A pseudoplastic metal nanoparticle fluid （PMNF） is used in nanoimprint to fabricate semiconductors and func- tional devices. The evaporation of the solvent and the sintering of the Au PMNF are investigated. The key ...A pseudoplastic metal nanoparticle fluid （PMNF） is used in nanoimprint to fabricate semiconductors and func- tional devices. The evaporation of the solvent and the sintering of the Au PMNF are investigated. The key parameters, which influence the morphology of patterning, such as the radius of metal particles, the concentra- tion of metal particles, the Hamaker constant of the solvent, viscosity of the fluids and the evaporation velocity, are analyzed. Based on a two-sphere sintering model, the equations are derived, which represent the relationships between the relative shrinkage and radius of the metal particles, sintering temperature and time. The optimal parameters for the heat treatment are provided in nanoimprint.展开更多
We present a theoretical analysis for fully developed convective beat transfer in a circular tube for power law fluids by assuming that the thermal diffusivity is a function of temperature gradient. The analytical eol...We present a theoretical analysis for fully developed convective beat transfer in a circular tube for power law fluids by assuming that the thermal diffusivity is a function of temperature gradient. The analytical eolution is obtained and the heat transfer behaviour is investigated under a constant heat flux boundary condition. It is shown that the Nusselt number strongly depends on the value of power law index n. The Nusselt number sharply decreases in the range of 0 〈 n 〈 0.1. However, for n 〉 0.5, the Nusselt number decreases monotonically with the increasing n, and for n 〉 20, the values of Nusselt number approach a constant.展开更多
The chaotic characteristics of bubbles rising with accompanying coalescences in pseudoplastic aqueous carboxymethylcellulose sodium(CMC)solution were studied by means of smoothed pseudo Wigner-Ville distribution and W...The chaotic characteristics of bubbles rising with accompanying coalescences in pseudoplastic aqueous carboxymethylcellulose sodium(CMC)solution were studied by means of smoothed pseudo Wigner-Ville distribution and Wigner-Hough distribution.The temporal signal of bubble passage was measured utilizing a photoconductive data acquisition system.As bubble coalescence occurred,the smoothed pseudo Wigner-Ville distribution of the signal revealed that the signal could be divided into low-frequency and high-frequency ranges and the transition range according to the distribution feature of frequency domain,which reflected eddy motion of fluid,high frequency fluctuations of fluid velocity and other random components measured in the signal,and bubbles rising accompanied with coalescences,respectively.However,bubble coalescence occurred in the lower position and the frequency range of bubbles motion became wide under higher gas flowrate,while the frequency range of bubbles motion became narrow when the CMC concentration increased.The typical dynamics of bubbles motion,such as periodicity,bifurcation and chaos,could be easily found in terms of the Wigner-Hough distribution.展开更多
The rheological behavior of low consistency thermomechanical pulp of Chinese fir harvested by intermediate thinning was analyzed. The results show that the apparent viscosity of pulp changed along with the beating deg...The rheological behavior of low consistency thermomechanical pulp of Chinese fir harvested by intermediate thinning was analyzed. The results show that the apparent viscosity of pulp changed along with the beating degree, pulp consistency and shearing velocity. With the increasing of pulp consistency, the apparent viscosity of pulp increased gradually. Beating degree of pulp had an effect on microstructure of pulp. The apparent viscosity of pulp declined as beating degree of pulp increased, and the apparent viscosity of pulp fell along with the shearing velocity increasing. Based on the results, the rheological models are set up. The models showed that the fluid types of the low consistency pulp could be described as pseudoplastics fluids （non-Newtonian fluids）.展开更多
Majority of non-Newtonian fluids are pseudoplastic with shear-thinning property, which means that the viscosity will be different in different parts of the stirred tank. In such mixing process, it is difficult to pred...Majority of non-Newtonian fluids are pseudoplastic with shear-thinning property, which means that the viscosity will be different in different parts of the stirred tank. In such mixing process, it is difficult to predict accurately the power consumption and mean shear rate for designing novel impeller. Metzner-Otto method is a widely accepted method to solve these questions in mixing non-Newtonian fluids. As a result, Metzner-Otto constant will become a key factor to achieve an optimum way of economical mixing. In this paper, taking glycerine and xanthan gum solutions as research system, the power consumption, stirred by the