To clarify the transformation mechanism of secondary phase and the mechanism of intergranular corrosion in laser welding Ni-based alloy (Hastelloy C-276)/304 stainless steel with filler wire,the secondary phase was an...To clarify the transformation mechanism of secondary phase and the mechanism of intergranular corrosion in laser welding Ni-based alloy (Hastelloy C-276)/304 stainless steel with filler wire,the secondary phase was analyzed by electron probe micro-analysis (EPMA) and transmission electron microscopy (TEM).The evaluation of intergranular corrosion resistance of the welded joints was conducted by double-loop electrochemical potentiokinetic reactivation(DL-EPR) method,and at the same time the chemical compositions of the corrosion surface were analyzed by energy-dispersive spectrometry (EDS).The results show that p phase has complete coherence relationship withμphase,and the coherent relationship is described as[001]p//■and[430]p//[0001]μ.Theμphase is rapidly transformed from p phase,which is the inhomogeneous phase transformation.The transformation of secondary phase will increase the susceptibility to intergranular corrosion.Therefore,the transformation of secondary phase should be avoided in the welding process.展开更多
Electron beam welding experiments of titanium alloy to stainless steel were carried out with different filler metals, such as Ni, V, and Cu. Microstructures of the joints were examined by optical microscopy, scanning ...Electron beam welding experiments of titanium alloy to stainless steel were carried out with different filler metals, such as Ni, V, and Cu. Microstructures of the joints were examined by optical microscopy, scanning electron microscopy and X-ray diffraction analysis. Mechanical properties of the joints were evaluated according to tensile strength and microhardness. As a result, influences of filler metals on microstructures and mechanical properties of electron beam welded titanium-stainless steel joints were discussed. The results showed that all the filler metals were helpful to restrain the Ti-Fe intermetallics. The welds with different filler metals were all characterized by solid solution and interfacial intermetallics. For each type of the filler metal, the type of solid solution and interfacial intermetallics depended on the metallurgical reactions between the filler metals and base metals. The interfacial intermetallics were Fe2Ti＋Ni3Ti＋NiTi2, TiFe, and Cu2Ti＋CuTi＋CuTi2 in the joints welded with Ni, V, and Cu filler metals, respectively. The tensile strengths of the joints were dependent on the hardness of the interfacial intermetallics. The joint welded with Ag filler metal had the highest tensile strength, which is about 310 MPa.展开更多
Laser welding with filler wire of AZ31 magnesium alloys is investigated using a CO2 laser experimental system. The effect of three different filler wires on the joint properties is researched. The results show that th...Laser welding with filler wire of AZ31 magnesium alloys is investigated using a CO2 laser experimental system. The effect of three different filler wires on the joint properties is researched. The results show that the weld appearance can be effectively improved when using laser welding with filler wire. The microhardness and tensile strength of joints are almost the same us those of the base metal when ER AZ31 or ER AZ61 wire is adopted. However, when the filler wire of ER 5356 aluminum alloy is used, the mechanical properties of flints become worse. For ER AZ31 and ER AZ61 filler wires, the microstructure of weld zone slws small dendrite grains. In comparison, for ER 5356 filler wire, the weld shows a structure of snowy dendrites and many intermetallic compounds and eutectic phases distribute in the dendrites. These intermetallic constituents with low melting point increase the tendency of hot crack and result in fiagile joint properties. Therefore, ER AZ31 and ER AZ61 wire are more suitable filler material than ER 5356 for CO2 laser welding of AZ31 magnesium alloys.展开更多
CO2 laser welding aluminum alloy with filler wire was studied. The results indicate that the problems in CO2 laser welding of Al alloy, such as bad appearance of weld, easily excessive penetration and low strength, ca...CO2 laser welding aluminum alloy with filler wire was studied. The results indicate that the problems in CO2 laser welding of Al alloy, such as bad appearance of weld, easily excessive penetration and low strength, can be improved effectively by using laser welding with filler wire, and the maximum tensile strength of weld can reach 94% for the base metal. It also can be found that, the linear energy have great influence on the microstructure and mechanical properties of the joint. As the heat input increases, the cellular fir-tree crystals in the weld zone become sparse and the form of tensile fracture transforms from gliding fracture to brittle fracture.展开更多
