Lithium-oxygen batteries(LOBs)with high energy density are a promising advanced energy storage technology.However,the slow cathodic redox kinetics during cycling causes the discharge products to fail to decompose in t...Lithium-oxygen batteries(LOBs)with high energy density are a promising advanced energy storage technology.However,the slow cathodic redox kinetics during cycling causes the discharge products to fail to decompose in time,resulting in large polarization and battery failure in a short time.Therefore,a self-supporting interconnected nanosheet array network NiCo_(2)O_(4)/MnO_(2)with a Mott-Schottky heterostructure on titanium paper(TP-NCO/MO)is ingeniously designed as an efficient cathode catalyst material for LOBs.This heterostructure can accelerate electron transfer and influence the charge transfer process during adsorption of intermediate by triggering the interface disturbance at the heterogeneous interface,thus accelerating oxygen reduction and oxygen evolution kinetics and regulating product decomposition,which is expected to solve the above problems.The meticulously designed unique structural advantages enable the TP-NCO/MO cathode catalyst to exhibit an astounding ultra-long cycle life of 800 cycles and an extraordinarily low overpotential of 0.73 V.This study utilizes a simple method to cleverly regulate the morphology of the discharge products by constructing a Mott-Schottky heterostructure,providing important reference for the design of efficient catalysts aimed at optimizing the adsorption of reaction intermediates.展开更多
The disparity in the transfer of carriers(electrons/mass)during the reaction in zinc-air batteries(ZABs)results in sluggish kinetics of the oxygen reduction reaction(ORR)and oxygen evolution reaction(OER),along with e...The disparity in the transfer of carriers(electrons/mass)during the reaction in zinc-air batteries(ZABs)results in sluggish kinetics of the oxygen reduction reaction(ORR)and oxygen evolution reaction(OER),along with elevated overpotentials,thereby imposing additional constraints on its utilization.Therefore,the pre-design and target-development of inexpensive,high-performance,and long-term stable bifunctional catalysts are urgently needed.In this work,an apically guiding dual-functional electrocatalyst(Ag-FeN_(x)-N-C)was prepared,in which a hierarchical porous nitrogen-doped carbon with three-dimensional(3D)hollow star-shaped structure is used as a substrate and high-conductivity Ag nanoparticles are coupled with iron nitride(FeN_(x))nanoparticles.Theoretical calculations indicate that the Mott-Schottky heterojunction as an inherent electric field comes from the two-phase bound of Ag and FeN_(x),of which electron accumulation in the FeN_(x)phase region and electron depletion in the Ag phase region promote orientated-guiding charge migration.The effective modulation of local electronic structures felicitously reforms the d-band electron-group distribution,and intellectually tunes the masstransfer reaction energy barriers for both ORR/OER.Additionally,the hollow star-s haped hierarchical porous structure provides an apical region for fast mass transfer.Experimental results show that the halfwave potential for ORR is 0.914 V,and the overpotential for OER is only 327 mV at 10 mA cm^(-2).A rechargeable ZAB with Ag-FeN_(x)-N-C as the air cathode demonstrates long-term cycling performance exceeding 1500 cycles(500 h),with a power density of 180 mW cm^(-2).Moreover,when employing AgFeN_(x)-N-C as the air cathode,flexible ZABs demonstrate a notable open-circuit voltage of 1.42 V and achieve a maximum power density of 65.6 mW cm^(-2).Ag-FeN_(x)-N-C shows guiding electron/mass transfer route and apical reaction microenvironment for the electrocatalyst architecture in the exploration prospects of ZABs.展开更多
The supercapacitor electrode materials suffer from structure pulverization and sluggish electrode kinetics under high current rates.Herein,a unique NiMoO_(4)@Co-B heterostructure composed of highly conductive Co-B nan...The supercapacitor electrode materials suffer from structure pulverization and sluggish electrode kinetics under high current rates.Herein,a unique NiMoO_(4)@Co-B heterostructure composed of highly conductive Co-B nanoflakes and a semiconductive NiMoO_(4) nanorod is designed as an electrode material to exert the energy storage effect on supercapacitors.The formed Mott-Schottky heterostructure is helpful to overcome the ion diffusion barrier and charge transfer resistance during charging and discharging.Moreover,this crystalline-amorphous heterogeneous phase could provide additional ion storage sites and better strain adaptability.Remarkably,the optimized NiMoO_(4)@Co-B hierarchical nanorods(the mass ratio of NiMoO_(4)/Co-B is 3:1)present greatly enhanced electrochemical characteristics compared with other components,and show superior specific capacity of 236.2 mA h g^(-1)at the current density of 0.5 A g^(-1),as well as remarked rate capability.The present work broadens the horizons of advanced electrode design with distinct heterogeneous interface in other energy storage and conversion field.展开更多
