The salt beds of the Middle-Lower Cambrian are widespread in the middle-west parts of the Central Uplift and adjacent areas, the Tarim Basin. This paper presents the results of seismic interpretation and drilling data...The salt beds of the Middle-Lower Cambrian are widespread in the middle-west parts of the Central Uplift and adjacent areas, the Tarim Basin. This paper presents the results of seismic interpretation and drilling data analysis, which discovered that the salt beds were formed in an old geologic age, deeply buried, with relatively small scaled flowing and gathering and uneven distribution. As the regional detachment layers, the salt sequences considerably control the structural deformation of the up-salt Paleozoic, forming a series of hydrocarbon traps. In due course, the salt beds of the Middle-Lower Cambrian provide excellent cap rocks and trap conditions; thus the value of exploring hydrocabon reservoir in the target strata of the sub-salt Sinian- Cambrian is greatly increased. Research has shown that the salt-related structures of the Middle-Lower Cambrian in the area mainly exist in the form of salt pillow, salt roller, up-salt anticline, salt diapir, assemblage of the salt arch and up-salt fault-block, assemblage of basement fault and salt anticline, assemblage of the basement fault-block and salt dome, assemblage of salt detachment and fault-related fold, and assemblage of basement fault-block, salt arch and up-salt imbricated thrusts. The evolution and deformation mechanisms of the salt-related structures are controlled largely by basement faulting, compressional shortening, plastic flowing and gathering, superstratum gravitation, and up-salt faulting and detaching. They are distributed in rows or belts along basement faults or fault block belts.展开更多
A polymetallic layer is usually developed at the bottom of the early Cambrian black shale in Guizhou Province.The mineral that makes up the polymetallic layer is related to the sedimentary facies.To analyze the differ...A polymetallic layer is usually developed at the bottom of the early Cambrian black shale in Guizhou Province.The mineral that makes up the polymetallic layer is related to the sedimentary facies.To analyze the differentiation mechanism between polymetallic deposits(Ni-Mo and V),the Zhijin Gezhongwu profile located in the outer shelf and the Sansui Haishan V deposit located in the lower slope are selected to study the in situ sulfur isotopes and trace elements of pyrite.The results show that δ^(34)S values of pyrite vary widely from−7.8‰to 28‰in the Gezhongwu profile,while the δ^(34)S values are relatively uniform(from 27.8‰to 38.4‰)in the Haishan profile.The isotopic S composition is consistent with the transition that occurs in the sedimentary phase from the shelf to the deep sea on the transgressive Yangtze platform;this indicates that the δ^(34)SO_(4)^(2−)values in seawater must be differently distributed in depositional environments.The sulfur in the Ni-Mo layer is produced after the mixing of seawater and hydrothermal fluid,while the V layer mainly originates from seawater.Overall,the Ni-Mo and V deposits have been differentiated primarily on the basis of the combined effect of continental weathering and hydrothermal fluid.展开更多
The Early Cambrian represents a critical time period characterized by extraordinary biological innovations and dynamic redox conditions in seawaters.Nitrogen isotopic signatures of ancient sediments have the potential...The Early Cambrian represents a critical time period characterized by extraordinary biological innovations and dynamic redox conditions in seawaters.Nitrogen isotopic signatures of ancient sediments have the potential to elucidate the evolutionary path of marine redox states and the biogeochemical nitrogen cycle within the water column of the Early Cambrian ocean.While existing research on this topic has predominantly focused on South China,the exploration of other continental margins has been limited,leaving contradictory hypotheses untested.In this study,pairedδ^(15)N andδ^(13)C org analyses were performed on the Lower Cambrian successions from the Shiairike section(inner ramp)and Well Tadong 2(deep shelf/basin)in the northwestern and eastern Tarim Basin,respectively.Our data from the Shiairike section reveal a discernible shift in the operation of different nitrogen cycles for the black chert-shale unit,also referred to as the black rock series in Chinese literature,of the Yurtus Formation(Fortunian stage to lower Stage 3).Oscillatingδ^(15)N values for its lower part are suggestive of alternating anaerobic assimilation of NH 4+and denitrification/anammox.This is likely attributed to a shallow,unstable chemocline consistent with the upwelling and incursion of deep,anoxic waters during a major transgression.In contrast,aerobic nitrogen cycling,indicated by positiveδ^(15)N values of>2‰,dominated the upper part alongside a reduction in upwelling intensity.On the other hand,theδ^(15)N signatures of Xishanbulake and Xidashan Formations of Well Tadong 2,which encompass a time interval from the Cambrian Fortunian Age to Age 4,are indicative of N_(2)fixation by diazotrophs as the major nitrogen source.The two studied intervals,although not time-equivalent,exhibit separated states of nitrogen cycling at least during the deposition of the Yurtus black rock series.The spatially different nitrogen cycling of the studied sections is compatible with a redox-stratified ocean during the deposition of the Yurtus black rock series.The build-up of a NO_(3)−reservoir and aerobic nitrogen cycling in seawater was largely restricted to near-shore settings whereas anaerobic nitrogen cycling dominated by N_(2)fixation served as the main nitrogen uptake pathway in off-shore settings.展开更多
Cambrian shales in China and elsewhere contain abundant oil and gas resources.However,due to its deep burial and limited outcrop,there has been relatively little research conducted on it.The Cambrian shale of the Tado...Cambrian shales in China and elsewhere contain abundant oil and gas resources.However,due to its deep burial and limited outcrop,there has been relatively little research conducted on it.The Cambrian shale of the Tadong low uplift in the Tarim Basin of western China,specifically the Xidashan-Xishanbulake Formation(Fm.)and overlying Moheershan Fm.provide a case study through the use of organic petrology,mineralogy,organic and elemental geochemistry,with the aim of analyzing and exploring the hydrocarbon generation potential(PG)and organic matter(OM)enrichment mechanisms within these shale formations.The results indicate that:(1)the Cambrian shale of the Tadong low uplift exhibits relatively dispersed OM that consists of vitrinite-like macerals and solid bitumen.These formations have a higher content of quartz and are primarily composed of silica-based lithology;(2)shale samples from the Xidashan-Xishanbulake and Moheershan formations demonstrate high total organic carbon(TOC)and low pyrolytic hydrocarbon content(S_(2))content.The OM is predominantly typeⅠand typeⅡkerogens,indicating a high level of maturation in the wet gas period.These shales have undergone extensive hydrocarbon generation,showing characteristics of relatively poor PG;(3)the sedimentary environments of the Xidashan-Xishanbulake and Moheershan formations in the Tadong low uplift are similar.They were deposited in warm and humid climatic conditions,in oxygen-deficient environments,with stable terrigenous inputs,high paleoproductivity,high paleosalinity,weak water-holding capacity,and no significant hydrothermal activity;and(4)the relationship between TOC and the paleoproductivity parameter(P/Ti)is most significant in the Lower Cambrian Xidashan-Xishanbulake Fm.,whereas correlation with other indicators is not evident.This suggests a productivity-driven OM enrichment model,where input of landderived material was relatively small during the Middle Cambrian,and the ancient water exhibited lower salinity.A comprehensive pattern was formed under the combined control of paleoproductivity and preservation conditions.This study provides valuable guidance for oil and gas exploration in the Tarim Basin.展开更多
The Lower Cambrian shale gas in the western Hubei area,South China has a great resource prospect,but the gas-in-place(GIP)content in different sedimentary facies varies widely,and the relevant mechanism has been not w...The Lower Cambrian shale gas in the western Hubei area,South China has a great resource prospect,but the gas-in-place(GIP)content in different sedimentary facies varies widely,and the relevant mechanism has been not well understood.In the present study,two sets of the Lower Cambrian shale samples from the Wells YD4 and YD5 in the western Hubei area,representing the deep-water shelf facies and shallowwater platform facies,respectively,were investigated on the differences of pore types,pore structure and methane adsorption capacity between them,and the main controlling factor and mechanism of their methane adsorption capacities and GIP contents were discussed.The results show that the organic matter(OM)pores in the YD4 shale samples are dominant,while the inorganic mineral(IM)pores in the YD5 shale samples are primary,with underdeveloped OM pores.The pore specific surface area(SSA)and pore volume(PV)of the YD4 shale samples are mainly from micropores and mesopores,respectively,while those of the YD5 shale samples are mainly from micropores and macropores,respectively.The methane adsorption capacity of the YD4 shale samples is significantly higher than that of the YD5 shale samples,with a maximum absolute adsorption capacity of 3.13 cm^(3)/g and 1.31 cm^(3)/g in average,respectively.Compared with the shallow-water platform shale,the deep-water shelf shale has a higher TOC content,a better kerogen type and more developed OM pores,which is the main mechanism for its higher adsorption capacity.The GIP content models based on two samples with a similar TOC content selected respectively from the Wells YD4 and YD5 further indicate that the GIP content of the deep-water shelf shale is mainly 34 m^(3)/t within a depth range of 1000—4000 m,with shale gas exploration and development potential,while the shallow-water platform shale has normally a GIP content of<1 m^(3)/t,with little shale gas potential.Considering the geological and geochemical conditions of shale gas formation and preservation,the deep-water shelf facies is the most favorable target for the Lower Cambrian shale gas exploration and development in the western Hubei area,South China.展开更多