The Al-Cu-Li alloy is welded by using laser beam welding,and the welding wire ER4043 is used as filler metal. The microstructure and mechanical property of welded joints are systematically investigated. Microstructure...The Al-Cu-Li alloy is welded by using laser beam welding,and the welding wire ER4043 is used as filler metal. The microstructure and mechanical property of welded joints are systematically investigated. Microstructure analyses show that the fusion zone is mainly composed of α-Al matrix phase and some strengthening phases including T,δ’,θ’,β’ and T1,etc. During welding,the weld formation and joint quality are obviously improved by the addition of Al-Si filler wire. The measurements of mechanical property indicate that,compared with that of the base metal(BM), the microhardness in the weld zone is decreased to a certain extent. Under the appropriate welding parameters,the tensile strength of welded joint reaches 369.4 MPa,which is 67.8% of that of the BM. There are many dimples on the joint fracture surface,and it mainly presents the fracture characteristic of dimple aggregation.展开更多
Repair welding of AA 6082-T6 joints was carried out using ER 4043 filler through the TIG welding process with or without pulsed current.Microstructure and mechanical characteristics of the joints before and after repa...Repair welding of AA 6082-T6 joints was carried out using ER 4043 filler through the TIG welding process with or without pulsed current.Microstructure and mechanical characteristics of the joints before and after repairing were investigated by examining macrostructure,microstructure,and distributions of porosity in the weld metal(WM),and by hardness,tensile,and bending tests.We observed that the welding current,phase transformations in heat-affected zone(HAZ)and porosity introduced in the WM during welding influence on its mechanical properties in sequence.The experimental results showed that the bead width and penetration as well as size of pores in the joints were mainly influenced by the welding currents.The sound joints were obtained at a welding current of 140 A with or without pulsed current when welding speed and gas flow rate were set at 20 cm·min-1 and 15 L·min-1,respectively.Among them,the decrease in mechanical properties of repair weld(RW)was directly related to the phase transformations in the over-ageing zone due to the double welding thermal cycles and elevated distribution of porosity in the WM.In addition,it was observed that the comparatively smaller grain size and lower porosity in WM of the RW produced by pulsed TIG welding gave a positive effect on its mechanical properties.展开更多
The influence of brazing temperature and brazing time on the microstructure and shear strength ofγ-TiAl/GH536 joints brazed with Ti-Zr-Cu-Ni-Fe-Co-Mo filler was investigated using SEM,EDS,XRD and universal testing ma...The influence of brazing temperature and brazing time on the microstructure and shear strength ofγ-TiAl/GH536 joints brazed with Ti-Zr-Cu-Ni-Fe-Co-Mo filler was investigated using SEM,EDS,XRD and universal testing machine.Results show that all the brazed joints mainly consist of four reaction layers regardless of the brazing temperature and brazing time.The thickness of the brazed seam and the average shear strength of the joint increase firstly and then decrease with brazing temperature in the range of 1090-1170℃and brazing time varying from 0 to 20 min.The maximum shear strength of 262 MPa is obtained at 1150℃for 10 min.The brittle Al3NiTi2 and TiNi3 intermetallics are the main controlling factors for the crack generation and deterioration of joint strength.The fracture surface is characterized as typical cleavage fracture and it mainly consists of massive brittle Al3NiTi2 intermetallics.展开更多
In the present work, the dissimilar joining of a Ti3Al-based alloy to a Ni-based superalloy was attempted by gas tungsten arc （GTA） welding technology. Sound joints were successfully achieved by using a Cu-Ni alloy ...In the present work, the dissimilar joining of a Ti3Al-based alloy to a Ni-based superalloy was attempted by gas tungsten arc （GTA） welding technology. Sound joints were successfully achieved by using a Cu-Ni alloy as filler material. According to X-ray energy dispersive spectroscopy and X-ray diffraction analysis results three transitional layers at the weld/Ti3Al interface were verified as follows： Ti2AlNb phase dissolved with Cu and Ni; Al（Cu,Ni）2Ti, （Cu,Ni）2Ti and （Nb, Ti） solid solution; Cu-rich phase and a complex multi-element phase. The In718/weld interface is characterized by solid solutions of Ni, Cu, Cr, Fe and Nb. The average tensile strength of the as-welded joints at room temperature is 163 MPa, and after a post-weld heat treatment it is increased slightly to 177 MPa. The fracture occurred at the surfacial layer of the joined Ti3Al base alloy, indicating that the Ti2AINb layer dissolved with Cu and Ni is the weak link of the Ti3Al/In718 joint.展开更多
