric charge distribution nonuniform in the film and destroyed the spatial isotropy. In the meantime, the center of positive and negative charges separated and a built-in electric field was formed which generated the optical second-order nonlinearity of the film.展开更多
文摘Efficient third-order nonlinearities of the Zinc Oxide and Al-doped Zinc Oxide were studied by Third Harmonic Generation (Third Harmonic Generation) Maker fringes to establish the effect Aluminum of Aluminum doping (Al-doping) on the cubic nonlinearities. Adding the Al-dopant to the Zinc Oxide crystal structure results in changes that affect the optical and nonlinear characteristics. Presented results indicate that the magnitude of X<sup>(3)</sup> was enhanced at single experimental wavelengths;however, across the broadband experimental spectrum, the effect of Al-doping remained relatively constant. The observed enhancement of third-order nonlinearity was purely from the bound electronic response. The observation is attributed to increased charge carriers and spontaneous polarization in the Zinc Oxide and Al-doped Zinc Oxide crystal structure.
基金Funded by the National Natural Science Foundaition of China(Nos.51172169 and 61177084),NCET\(NCET-11-0687)the Fundamental Research Funds for the Central Universities(Wuhan University of Technology)
文摘With the pulsed laser deposition （PLD） method, amorphous 80GeS2-15Ga2S3-5CdS chalcogenide film was deposited on glassy substrate. Obvious second harmonic generation （SHG） was observed in the ultraviolet （UV）-polarized film and the SHG intensity increased with the increase in single pulse energy and irradiation time. Through Raman spectra and transmission spectra, the mechanism of SHG was studied. The experimental results demonstrated that effective electron traps and hole traps were generated in the UV- polarized film. The energy of electrons and holes was using up due to the collision with other particles and crystal fields during their movement and finally they were captured by the traps and fixed, which made the electric charge distribution nonuniform in the film and destroyed the spatial isotropy. In the meantime, the center of positive and negative charges separated and a built-in electric field was formed which generated the optical second-order nonlinearity of the film.