The Tongling area is one of the 7 ore-cluster areas in the Middle-Lower Yangtze metallogenic belt, East China, and has tectonically undergone a long-term geologic history from the late Paleozoic continental rifting, t...The Tongling area is one of the 7 ore-cluster areas in the Middle-Lower Yangtze metallogenic belt, East China, and has tectonically undergone a long-term geologic history from the late Paleozoic continental rifting, through the Middle Triassic continent-continent collision to the Jurassic-Cretaceous intracontinental tectono-magmatic activation. The Carboniferous sedimentary-exhalative processes in the area produced widespread massive sulfides with ages of 303-321 Ma, which partly formed massive pyrite-Cu deposits, but mostly provided significant sulfur and metals to the skarn Cu mineralization associated with the Yanshanian felsic intrusions.To understand the Carboniferous submarine hydrothermal system, an area of about 1046 km^2 was chosen to carry out the geological fluid mapping. Associated with massive sulfide formation, footwall sequences 948 m to 1146 m thick, composed of the Lower Silurian-Upper Devonian sandstone, siltstone and thin-layered shale, were widely altered. This hydrothermal alteration is interpreted to reflect largescale hydrothermal fluid flow associated with the late Paleozoic crustal rifting and subsidence. Three hydrothermal alteration types, i.e., deep-level semiconformable siliclfication （S1）, fracture-controlled quartz-sericite-pyrite alteration （S2-3）, and upper-level sub-discordant quartz-sericite-chlorite alteration （D3）, were developed to form distinct zones in the mapped area. About 50-m thick semiconformable silicification zones are located at -1-km depth below massive sulfides and developed between an impermeable shale caprock （S1） and the underlying Ordovician unaltered limestone. Comparisons with modern geothermal systems suggest that the alteration zones record a sub-seafioor aquifer with the most productive hydrothermal fluid flow. Fracture-controlled quartz-sericite-pyrite alteration formed transgressive zones, which downward crosscut the semiconformable alteration zones, and upwards grade into sub-discordant alteration zones that enveloped no economic stringer- stockwork zones beneath massive sulfides. This transgressive zone likely marks an upfiow path of high- flux fluids from the hydrothermal aquifer. Lateral zonation of the sub-discordant alteration zones and their relationship to overlying massive sulfide lenses suggest lateral flows and diffusive discharging of the hydrothermal fluids in a permeable sandstone sequence. Three large-sized, 14 middle-small massive sulfide deposits, and 40 massive sulfide sites have been mapped in detail. They show regional strata- bound characters and two major styles, i.e., the layered sheet plus strata-bound stringer-style and the mound-style. Associated exhalite and chemical sedimentary rock suites include （1） anhydrite-barite, （2） jasper-chert, （3） Mg-rich mudstone-pyrite shale, （4） barite lens, （5） siderite-Fe-bearing dolomite, and （6） Mn-rich shale-mudstone, which usually comprise three sulfide-exhalite cyclic units in the area.The spatial distribution of these alteration zones （minerals） and associated massive sulfdes and exhalites, and regional variation in δ^34S of hydrothermal pyrite and in δ^18O-δ^34C of hanging wall carbonates, suggest three WNW-extending domains of fluid flow, controlled by the basement faults and syn-depositional faults. Each fluid domain appears to have at least two upflow zones, with estimated even spacing of about 5-8 km in the mapped area. The repeated appearance of sulfide-sulfate or sulfide-carbonate rhythmic units in the area suggests episodically venting of fluids through the upfiow conduits by breaking the overlying seals of the hydrothermal aquifer.展开更多
In the East Asian monsoon region, eolian deposits widely distributed in the middle-lower reaches of the Yantgze River are among the best materials available for studies on Quaternary climate change in the subtropical ...In the East Asian monsoon region, eolian deposits widely distributed in the middle-lower reaches of the Yantgze River are among the best materials available for studies on Quaternary climate change in the subtropical zone of Southern China. Typical eolian deposits in this region include upper Xiashu Loess （XL） and underlying Vermiculated Red Soil （VRS） layers. In this paper, chronological and paleoclimatic studies are conducted on an eolian deposit sequence near Jiujiang （J J） city in northern Jiangxi province. A magnetostratigraphic study, combined with optically stimulated luminescence （OSL） dating, is conducted on the JJ section and provides further evidence that eolian deposits in the middle-lower reaches of the Yangtze River have been formed since the late Early Pleistocene, and that the boundary age between the XL and VRS layers is about 300-400 kaBP. In grain-size records of the JJ section, the median grain-size and content of the 〉30μn size fraction increase sharply after 300-400 kaBP, representing an East Asian winter monsoon intensification event. Further pollen analysis reveals differing pollen assemblages before and after 300-400 kaBP： there is an evident increase in plants adapted to grow in a warm humid environment after 300-400 kaBP, implying an increase in precipitation caused by intensification of the East Asian summer monsoon. Global ice volume and uplift of the Tibet Plateau （TP） are regarded as crucial factors influencing variations of the East Asian monsoon on a long-term scale. The deep-sea JlSO record, which reflects variations in global ice volume, shows no obvious change after 300-400 kaBP. Moreover, the influence of global ice volume changes on the East Asian summer and winter monsoons is inverse; the global ice volume increase （decrease） implies a strengthened （weakened） winter monsoon and weakened （strengthened） summer monsoon. We therefore interpret the coupled intensifications of the East Asian summer and winter monsoons at about 300-400 kaBP to the uplift of the TP in the Middle Pleistocene. This climate event is also documented in eolian deposits from the southern margin of the Chinese Loess Plateau （CLP） and from the desert-loess transitional belt. However, it is not recorded in the loess-paleosol sequences from the central part of the CLP, thereby indicating differing climate responses to TP uplift in different regions, which requires further study.展开更多
The Tongshankou Cu-Mo deposit, located in southeast Hubei province, is a typical skarn–porphyry type ore deposit closely related to the Tongshankou granodiorite porphyry, characterized by a high Sr/Y ratio.Detailed i...The Tongshankou Cu-Mo deposit, located in southeast Hubei province, is a typical skarn–porphyry type ore deposit closely related to the Tongshankou granodiorite porphyry, characterized by a high Sr/Y ratio.Detailed in situ analyses of the trace elements and U–Pb and Lu–Hf isotopes in zircons from the Tongshankou granodiorite porphyry were performed.Scarcely any inherited zircons were observed, and the analyzed zircons yielded highly concordant results with a weighted mean 206Pb/238 U age of 143.5 ± 0.45 Ma（n=20, mean square weighted deviation was 0.75）, which was interpreted to represent the crystallization age of the Tongshankou granodiorite porphyry.The chondrite-normalized rare-earth element pattern was characterized by a slope that steeply rises from the light-group rare-earth elements（LREE） to the heavy-group rare-earth elements（HREE） with a positive Ce-anomaly and inconspicuous Eu-anomaly, which was coincident with the pattern of the zircons from the Chuquicamata West porphyry, Chile.The analyzed zircons also had relatively low 176Hf/177 Hf ratios of 0.282526–0.282604.Assuming t=143 Ma, the corresponding calculated initial Hf isotope compositions（εHf（t）） ranged from-5.6 to-2.9.The results of the in situ analysis of trace elements and U–Pb and Lu–Hf isotopes in zircons from the Tongshankou granodiorite porphyry suggest that a deep-seated process involving a thickened-crust/enriched-mantle interaction may play an important role in the generation of high Sr/Y-ratio magma and potentially in the generation of porphyry Cu-Mo systems.展开更多
The middle-lower Yangtze area underwent a series of complex tectonic evolution, such as Hercynian extensional rifting, Indosinian foreland basining, and Yanshanian transpression-transtension, resulting in a large dist...The middle-lower Yangtze area underwent a series of complex tectonic evolution, such as Hercynian extensional rifting, Indosinian foreland basining, and Yanshanian transpression-transtension, resulting in a large distinctive Cu-Fe-Au metallogenic belt. In the tectonic evolution, large-scale migration and convergence of fluids toward foreland basins induced during the collisional orogeny of the Yangtze and North China continental blocks were of vital importance for the formation of the metallogenic belt. Through geological surveys of the middle-lower Yangtze area, three lines of evidence of large-scale fluid migration are proposed: (1) The extensive dolomitic and silicic alteration penetrating Cambrian-Triassic strata generally occurs in a region sandwiched between the metallogenic belt along the Yangtze River and the Dabie orogenic belt, and in the alteration domain alternately strong and weak alteration zones extend in a NW direction and are controlled by the fault system of the Dabie orogenic belt; it might record the locus of the activities of long-distance migrating fluids. (2) The textures and structures of very thick Middle-Lower Triassic anhydrock sequences in restricted basins along the river reveal the important contribution of the convergence of regional hot brine in restricted basins and the chemical deposition or their formation. (3) Early-Middle Triassic syndepositional iron carbonate sequences and Fe-Cu-Pb-Zn massive sulfide deposits alternate with anhydrock sequences or are separated from the latter, but all of them occur in the same stratigraphic horizon and are intimately associated with each other, being the product of syndeposition of high-salinity hot brine. According to the geological surveys, combined with previous data, the authors propose a conceptual model of fluid migration-convergence and mineralization during the Dabie collisional orogeny.展开更多