The characteristics of weld shape,microstructure,mechanical properties and defects of 5A90 Al-Li alloy joint by laser welding (LBW) and laser welding with filler wire (LWFW) were studied and analyzed.The results indic...The characteristics of weld shape,microstructure,mechanical properties and defects of 5A90 Al-Li alloy joint by laser welding (LBW) and laser welding with filler wire (LWFW) were studied and analyzed.The results indicated that the microstructure of joint by LWFW was fine-grained layer and the equiaxed grain in most of seams,which were similar to the joint by LBW.Compared with the joint by LBW,the microstructure of joint by LWFW tended to fine,and the range of the columnar crystals zone was prone to decrease.The Microhardness of the joint by LWFW (92.57HV0.2) was lower than that by LBW (95.65HV0.2),but the uniformity was better.The ultimate tensile strength of the joint by LWFW was lower than that by LBW slightly,which reached to 73.03% and 79.22% of the base metal respectively.However,the elongation of the LWFW joint was higher than that of the LBW joint significantly,which reached to 38.65% and 20.38% of the base metal respectively.The microstructure and mechanical properties of 5A90 Al-Li alloy by LWFW were better than that by LBW.The defects of joint were mainly forming defects which were caused by improper parameters and porosity inside the joint,which was caused by uncleaned surface and incomplete penetration.展开更多
The microstructures and corrosion behaviors of AA2198-T851 alloy and weld were analyzed under corrosive conditions. Weld was formed using an innovative fiber laser welding process with AA2319 Al-Cu filler wire. The me...The microstructures and corrosion behaviors of AA2198-T851 alloy and weld were analyzed under corrosive conditions. Weld was formed using an innovative fiber laser welding process with AA2319 Al-Cu filler wire. The metallurgic morphology and distribution of the chemical compositions were determined using imaging techniques such as optical micrograph, scanning electron micrograph, high-resolution transmission electron microscopy, energy-dispersive X-ray spectrometry and X-ray diffraction. Corrosion was evaluated using an immersion test and electrochemical impedance spectroscopy in 3.5% NaC1 solution at room temperature. Results indicate that the parent alloy suffered from pitting corrosion during the initial 4-h immersion which was caused by the inhomogeneous distribution of its chemical compo- nents and the different intermetallics formed during the rolling process. The weld experienced dendritic boundary corrosion under the same conditions due to the addition of the Al-Cu filler and rapid solidification during laser welding, which led to the precipitates Cu enrichment along the grain boundary. When a welding joint was immersed in the solution for 5 days, a big crack was observed across the center of the weld. In comparison, there was good corrosion resistance in the heat- affected zone with a compact protective film.展开更多
基金The authors would like to acknowledge the financial support from National Key Research and Development Program of China(2018YFB1107801 and 2018YFB1107802)Science Fund for Creative Research Groups of NSFC(51621064)+1 种基金National Natural Science Foundation of China(51790172)Fundamental Research Funds for the Central University(DUT19LAB06).
文摘To clarify the transformation mechanism of secondary phase and the mechanism of intergranular corrosion in laser welding Ni-based alloy (Hastelloy C-276)/304 stainless steel with filler wire,the secondary phase was analyzed by electron probe micro-analysis (EPMA) and transmission electron microscopy (TEM).The evaluation of intergranular corrosion resistance of the welded joints was conducted by double-loop electrochemical potentiokinetic reactivation(DL-EPR) method,and at the same time the chemical compositions of the corrosion surface were analyzed by energy-dispersive spectrometry (EDS).The results show that p phase has complete coherence relationship withμphase,and the coherent relationship is described as[001]p//■and[430]p//[0001]μ.Theμphase is rapidly transformed from p phase,which is the inhomogeneous phase transformation.The transformation of secondary phase will increase the susceptibility to intergranular corrosion.Therefore,the transformation of secondary phase should be avoided in the welding process.
基金Project(2011DFR50760)supported by International Science&Technology Cooperation Program of China
文摘Electron beam welding experiments of titanium alloy to stainless steel were carried out with different filler metals, such as Ni, V, and Cu. Microstructures of the joints were examined by optical microscopy, scanning electron microscopy and X-ray diffraction analysis. Mechanical properties of the joints were evaluated according to tensile strength and microhardness. As a result, influences of filler metals on microstructures and mechanical properties of electron beam welded titanium-stainless steel joints were discussed. The results showed that all the filler metals were helpful to restrain the Ti-Fe intermetallics. The welds with different filler metals were all characterized by solid solution and interfacial intermetallics. For each type of the filler metal, the type of solid solution and interfacial intermetallics depended on the metallurgical reactions between the filler metals and base metals. The interfacial intermetallics were Fe2Ti＋Ni3Ti＋NiTi2, TiFe, and Cu2Ti＋CuTi＋CuTi2 in the joints welded with Ni, V, and Cu filler metals, respectively. The tensile strengths of the joints were dependent on the hardness of the interfacial intermetallics. The joint welded with Ag filler metal had the highest tensile strength, which is about 310 MPa.