Recognition of pulse repetition interval(PRI)modulation is a fundamental task in the interpretation of radar intentions.However,the existing PRI modulation recognition methods mainly focus on single-label classificati...Recognition of pulse repetition interval(PRI)modulation is a fundamental task in the interpretation of radar intentions.However,the existing PRI modulation recognition methods mainly focus on single-label classification of PRI sequences.The prerequisite for the effectiveness of these methods is that the PRI sequences are perfectly divided according to different modulation types before identification,while the actual situation is that radar pulses reach the receiver continuously,and there is no completely reliable method to achieve this division in the case of non-cooperative reception.Based on the above actual needs,this paper implements an algorithm based on the recurrence plot technique and the multi-target detection model,which does not need to divide the PRI sequence in advance.Compared with the sliding window method,it can more effectively realize the recognition of the dynamically varying PRI mo dulation.展开更多
Fractional factorial split-plot design has been widely used in many fields due to its advantage of saving experimental cost. The general minimum lower order confounding criterion is usually used as one of the attracti...Fractional factorial split-plot design has been widely used in many fields due to its advantage of saving experimental cost. The general minimum lower order confounding criterion is usually used as one of the attractive design criterion for selecting fractional factorial split-plot design. In this paper, we are interested in the theoretical construction methods of the optimal fractional factorial split-plot designs under the general minimum lower order confounding criterion. We present the theoretical construction methods of optimal fractional factorial split-plot designs under general minimum lower order confounding criterion under several conditions.展开更多
中国生态系统研究网络(Chinese Ecosystem Research Network,CERN)生物长期样地背景和植被分类特征本底数据集是22个CERN自然生态系统生态站95个长期样地的本底数据的综合集成。基于对CERN生态站长期样地地理位置、建立时间、面积、样...中国生态系统研究网络(Chinese Ecosystem Research Network,CERN)生物长期样地背景和植被分类特征本底数据集是22个CERN自然生态系统生态站95个长期样地的本底数据的综合集成。基于对CERN生态站长期样地地理位置、建立时间、面积、样地代表性等背景信息的梳理,依据样地建立之初的植物群落调查数据,参照最新的中国植被分类系统,对每个样地植物群落所属的植被型组、植被型、植被亚型进行了明确划分,并依据每个样地的优势种名单,对样地植被所属群系和群丛进行了鉴定和命名。本数据集构建通过了多轮的专家审核-台站核查-专家复审-台站接受等过程,包含生态站代码、生态站名称、样地代码、样地名称、样地类别、样地代表性、地理位置、海拔高度、样地面积及形状、样地建立时间和设计使用年数、植被型组、植被型、植被亚型、群系、群丛、优势种等信息。本数据集可以为植物区系、植被资源分布、生物多样性保护等方面的研究提供基础数据支持。展开更多
基金the financial support from the National Natural Science Foundation of China (grant nos. 51971184 and 51931006)the Natural Science Foundation of Fujian Province of China (no. 2023J01033)+1 种基金the Fundamental Research Funds for the Central Universities of China (Xiamen University: no. 20 720 200 068)the “Double First Class” Foundation of Materials Intelligent Manufacturing Discipline of Xiamen University
文摘Lithium-oxygen batteries(LOBs)with high energy density are a promising advanced energy storage technology.However,the slow cathodic redox kinetics during cycling causes the discharge products to fail to decompose in time,resulting in large polarization and battery failure in a short time.Therefore,a self-supporting interconnected nanosheet array network NiCo_(2)O_(4)/MnO_(2)with a Mott-Schottky heterostructure on titanium paper(TP-NCO/MO)is ingeniously designed as an efficient cathode catalyst material for LOBs.This heterostructure can accelerate electron transfer and influence the charge transfer process during adsorption of intermediate by triggering the interface disturbance at the heterogeneous interface,thus accelerating oxygen reduction and oxygen evolution kinetics and regulating product decomposition,which is expected to solve the above problems.The meticulously designed unique structural advantages enable the TP-NCO/MO cathode catalyst to exhibit an astounding ultra-long cycle life of 800 cycles and an extraordinarily low overpotential of 0.73 V.This study utilizes a simple method to cleverly regulate the morphology of the discharge products by constructing a Mott-Schottky heterostructure,providing important reference for the design of efficient catalysts aimed at optimizing the adsorption of reaction intermediates.