The Datuanshan deposit is one of the largest and most representative stratabound copper deposits in the Tongling area,the largest ore district in the Middle-Lower Yangtze River metallogenic belt.The location of the or...The Datuanshan deposit is one of the largest and most representative stratabound copper deposits in the Tongling area,the largest ore district in the Middle-Lower Yangtze River metallogenic belt.The location of the orebodies is controlled by the interlayer-slipping faults between the Triassic and Permian strata,and all the orebodies are distributed in stratiform shape around the Mesozoic quartz monzodiorite dikes.Based on field evidence and petrographic observations,four mineralization stages in the Datuanshan deposit have been identified：the skarn,early quartz-sulfide,late quartzsulfide and carbonate stages.Chalcopytite is the main copper mineral and mainly formed at the late quartz-sulfide stage.Fluid inclusions at different stages were studied for petrography,microthermometry,laser Raman spectrometry and stable isotopes.Four types of fluid inclusions,including three-phase fluid inclusions（type 1）,liquid-rich fluid inclusions（type 2）,vapour-rich fluid inclusions（type 3） and pure vapour fluid inclusions（type 4）,were observed.The minerals from the skarn,early and late quartz-sulfide stages contain all fluid inclusion types,but only type 2 fluid inclusions were observed at the carbonate stage.Petrographic observations suggest that most of the inclusions studied in this paper are likely primary.The coexistence of different types of fluid inclusions with contrasting homogenization characteristics（to the liquid and vapour phase,respectively） and similar homogenization temperatures（the modes are 440-480℃,380-400℃ and 280-320℃ for the skarn,early and late quartz-sulfide stages,respectively） in the first three stages,strongly suggests that three episodes of fluid boiling occurred during these stages,which is supported by the hydrogen isotope data.Laser Raman spectra identified CH_4 at the skarn and early quartz-sulfide stages.Combined with other geological features,the early ore-forming fluids were inferred to be under a relatively reduced environment.The CO_2 component has been identified at the late quartz-sulfide and carbonate stages,indicating that the late ore-forming fluids were under a relatively oxidized environment,probably as a result of inflow of and mixing with meteoric water.In addition,microthermometric results of fluid inclusions and H-O isotope data mdicate that the ore forming fluids were dominated by magmatic water in the early stages（skarn and early quartz-sulfide stages） and mixed with meteoric water in the late stages（late quartz-sulfide and carbonate stages）.The evidence listed above suggests that the chalcopyrite deposition in the Datuanshan deposit probably resulted from the combination of multiepisode fluid boiling and mixing of magmatic and meteoric water.展开更多
In order to examine the impacts of water-sediment regulation on regional carbon cycling,we collected water,particulate and sediment samples from the middle-lower Yellow River in late June and early July,2015 and analy...In order to examine the impacts of water-sediment regulation on regional carbon cycling,we collected water,particulate and sediment samples from the middle-lower Yellow River in late June and early July,2015 and analyzed their specific amino acids(AA),DOC,POC,and bacteria abundance.Summarized by 14 specific AA,the total hydrolysable AA(THAA),particulate AA(PAA),and sediment AA(SAA)varied in ranges of 2.29-9.05μmol L^-1,5.22-22.96μmol L^-1,and 81.7-137.19μg g^-1 dry weight.After the regulation,dissolved free AA(DFAA)decreased by 29%while DCAA increased by 72%.These variations suggested that DFAA were further degraded,while DCAA molecules were further activated.Meanwhile,PAA increased almost 4 times as many as those before regulation,and SAA increased as well.After regulation,the amounts of bioactive amino acids(Asp,Glu and Gly)increased in THAA but decreased in PAA,with little changes in SAA.The ratios of Asp/Gly in different phases increased after regulation,indicating the AA contributions were promoted by calcareous organisms rather than by siliceous organisms.Multiple correlation analysis showed that PAA was primary representatives of AA and organic carbon,followed by DCAA and POC.Moreover,bacterial reproduction played a key role in shaping the AA compositions and properties,followed by the redox condition and acid-base balance.The results of this study provided a clear evidence for the effects of water-sediment regulation on regional biogeochemistry of organic carbon in the middle-lower Yellow River.展开更多
The Middle-Lower Yangtze River Metallogenic Belt(MLYB)is known to contain abundant copper and iron porphyry-skarn deposits,with an increasing number of tungsten deposits and scheelite in Fe-Cu deposits being discovere...The Middle-Lower Yangtze River Metallogenic Belt(MLYB)is known to contain abundant copper and iron porphyry-skarn deposits,with an increasing number of tungsten deposits and scheelite in Fe-Cu deposits being discovered in the MLYB during recent decades.The ore genesis of the newly-discovered tungsten mineralization in the MLYB is poorly understood.We investigate four sets of scheelite samples from tungsten,iron and copper deposits,using CL imaging and LA-ICP-MS techniques to reveal internal zonation patterns and trace element compositions.The REE distribution patterns of four studied deposits show varying degrees of LREE enrichment with negative Eu anomalies.The oxygen fugacity of ore-forming fluid increased in Donggushan,while the oxygen fugacity of ore-forming fluid decreased in Ruanjiawan,Guilinzheng and Gaojiabang.The scheelites from the Donggushan,Ruanjiawan,Guilinzheng and Gaojiabang deposits show enrichment in LREEs and HFSE,with Nb/La ratios ranging from 1.217 to 52.455,indicating that the four tungsten deposits are enriched in the volatile fluorine.A plot of(La/Lu)N versus Mo/δEu can be used to distinguish quartz vein type,porphyry and skarn tungsten deposits.This study demonstrates that scheelite grains can be used to infer tungsten mineralization and are effective in identifying magmatic types of tungsten deposits in prospective mining sites.展开更多
Thallium has been used geochemical exploration of gold deposits. However, as an indicator element in searching for hydrothermal the T1 minerals and mineralization are rare in nature. Lorandite T1AsS2, a relatively un...Thallium has been used geochemical exploration of gold deposits. However, as an indicator element in searching for hydrothermal the T1 minerals and mineralization are rare in nature. Lorandite T1AsS2, a relatively uncommon mineral, has been dominantly discovered in some Carlin gold deposits, and minor Sb- Hg, U and Pb-Zn-Ag deposits.展开更多
The Magushan skarn Cu-Mo deposit is a representative example of the skarn mineralization occurring within the Xuancheng ore district of the Middle-Lower Yangtze River Metallogenic Belt of eastern China.The precise age...The Magushan skarn Cu-Mo deposit is a representative example of the skarn mineralization occurring within the Xuancheng ore district of the Middle-Lower Yangtze River Metallogenic Belt of eastern China.The precise age of an ore deposit is important for understanding the timing of mineralization relative to other geological events in a region and to fully place the formation of a mineral deposit within the geological context of other processes that occur within the study area.Here,we present new molybdenite Re-Os and titanite and andradite garnet U-Pb ages for the Magushan deposit and use these data to outline possible approaches for identifying genetic relationships in geologically complex areas.The spatial and paragenetic relationships between the intrusions,alteration,and mineralization within the study area indicates that the formation of the Magushan deposit is genetically associated with the porphyritic granodiorite.However,this is not always the case,as some areas contain complexly zoned plutons with multiple phases of intrusion or mineralization may be distal from or may not have any clear spatial relationship to a pluton.This means that it may not be possible to determine whether the mineralization formed as a result of single or multiple magmatic/hydrothermal events.As such,the approaches presented in this study provide an approach that allows the identification of any geochronological relationships between mineralization and intrusive events in areas more complex than the study area.Previously published zircon U-Pb data for the mineralization-related porphyritic granodiorite in this area yielded an age of 134.2±1.2 Ma(MSWD=1.4)whereas the Re-Os dating of molybdenite from the study area yielded an isochron age of 137.7±2.5 Ma(MSWD=0.43).The timing of the mineralizing event in the study area was further examined by the dating of magmatic accessory titanite and skarn-related andradite garnet,yielding U-Pb ages of 136.3±2.5 Ma(MSWD=3.2)and 135.9±2.7 Ma(MSWD=2.5),respectively.The dating of magmatic and hydrothermal activity within the Magushan area yields ages around 136 Ma,strongly suggesting that the mineralization in this area formed as a result of the emplacement of the intrusion.The dates presented in this study also provide the first indication of the timing of mineralization within the Xuancheng district.providing evidence of a close genetic relationship between the formation of the mineralization within the Xuancheng district and the Early Cretaceous magmatism that occurred in this area.This in turn suggests that other Early Cretaceous intrusive rocks within this region are likely to be associated with mineralization and should be considered highly prospective for future mineral exploration.This study also indicates that the dating of garnet and titanite can also provide reliable geochronological data and evidence of the timing of mineralization and magmatism,respectively,in areas lacking other dateable minerals(e.g.,molybdenite)or where the relationship between mineralization and magmatism is unclear,for example in areas with multiple stages of magmatism,with complexly zoned plutons,and with distal skarn mineralization.展开更多
Based on the latest drilling, seismic and field outcrop data, the geological characteristics(e.g. strata, development and sedimentary evolution) of the southern segment of the Late Sinian–Early Cambrian Deyang–Anyue...Based on the latest drilling, seismic and field outcrop data, the geological characteristics(e.g. strata, development and sedimentary evolution) of the southern segment of the Late Sinian–Early Cambrian Deyang–Anyue rift trough in the Sichuan Basin are analyzed. First, the strata in the southern segment are complete. The first to second members of Dengying Formation(Deng 1 + Deng 2) are found with relatively stable thickness(400–550 m), and the third to fourth members(Deng 3+ Deng 4) show great thickness difference between the marginal trough and the inner trough, which is up to 250 m. The Cambrian Maidiping Formation and Qiongzhusi Formation in southern Sichuan Basin are relatively thin, with the thickness changing greatly and frequently. Second, the Deyang–Anyue rift trough extended southward during the Deng 4 period, affecting southern Sichuan Basin. Compared to the middle and northern segments of the rift trough, the southern segment is generally wide, gentle and shallow, with multiple steps, and alternating uplifts and sags, which are distributed in finger shape. Third, the Deng 1 + Deng 2 in southern Sichuan Basin records the dominance of carbonate platform and unobvious sedimentary differentiation, and the Deng 4 exhibits obvious sedimentary differentiation, namely, basin–slope–secondary slope–slope–secondary slope–platform margin–restricted platform, from the inner trough to the marginal trough. Fourth, the rift trough in southern Sichuan Basin has evolved in four stages: stabilization of Deng 1–Deng 2, initialization of Deng 3–Deng 4, filling of Maidiping–Qiongzhusi, and extinction of Canglangpu Formation.展开更多