impeller composed of perturbed six-bent-bladed turbine （6PBT） with differently geometrical characteristics in a cylindrical vessel, is studied by means of computational fluid dynamics （CFD）. The flow is modeled as laminar and a multiple reference frame （MRF） approach is used to solve the discretized equations of motion. In order to determine the capability of CFD to forecast the flow process, the torque test experiment is used to measure the glycerine solution power consumption. The theological properties of the xanthan gum solutions are determined by a Brookfleld rheometer. It is observed that the power consumption predicted by numerical simulation agrees well with those measured using torque experiment method in stirring glycerine solution, which validate the numerical model. Metzner-Otto constant is almost not correlated with the flow behavior index of pseudoplastic fluids. This paper establishes the complete correlations of power constant and Metzner-Otto constant with impeller geometrical characteristics through linear regression analysis, which provides the valuable instructions and references for accurately predicting the power consumption and mean shear rate of pseudoplastic fluids in laminar flow, comparatively.展开更多
This paper puts forward a physical and mathematical model for the rheological properties of a plant cell suspension culture system.The model can explain why the system is pseudoplastic satisfactorily,thus the rheologi...This paper puts forward a physical and mathematical model for the rheological properties of a plant cell suspension culture system.The model can explain why the system is pseudoplastic satisfactorily,thus the rheological properties of the system as the effect of the flow behavior index on plant cell concentration are interpreted correctly and the mechanism of the rheological properties of the system is further understood.Therefore the model can be applied in the technological design and optimum conditions of the system and the reformation,evaluation and scale up of reactors.展开更多
In this paper, laminar and turbulent flows of pseudoplastic fluids(0.1% and 0.2% by weight aqueous solutions of carboxymethylcellulose) in a square duct of strong curvature were measured using an ultrasonic Doppler ve...In this paper, laminar and turbulent flows of pseudoplastic fluids(0.1% and 0.2% by weight aqueous solutions of carboxymethylcellulose) in a square duct of strong curvature were measured using an ultrasonic Doppler velocimetry and microphones. Streamwise velocity in cross-sections of the duct and the fluctuating pressure on walls were measured for different flow rates. The velocity contours and their development along the duct were presented and compared with benchmark experiments by Taylor, Whitelaw and Yianneskis(1982) which were for the laminar and turbulent flows of water. The spectra of fluctuating wall pressures were also presented and analyzed. The objective of this paper was to provide a basis for understanding the pseudoplastic fluid flows in curved ducts. The results were also intended for use in the further development of numerical methods and turbulence models for shear-thinning fluids.展开更多
基金Supported by the National Natural Science Foundation of China under Grant Nos 51175479 and 51475436the Education Department of Henan Province under Grant Nos 13A460725 and 2013GGJS-001
文摘A pseudoplastic metal nanoparticle fluid （PMNF） is used in nanoimprint to fabricate semiconductors and func- tional devices. The evaporation of the solvent and the sintering of the Au PMNF are investigated. The key parameters, which influence the morphology of patterning, such as the radius of metal particles, the concentra- tion of metal particles, the Hamaker constant of the solvent, viscosity of the fluids and the evaporation velocity, are analyzed. Based on a two-sphere sintering model, the equations are derived, which represent the relationships between the relative shrinkage and radius of the metal particles, sintering temperature and time. The optimal parameters for the heat treatment are provided in nanoimprint.
基金Supported by the National Natural Science Foundations of China under Grant No 50476083.
文摘We present a theoretical analysis for fully developed convective beat transfer in a circular tube for power law fluids by assuming that the thermal diffusivity is a function of temperature gradient. The analytical eolution is obtained and the heat transfer behaviour is investigated under a constant heat flux boundary condition. It is shown that the Nusselt number strongly depends on the value of power law index n. The Nusselt number sharply decreases in the range of 0 〈 n 〈 0.1. However, for n 〉 0.5, the Nusselt number decreases monotonically with the increasing n, and for n 〉 20, the values of Nusselt number approach a constant.
基金Supported by the National Natural Science Foundation of China （20476073）, the Opening Project of State Key Laboratory of Chemical Engineering （SKL-ChE-08B03） and the Program of Introducing Talents of Discipline to Universities （B06006）.