文摘Laser welding with filler wire of AZ31 magnesium alloys is investigated using a CO2 laser experimental system. The effect of three different filler wires on the joint properties is researched. The results show that the weld appearance can be effectively improved when using laser welding with filler wire. The microhardness and tensile strength of joints are almost the same us those of the base metal when ER AZ31 or ER AZ61 wire is adopted. However, when the filler wire of ER 5356 aluminum alloy is used, the mechanical properties of flints become worse. For ER AZ31 and ER AZ61 filler wires, the microstructure of weld zone slws small dendrite grains. In comparison, for ER 5356 filler wire, the weld shows a structure of snowy dendrites and many intermetallic compounds and eutectic phases distribute in the dendrites. These intermetallic constituents with low melting point increase the tendency of hot crack and result in fiagile joint properties. Therefore, ER AZ31 and ER AZ61 wire are more suitable filler material than ER 5356 for CO2 laser welding of AZ31 magnesium alloys.
文摘CO2 laser welding aluminum alloy with filler wire was studied. The results indicate that the problems in CO2 laser welding of Al alloy, such as bad appearance of weld, easily excessive penetration and low strength, can be improved effectively by using laser welding with filler wire, and the maximum tensile strength of weld can reach 94% for the base metal. It also can be found that, the linear energy have great influence on the microstructure and mechanical properties of the joint. As the heat input increases, the cellular fir-tree crystals in the weld zone become sparse and the form of tensile fracture transforms from gliding fracture to brittle fracture.
基金supported by the Key Research and Development Program of Zhenjiang City(No. GY2019004).
文摘The Al-Cu-Li alloy is welded by using laser beam welding,and the welding wire ER4043 is used as filler metal. The microstructure and mechanical property of welded joints are systematically investigated. Microstructure analyses show that the fusion zone is mainly composed of α-Al matrix phase and some strengthening phases including T,δ’,θ’,β’ and T1,etc. During welding,the weld formation and joint quality are obviously improved by the addition of Al-Si filler wire. The measurements of mechanical property indicate that,compared with that of the base metal(BM), the microhardness in the weld zone is decreased to a certain extent. Under the appropriate welding parameters,the tensile strength of welded joint reaches 369.4 MPa,which is 67.8% of that of the BM. There are many dimples on the joint fracture surface,and it mainly presents the fracture characteristic of dimple aggregation.
基金Funded by the Center of Excellence in Metals and Materials Engineering(CEMME),Faculty of Engineering,Prince of Songkla UniversitySupported by the National Science,Research and Innovation Fund(NSRF)and Prince of Songkla University(No.ENG6505079S)。
文摘Repair welding of AA 6082-T6 joints was carried out using ER 4043 filler through the TIG welding process with or without pulsed current.Microstructure and mechanical characteristics of the joints before and after repairing were investigated by examining macrostructure,microstructure,and distributions of porosity in the weld metal(WM),and by hardness,tensile,and bending tests.We observed that the welding current,phase transformations in heat-affected zone(HAZ)and porosity introduced in the WM during welding influence on its mechanical properties in sequence.The experimental results showed that the bead width and penetration as well as size of pores in the joints were mainly influenced by the welding currents.The sound joints were obtained at a welding current of 140 A with or without pulsed current when welding speed and gas flow rate were set at 20 cm·min-1 and 15 L·min-1,respectively.Among them,the decrease in mechanical properties of repair weld(RW)was directly related to the phase transformations in the over-ageing zone due to the double welding thermal cycles and elevated distribution of porosity in the WM.In addition,it was observed that the comparatively smaller grain size and lower porosity in WM of the RW produced by pulsed TIG welding gave a positive effect on its mechanical properties.