The building of Shuikou Hydropower Station in the Minjiang River is the largest one in the region of east China. Its install capacity is 1.4 million kw., and its generated energy of planning is 4.95 billion kwh each y...The building of Shuikou Hydropower Station in the Minjiang River is the largest one in the region of east China. Its install capacity is 1.4 million kw., and its generated energy of planning is 4.95 billion kwh each year. In accordance with a comprehensive survey of the valley of the middle-lower reaches of the Minjiang River and the characteristic of hydrography and in association with the specific type of the hydrography station, we can be sure that no harm will be done to the ecological environment when a hydropower station is built at Shuikou. Not only the deposition of silt within the reservoir must not be very serious, it is also more favorable than before for the irrigation of farmland on plains in the lower reaches of the Minjiang River and inland navigation.In addition, after the completion of the power station, the ecological environment will be the same as before both at the Minjiang River estuary and beyond it.展开更多
The evaluation method, model and process for the flood and waterlogging disaster condition by GIS,RS and GPS technology and the method for setting up disaster condition database, dyke database and historical disaster ...The evaluation method, model and process for the flood and waterlogging disaster condition by GIS,RS and GPS technology and the method for setting up disaster condition database, dyke database and historical disaster damage database are presented. An index of flood damage degree(FDD) used to evaluate the relative degree of disaster loss and divide flood and waterlogging area is suggested. The value of flood damage degree can be calculated as follows :taking the various disaster losses of sample area in a base year as standard value and computing the ratios of various disaster loss values in different areas and years to the standard flood disaster loss values, then summing up the weighted ratios. The computed results are the value of flood damage degree in the every year. The macroscopic flood disaster distribution can be evaluated by the values of flood loss degree.展开更多
The Xixiangchi Group in eastern Sichuan Basin has great potential for natural gas exploration.However,there is a lack of in-depth studies of the hydrocarbon sources and the formation and evolution of gas reservoirs in...The Xixiangchi Group in eastern Sichuan Basin has great potential for natural gas exploration.However,there is a lack of in-depth studies of the hydrocarbon sources and the formation and evolution of gas reservoirs in this Group.Systematic investigation about the gas reservoir in Pingqiao anticline was consequently carried out in terms of characteristics of reservoir bitumen,the geochemical characteristics of natural gas,diagenetic minerals,and fluid inclusions.Based on this,combined with the reconstruction of the burial history,thermal evolution history and uplifting history of strata,and analysis of the regional tectonic settings,the hydrocarbon sources were identified and the formation and evolutionary processes of the gas reservoirs in Xixiangchi Group was revealed in this study.It was shown that the gas reservoirs have mixed gas sources from the shale source rocks in the Lower Cambrian Qiongzhusi Formation and in the Upper Ordovician Wufeng Formation-Lower Silurian Longmaxi Formation,and experienced several evolutionary stages,including the paleo-oil reservoir stage from the Late Siliurian to the Middle Permian,the paleo-gas reservoir stage from the Late Permian to the Early Cretaceous,and the superimposed accumulation and mixed-source gas reservoir stage since the Late Cretaceous.The mixed-source gas reservoir is formed by the adjustment of the Xixiangchi Group paleo-gas reservoirs and depressurization of the overpressure Wufeng-Longmaxi shale gas reservoirs and the charging of gas into the Xixiangchi Group reservoir of the Pingqiao anticline since the Late Cretaceous,which show obvious superimposed accumulation characteristics.There are different accumulation patterns in different geological periods.The accumulation pattern of the“old source-young reservoir”(i.e.hydrocarbons generated from older source rocks accumulating in younger reservoirs)dominates before the Late Cretaceous,and that of“juxtaposed young source-old reservoir”(i.e.hydrocarbons generated from younger source rocks accumulating in juxtaposed older reservoirs)dominates after the Early Cretaceous.Moreover,faults acted as critical vertical pathways for hydrocarbon migration during the evolution of the Xixiangchi Group gas reservoirs.This model provides new insights and theoretical basis for evaluation and mapping of the Xixiangchi Group play fairway in eastern Sichuan Basin.展开更多
Under the tectonodynamic process, crustal materials tend to experience two modes of adjustment: (1) structural (physical) adjustment, manifested by folding, faulting, uplifting, downwarping, etc.: (2) compositional ad...Under the tectonodynamic process, crustal materials tend to experience two modes of adjustment: (1) structural (physical) adjustment, manifested by folding, faulting, uplifting, downwarping, etc.: (2) compositional adjustment, represented by element migration, concentration and dispersion, crystalline and dynamic differentiation of crystals, metamorphism, etc. (Yang Kaiqing. 1986; Yang Kaiqing et al., 1986). The dynamic adjustment of crustal materials in the middle-lower reaches of the Yangtze mainly occurred in the Mesozoic under the conditions of intense collision between the North China (Dabie) massif and the Yangtze massif. The structural adjustment refers to various types of deformation within the two massifs and the intensive shortening of the stratigraphic coyer of the Yangtze massif, whereas the compositional adjustment implies the structural remelting of the basement and the ore. and rock- forming processes in the two massifs.展开更多
Micromotion is the daily tiny vibration of the earth</span><span style="font-family:Verdana;">’</span><span style="font-family:Verdana;">s surface. Micromotional exploratio...Micromotion is the daily tiny vibration of the earth</span><span style="font-family:Verdana;">’</span><span style="font-family:Verdana;">s surface. Micromotional exploration can use the surface wave information of micro motion to study the shallow structure of underground media. In this study, we collected microtremor data at 68 stations in the Middle-Lower Yangtze Metallogenic Belt (MLYMB) and determined the resonant frequency and obtained the distribution of sedimentary thickness in this area by using H/V spectral ratio. According to the results of H/V, the sedimentary layer in the basin is thick, and the predominant frequency of the basin is 0.05</span><span style="font-family:""> </span><span style="font-family:Verdana;">-</span><span style="font-family:""> </span><span style="font-family:Verdana;">0.1</span><span style="font-family:""> </span><span style="font-family:Verdana;">Hz. There are no obvious lateral changes in the impedance interface between bedrock and sedimentary layer in this area. The basement of Tongling, Anqing and Luzhou mining areas and their adjacent areas is Kongling-Dongling type basement, which is composed of a set of metamorphic core complex. The predominant frequency is 0.05</span><span style="font-family:""> </span><span style="font-family:Verdana;">-</span><span style="font-family:""> </span><span style="font-family:Verdana;">0.1</span><span style="font-family:""> </span><span style="font-family:Verdana;">Hz. The sedimentary thickness gradually thinned from 3800</span><span style="font-family:""> </span><span style="font-family:Verdana;">m in the west to 2100</span><span style="font-family:""> </span><span style="font-family:Verdana;">m in the East. Moreover, this article used SPAC (spatial autocorrelation) method to obtain the S-wave velocity structure of the mining area near Luzong. The SPAC method reveals that the depth of the interface between the loose sediments and the volcanic rocks is about 600 m in the study area near the Luzhou mining area in the Middle-Lower Yangtze Metallogenic Belt, and the average depth of the interface between the volcanic rock section and the intrusive complex section is about 1000</span><span style="font-family:""> </span><span style="font-family:Verdana;">m. The thickness of the intrusive rock is more than 2500</span><span style="font-family:""> </span><span style="font-family:Verdana;">m. Tourmaline is developed in the interior of the intrusive rock, which may have better exploration value.展开更多
基金supported by National Natural Science Foundation of China (Grant Nos. 41172125, 40972090, 40802030, 40672143 and 40472107)National Basic Research Program of China (Grant Nos. 2012CB214804,2005CB422107 and G1999043305)+3 种基金Investigation and Evaluation on Strategic Region of National Oil and Gas Resource (Grant No. 2009GYXQ0205)Doctoral Fund of Ministry of Education of China (Grant No.200804250001)National Key Scientific Project (Grant No.2011ZX05002-003-001HZ)Northwest Oilfield Company of SINOPEC has given full support with fundamental geologic data
文摘The salt beds of the Middle-Lower Cambrian are widespread in the middle-west parts of the Central Uplift and adjacent areas, the Tarim Basin. This paper presents the results of seismic interpretation and drilling data analysis, which discovered that the salt beds were formed in an old geologic age, deeply buried, with relatively small scaled flowing and gathering and uneven distribution. As the regional detachment layers, the salt sequences considerably control the structural deformation of the up-salt Paleozoic, forming a series of hydrocarbon traps. In due course, the salt beds of the Middle-Lower Cambrian provide excellent cap rocks and trap conditions; thus the value of exploring hydrocabon reservoir in the target strata of the sub-salt Sinian- Cambrian is greatly increased. Research has shown that the salt-related structures of the Middle-Lower Cambrian in the area mainly exist in the form of salt pillow, salt roller, up-salt anticline, salt diapir, assemblage of the salt arch and up-salt fault-block, assemblage of basement fault and salt anticline, assemblage of the basement fault-block and salt dome, assemblage of salt detachment and fault-related fold, and assemblage of basement fault-block, salt arch and up-salt imbricated thrusts. The evolution and deformation mechanisms of the salt-related structures are controlled largely by basement faulting, compressional shortening, plastic flowing and gathering, superstratum gravitation, and up-salt faulting and detaching. They are distributed in rows or belts along basement faults or fault block belts.