基金the financial support of the National Natural Science Foundation of China(52002079,22378074,22179025 and U20A20340)the Guangdong Basic and Applied Basic Research Foundation(2022A1515140085)+2 种基金the Research Fund Program of Guangdong Provincial Key Laboratory of Fuel Cell Technology(FC202209)the Guangzhou Hongmian Project(HMJH-20200012)the Foshan Introducing Innovative and Entrepreneurial Teams(1920001000108)。
文摘The disparity in the transfer of carriers(electrons/mass)during the reaction in zinc-air batteries(ZABs)results in sluggish kinetics of the oxygen reduction reaction(ORR)and oxygen evolution reaction(OER),along with elevated overpotentials,thereby imposing additional constraints on its utilization.Therefore,the pre-design and target-development of inexpensive,high-performance,and long-term stable bifunctional catalysts are urgently needed.In this work,an apically guiding dual-functional electrocatalyst(Ag-FeN_(x)-N-C)was prepared,in which a hierarchical porous nitrogen-doped carbon with three-dimensional(3D)hollow star-shaped structure is used as a substrate and high-conductivity Ag nanoparticles are coupled with iron nitride(FeN_(x))nanoparticles.Theoretical calculations indicate that the Mott-Schottky heterojunction as an inherent electric field comes from the two-phase bound of Ag and FeN_(x),of which electron accumulation in the FeN_(x)phase region and electron depletion in the Ag phase region promote orientated-guiding charge migration.The effective modulation of local electronic structures felicitously reforms the d-band electron-group distribution,and intellectually tunes the masstransfer reaction energy barriers for both ORR/OER.Additionally,the hollow star-s haped hierarchical porous structure provides an apical region for fast mass transfer.Experimental results show that the halfwave potential for ORR is 0.914 V,and the overpotential for OER is only 327 mV at 10 mA cm^(-2).A rechargeable ZAB with Ag-FeN_(x)-N-C as the air cathode demonstrates long-term cycling performance exceeding 1500 cycles(500 h),with a power density of 180 mW cm^(-2).Moreover,when employing AgFeN_(x)-N-C as the air cathode,flexible ZABs demonstrate a notable open-circuit voltage of 1.42 V and achieve a maximum power density of 65.6 mW cm^(-2).Ag-FeN_(x)-N-C shows guiding electron/mass transfer route and apical reaction microenvironment for the electrocatalyst architecture in the exploration prospects of ZABs.
基金supported by the National Natural Science Foundation of China(52261040,51971104)the Outstanding Postgraduate Innovation Star Project of Gansu Provincial Department of Education(2022CXZX-383)。
文摘The supercapacitor electrode materials suffer from structure pulverization and sluggish electrode kinetics under high current rates.Herein,a unique NiMoO_(4)@Co-B heterostructure composed of highly conductive Co-B nanoflakes and a semiconductive NiMoO_(4) nanorod is designed as an electrode material to exert the energy storage effect on supercapacitors.The formed Mott-Schottky heterostructure is helpful to overcome the ion diffusion barrier and charge transfer resistance during charging and discharging.Moreover,this crystalline-amorphous heterogeneous phase could provide additional ion storage sites and better strain adaptability.Remarkably,the optimized NiMoO_(4)@Co-B hierarchical nanorods(the mass ratio of NiMoO_(4)/Co-B is 3:1)present greatly enhanced electrochemical characteristics compared with other components,and show superior specific capacity of 236.2 mA h g^(-1)at the current density of 0.5 A g^(-1),as well as remarked rate capability.The present work broadens the horizons of advanced electrode design with distinct heterogeneous interface in other energy storage and conversion field.
基金supported by the National Defense Science and Technology Outstanding Youth Science Fund Project(2018-JCJQ-ZQ-023)the Hunan Provincial Natural Science Foundation of Innovation Research Group Project(2019JJ10004)。
文摘Recognition of pulse repetition interval(PRI)modulation is a fundamental task in the interpretation of radar intentions.However,the existing PRI modulation recognition methods mainly focus on single-label classification of PRI sequences.The prerequisite for the effectiveness of these methods is that the PRI sequences are perfectly divided according to different modulation types before identification,while the actual situation is that radar pulses reach the receiver continuously,and there is no completely reliable method to achieve this division in the case of non-cooperative reception.Based on the above actual needs,this paper implements an algorithm based on the recurrence plot technique and the multi-target detection model,which does not need to divide the PRI sequence in advance.Compared with the sliding window method,it can more effectively realize the recognition of the dynamically varying PRI mo dulation.
文摘Fractional factorial split-plot design has been widely used in many fields due to its advantage of saving experimental cost. The general minimum lower order confounding criterion is usually used as one of the attractive design criterion for selecting fractional factorial split-plot design. In this paper, we are interested in the theoretical construction methods of the optimal fractional factorial split-plot designs under the general minimum lower order confounding criterion. We present the theoretical construction methods of optimal fractional factorial split-plot designs under general minimum lower order confounding criterion under several conditions.
文摘中国生态系统研究网络(Chinese Ecosystem Research Network,CERN)生物长期样地背景和植被分类特征本底数据集是22个CERN自然生态系统生态站95个长期样地的本底数据的综合集成。基于对CERN生态站长期样地地理位置、建立时间、面积、样地代表性等背景信息的梳理,依据样地建立之初的植物群落调查数据,参照最新的中国植被分类系统,对每个样地植物群落所属的植被型组、植被型、植被亚型进行了明确划分,并依据每个样地的优势种名单,对样地植被所属群系和群丛进行了鉴定和命名。本数据集构建通过了多轮的专家审核-台站核查-专家复审-台站接受等过程,包含生态站代码、生态站名称、样地代码、样地名称、样地类别、样地代表性、地理位置、海拔高度、样地面积及形状、样地建立时间和设计使用年数、植被型组、植被型、植被亚型、群系、群丛、优势种等信息。本数据集可以为植物区系、植被资源分布、生物多样性保护等方面的研究提供基础数据支持。