文摘The chaotic characteristics of bubbles rising with accompanying coalescences in pseudoplastic aqueous carboxymethylcellulose sodium(CMC)solution were studied by means of smoothed pseudo Wigner-Ville distribution and Wigner-Hough distribution.The temporal signal of bubble passage was measured utilizing a photoconductive data acquisition system.As bubble coalescence occurred,the smoothed pseudo Wigner-Ville distribution of the signal revealed that the signal could be divided into low-frequency and high-frequency ranges and the transition range according to the distribution feature of frequency domain,which reflected eddy motion of fluid,high frequency fluctuations of fluid velocity and other random components measured in the signal,and bubbles rising accompanied with coalescences,respectively.However,bubble coalescence occurred in the lower position and the frequency range of bubbles motion became wide under higher gas flowrate,while the frequency range of bubbles motion became narrow when the CMC concentration increased.The typical dynamics of bubbles motion,such as periodicity,bifurcation and chaos,could be easily found in terms of the Wigner-Hough distribution.
基金This study was sponsored by the Research Funding for Outstanding Young University Faculty of China Ministry of Education (No. 2001-39), Fujian Provincial Innovation Fundation for Young Science and Technology Talents (No. 2004J012), and the National Natural Science Funda-tion of China (No. 30571461)
文摘The rheological behavior of low consistency thermomechanical pulp of Chinese fir harvested by intermediate thinning was analyzed. The results show that the apparent viscosity of pulp changed along with the beating degree, pulp consistency and shearing velocity. With the increasing of pulp consistency, the apparent viscosity of pulp increased gradually. Beating degree of pulp had an effect on microstructure of pulp. The apparent viscosity of pulp declined as beating degree of pulp increased, and the apparent viscosity of pulp fell along with the shearing velocity increasing. Based on the results, the rheological models are set up. The models showed that the fluid types of the low consistency pulp could be described as pseudoplastics fluids （non-Newtonian fluids）.
基金Supported by Shandong Provincial Science and Technology Development planning Program of China(Grant No.2013YD09007)Scientific Foundation of Qingdao University of Science and Technology of China
文摘Majority of non-Newtonian fluids are pseudoplastic with shear-thinning property, which means that the viscosity will be different in different parts of the stirred tank. In such mixing process, it is difficult to predict accurately the power consumption and mean shear rate for designing novel impeller. Metzner-Otto method is a widely accepted method to solve these questions in mixing non-Newtonian fluids. As a result, Metzner-Otto constant will become a key factor to achieve an optimum way of economical mixing. In this paper, taking glycerine and xanthan gum solutions as research system, the power consumption, stirred by the impeller composed of perturbed six-bent-bladed turbine （6PBT） with differently geometrical characteristics in a cylindrical vessel, is studied by means of computational fluid dynamics （CFD）. The flow is modeled as laminar and a multiple reference frame （MRF） approach is used to solve the discretized equations of motion. In order to determine the capability of CFD to forecast the flow process, the torque test experiment is used to measure the glycerine solution power consumption. The theological properties of the xanthan gum solutions are determined by a Brookfleld rheometer. It is observed that the power consumption predicted by numerical simulation agrees well with those measured using torque experiment method in stirring glycerine solution, which validate the numerical model. Metzner-Otto constant is almost not correlated with the flow behavior index of pseudoplastic fluids. This paper establishes the complete correlations of power constant and Metzner-Otto constant with impeller geometrical characteristics through linear regression analysis, which provides the valuable instructions and references for accurately predicting the power consumption and mean shear rate of pseudoplastic fluids in laminar flow, comparatively.
文摘This paper puts forward a physical and mathematical model for the rheological properties of a plant cell suspension culture system.The model can explain why the system is pseudoplastic satisfactorily,thus the rheological properties of the system as the effect of the flow behavior index on plant cell concentration are interpreted correctly and the mechanism of the rheological properties of the system is further understood.Therefore the model can be applied in the technological design and optimum conditions of the system and the reformation,evaluation and scale up of reactors.
基金funded by the National Natural Science Foundation of China under Grant No.51176048
文摘In this paper, laminar and turbulent flows of pseudoplastic fluids(0.1% and 0.2% by weight aqueous solutions of carboxymethylcellulose) in a square duct of strong curvature were measured using an ultrasonic Doppler velocimetry and microphones. Streamwise velocity in cross-sections of the duct and the fluctuating pressure on walls were measured for different flow rates. The velocity contours and their development along the duct were presented and compared with benchmark experiments by Taylor, Whitelaw and Yianneskis(1982) which were for the laminar and turbulent flows of water. The spectra of fluctuating wall pressures were also presented and analyzed. The objective of this paper was to provide a basis for understanding the pseudoplastic fluid flows in curved ducts. The results were also intended for use in the further development of numerical methods and turbulence models for shear-thinning fluids.