基金supported by the National Natural Science Foundation of China(Grant Nos.42272103,92062221,42063009,U1812402)the Guizhou Provincial Science and Technology Projects(Grant No.Qiankehejichu–ZK[2022]common 213)the Higher Education Scientific Research Projects of the Education Department of Guizhou Province(Grant No.Qianjiaoji[2022]157).
文摘A polymetallic layer is usually developed at the bottom of the early Cambrian black shale in Guizhou Province.The mineral that makes up the polymetallic layer is related to the sedimentary facies.To analyze the differentiation mechanism between polymetallic deposits(Ni-Mo and V),the Zhijin Gezhongwu profile located in the outer shelf and the Sansui Haishan V deposit located in the lower slope are selected to study the in situ sulfur isotopes and trace elements of pyrite.The results show that δ^(34)S values of pyrite vary widely from−7.8‰to 28‰in the Gezhongwu profile,while the δ^(34)S values are relatively uniform(from 27.8‰to 38.4‰)in the Haishan profile.The isotopic S composition is consistent with the transition that occurs in the sedimentary phase from the shelf to the deep sea on the transgressive Yangtze platform;this indicates that the δ^(34)SO_(4)^(2−)values in seawater must be differently distributed in depositional environments.The sulfur in the Ni-Mo layer is produced after the mixing of seawater and hydrothermal fluid,while the V layer mainly originates from seawater.Overall,the Ni-Mo and V deposits have been differentiated primarily on the basis of the combined effect of continental weathering and hydrothermal fluid.
基金supported by the Fundamental Research Funds for the Central Universities(No.B200202009).
文摘The Early Cambrian represents a critical time period characterized by extraordinary biological innovations and dynamic redox conditions in seawaters.Nitrogen isotopic signatures of ancient sediments have the potential to elucidate the evolutionary path of marine redox states and the biogeochemical nitrogen cycle within the water column of the Early Cambrian ocean.While existing research on this topic has predominantly focused on South China,the exploration of other continental margins has been limited,leaving contradictory hypotheses untested.In this study,pairedδ^(15)N andδ^(13)C org analyses were performed on the Lower Cambrian successions from the Shiairike section(inner ramp)and Well Tadong 2(deep shelf/basin)in the northwestern and eastern Tarim Basin,respectively.Our data from the Shiairike section reveal a discernible shift in the operation of different nitrogen cycles for the black chert-shale unit,also referred to as the black rock series in Chinese literature,of the Yurtus Formation(Fortunian stage to lower Stage 3).Oscillatingδ^(15)N values for its lower part are suggestive of alternating anaerobic assimilation of NH 4+and denitrification/anammox.This is likely attributed to a shallow,unstable chemocline consistent with the upwelling and incursion of deep,anoxic waters during a major transgression.In contrast,aerobic nitrogen cycling,indicated by positiveδ^(15)N values of>2‰,dominated the upper part alongside a reduction in upwelling intensity.On the other hand,theδ^(15)N signatures of Xishanbulake and Xidashan Formations of Well Tadong 2,which encompass a time interval from the Cambrian Fortunian Age to Age 4,are indicative of N_(2)fixation by diazotrophs as the major nitrogen source.The two studied intervals,although not time-equivalent,exhibit separated states of nitrogen cycling at least during the deposition of the Yurtus black rock series.The spatially different nitrogen cycling of the studied sections is compatible with a redox-stratified ocean during the deposition of the Yurtus black rock series.The build-up of a NO_(3)−reservoir and aerobic nitrogen cycling in seawater was largely restricted to near-shore settings whereas anaerobic nitrogen cycling dominated by N_(2)fixation served as the main nitrogen uptake pathway in off-shore settings.
基金supported by the National Major Science and Technology Project of China(Grant Nos.2016ZX05066001-0022017ZX05064-003-001+3 种基金2017ZX05035-02 and 2016ZX05034-001-05)the Innovative Research Group Project of the National Natural Science Foundation of China(Grant Nos.4187213542072151 and 42372144)the Project of Education Department of Liaoning Province(Grant No.LJKMZ20220744)。
文摘Cambrian shales in China and elsewhere contain abundant oil and gas resources.However,due to its deep burial and limited outcrop,there has been relatively little research conducted on it.The Cambrian shale of the Tadong low uplift in the Tarim Basin of western China,specifically the Xidashan-Xishanbulake Formation(Fm.)and overlying Moheershan Fm.provide a case study through the use of organic petrology,mineralogy,organic and elemental geochemistry,with the aim of analyzing and exploring the hydrocarbon generation potential(PG)and organic matter(OM)enrichment mechanisms within these shale formations.The results indicate that:(1)the Cambrian shale of the Tadong low uplift exhibits relatively dispersed OM that consists of vitrinite-like macerals and solid bitumen.These formations have a higher content of quartz and are primarily composed of silica-based lithology;(2)shale samples from the Xidashan-Xishanbulake and Moheershan formations demonstrate high total organic carbon(TOC)and low pyrolytic hydrocarbon content(S_(2))content.The OM is predominantly typeⅠand typeⅡkerogens,indicating a high level of maturation in the wet gas period.These shales have undergone extensive hydrocarbon generation,showing characteristics of relatively poor PG;(3)the sedimentary environments of the Xidashan-Xishanbulake and Moheershan formations in the Tadong low uplift are similar.They were deposited in warm and humid climatic conditions,in oxygen-deficient environments,with stable terrigenous inputs,high paleoproductivity,high paleosalinity,weak water-holding capacity,and no significant hydrothermal activity;and(4)the relationship between TOC and the paleoproductivity parameter(P/Ti)is most significant in the Lower Cambrian Xidashan-Xishanbulake Fm.,whereas correlation with other indicators is not evident.This suggests a productivity-driven OM enrichment model,where input of landderived material was relatively small during the Middle Cambrian,and the ancient water exhibited lower salinity.A comprehensive pattern was formed under the combined control of paleoproductivity and preservation conditions.This study provides valuable guidance for oil and gas exploration in the Tarim Basin.
基金financially supported by the National Natural Science Foundation of China(Grant Nos.42030804 and 42330811)the“Deep-time Digital Earth”Science and Technology Leading Talents Team Funds for the Central Universities for the Frontiers Science Center for Deep-time Digital Earth,China University of Geosciences(Beijing)(Fundamental Research Funds for the Central UniversitiesGrant No.2652023001)。
文摘The Lower Cambrian shale gas in the western Hubei area,South China has a great resource prospect,but the gas-in-place(GIP)content in different sedimentary facies varies widely,and the relevant mechanism has been not well understood.In the present study,two sets of the Lower Cambrian shale samples from the Wells YD4 and YD5 in the western Hubei area,representing the deep-water shelf facies and shallowwater platform facies,respectively,were investigated on the differences of pore types,pore structure and methane adsorption capacity between them,and the main controlling factor and mechanism of their methane adsorption capacities and GIP contents were discussed.The results show that the organic matter(OM)pores in the YD4 shale samples are dominant,while the inorganic mineral(IM)pores in the YD5 shale samples are primary,with underdeveloped OM pores.The pore specific surface area(SSA)and pore volume(PV)of the YD4 shale samples are mainly from micropores and mesopores,respectively,while those of the YD5 shale samples are mainly from micropores and macropores,respectively.The methane adsorption capacity of the YD4 shale samples is significantly higher than that of the YD5 shale samples,with a maximum absolute adsorption capacity of 3.13 cm^(3)/g and 1.31 cm^(3)/g in average,respectively.Compared with the shallow-water platform shale,the deep-water shelf shale has a higher TOC content,a better kerogen type and more developed OM pores,which is the main mechanism for its higher adsorption capacity.The GIP content models based on two samples with a similar TOC content selected respectively from the Wells YD4 and YD5 further indicate that the GIP content of the deep-water shelf shale is mainly 34 m^(3)/t within a depth range of 1000—4000 m,with shale gas exploration and development potential,while the shallow-water platform shale has normally a GIP content of<1 m^(3)/t,with little shale gas potential.Considering the geological and geochemical conditions of shale gas formation and preservation,the deep-water shelf facies is the most favorable target for the Lower Cambrian shale gas exploration and development in the western Hubei area,South China.