基金Project(51865012)supported by the National Natural Science Foundation of ChinaProject(20202BABL204040)supported by the Natural Science Foundation of Jiangxi Province,China+3 种基金Project(2016005)supported by the Open Foundation of National Engineering Research Center of Near-net-shape Forming for Metallic Materials,ChinaProject(GJJ170372)supported by the Science Foundation of Educational Department of Jiangxi Province,ChinaProject(JCKY2016603C003)supported by the GF Basic Research Project,ChinaProject(JPPT125GH038)supported by the Research Project of Special Furnishment and Part,China。
文摘The influence of brazing temperature and brazing time on the microstructure and shear strength ofγ-TiAl/GH536 joints brazed with Ti-Zr-Cu-Ni-Fe-Co-Mo filler was investigated using SEM,EDS,XRD and universal testing machine.Results show that all the brazed joints mainly consist of four reaction layers regardless of the brazing temperature and brazing time.The thickness of the brazed seam and the average shear strength of the joint increase firstly and then decrease with brazing temperature in the range of 1090-1170℃and brazing time varying from 0 to 20 min.The maximum shear strength of 262 MPa is obtained at 1150℃for 10 min.The brittle Al3NiTi2 and TiNi3 intermetallics are the main controlling factors for the crack generation and deterioration of joint strength.The fracture surface is characterized as typical cleavage fracture and it mainly consists of massive brittle Al3NiTi2 intermetallics.
文摘In the present work, the dissimilar joining of a Ti3Al-based alloy to a Ni-based superalloy was attempted by gas tungsten arc （GTA） welding technology. Sound joints were successfully achieved by using a Cu-Ni alloy as filler material. According to X-ray energy dispersive spectroscopy and X-ray diffraction analysis results three transitional layers at the weld/Ti3Al interface were verified as follows： Ti2AlNb phase dissolved with Cu and Ni; Al（Cu,Ni）2Ti, （Cu,Ni）2Ti and （Nb, Ti） solid solution; Cu-rich phase and a complex multi-element phase. The In718/weld interface is characterized by solid solutions of Ni, Cu, Cr, Fe and Nb. The average tensile strength of the as-welded joints at room temperature is 163 MPa, and after a post-weld heat treatment it is increased slightly to 177 MPa. The fracture occurred at the surfacial layer of the joined Ti3Al base alloy, indicating that the Ti2AINb layer dissolved with Cu and Ni is the weak link of the Ti3Al/In718 joint.
文摘The characteristics of weld shape,microstructure,mechanical properties and defects of 5A90 Al-Li alloy joint by laser welding (LBW) and laser welding with filler wire (LWFW) were studied and analyzed.The results indicated that the microstructure of joint by LWFW was fine-grained layer and the equiaxed grain in most of seams,which were similar to the joint by LBW.Compared with the joint by LBW,the microstructure of joint by LWFW tended to fine,and the range of the columnar crystals zone was prone to decrease.The Microhardness of the joint by LWFW (92.57HV0.2) was lower than that by LBW (95.65HV0.2),but the uniformity was better.The ultimate tensile strength of the joint by LWFW was lower than that by LBW slightly,which reached to 73.03% and 79.22% of the base metal respectively.However,the elongation of the LWFW joint was higher than that of the LBW joint significantly,which reached to 38.65% and 20.38% of the base metal respectively.The microstructure and mechanical properties of 5A90 Al-Li alloy by LWFW were better than that by LBW.The defects of joint were mainly forming defects which were caused by improper parameters and porosity inside the joint,which was caused by uncleaned surface and incomplete penetration.
基金financially supported by the National Natural Science Foundation of China (Grant Number: 51505010)Beijing Natural Science Foundation (Grant Number: 2152007)
文摘The microstructures and corrosion behaviors of AA2198-T851 alloy and weld were analyzed under corrosive conditions. Weld was formed using an innovative fiber laser welding process with AA2319 Al-Cu filler wire. The metallurgic morphology and distribution of the chemical compositions were determined using imaging techniques such as optical micrograph, scanning electron micrograph, high-resolution transmission electron microscopy, energy-dispersive X-ray spectrometry and X-ray diffraction. Corrosion was evaluated using an immersion test and electrochemical impedance spectroscopy in 3.5% NaC1 solution at room temperature. Results indicate that the parent alloy suffered from pitting corrosion during the initial 4-h immersion which was caused by the inhomogeneous distribution of its chemical compo- nents and the different intermetallics formed during the rolling process. The weld experienced dendritic boundary corrosion under the same conditions due to the addition of the Al-Cu filler and rapid solidification during laser welding, which led to the precipitates Cu enrichment along the grain boundary. When a welding joint was immersed in the solution for 5 days, a big crack was observed across the center of the weld. In comparison, there was good corrosion resistance in the heat- affected zone with a compact protective film.