文摘The Tongling area is one of the 7 ore-cluster areas in the Middle-Lower Yangtze metallogenic belt, East China, and has tectonically undergone a long-term geologic history from the late Paleozoic continental rifting, through the Middle Triassic continent-continent collision to the Jurassic-Cretaceous intracontinental tectono-magmatic activation. The Carboniferous sedimentary-exhalative processes in the area produced widespread massive sulfides with ages of 303-321 Ma, which partly formed massive pyrite-Cu deposits, but mostly provided significant sulfur and metals to the skarn Cu mineralization associated with the Yanshanian felsic intrusions.To understand the Carboniferous submarine hydrothermal system, an area of about 1046 km^2 was chosen to carry out the geological fluid mapping. Associated with massive sulfide formation, footwall sequences 948 m to 1146 m thick, composed of the Lower Silurian-Upper Devonian sandstone, siltstone and thin-layered shale, were widely altered. This hydrothermal alteration is interpreted to reflect largescale hydrothermal fluid flow associated with the late Paleozoic crustal rifting and subsidence. Three hydrothermal alteration types, i.e., deep-level semiconformable siliclfication （S1）, fracture-controlled quartz-sericite-pyrite alteration （S2-3）, and upper-level sub-discordant quartz-sericite-chlorite alteration （D3）, were developed to form distinct zones in the mapped area. About 50-m thick semiconformable silicification zones are located at -1-km depth below massive sulfides and developed between an impermeable shale caprock （S1） and the underlying Ordovician unaltered limestone. Comparisons with modern geothermal systems suggest that the alteration zones record a sub-seafioor aquifer with the most productive hydrothermal fluid flow. Fracture-controlled quartz-sericite-pyrite alteration formed transgressive zones, which downward crosscut the semiconformable alteration zones, and upwards grade into sub-discordant alteration zones that enveloped no economic stringer- stockwork zones beneath massive sulfides. This transgressive zone likely marks an upfiow path of high- flux fluids from the hydrothermal aquifer. Lateral zonation of the sub-discordant alteration zones and their relationship to overlying massive sulfide lenses suggest lateral flows and diffusive discharging of the hydrothermal fluids in a permeable sandstone sequence. Three large-sized, 14 middle-small massive sulfide deposits, and 40 massive sulfide sites have been mapped in detail. They show regional strata- bound characters and two major styles, i.e., the layered sheet plus strata-bound stringer-style and the mound-style. Associated exhalite and chemical sedimentary rock suites include （1） anhydrite-barite, （2） jasper-chert, （3） Mg-rich mudstone-pyrite shale, （4） barite lens, （5） siderite-Fe-bearing dolomite, and （6） Mn-rich shale-mudstone, which usually comprise three sulfide-exhalite cyclic units in the area.The spatial distribution of these alteration zones （minerals） and associated massive sulfdes and exhalites, and regional variation in δ^34S of hydrothermal pyrite and in δ^18O-δ^34C of hanging wall carbonates, suggest three WNW-extending domains of fluid flow, controlled by the basement faults and syn-depositional faults. Each fluid domain appears to have at least two upflow zones, with estimated even spacing of about 5-8 km in the mapped area. The repeated appearance of sulfide-sulfate or sulfide-carbonate rhythmic units in the area suggests episodically venting of fluids through the upfiow conduits by breaking the overlying seals of the hydrothermal aquifer.
基金supported by the National Department Public Benefit Research Foundation of China(grant no. 201211077)the Mineral Resources Investigation and Appraisal Project of the Ministry of Land and Resources (grant no.12120114001501)the Fundamental Research Funds for the Central Universities(grant no. 53200859557)
文摘In the East Asian monsoon region, eolian deposits widely distributed in the middle-lower reaches of the Yantgze River are among the best materials available for studies on Quaternary climate change in the subtropical zone of Southern China. Typical eolian deposits in this region include upper Xiashu Loess （XL） and underlying Vermiculated Red Soil （VRS） layers. In this paper, chronological and paleoclimatic studies are conducted on an eolian deposit sequence near Jiujiang （J J） city in northern Jiangxi province. A magnetostratigraphic study, combined with optically stimulated luminescence （OSL） dating, is conducted on the JJ section and provides further evidence that eolian deposits in the middle-lower reaches of the Yangtze River have been formed since the late Early Pleistocene, and that the boundary age between the XL and VRS layers is about 300-400 kaBP. In grain-size records of the JJ section, the median grain-size and content of the 〉30μn size fraction increase sharply after 300-400 kaBP, representing an East Asian winter monsoon intensification event. Further pollen analysis reveals differing pollen assemblages before and after 300-400 kaBP： there is an evident increase in plants adapted to grow in a warm humid environment after 300-400 kaBP, implying an increase in precipitation caused by intensification of the East Asian summer monsoon. Global ice volume and uplift of the Tibet Plateau （TP） are regarded as crucial factors influencing variations of the East Asian monsoon on a long-term scale. The deep-sea JlSO record, which reflects variations in global ice volume, shows no obvious change after 300-400 kaBP. Moreover, the influence of global ice volume changes on the East Asian summer and winter monsoons is inverse; the global ice volume increase （decrease） implies a strengthened （weakened） winter monsoon and weakened （strengthened） summer monsoon. We therefore interpret the coupled intensifications of the East Asian summer and winter monsoons at about 300-400 kaBP to the uplift of the TP in the Middle Pleistocene. This climate event is also documented in eolian deposits from the southern margin of the Chinese Loess Plateau （CLP） and from the desert-loess transitional belt. However, it is not recorded in the loess-paleosol sequences from the central part of the CLP, thereby indicating differing climate responses to TP uplift in different regions, which requires further study.
基金supported by geological survey projects of the China Geological Survey (1212011120863, 12120114039401, 12120114005901 and 12120115029401)
文摘The Tongshankou Cu-Mo deposit, located in southeast Hubei province, is a typical skarn–porphyry type ore deposit closely related to the Tongshankou granodiorite porphyry, characterized by a high Sr/Y ratio.Detailed in situ analyses of the trace elements and U–Pb and Lu–Hf isotopes in zircons from the Tongshankou granodiorite porphyry were performed.Scarcely any inherited zircons were observed, and the analyzed zircons yielded highly concordant results with a weighted mean 206Pb/238 U age of 143.5 ± 0.45 Ma（n=20, mean square weighted deviation was 0.75）, which was interpreted to represent the crystallization age of the Tongshankou granodiorite porphyry.The chondrite-normalized rare-earth element pattern was characterized by a slope that steeply rises from the light-group rare-earth elements（LREE） to the heavy-group rare-earth elements（HREE） with a positive Ce-anomaly and inconspicuous Eu-anomaly, which was coincident with the pattern of the zircons from the Chuquicamata West porphyry, Chile.The analyzed zircons also had relatively low 176Hf/177 Hf ratios of 0.282526–0.282604.Assuming t=143 Ma, the corresponding calculated initial Hf isotope compositions（εHf（t）） ranged from-5.6 to-2.9.The results of the in situ analysis of trace elements and U–Pb and Lu–Hf isotopes in zircons from the Tongshankou granodiorite porphyry suggest that a deep-seated process involving a thickened-crust/enriched-mantle interaction may play an important role in the generation of high Sr/Y-ratio magma and potentially in the generation of porphyry Cu-Mo systems.
文摘The middle-lower Yangtze area underwent a series of complex tectonic evolution, such as Hercynian extensional rifting, Indosinian foreland basining, and Yanshanian transpression-transtension, resulting in a large distinctive Cu-Fe-Au metallogenic belt. In the tectonic evolution, large-scale migration and convergence of fluids toward foreland basins induced during the collisional orogeny of the Yangtze and North China continental blocks were of vital importance for the formation of the metallogenic belt. Through geological surveys of the middle-lower Yangtze area, three lines of evidence of large-scale fluid migration are proposed: (1) The extensive dolomitic and silicic alteration penetrating Cambrian-Triassic strata generally occurs in a region sandwiched between the metallogenic belt along the Yangtze River and the Dabie orogenic belt, and in the alteration domain alternately strong and weak alteration zones extend in a NW direction and are controlled by the fault system of the Dabie orogenic belt; it might record the locus of the activities of long-distance migrating fluids. (2) The textures and structures of very thick Middle-Lower Triassic anhydrock sequences in restricted basins along the river reveal the important contribution of the convergence of regional hot brine in restricted basins and the chemical deposition or their formation. (3) Early-Middle Triassic syndepositional iron carbonate sequences and Fe-Cu-Pb-Zn massive sulfide deposits alternate with anhydrock sequences or are separated from the latter, but all of them occur in the same stratigraphic horizon and are intimately associated with each other, being the product of syndeposition of high-salinity hot brine. According to the geological surveys, combined with previous data, the authors propose a conceptual model of fluid migration-convergence and mineralization during the Dabie collisional orogeny.
基金supported financially by the National Natural Science Foundation of China(grant 41302062)the Fundamental Research Funds for the Central Universities(grant 2652015053,2011YYL125)the China Geological Survey(grant 12120113069900)
文摘The Datuanshan deposit is one of the largest and most representative stratabound copper deposits in the Tongling area,the largest ore district in the Middle-Lower Yangtze River metallogenic belt.The location of the orebodies is controlled by the interlayer-slipping faults between the Triassic and Permian strata,and all the orebodies are distributed in stratiform shape around the Mesozoic quartz monzodiorite dikes.Based on field evidence and petrographic observations,four mineralization stages in the Datuanshan deposit have been identified：the skarn,early quartz-sulfide,late quartzsulfide and carbonate stages.Chalcopytite is the main copper mineral and mainly formed at the late quartz-sulfide stage.Fluid inclusions at different stages were studied for petrography,microthermometry,laser Raman spectrometry and stable isotopes.Four types of fluid inclusions,including three-phase fluid inclusions（type 1）,liquid-rich fluid inclusions（type 2）,vapour-rich fluid inclusions（type 3） and pure vapour fluid inclusions（type 4）,were observed.The minerals from the skarn,early and late quartz-sulfide stages contain all fluid inclusion types,but only type 2 fluid inclusions were observed at the carbonate stage.Petrographic observations suggest that most of the inclusions studied in this paper are likely primary.The coexistence of different types of fluid inclusions with contrasting homogenization characteristics（to the liquid and vapour phase,respectively） and similar homogenization temperatures（the modes are 440-480℃,380-400℃ and 280-320℃ for the skarn,early and late quartz-sulfide stages,respectively） in the first three stages,strongly suggests that three episodes of fluid boiling occurred during these stages,which is supported by the hydrogen isotope data.Laser Raman spectra identified CH_4 at the skarn and early quartz-sulfide stages.Combined with other geological features,the early ore-forming fluids were inferred to be under a relatively reduced environment.The CO_2 component has been identified at the late quartz-sulfide and carbonate stages,indicating that the late ore-forming fluids were under a relatively oxidized environment,probably as a result of inflow of and mixing with meteoric water.In addition,microthermometric results of fluid inclusions and H-O isotope data mdicate that the ore forming fluids were dominated by magmatic water in the early stages（skarn and early quartz-sulfide stages） and mixed with meteoric water in the late stages（late quartz-sulfide and carbonate stages）.The evidence listed above suggests that the chalcopyrite deposition in the Datuanshan deposit probably resulted from the combination of multiepisode fluid boiling and mixing of magmatic and meteoric water.
基金supported by the National Key Research and Development Program of China(No.2018YFC1407 601)the National Natural Science Foundation of China(No.41176064)
文摘In order to examine the impacts of water-sediment regulation on regional carbon cycling,we collected water,particulate and sediment samples from the middle-lower Yellow River in late June and early July,2015 and analyzed their specific amino acids(AA),DOC,POC,and bacteria abundance.Summarized by 14 specific AA,the total hydrolysable AA(THAA),particulate AA(PAA),and sediment AA(SAA)varied in ranges of 2.29-9.05μmol L^-1,5.22-22.96μmol L^-1,and 81.7-137.19μg g^-1 dry weight.After the regulation,dissolved free AA(DFAA)decreased by 29%while DCAA increased by 72%.These variations suggested that DFAA were further degraded,while DCAA molecules were further activated.Meanwhile,PAA increased almost 4 times as many as those before regulation,and SAA increased as well.After regulation,the amounts of bioactive amino acids(Asp,Glu and Gly)increased in THAA but decreased in PAA,with little changes in SAA.The ratios of Asp/Gly in different phases increased after regulation,indicating the AA contributions were promoted by calcareous organisms rather than by siliceous organisms.Multiple correlation analysis showed that PAA was primary representatives of AA and organic carbon,followed by DCAA and POC.Moreover,bacterial reproduction played a key role in shaping the AA compositions and properties,followed by the redox condition and acid-base balance.The results of this study provided a clear evidence for the effects of water-sediment regulation on regional biogeochemistry of organic carbon in the middle-lower Yellow River.
基金funded by grants from the National Key Research and Development Program(2016YFC0600206)the National Natural Science Foundation of China(41872081)+1 种基金the Doctoral initial funding project of Anhui Jianzhu University(2019QDZ33)the Anhui Province Science and Technology Plan Project for Housing Urban-rural Construction(2020-YF35)。
文摘The Middle-Lower Yangtze River Metallogenic Belt(MLYB)is known to contain abundant copper and iron porphyry-skarn deposits,with an increasing number of tungsten deposits and scheelite in Fe-Cu deposits being discovered in the MLYB during recent decades.The ore genesis of the newly-discovered tungsten mineralization in the MLYB is poorly understood.We investigate four sets of scheelite samples from tungsten,iron and copper deposits,using CL imaging and LA-ICP-MS techniques to reveal internal zonation patterns and trace element compositions.The REE distribution patterns of four studied deposits show varying degrees of LREE enrichment with negative Eu anomalies.The oxygen fugacity of ore-forming fluid increased in Donggushan,while the oxygen fugacity of ore-forming fluid decreased in Ruanjiawan,Guilinzheng and Gaojiabang.The scheelites from the Donggushan,Ruanjiawan,Guilinzheng and Gaojiabang deposits show enrichment in LREEs and HFSE,with Nb/La ratios ranging from 1.217 to 52.455,indicating that the four tungsten deposits are enriched in the volatile fluorine.A plot of(La/Lu)N versus Mo/δEu can be used to distinguish quartz vein type,porphyry and skarn tungsten deposits.This study demonstrates that scheelite grains can be used to infer tungsten mineralization and are effective in identifying magmatic types of tungsten deposits in prospective mining sites.
基金supported by the National Science Foundation of China(grants No.41372090 and 41573042)the National Special Research Programs for Non-Profit Trades (grant No.201311136)Basic Scientific Research Operation Cost of State-Leveled Public Welfare Scientific Research Courtyard(grant No.K1203)
文摘Thallium has been used geochemical exploration of gold deposits. However, as an indicator element in searching for hydrothermal the T1 minerals and mineralization are rare in nature. Lorandite T1AsS2, a relatively uncommon mineral, has been dominantly discovered in some Carlin gold deposits, and minor Sb- Hg, U and Pb-Zn-Ag deposits.
基金financially supported by funds from the National Key R&D Program of China(Grant Nos.2016YFC0600209,2016YFC0600206)the National Natural Science Foundation of China(Grant No.41820104007)+1 种基金the Scientific and Technological Program of Land and Resources of Anhui province(Grant No.2016-K-4)the China Scholarship Council(Grant No.201906690036)。
文摘The Magushan skarn Cu-Mo deposit is a representative example of the skarn mineralization occurring within the Xuancheng ore district of the Middle-Lower Yangtze River Metallogenic Belt of eastern China.The precise age of an ore deposit is important for understanding the timing of mineralization relative to other geological events in a region and to fully place the formation of a mineral deposit within the geological context of other processes that occur within the study area.Here,we present new molybdenite Re-Os and titanite and andradite garnet U-Pb ages for the Magushan deposit and use these data to outline possible approaches for identifying genetic relationships in geologically complex areas.The spatial and paragenetic relationships between the intrusions,alteration,and mineralization within the study area indicates that the formation of the Magushan deposit is genetically associated with the porphyritic granodiorite.However,this is not always the case,as some areas contain complexly zoned plutons with multiple phases of intrusion or mineralization may be distal from or may not have any clear spatial relationship to a pluton.This means that it may not be possible to determine whether the mineralization formed as a result of single or multiple magmatic/hydrothermal events.As such,the approaches presented in this study provide an approach that allows the identification of any geochronological relationships between mineralization and intrusive events in areas more complex than the study area.Previously published zircon U-Pb data for the mineralization-related porphyritic granodiorite in this area yielded an age of 134.2±1.2 Ma(MSWD=1.4)whereas the Re-Os dating of molybdenite from the study area yielded an isochron age of 137.7±2.5 Ma(MSWD=0.43).The timing of the mineralizing event in the study area was further examined by the dating of magmatic accessory titanite and skarn-related andradite garnet,yielding U-Pb ages of 136.3±2.5 Ma(MSWD=3.2)and 135.9±2.7 Ma(MSWD=2.5),respectively.The dating of magmatic and hydrothermal activity within the Magushan area yields ages around 136 Ma,strongly suggesting that the mineralization in this area formed as a result of the emplacement of the intrusion.The dates presented in this study also provide the first indication of the timing of mineralization within the Xuancheng district.providing evidence of a close genetic relationship between the formation of the mineralization within the Xuancheng district and the Early Cretaceous magmatism that occurred in this area.This in turn suggests that other Early Cretaceous intrusive rocks within this region are likely to be associated with mineralization and should be considered highly prospective for future mineral exploration.This study also indicates that the dating of garnet and titanite can also provide reliable geochronological data and evidence of the timing of mineralization and magmatism,respectively,in areas lacking other dateable minerals(e.g.,molybdenite)or where the relationship between mineralization and magmatism is unclear,for example in areas with multiple stages of magmatism,with complexly zoned plutons,and with distal skarn mineralization.
基金Supported by the PetroChina Science and Technology Project (2021DJ0605,2022KT0101)the CNPC Major Science and Technology Project (2021DJ0501)。
文摘Based on the latest drilling, seismic and field outcrop data, the geological characteristics(e.g. strata, development and sedimentary evolution) of the southern segment of the Late Sinian–Early Cambrian Deyang–Anyue rift trough in the Sichuan Basin are analyzed. First, the strata in the southern segment are complete. The first to second members of Dengying Formation(Deng 1 + Deng 2) are found with relatively stable thickness(400–550 m), and the third to fourth members(Deng 3+ Deng 4) show great thickness difference between the marginal trough and the inner trough, which is up to 250 m. The Cambrian Maidiping Formation and Qiongzhusi Formation in southern Sichuan Basin are relatively thin, with the thickness changing greatly and frequently. Second, the Deyang–Anyue rift trough extended southward during the Deng 4 period, affecting southern Sichuan Basin. Compared to the middle and northern segments of the rift trough, the southern segment is generally wide, gentle and shallow, with multiple steps, and alternating uplifts and sags, which are distributed in finger shape. Third, the Deng 1 + Deng 2 in southern Sichuan Basin records the dominance of carbonate platform and unobvious sedimentary differentiation, and the Deng 4 exhibits obvious sedimentary differentiation, namely, basin–slope–secondary slope–slope–secondary slope–platform margin–restricted platform, from the inner trough to the marginal trough. Fourth, the rift trough in southern Sichuan Basin has evolved in four stages: stabilization of Deng 1–Deng 2, initialization of Deng 3–Deng 4, filling of Maidiping–Qiongzhusi, and extinction of Canglangpu Formation.
文摘The building of Shuikou Hydropower Station in the Minjiang River is the largest one in the region of east China. Its install capacity is 1.4 million kw., and its generated energy of planning is 4.95 billion kwh each year. In accordance with a comprehensive survey of the valley of the middle-lower reaches of the Minjiang River and the characteristic of hydrography and in association with the specific type of the hydrography station, we can be sure that no harm will be done to the ecological environment when a hydropower station is built at Shuikou. Not only the deposition of silt within the reservoir must not be very serious, it is also more favorable than before for the irrigation of farmland on plains in the lower reaches of the Minjiang River and inland navigation.In addition, after the completion of the power station, the ecological environment will be the same as before both at the Minjiang River estuary and beyond it.
文摘The evaluation method, model and process for the flood and waterlogging disaster condition by GIS,RS and GPS technology and the method for setting up disaster condition database, dyke database and historical disaster damage database are presented. An index of flood damage degree(FDD) used to evaluate the relative degree of disaster loss and divide flood and waterlogging area is suggested. The value of flood damage degree can be calculated as follows :taking the various disaster losses of sample area in a base year as standard value and computing the ratios of various disaster loss values in different areas and years to the standard flood disaster loss values, then summing up the weighted ratios. The computed results are the value of flood damage degree in the every year. The macroscopic flood disaster distribution can be evaluated by the values of flood loss degree.
基金supported by the National Key R&D Program of China grant(2017YFC0603105).
文摘The Xixiangchi Group in eastern Sichuan Basin has great potential for natural gas exploration.However,there is a lack of in-depth studies of the hydrocarbon sources and the formation and evolution of gas reservoirs in this Group.Systematic investigation about the gas reservoir in Pingqiao anticline was consequently carried out in terms of characteristics of reservoir bitumen,the geochemical characteristics of natural gas,diagenetic minerals,and fluid inclusions.Based on this,combined with the reconstruction of the burial history,thermal evolution history and uplifting history of strata,and analysis of the regional tectonic settings,the hydrocarbon sources were identified and the formation and evolutionary processes of the gas reservoirs in Xixiangchi Group was revealed in this study.It was shown that the gas reservoirs have mixed gas sources from the shale source rocks in the Lower Cambrian Qiongzhusi Formation and in the Upper Ordovician Wufeng Formation-Lower Silurian Longmaxi Formation,and experienced several evolutionary stages,including the paleo-oil reservoir stage from the Late Siliurian to the Middle Permian,the paleo-gas reservoir stage from the Late Permian to the Early Cretaceous,and the superimposed accumulation and mixed-source gas reservoir stage since the Late Cretaceous.The mixed-source gas reservoir is formed by the adjustment of the Xixiangchi Group paleo-gas reservoirs and depressurization of the overpressure Wufeng-Longmaxi shale gas reservoirs and the charging of gas into the Xixiangchi Group reservoir of the Pingqiao anticline since the Late Cretaceous,which show obvious superimposed accumulation characteristics.There are different accumulation patterns in different geological periods.The accumulation pattern of the“old source-young reservoir”(i.e.hydrocarbons generated from older source rocks accumulating in younger reservoirs)dominates before the Late Cretaceous,and that of“juxtaposed young source-old reservoir”(i.e.hydrocarbons generated from younger source rocks accumulating in juxtaposed older reservoirs)dominates after the Early Cretaceous.Moreover,faults acted as critical vertical pathways for hydrocarbon migration during the evolution of the Xixiangchi Group gas reservoirs.This model provides new insights and theoretical basis for evaluation and mapping of the Xixiangchi Group play fairway in eastern Sichuan Basin.
文摘Under the tectonodynamic process, crustal materials tend to experience two modes of adjustment: (1) structural (physical) adjustment, manifested by folding, faulting, uplifting, downwarping, etc.: (2) compositional adjustment, represented by element migration, concentration and dispersion, crystalline and dynamic differentiation of crystals, metamorphism, etc. (Yang Kaiqing. 1986; Yang Kaiqing et al., 1986). The dynamic adjustment of crustal materials in the middle-lower reaches of the Yangtze mainly occurred in the Mesozoic under the conditions of intense collision between the North China (Dabie) massif and the Yangtze massif. The structural adjustment refers to various types of deformation within the two massifs and the intensive shortening of the stratigraphic coyer of the Yangtze massif, whereas the compositional adjustment implies the structural remelting of the basement and the ore. and rock- forming processes in the two massifs.
文摘Micromotion is the daily tiny vibration of the earth</span><span style="font-family:Verdana;">’</span><span style="font-family:Verdana;">s surface. Micromotional exploration can use the surface wave information of micro motion to study the shallow structure of underground media. In this study, we collected microtremor data at 68 stations in the Middle-Lower Yangtze Metallogenic Belt (MLYMB) and determined the resonant frequency and obtained the distribution of sedimentary thickness in this area by using H/V spectral ratio. According to the results of H/V, the sedimentary layer in the basin is thick, and the predominant frequency of the basin is 0.05</span><span style="font-family:""> </span><span style="font-family:Verdana;">-</span><span style="font-family:""> </span><span style="font-family:Verdana;">0.1</span><span style="font-family:""> </span><span style="font-family:Verdana;">Hz. There are no obvious lateral changes in the impedance interface between bedrock and sedimentary layer in this area. The basement of Tongling, Anqing and Luzhou mining areas and their adjacent areas is Kongling-Dongling type basement, which is composed of a set of metamorphic core complex. The predominant frequency is 0.05</span><span style="font-family:""> </span><span style="font-family:Verdana;">-</span><span style="font-family:""> </span><span style="font-family:Verdana;">0.1</span><span style="font-family:""> </span><span style="font-family:Verdana;">Hz. The sedimentary thickness gradually thinned from 3800</span><span style="font-family:""> </span><span style="font-family:Verdana;">m in the west to 2100</span><span style="font-family:""> </span><span style="font-family:Verdana;">m in the East. Moreover, this article used SPAC (spatial autocorrelation) method to obtain the S-wave velocity structure of the mining area near Luzong. The SPAC method reveals that the depth of the interface between the loose sediments and the volcanic rocks is about 600 m in the study area near the Luzhou mining area in the Middle-Lower Yangtze Metallogenic Belt, and the average depth of the interface between the volcanic rock section and the intrusive complex section is about 1000</span><span style="font-family:""> </span><span style="font-family:Verdana;">m. The thickness of the intrusive rock is more than 2500</span><span style="font-family:""> </span><span style="font-family:Verdana;">m. Tourmaline is developed in the interior of the intrusive rock, which may have better exploration value.
